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Bioactive Compounds and Insecticidal Activity of Hysterionica pinifolia, a Native South American Plant
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作者 Ingrid M. Cufre Lucas E. Fabián +2 位作者 Sandra V. Clemente Arnaldo L. Bandoni Adriana M. Broussalis 《American Journal of Plant Sciences》 2022年第6期815-832,共18页
Phytochemical investigation of the purified fractions of the active dichloromethane extract of Hysterionica pinifolia (Poir.) Baker led to the identification of five compounds. New acetylenic alcohol (E)-undec-3-en-5,... Phytochemical investigation of the purified fractions of the active dichloromethane extract of Hysterionica pinifolia (Poir.) Baker led to the identification of five compounds. New acetylenic alcohol (E)-undec-3-en-5,7-diyne-1-ol (1) and three other compounds (3), (4), and (5) were reported for the first time in this species. Furthermore, forty-six components from the volatile fraction of H. pinifolia were identified. These compounds were elucidated using 1D and 2D NMR spectroscopy as well as MS-ESI and GC-FID-MS experiments. The dichloromethane extract, its fractions, and the methanolic extract were tested for insecticidal activity against Tribolium castaneum under laboratory conditions. The dichloromethane extract and the fraction F2 were found to be active, showing high larval mortality. The dichloromethane extract was also active against T. castaneum adults. The results have shown that H. pinifolia could be considered, in a near future, as a potential source for the development of a botanical insecticide for pest control. 展开更多
关键词 Hysterionica pinifolia Bioactive Compounds Polyacetylene Compounds (E)-undec-3-en-5 7-diyne-1-ol Insecticidal Activity
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离子液体中钯催化合成cis-1,2-二卤代-1,7-辛二烯的反应研究 被引量:3
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作者 杨少容 凌厂围 +3 位作者 马建业 张蕾 李建晓 罗维 《有机化学》 SCIE CAS CSCD 北大核心 2014年第6期1148-1153,共6页
发展了一种以PdBr2为催化剂,以[Bmim]X/HXaq为溶剂,炔卤与5-己烯-1-醇进行交叉偶联反应的新方法,以中等及优良的产率(73%~94%)合成了系列cis-1,2-二卤代-1,7-辛二烯衍生物.反应表现出较高的区域选择性和立体选择性.并且该偶联反应合... 发展了一种以PdBr2为催化剂,以[Bmim]X/HXaq为溶剂,炔卤与5-己烯-1-醇进行交叉偶联反应的新方法,以中等及优良的产率(73%~94%)合成了系列cis-1,2-二卤代-1,7-辛二烯衍生物.反应表现出较高的区域选择性和立体选择性.并且该偶联反应合成途径简捷、反应条件温和,可为cis-1,2-二卤代烯烃类化合物的合成提供简便的途径. 展开更多
关键词 离子液体 钯催化 炔卤 5-己烯-1-醇 cis-1 2-二卤代烯烃
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