High strength steel thick plate is widely used in shipbuilding, pressure vessels, etc. , the balance between weld quality and welding efficiency is becoming a research focus. In this paper, double-sided double arc fia...High strength steel thick plate is widely used in shipbuilding, pressure vessels, etc. , the balance between weld quality and welding efficiency is becoming a research focus. In this paper, double-sided double arc fiat-overhead welding experiments for high strength steel thick plate were conducted. Microstructures of weld have been observed through optical microscope (OM) and scanning electron microscope (SEM). Transformation of microstructures under thermal cycles of multi peaks was analyzed. Macro and micro hardness were also tested. The results show that the heat-affected zone (HAZ) near the fusion line experiences thermal cycles up to three times. The microstructures there are the most complex, including coarse lath martensite in original coarse-grained zone, and net-like structure along grain boundaries in critical reheat coarse-grained zone. After several times of tempering for bucking welding, the features of acicula and lath are weakened. Its microstructure approaches to the microstructure of base metal which is tempering sorbite. The hardness test shows that the maximum hardness occurs at critical reheat coarse-grained zone, the hardness of reticulation structure at grain boundary can be up to 450 HV.展开更多
Lightweight structure is an important method to increase vehicle fuel efficiency. High strength steel is applied for replacing mild steel in automotive structures to decrease thickness of parts for lightweight. Howeve...Lightweight structure is an important method to increase vehicle fuel efficiency. High strength steel is applied for replacing mild steel in automotive structures to decrease thickness of parts for lightweight. However, the lightweight structures must show the improved capability for structural rigidity and crash energy absorption. Advanced high strength steels are attractive materials to achieve higher strength for energy absorption and reduce weight of vehicles. Currently, many research works focus on component level axial crash testing and simulation of high strength steels. However, the effects of high strength steel parts to the impact of auto body are not considered. The goal of this research is to study the application of hot forming high strength steel(HFHSS) in order to evaluate the potential using in vehicle design for lightweight and passive safety. The performance of HFHSS is investigated by using both experimental and analytical techniques. In particular, the focus is on HFHSS which may have potential to enhance the passive safety for lightweight auto body. Automotive components made of HFHSS and general high strength steel(GHSS) are considered in this study. The material characterization of HFHSS is carried out through material experiments. The finite element method, in conjunction with the validated model is used to simulate the side impact of a car with GHSS and HFHSS parts according to China New Car Assessment Programme(C-NCAP) crash test. The deformation and acceleration characteristics of car body are analyzed and the injuries of an occupant are calculated. The results from the simulation analyses of HFHSS are compared with those of GHSS. The comparison indicates that the HFHSS parts on car body enhance the passive safety for the lightweight car body in side impact. Parts of HFHSS reduce weight of vehicle through thinner thickness offering higher strength of parts. Passive safety of lightweight car body is improved through reduction of crash deformation on car body by the application of HFHSS parts. The experiments and simulation are conducted to the HFHSS parts on auto body. The results demonstrate the feasibility of the application of HFHSS materials on automotive components for improved capability of passive safety and lightweight.展开更多
The effects of chromium on the corrosion and the electrochemical behaviors of ultra high strength steels were studied by the salt spray test and electrochemical methods. The results show that ultra high strength steel...The effects of chromium on the corrosion and the electrochemical behaviors of ultra high strength steels were studied by the salt spray test and electrochemical methods. The results show that ultra high strength steels remain martensite structures and have anodic dissolution characteristic with an increase of chromium content. There is no typical passive region on the polarization curves of an ultra high strength stainless steel, AerMet 100 steel, and 300M steel. However, chromium improves the corrosion resistance of the stainless steel remarkably. It has the slowest corrosion rate in the salt spray test, one order of magnitude less than that of AerMet 100 and 300M steels. With the increase of chromium content, the polarization resistance becomes larger, the corrosion potential shifts towards the positive direction with a value of 545 mV, and the corrosion current density decreases in electrochemical measures in 3.5wt% NaCl solutions. Because of the higher content of chromium, the ultra high strength stainless steel has a better corrosion resistance than AerMet 100 and 300M steels.展开更多
To develop a high strength low alloy (HSLA) steel with high strength and high toughness, a series of martensitic steels were studied through alloying with various elements and thermodynamic simulation. The microstru...To develop a high strength low alloy (HSLA) steel with high strength and high toughness, a series of martensitic steels were studied through alloying with various elements and thermodynamic simulation. The microstructure and mechanical properties of the designed steel were investigated by optical microscopy, scanning electron microscopy, tensile testing and Charpy impact test. The results show that cementite exists between 500℃ and 700℃, M7C3 exits below 720℃, and they are much lower than the austenitizing temperature of the designed steel. Furthermore, the Ti(C,N) precipitate exists until 1280℃, which refines the microstructure and increases the strength and toughness. The optimal alloying components are 0.19% C, 1.19% Si, 2.83% Mn, 1.24% Ni, and 0.049% Ti; the tensile strength and the V notch impact toughness of the designed steel are more than 1500 MPa and 100 J, respectively.展开更多
The microstructures and mechanical properties of C-Mn-Cr-Nb and C-Mn-Si-Nb ultra-high strength dual-phase steels were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and tens...The microstructures and mechanical properties of C-Mn-Cr-Nb and C-Mn-Si-Nb ultra-high strength dual-phase steels were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and tensile test. The results show that Si can promote the transformation of austenite (γ) to ferrite (α), enlarge the (α+γ) region, and increase the aging stability of martensite by inhibiting carbide precipitation. Adding Cr leads to the formation of retained austenite and martensite/austenite (M/A) constituents, as well as the decomposi- tion of martensite during the overaging stage. Both of the steels show higher initial strain-hardening rates and two-stage strain-hardening characteristics. The C-Mn-Si-Nb steel shows the higher strain-hardening rate than the C-Mn-Cr-Nb steel in the first stage; however, there is no significant difference in the second stage. Although the tensile strength and elongation of the two steels both exceed 1000 MPa and 15%, respectively, the comprehensive mechanical properties of the C-Mn-Si-Nb steel are superior.展开更多
Microstructure observations and drop-weight tear test were performed to study the microstructures and mechanical properties of two kinds of industrial X70 and two kinds of industrial X80 grade pipeline steels. The eff...Microstructure observations and drop-weight tear test were performed to study the microstructures and mechanical properties of two kinds of industrial X70 and two kinds of industrial X80 grade pipeline steels. The effective grain size and the fraction of high angle grain boundaries in the pipeline steels were investigated by electron backscatter diffraction analysis. It is found that the low temperature toughness of the pipeline steels depends not only on the effective grain size, but also on other microstructural factors such as martensite-austenite (MA) constituents and precipitates. The morphology and size of MA constituents significantly affect the mechanical properties of the pipeline steels. Nubby MA constituents with large size have significant negative effects on the toughness, while smaller granular MA constituents have less harmful effects. Similarly, larger Ti-rich nitrides with sharp corners have a strongly negative effect on the toughness, while fine, spherical Nb-rich carbides have a less deleterious effect. The low temperature toughness of the steels is independent of the fraction of high angle grain boundaries.展开更多
The delayed fracture behaviors of CrMo-type high strength steels containing different amount of titanium(0to 0.10%)were studied.The steels were quenched at 880℃ and tempered from 400℃ to 650℃,and a wide range of te...The delayed fracture behaviors of CrMo-type high strength steels containing different amount of titanium(0to 0.10%)were studied.The steels were quenched at 880℃ and tempered from 400℃ to 650℃,and a wide range of tensile strength was obtained.The sustained load tensile test was carried out by using notched tensile specimens in Walpole solution.The experimental results showed that with higher strength,the Ti-microalloyed steels show higher resistance to delayed fracture compared with non-microalloyed steel due to titanium beneficial role and microstructure changes.The undissolved TiC is uniformly distributed as strong hydrogen traps,retarding or preventing the diffusion and accumulation of hydrogen to lower-interaction energy sites,such as prior austenite and martensite lath boundaries in stress concentration area.Meanwhile,the grain refining effect of titanium is also an important factor to improve the delayed fracture resistance of Ti-microalloyed steels.The characteristics of delayed fracture remain nearly the same with titanium addition.展开更多
The ultra-high cycle fatigue behavior of a novel high strength steel with carbide-free bainite/martensite (CFB/M) complex microstructure was studied. The ultra-high cycle fatigue properties were measured by ultrason...The ultra-high cycle fatigue behavior of a novel high strength steel with carbide-free bainite/martensite (CFB/M) complex microstructure was studied. The ultra-high cycle fatigue properties were measured by ultrasonic fatigue testing equipment at a frequency of 20 kHz. It is found that there is no horizontal part in the S-N curve and fatigue fracture occurs when the life of specimens exceeds 10^7 cycles. In addition, the origination of fatigue cracks tends to transfer from the surface to interior of specimens as the fatigue cycle exceeds 10^7, and the fatigue crack originations of many specimens are not induced by inclusions, but by some kind of "soft structure". It is shown that the studied high strength steel performs good ultra-high cycle fatigue properties. The ultra-high fatigue mechanism was discussed and it is suggested that specific CFB/M complex microstructure of the studied steel contributes to its superior properties.展开更多
To investigate the seismic behavior of I-section columns made of 460 MPa high strength steel (HSS), six specimens were tested under constant axial load and cyclic horizontal load. The specimens were designed with di...To investigate the seismic behavior of I-section columns made of 460 MPa high strength steel (HSS), six specimens were tested under constant axial load and cyclic horizontal load. The specimens were designed with different width-to-thickness ratios and loaded under different axial load ratios. For each specimen, the failure mode was observed and hysteretic curve was measured. Comparison of different specimens on hysteretic characteristic, energy dissipation capacity and deformation capacity were further investigated. Test results showed that the degradation of bearing capacity was due to local buckling of flange and web. Under the same axial load ratio, as width-to-thickness ratio increased, the deformation area of local buckling became smaller. And also, displacement level at both peak load and failure load became smaller. In addition, the full extent of hysteretic curve, energy dissipation capacity, ultimate story drift angle decreased, and capacity degradation occurred more rapidly with the increase of width-to-thickness ratio or axial load ratio. Based on the capacity of story drift angle, limiting values which shall not be exceeded are suggested respectively for flange and web plate of 460 MPa HSS I-section columns when used in SMFs and in IMFs in the case of axial load ratio no more than 0.2. Such values should be smaller when the axial load ratio increases.展开更多
Laboratory and industrial studies were carried out to investigate non-metallic inclusions in high strength alloy steel refined by high basicity and high Al_2O_3 slag.It was found that the steel/slag reaction time larg...Laboratory and industrial studies were carried out to investigate non-metallic inclusions in high strength alloy steel refined by high basicity and high Al_2O_3 slag.It was found that the steel/slag reaction time largely affected non-metallic inclusions.With the reaction time increased from 30 min to 90 min in laboratory study,MgO-Al_2O_3 spinels were gradually changed into CaO-MgO-Al_2O_3 system inclusions surrounded by softer CaO-Al_2O_3 surface layers.By using high basicity slag which contained as much as 41%Al_2O_3 in the laboratory study,ratio of low melting temperature CaO-MgO-Al_2O_3 system inclusions was remarkably increased to above 80%.In the industrial experiment,during the secondary refining,the inclusions changed in order of 'Al_2O_3→MgO-Al_2O_3→CaO-MgO-Al_2O_3'.Through the LF and RH refining,most inclusions could be transferred to lower melting temperature CaO-Al_2O_3 and CaO-MgO-Al_2O_3 system inclusions.展开更多
Powdering/exfoliating of coatings and scratching galvanized steels and high strength steels (HSS), are the main forms of surface damage in the forming of which result in increased die maintenance cost and scrap rate...Powdering/exfoliating of coatings and scratching galvanized steels and high strength steels (HSS), are the main forms of surface damage in the forming of which result in increased die maintenance cost and scrap rate. In this study, a special rectangular box was developed to investigate the behavior and characteristics of surface damage in sheet metal forming (SMF) processes. U-channel forming tests were conducted to study the effect of tool hardness on surface damage in the forming of high strength steels and galvanized steels (hot-dip galvanized and galvannealed steels). Experimental results indicate that sheet deformation mode influences the severity of surface damage in SMF and surface damage occurs easily at the regions where sheet specimen deforms under the action of compressive stress. Die corner is the position where surface damage initiates. For HSS sheet, surface damage is of major interest due to high forming pressure. The HSS and hot-dip galvanized steels show improved ability of damage-resistance with increased hardness of the forming tool. However, for galvannealed steel it is not the forming tool with the highest hardness value that performs best.展开更多
The transformation behavior and tensile properties of an ultra-high-strength transformation-induced plasticity (TRIP) steel (0.2C-2.0Si-I.SMn) were investigated by different heat treatments for automobile applicat...The transformation behavior and tensile properties of an ultra-high-strength transformation-induced plasticity (TRIP) steel (0.2C-2.0Si-I.SMn) were investigated by different heat treatments for automobile applications. The results show that F-TRIP steel, a tradi- tional TRIP steel containing as-cold-rolled ferfite and pearlite as the original microstructure, consists of equiaxed grains of intercritical ferrite surrounded by discrete particles of M/RA and B. In contrast, M-TRIP steel, a modified TRiP-aided steel with martensite as the original mi- crostlucture, containing full martensite as the original microstructure is comprised of lath-shaped grains of ferrite separated by lath-shaped martensite/retained austenite and bainite. Most of the austenite in F-TRIP steel is granular, while the austenite in M-TRIP steel is lath-shaped. The volume fraction of the retained austenite as well as its carbon content is lower in F-TRIP steel than in M-TRIP steel, and austenite grains in M-TRIP steel are much finer than those in F-TRIP steel. Therefore, M-TRIP steel was concluded to have a higher austenite stability, re- sulting in a lower transformation rate and consequently contributing to a higher elongation compared to F-TRIP steel. Work hardening be- havior is also discussed for both types of steel.展开更多
The high-temperature mechanical properties and microstructure of forging billets of C-Si-Mn-Cr and C-Si-Mn-Cr-Mo ultra-high-strength cold-rolled steels(tensile strength≥1000 MPa,elongation≥10%) were studied.Throug...The high-temperature mechanical properties and microstructure of forging billets of C-Si-Mn-Cr and C-Si-Mn-Cr-Mo ultra-high-strength cold-rolled steels(tensile strength≥1000 MPa,elongation≥10%) were studied.Through the comparison of reduction in area and hot deformation resistance at 600-1300°C,the Mo-containing steel was found to possess a higher strength and a better plasticity than the Mo-free one.The equilibrium phase diagram and atom fraction of Mo in different phases at different temperatures were calculated by Thermo-Calc software(TCW).The results analyzed by using transmission electron microscopy and TCW show that precipitates in the Mo-containing steel are primarily M23C6,which promote pearlite formation.The experimental data also show that a lower ductility point existing in the Mo-free steel at 850°C is eliminated in the Mo-containing one.This is mainly due to the segregation of Mo at grain boundaries investigated by electron probe microanalysis(EPMA),which improves the strength of grain boundaries.展开更多
The fatigue cracking behavior of ultra-high strength steels containing rectangular inclusions of small sizes were investigated based on in situ observations by scanning electron microscopy (SEM). The size and shape ...The fatigue cracking behavior of ultra-high strength steels containing rectangular inclusions of small sizes were investigated based on in situ observations by scanning electron microscopy (SEM). The size and shape of rectangular inclusions affect markedly the initiation site and propagation path of a fatigue crack. Especially, the initiation site of a fatigue crack depends strongly on the angle between the long-axis of a rectangle inclusion and the loading direction, and the length/width ratio of this rectangle inclusion because the residual stress distribution fields vary with these conditions. The results coincide very well with those of finite element analysis.展开更多
The addition of high Ti(>0.1%) in microalloyed bainitic high strength steel was designed, and the precipitation morphology of steels with different Ti, Nb, and V contents was studied by utilizing transmission elect...The addition of high Ti(>0.1%) in microalloyed bainitic high strength steel was designed, and the precipitation morphology of steels with different Ti, Nb, and V contents was studied by utilizing transmission electron microscopy(TEM). Based on the classical nucleation-crystal growth theory and the Johnson-Mehl-Avrami equation, the precipitation thermodynamic and kinetic model of second phase particles in austenite was established in the form of(Nbx,Vy,Tiz)C, and the complex precipitation mechanism of second phase particles was emphatically studied. The experimental results show that the complex precipitation particles could be divided into two categories: the coarser particles with about 100 nm grain size and the independent complex precipitation particles in the form of(Nb,V,Ti)C with 35-50 nm grain size. The latter has a better precipitation strengthening effect, and the calculated PTT curve shows a typical "C" shape. When the deformed storage energy is 3 820 J·mol^-1, the fastest precipitation temperature of calculated PTT curve is 925℃, and the calculated result is essentially consistent with experimental values. The increase of Ti content increased the nose point temperature and expanded the range of fastest precipitation temperature.展开更多
A high-building multi-directional pipe joint(HBMDPJ)was fabricated by wire and arc additive manufacturing using high-strength low-alloy(HSLA)steel.The microstructure characteristics and transformation were observed an...A high-building multi-directional pipe joint(HBMDPJ)was fabricated by wire and arc additive manufacturing using high-strength low-alloy(HSLA)steel.The microstructure characteristics and transformation were observed and analyzed.The results show that the forming part includes four regions.The solidification zone solidifies as typical columnar crystals from a molten pool.The complete austenitizing zone forms from the solidification zone heated to a temperature greater than 1100℃,and the typical columnar crystals in this zone are difficult to observe.The partial austenitizing zone forms from the completely austenite zone heated between Ac1(austenite transition temperature)and1100℃,which is mainly equiaxed grains.After several thermal cycles,the partial austenitizing zone transforms to the tempering zone,which consistes of fully equiaxed grains.From the solidification zone to the tempering zone,the average grain size decreases from 75 to20μm.The mechanical properties of HBMDPJ satisfies the requirement for the intended application.展开更多
An ultra-low carbon acicular ferrite steel heavy plate was obtained with an advanced thermo-mechanical control process-relaxed precipitation controlled transformation (TMCP-RPC) at Xiangtan Steel, Valin Group. The h...An ultra-low carbon acicular ferrite steel heavy plate was obtained with an advanced thermo-mechanical control process-relaxed precipitation controlled transformation (TMCP-RPC) at Xiangtan Steel, Valin Group. The heavy plate has a tensile strength of approximately 600 MPa with a lower yield ratio. The impact toughness of the heavy plate achieves 280 J at ?40°C. The fine-grained mixed microstructures of the heavy plate mainly consist of acicular ferrite, granular bainite, and polygonal ferrite. The high strength and excellent toughness of the heavy plate are attributed to the formation of acicular ferrite microstructure. The prevention of blocks of martensite/retained austenite (M/A) and the higher cleanness are also responsible for the superior toughness.展开更多
By the increase in Mo content,the addition of microalloying elements V and Nb and by reducing the contents of Mn,P and S based on the composition of steel 42 CrMo,we have developed a 1 300 MPa-grade high strength stee...By the increase in Mo content,the addition of microalloying elements V and Nb and by reducing the contents of Mn,P and S based on the composition of steel 42 CrMo,we have developed a 1 300 MPa-grade high strength steel(ADF1)for bolts.The sustained load bending test,sustained load tensile test and stress corrosion cracking test have been carried out to evaluate the delayed fracture resistance of steel ADFl and commercial steel 42 CrMo.The results showed that steel ADF1 has superior delayed fracture resistance to that of 42 CrMo steel.It's concluded that the superior delayed fracture resistance of ADF1 is mainly due to the increase of tempering temperature,fine homogeneously distributed MC carbide and fine prior austenite grain size.展开更多
In this paper, the performance of HG70D welded joint of ultra-high strength steel plates is presented, and the performance of HG70D and Q345B welded joints is studied. The high strength steel plate HG70D showed excell...In this paper, the performance of HG70D welded joint of ultra-high strength steel plates is presented, and the performance of HG70D and Q345B welded joints is studied. The high strength steel plate HG70D showed excellent weldability. Through the X-ray inspection of welded joints, tensile strength, impact test and bending performance test, the comprehensive performance of the joint was excellent. The macroscopic and microscopic metallographic analysises of the welded joints show that the welding seams included pearlite, sorbite, ferrite, etc. The influence of stress annealing temperature on HG70D of high strength steel plate was analyzed by heat treatment.展开更多
基金Acknowledgments The authors gratefully acknowledge the financial support provided by the National Natural Science Foundation of China under grant No. 51175119.
文摘High strength steel thick plate is widely used in shipbuilding, pressure vessels, etc. , the balance between weld quality and welding efficiency is becoming a research focus. In this paper, double-sided double arc fiat-overhead welding experiments for high strength steel thick plate were conducted. Microstructures of weld have been observed through optical microscope (OM) and scanning electron microscope (SEM). Transformation of microstructures under thermal cycles of multi peaks was analyzed. Macro and micro hardness were also tested. The results show that the heat-affected zone (HAZ) near the fusion line experiences thermal cycles up to three times. The microstructures there are the most complex, including coarse lath martensite in original coarse-grained zone, and net-like structure along grain boundaries in critical reheat coarse-grained zone. After several times of tempering for bucking welding, the features of acicula and lath are weakened. Its microstructure approaches to the microstructure of base metal which is tempering sorbite. The hardness test shows that the maximum hardness occurs at critical reheat coarse-grained zone, the hardness of reticulation structure at grain boundary can be up to 450 HV.
基金supported by National Natural Science Foundation of China(Grant No.19832020)National Science Fund of Outstanding Youths of China (Grant No.10125208)+1 种基金Chongqing Municipal Programs for Science and Technology Development of China(Grant No.CSTC, 2007AA4008)National Key Technology R&D Program of China(Grant No.2006BA104B04-2)
文摘Lightweight structure is an important method to increase vehicle fuel efficiency. High strength steel is applied for replacing mild steel in automotive structures to decrease thickness of parts for lightweight. However, the lightweight structures must show the improved capability for structural rigidity and crash energy absorption. Advanced high strength steels are attractive materials to achieve higher strength for energy absorption and reduce weight of vehicles. Currently, many research works focus on component level axial crash testing and simulation of high strength steels. However, the effects of high strength steel parts to the impact of auto body are not considered. The goal of this research is to study the application of hot forming high strength steel(HFHSS) in order to evaluate the potential using in vehicle design for lightweight and passive safety. The performance of HFHSS is investigated by using both experimental and analytical techniques. In particular, the focus is on HFHSS which may have potential to enhance the passive safety for lightweight auto body. Automotive components made of HFHSS and general high strength steel(GHSS) are considered in this study. The material characterization of HFHSS is carried out through material experiments. The finite element method, in conjunction with the validated model is used to simulate the side impact of a car with GHSS and HFHSS parts according to China New Car Assessment Programme(C-NCAP) crash test. The deformation and acceleration characteristics of car body are analyzed and the injuries of an occupant are calculated. The results from the simulation analyses of HFHSS are compared with those of GHSS. The comparison indicates that the HFHSS parts on car body enhance the passive safety for the lightweight car body in side impact. Parts of HFHSS reduce weight of vehicle through thinner thickness offering higher strength of parts. Passive safety of lightweight car body is improved through reduction of crash deformation on car body by the application of HFHSS parts. The experiments and simulation are conducted to the HFHSS parts on auto body. The results demonstrate the feasibility of the application of HFHSS materials on automotive components for improved capability of passive safety and lightweight.
基金supported by the National Science and Technology Infrastructure Platforms Construction Projects of China (Grant No2005DKA10400)the National Science Foundation of China (No50871021)
文摘The effects of chromium on the corrosion and the electrochemical behaviors of ultra high strength steels were studied by the salt spray test and electrochemical methods. The results show that ultra high strength steels remain martensite structures and have anodic dissolution characteristic with an increase of chromium content. There is no typical passive region on the polarization curves of an ultra high strength stainless steel, AerMet 100 steel, and 300M steel. However, chromium improves the corrosion resistance of the stainless steel remarkably. It has the slowest corrosion rate in the salt spray test, one order of magnitude less than that of AerMet 100 and 300M steels. With the increase of chromium content, the polarization resistance becomes larger, the corrosion potential shifts towards the positive direction with a value of 545 mV, and the corrosion current density decreases in electrochemical measures in 3.5wt% NaCl solutions. Because of the higher content of chromium, the ultra high strength stainless steel has a better corrosion resistance than AerMet 100 and 300M steels.
基金financially supported by the Scientific Research Foundation of Guangxi University (No.XBZ110407)
文摘To develop a high strength low alloy (HSLA) steel with high strength and high toughness, a series of martensitic steels were studied through alloying with various elements and thermodynamic simulation. The microstructure and mechanical properties of the designed steel were investigated by optical microscopy, scanning electron microscopy, tensile testing and Charpy impact test. The results show that cementite exists between 500℃ and 700℃, M7C3 exits below 720℃, and they are much lower than the austenitizing temperature of the designed steel. Furthermore, the Ti(C,N) precipitate exists until 1280℃, which refines the microstructure and increases the strength and toughness. The optimal alloying components are 0.19% C, 1.19% Si, 2.83% Mn, 1.24% Ni, and 0.049% Ti; the tensile strength and the V notch impact toughness of the designed steel are more than 1500 MPa and 100 J, respectively.
基金financially supported by the National Natural Science Foundation of China(No.50904006)the Fundamental Research Funds for the Central Universities of China(No.FRT-TP-10-001A)
文摘The microstructures and mechanical properties of C-Mn-Cr-Nb and C-Mn-Si-Nb ultra-high strength dual-phase steels were studied by scanning electron microscopy (SEM), transmission electron microscopy (TEM), and tensile test. The results show that Si can promote the transformation of austenite (γ) to ferrite (α), enlarge the (α+γ) region, and increase the aging stability of martensite by inhibiting carbide precipitation. Adding Cr leads to the formation of retained austenite and martensite/austenite (M/A) constituents, as well as the decomposi- tion of martensite during the overaging stage. Both of the steels show higher initial strain-hardening rates and two-stage strain-hardening characteristics. The C-Mn-Si-Nb steel shows the higher strain-hardening rate than the C-Mn-Cr-Nb steel in the first stage; however, there is no significant difference in the second stage. Although the tensile strength and elongation of the two steels both exceed 1000 MPa and 15%, respectively, the comprehensive mechanical properties of the C-Mn-Si-Nb steel are superior.
文摘Microstructure observations and drop-weight tear test were performed to study the microstructures and mechanical properties of two kinds of industrial X70 and two kinds of industrial X80 grade pipeline steels. The effective grain size and the fraction of high angle grain boundaries in the pipeline steels were investigated by electron backscatter diffraction analysis. It is found that the low temperature toughness of the pipeline steels depends not only on the effective grain size, but also on other microstructural factors such as martensite-austenite (MA) constituents and precipitates. The morphology and size of MA constituents significantly affect the mechanical properties of the pipeline steels. Nubby MA constituents with large size have significant negative effects on the toughness, while smaller granular MA constituents have less harmful effects. Similarly, larger Ti-rich nitrides with sharp corners have a strongly negative effect on the toughness, while fine, spherical Nb-rich carbides have a less deleterious effect. The low temperature toughness of the steels is independent of the fraction of high angle grain boundaries.
基金Item Sponsored by National Key Fundamental Research and Development Project of China(G1998061503)National Science and Technology Development Project of China(2002BA314B08)
文摘The delayed fracture behaviors of CrMo-type high strength steels containing different amount of titanium(0to 0.10%)were studied.The steels were quenched at 880℃ and tempered from 400℃ to 650℃,and a wide range of tensile strength was obtained.The sustained load tensile test was carried out by using notched tensile specimens in Walpole solution.The experimental results showed that with higher strength,the Ti-microalloyed steels show higher resistance to delayed fracture compared with non-microalloyed steel due to titanium beneficial role and microstructure changes.The undissolved TiC is uniformly distributed as strong hydrogen traps,retarding or preventing the diffusion and accumulation of hydrogen to lower-interaction energy sites,such as prior austenite and martensite lath boundaries in stress concentration area.Meanwhile,the grain refining effect of titanium is also an important factor to improve the delayed fracture resistance of Ti-microalloyed steels.The characteristics of delayed fracture remain nearly the same with titanium addition.
基金supported by the National Key Fundamental Research and Development Program of China (No.2004CB619105)
文摘The ultra-high cycle fatigue behavior of a novel high strength steel with carbide-free bainite/martensite (CFB/M) complex microstructure was studied. The ultra-high cycle fatigue properties were measured by ultrasonic fatigue testing equipment at a frequency of 20 kHz. It is found that there is no horizontal part in the S-N curve and fatigue fracture occurs when the life of specimens exceeds 10^7 cycles. In addition, the origination of fatigue cracks tends to transfer from the surface to interior of specimens as the fatigue cycle exceeds 10^7, and the fatigue crack originations of many specimens are not induced by inclusions, but by some kind of "soft structure". It is shown that the studied high strength steel performs good ultra-high cycle fatigue properties. The ultra-high fatigue mechanism was discussed and it is suggested that specific CFB/M complex microstructure of the studied steel contributes to its superior properties.
基金the National Natural Science Foundation of China under Grant No.51478244
文摘To investigate the seismic behavior of I-section columns made of 460 MPa high strength steel (HSS), six specimens were tested under constant axial load and cyclic horizontal load. The specimens were designed with different width-to-thickness ratios and loaded under different axial load ratios. For each specimen, the failure mode was observed and hysteretic curve was measured. Comparison of different specimens on hysteretic characteristic, energy dissipation capacity and deformation capacity were further investigated. Test results showed that the degradation of bearing capacity was due to local buckling of flange and web. Under the same axial load ratio, as width-to-thickness ratio increased, the deformation area of local buckling became smaller. And also, displacement level at both peak load and failure load became smaller. In addition, the full extent of hysteretic curve, energy dissipation capacity, ultimate story drift angle decreased, and capacity degradation occurred more rapidly with the increase of width-to-thickness ratio or axial load ratio. Based on the capacity of story drift angle, limiting values which shall not be exceeded are suggested respectively for flange and web plate of 460 MPa HSS I-section columns when used in SMFs and in IMFs in the case of axial load ratio no more than 0.2. Such values should be smaller when the axial load ratio increases.
文摘Laboratory and industrial studies were carried out to investigate non-metallic inclusions in high strength alloy steel refined by high basicity and high Al_2O_3 slag.It was found that the steel/slag reaction time largely affected non-metallic inclusions.With the reaction time increased from 30 min to 90 min in laboratory study,MgO-Al_2O_3 spinels were gradually changed into CaO-MgO-Al_2O_3 system inclusions surrounded by softer CaO-Al_2O_3 surface layers.By using high basicity slag which contained as much as 41%Al_2O_3 in the laboratory study,ratio of low melting temperature CaO-MgO-Al_2O_3 system inclusions was remarkably increased to above 80%.In the industrial experiment,during the secondary refining,the inclusions changed in order of 'Al_2O_3→MgO-Al_2O_3→CaO-MgO-Al_2O_3'.Through the LF and RH refining,most inclusions could be transferred to lower melting temperature CaO-Al_2O_3 and CaO-MgO-Al_2O_3 system inclusions.
基金supported by the National Natural Science Foundation of China under grant No. 50605043
文摘Powdering/exfoliating of coatings and scratching galvanized steels and high strength steels (HSS), are the main forms of surface damage in the forming of which result in increased die maintenance cost and scrap rate. In this study, a special rectangular box was developed to investigate the behavior and characteristics of surface damage in sheet metal forming (SMF) processes. U-channel forming tests were conducted to study the effect of tool hardness on surface damage in the forming of high strength steels and galvanized steels (hot-dip galvanized and galvannealed steels). Experimental results indicate that sheet deformation mode influences the severity of surface damage in SMF and surface damage occurs easily at the regions where sheet specimen deforms under the action of compressive stress. Die corner is the position where surface damage initiates. For HSS sheet, surface damage is of major interest due to high forming pressure. The HSS and hot-dip galvanized steels show improved ability of damage-resistance with increased hardness of the forming tool. However, for galvannealed steel it is not the forming tool with the highest hardness value that performs best.
基金financially supported by the National Natural Science Foundation of China (No. 51271035)The financial support of the Beijing Laboratory of Metallic Materials and Processing for Modern Transportation
文摘The transformation behavior and tensile properties of an ultra-high-strength transformation-induced plasticity (TRIP) steel (0.2C-2.0Si-I.SMn) were investigated by different heat treatments for automobile applications. The results show that F-TRIP steel, a tradi- tional TRIP steel containing as-cold-rolled ferfite and pearlite as the original microstructure, consists of equiaxed grains of intercritical ferrite surrounded by discrete particles of M/RA and B. In contrast, M-TRIP steel, a modified TRiP-aided steel with martensite as the original mi- crostlucture, containing full martensite as the original microstructure is comprised of lath-shaped grains of ferrite separated by lath-shaped martensite/retained austenite and bainite. Most of the austenite in F-TRIP steel is granular, while the austenite in M-TRIP steel is lath-shaped. The volume fraction of the retained austenite as well as its carbon content is lower in F-TRIP steel than in M-TRIP steel, and austenite grains in M-TRIP steel are much finer than those in F-TRIP steel. Therefore, M-TRIP steel was concluded to have a higher austenite stability, re- sulting in a lower transformation rate and consequently contributing to a higher elongation compared to F-TRIP steel. Work hardening be- havior is also discussed for both types of steel.
基金supported by the National High-tech Research and Development Program of China (No.2009AA03Z518)
文摘The high-temperature mechanical properties and microstructure of forging billets of C-Si-Mn-Cr and C-Si-Mn-Cr-Mo ultra-high-strength cold-rolled steels(tensile strength≥1000 MPa,elongation≥10%) were studied.Through the comparison of reduction in area and hot deformation resistance at 600-1300°C,the Mo-containing steel was found to possess a higher strength and a better plasticity than the Mo-free one.The equilibrium phase diagram and atom fraction of Mo in different phases at different temperatures were calculated by Thermo-Calc software(TCW).The results analyzed by using transmission electron microscopy and TCW show that precipitates in the Mo-containing steel are primarily M23C6,which promote pearlite formation.The experimental data also show that a lower ductility point existing in the Mo-free steel at 850°C is eliminated in the Mo-containing one.This is mainly due to the segregation of Mo at grain boundaries investigated by electron probe microanalysis(EPMA),which improves the strength of grain boundaries.
文摘The fatigue cracking behavior of ultra-high strength steels containing rectangular inclusions of small sizes were investigated based on in situ observations by scanning electron microscopy (SEM). The size and shape of rectangular inclusions affect markedly the initiation site and propagation path of a fatigue crack. Especially, the initiation site of a fatigue crack depends strongly on the angle between the long-axis of a rectangle inclusion and the loading direction, and the length/width ratio of this rectangle inclusion because the residual stress distribution fields vary with these conditions. The results coincide very well with those of finite element analysis.
基金Funded by the National Natural Science Foundation of China(No.U1860112)the State Key Laboratory of Marine Equipment made of Metal Material and Application(No.SKLMEAUSTL-201708 and No.SKLMEA-USTL-201703)+1 种基金the Key Project of Liaoning Education Department(No.2019FWDF03)the National Natural Science Foundation of USTL(No.2017QN11)
文摘The addition of high Ti(>0.1%) in microalloyed bainitic high strength steel was designed, and the precipitation morphology of steels with different Ti, Nb, and V contents was studied by utilizing transmission electron microscopy(TEM). Based on the classical nucleation-crystal growth theory and the Johnson-Mehl-Avrami equation, the precipitation thermodynamic and kinetic model of second phase particles in austenite was established in the form of(Nbx,Vy,Tiz)C, and the complex precipitation mechanism of second phase particles was emphatically studied. The experimental results show that the complex precipitation particles could be divided into two categories: the coarser particles with about 100 nm grain size and the independent complex precipitation particles in the form of(Nb,V,Ti)C with 35-50 nm grain size. The latter has a better precipitation strengthening effect, and the calculated PTT curve shows a typical "C" shape. When the deformed storage energy is 3 820 J·mol^-1, the fastest precipitation temperature of calculated PTT curve is 925℃, and the calculated result is essentially consistent with experimental values. The increase of Ti content increased the nose point temperature and expanded the range of fastest precipitation temperature.
基金financially supported by the National Key R&D Program of China(No.2017YFB1103200)the Independent Innovation Research Fund Project of Huazhong University of Science and Technology(No.2018KFYXMPT002)。
文摘A high-building multi-directional pipe joint(HBMDPJ)was fabricated by wire and arc additive manufacturing using high-strength low-alloy(HSLA)steel.The microstructure characteristics and transformation were observed and analyzed.The results show that the forming part includes four regions.The solidification zone solidifies as typical columnar crystals from a molten pool.The complete austenitizing zone forms from the solidification zone heated to a temperature greater than 1100℃,and the typical columnar crystals in this zone are difficult to observe.The partial austenitizing zone forms from the completely austenite zone heated between Ac1(austenite transition temperature)and1100℃,which is mainly equiaxed grains.After several thermal cycles,the partial austenitizing zone transforms to the tempering zone,which consistes of fully equiaxed grains.From the solidification zone to the tempering zone,the average grain size decreases from 75 to20μm.The mechanical properties of HBMDPJ satisfies the requirement for the intended application.
基金supported by the National Natural Science Foundation of China (Nos.50471107 and 50734004)
文摘An ultra-low carbon acicular ferrite steel heavy plate was obtained with an advanced thermo-mechanical control process-relaxed precipitation controlled transformation (TMCP-RPC) at Xiangtan Steel, Valin Group. The heavy plate has a tensile strength of approximately 600 MPa with a lower yield ratio. The impact toughness of the heavy plate achieves 280 J at ?40°C. The fine-grained mixed microstructures of the heavy plate mainly consist of acicular ferrite, granular bainite, and polygonal ferrite. The high strength and excellent toughness of the heavy plate are attributed to the formation of acicular ferrite microstructure. The prevention of blocks of martensite/retained austenite (M/A) and the higher cleanness are also responsible for the superior toughness.
基金Sponsored by National Key Fundamental Research Project(G1998061503)
文摘By the increase in Mo content,the addition of microalloying elements V and Nb and by reducing the contents of Mn,P and S based on the composition of steel 42 CrMo,we have developed a 1 300 MPa-grade high strength steel(ADF1)for bolts.The sustained load bending test,sustained load tensile test and stress corrosion cracking test have been carried out to evaluate the delayed fracture resistance of steel ADFl and commercial steel 42 CrMo.The results showed that steel ADF1 has superior delayed fracture resistance to that of 42 CrMo steel.It's concluded that the superior delayed fracture resistance of ADF1 is mainly due to the increase of tempering temperature,fine homogeneously distributed MC carbide and fine prior austenite grain size.
文摘In this paper, the performance of HG70D welded joint of ultra-high strength steel plates is presented, and the performance of HG70D and Q345B welded joints is studied. The high strength steel plate HG70D showed excellent weldability. Through the X-ray inspection of welded joints, tensile strength, impact test and bending performance test, the comprehensive performance of the joint was excellent. The macroscopic and microscopic metallographic analysises of the welded joints show that the welding seams included pearlite, sorbite, ferrite, etc. The influence of stress annealing temperature on HG70D of high strength steel plate was analyzed by heat treatment.