Superhydrophobic surfaces are often found in nature, such as plant leaves and insect wings. Inspired by superhydrophobic phenomenon of the rose petals and the lotus leaves, biomimetic hydrophnbic surfaces with high or...Superhydrophobic surfaces are often found in nature, such as plant leaves and insect wings. Inspired by superhydrophobic phenomenon of the rose petals and the lotus leaves, biomimetic hydrophnbic surfaces with high or low adhesion were prepared with a facile drop-coating approach in this paper. Poly（vinyl alcohol） （PVA） was used as adhesive and SiO2 nanoparticles were used to fabricate surface micro-structure. Stearic acid or dodecafluoroheptyl-propyl-trimethoxysilane （DFTMS） were used as low surface energy materials to modify the prepared PVA/SiO2 coating surfaces. The effects of size of SiO2 nanoparticles, concentration of SiO2 nanoparticle suspensions and the modifications on the wettability of the surface were investigated. The morphology of the PVA/SiO2 coating surfaces was observed by using scanning electron microscope. Water contact angle of the obtained superhydrophilic surface could reach to 3°. Stearic acid modified PVA/SiO2 coating surfaces showed hydrophobicity with high adhesion. By mixing the SiO2 nanoparticles with sizes of 40 nm and 200 nm and modifying with DFTMS, water contact angle of the obtained coating surface could be up to 155° and slide angle was only 5°. This work provides a facile and useful method to control surface wettability through changing the roughness and chemical composition of a surface.展开更多
The oxide dispersion strengthened Mo alloys(ODS-Mo)prepared by traditional ball milling and subsequent sintering technique generally possess comparatively coarse Mo grains and large oxide particles at Mo grain boundar...The oxide dispersion strengthened Mo alloys(ODS-Mo)prepared by traditional ball milling and subsequent sintering technique generally possess comparatively coarse Mo grains and large oxide particles at Mo grain boundaries(GBs),which obviously suppress the corresponding strengthening effect of oxide addition.In this work,the Y_(2)O_(3) and TiC particles were simultaneously doped into Mo alloys using ball-milling and subsequent low temperature sintering.Accompanied by TiC addition,the Mo-Y_(2)O_(3) grains are sharply refined from 3.12 to 1.36μm.In particular,Y_(2)O_(3) and TiC can form smaller Y-Ti-O-C quaternary phase particles(~230 nm)at Mo GBs compared to single Y_(2)O_(3) particles(~420 nm),so as to these new formed Y-Ti-O-C particles can more effectively pin and hinder GBs movement.In addition to Y-Ti-O-C particles at GBs,Y_(2)O_(3),TiOx,and TiCx nanoparticles(<100 nm)also exist within Mo grains,which is significantly different from traditional ODS-Mo.The appearance of TiOx phase indicates that some active Ti within TiC can adsorb oxygen impurities of Mo matrix to form a new strengthening phase,thus strengthening and purifying Mo matrix.Furthermore,the pure Mo,Mo-Y_(2)O_(3),and Mo-Y_(2)O_(3)-TiC alloys have similar relative densities(97.4%-98.0%).More importantly,the Mo-Y_(2)O_(3)-TiC alloys exhibit higher hardness(HV0.2(425±25))compared to Mo-Y_(2)O_(3) alloys(HV0.2(370±25)).This work could provide a relevant strategy for the preparation of ultrafine Mo alloys by facile ball-milling.展开更多
基金This work is supported by the National Natural Science Foundation of China （51273083 and 51405188） and China Postdoctoral Science Foundation （2015T80307）.
文摘Superhydrophobic surfaces are often found in nature, such as plant leaves and insect wings. Inspired by superhydrophobic phenomenon of the rose petals and the lotus leaves, biomimetic hydrophnbic surfaces with high or low adhesion were prepared with a facile drop-coating approach in this paper. Poly（vinyl alcohol） （PVA） was used as adhesive and SiO2 nanoparticles were used to fabricate surface micro-structure. Stearic acid or dodecafluoroheptyl-propyl-trimethoxysilane （DFTMS） were used as low surface energy materials to modify the prepared PVA/SiO2 coating surfaces. The effects of size of SiO2 nanoparticles, concentration of SiO2 nanoparticle suspensions and the modifications on the wettability of the surface were investigated. The morphology of the PVA/SiO2 coating surfaces was observed by using scanning electron microscope. Water contact angle of the obtained superhydrophilic surface could reach to 3°. Stearic acid modified PVA/SiO2 coating surfaces showed hydrophobicity with high adhesion. By mixing the SiO2 nanoparticles with sizes of 40 nm and 200 nm and modifying with DFTMS, water contact angle of the obtained coating surface could be up to 155° and slide angle was only 5°. This work provides a facile and useful method to control surface wettability through changing the roughness and chemical composition of a surface.
基金financially supported by the National Natural Science Foundation of China (Nos. 52171044 and 51804218)the Innovation and Entrepreneurship Training Program for College Students in Fujian Province, China (No. S202111312029)
文摘The oxide dispersion strengthened Mo alloys(ODS-Mo)prepared by traditional ball milling and subsequent sintering technique generally possess comparatively coarse Mo grains and large oxide particles at Mo grain boundaries(GBs),which obviously suppress the corresponding strengthening effect of oxide addition.In this work,the Y_(2)O_(3) and TiC particles were simultaneously doped into Mo alloys using ball-milling and subsequent low temperature sintering.Accompanied by TiC addition,the Mo-Y_(2)O_(3) grains are sharply refined from 3.12 to 1.36μm.In particular,Y_(2)O_(3) and TiC can form smaller Y-Ti-O-C quaternary phase particles(~230 nm)at Mo GBs compared to single Y_(2)O_(3) particles(~420 nm),so as to these new formed Y-Ti-O-C particles can more effectively pin and hinder GBs movement.In addition to Y-Ti-O-C particles at GBs,Y_(2)O_(3),TiOx,and TiCx nanoparticles(<100 nm)also exist within Mo grains,which is significantly different from traditional ODS-Mo.The appearance of TiOx phase indicates that some active Ti within TiC can adsorb oxygen impurities of Mo matrix to form a new strengthening phase,thus strengthening and purifying Mo matrix.Furthermore,the pure Mo,Mo-Y_(2)O_(3),and Mo-Y_(2)O_(3)-TiC alloys have similar relative densities(97.4%-98.0%).More importantly,the Mo-Y_(2)O_(3)-TiC alloys exhibit higher hardness(HV0.2(425±25))compared to Mo-Y_(2)O_(3) alloys(HV0.2(370±25)).This work could provide a relevant strategy for the preparation of ultrafine Mo alloys by facile ball-milling.
