HIGH T_c SUPERCONDUCTOR YBa_2 Cu_3 O_x SYNTHESIZED BY UNIDIRECTIONAL REACTION

A unidirectional reaction for synthesis of the high T_c superconductor YBa_2Cu_3O_x has been proposed, Its T_c is 90-94.5 K and △T is 1 K. The phase relationships in the system Y_2BaCuO_5-Y_2Cu_2O_5-CuO-YBa_2Cu_3O_x were studied and discussed.

Speciflc Heat-Phonon Spectrum Inversion Problem of High T_c Superconductor

The phonon density of states of YBa2Cu3O6.92 is obtained with the method of Fourier decon-volution and Tikhonov-s regularization technique from the experimental specific heat data. The result is compared with that of neutron inelastic scattering.

The Holographic study for the high T_c superconductor YBCO and recent development of studies of a class of inverse problems

A dream or interesting problem is to obtain more information based on one measurement,for example to obtain all the thermodynamic functions based on specific heat only. We call it"holographic"study.After more than 10 year's efforts,we suggest one possibility(or only one)is to solve an inverse problem(specific heat-phonon spectrum inversion,SPI).In this talk we will review recent development of studies of a class of inverse problems,including Dai's exact solution and Chen's formula and their unification.T...

High T_c Superconductor Theoretical Models and Electromagnetic Flux Characteristics

High Tc Superconductors （HTS） have special electromagnetic characteristics and phenomena. Effort has been made in order to theoretically understand the appfied HTS superconductivity and HTS behaviors for practical appfications, various theoretical models related to the HTS electromagnetic properties have been developed. The theoretical models and analytic methods are summarized with regard to understanding the HTS magnetic flux characteristic which is one of the most critical issues related to HTS appfications such as for HTS magnetic levitation application.

An Experimental Setup for Study of Photoresponse of High T_c Superconductors

We have developed an experimental setup that has been proven suitable for the study of photoresponse of high Tc superconductors. The distinguish feature of this experimental setup lies mainly in the data acquisition system which is equipped with computer as well as the IEEE-488 interface bus. which ensures the accuracy to experimental results. Using the experimental setup, the optical response to laser radiation in high-Tc superconductors has been examined, both of bolometric effect and nonequilibrium optical response are revealed.

ON THE VALENCE STATE OF COPPER IN HIGH T_c SUPERCONDUCTOR YBa_2Cu_3O_x

Various optical luminescence spectroscopic techniques were used to characterize the high T_c superconductor YBa_2Cu_3O_x.The emission bands reveal that Cu^(3+) coexist with Cu^(2+) and Cu^+ in this material.

CHARACTERISTIC CURVES OF M-H AND COEXISTENCE OF MAGNETISM WITH SUPERCONDUCTIVITY FOR HIGH T_c SUPERCONDUCTORS REBa_2Cu_3OT_(7-x)

Some high T_c superconductors REBa_2Cu_3O_(7-x)(RE=Sm,Eu,Gd,Dy,Ho,Er,Tm) with zero resist- ance temperatures were about 90K have been prepared.The effect of magnetic rare earth ions on the transi- tion temperatures is not very great,but their magnetic behaviours are different from each other.The magnetization loops of these compounds have been measured at 77K.The coexistence of superconductivity with magnetic ordering (COSM) found in the samples with RE=Gd,Dy,Ho,Er,Tm,indicates that there are two possible ways of coexistence in the samples.These expertments show that the relation of paramagnetism to the atomtc number of rare earth elements for these superconductors is similar to that of rare earth ions in some paramagnetic salt crystals,which indicates that the magnetism of the samples origi- nates from the local magnetic moments of rare earth ions.In some samples there is antiferromagnetie ordering at low temperatures,and the effective Bohr magneton numbers are consistent with that of free rare earth ions. Some superconducting parameters including the critical current density are calculated according to Ginzburg-Landau theory and the critical state model.

First-principles study of moderate phonon-mediated pairing in high-pressure monoclinic phase of BiS_(2)-based superconductors

Isotope effect on superconductive transition temperature(T_c)is an essential indicator to examine whether the mechanism of superconductors is conventional.Unconventional isotope effect of BiS_(2)-based superconductors has been previously reported in ambient-pressure tetragonal phase.However,to comprehensively ascertain the nature of superconductivity,the investigation of BiS_(2)-based system in high-pressure structure is highly desirable.In this work,we carried out the first-principles calculations of phonon spectra and superconductivity in high-pressure monoclinic phase of LaO_(0.5)F_(0.5)BiS_(2)with ^(32)S and ^(34)S,and observed that the corresponding isotope coefficient is 0.13≤α≤0.20.This value is much greater than that of BiS_(2)-based superconductors in ambient-pressure phase,but slightly smaller than that of conventional MgB_2.Taking into account the calculated T_(c) lower than experimental results,we finally conclude that the moderate phonon-mediated pairing plays a significant role in forming superconductivity of BiS_(2)-based system in high-pressure phase,moreover,the cooperative multiple paring interactions should also be considered.

Robust T_c in element molybdenum up to 160 GPa

Element superconductors with the single atoms provide clean and fundamental platforms for studying superconductivity.Although elements with d electrons are usually not favored by conventional BCS,the record superconducting critical temperature(T_(c))in element scandium(S_(c))has further ignited the intensive attention on transition metals.The element molybdenum(M_o)with a half-full d-orbital is studied in our work,which fills the gap in the study of Mo under high pressure and investigates the pressure dependence of superconductivity.In this work,we exhibit a robust superconductivity of Mo in the pressure range of 5 GPa to 160 GPa via high-pressure electrical transport measurements,the T_(c) varies at a rate of0.013 K/GPa to 8.56 K at 160 GPa.Moreover,the superconductivity is evidenced by the T_(c) shifting to lower temperature under applied magnetic fields,and the upper critical magnetic fields are extrapolated by the WHH equation and GL equation;the results indicate that the maximum upper critical magnetic field is estimated to be 8.24 T at 137 GPa.We further investigate the superconducting mechanism of Mo,the theoretical calculations indicate that the superconductivity can be attributed to the strong coupling between the electrons from the partially filled d band and the phonons from the frequency zone of 200-400 cm^(-1).

INFRARED SPECTRA OF Bi(Pb)-Sr-Ca-Cu-O HIGH T_c SUPERCONDUCTOR

I. INTRODUCTIONFrom the reflection-absorption spectra, Raman spectra and fluorescence spectra etc. of Y-Ba-Cu-O high T_c superconductor, much information concerning the structure of energy band, the density of states and the electron-phonon coupling strength has been obtained. The discovery of Bi-Sr-Ca-Cu-O system indicates a new direction for the re-

HIGH T_c SUPERCONDUCTOR WITHOUT RARE-EARTH ELEMENT Bi-Sr-Ca-Cu-O SYSTEM

Ⅰ. INTRODUCTIONSince the discovery of oxide superconductor YBa2Cu3O7-δ with transition temperature above liquid nitrogen one year ago, a tremendous amount of work has been done on oxide superconductors in thousands of laboratories in the world. It has already been shown that yttrium could be replaced by other rare-earth elements

An Extended Model for Coexistence of Superconductivity and Paramagnetism in High-T_c Superconductors

在现在的工作，处于超导的状态的全部的磁化以一个 H (x) 依赖者被分开成批评州、顺磁的部件磁性的流动密度。利用这个模型，我们成功地复制 Sandu 等测量的 M-H 曲线。[Phys。加快。B 74 (2006 ) 184511 ] 并且 Sandu 等。[J。Supercond。Incorp。新奇 Magn。17 (2004 ) 701 ] 为 J c 。

A Study on Synthesis Kinetics of YBa_2Cu_3O_x High Tc Superconductor Powder

The synthesis kinetics of YBa_2Cu_30_x supercon- ductor was studied through comparing the calcina- tion (sintering) processes of different kinds of powders. It was shown that the temperature of synthesis of YBa_2Cu_30_x phase can be lowered from 950℃ to 800℃ through direct calcination of multiphase powder with uniform chemical com- position. The stress which is caused by the volume change during synthetic reaction breaks the particles. It facilitates the formation of highly active superfines of superconductor.

Principle of X-ray Ф-scan and Application ofHigh T_c Bi-epitaxial Junction

The X-ray Ф-scan technique was applied to determine the in-plane orientation relationship of the high T_csuperconductins bi-epitaxial junction. The result shows that the in-plane orientation relation of the films in thetwo sides of the grain boundary can be easily obtained with this method. By controlling the growth condition,a 45° YBCO grain boundary can be made on the SrTiO_3 substrate.

Explanation of Pressure Effect for High Temperature Superconductors Using Pressure Dependent Schrodinger Equation and String Theory

A pressure dependent Schrodinger equation is used to find the conditions that lead to superconductivity. When no pressure is exerted, the superconductor resistance vanishes beyond a critical temperature related to the repulsive force potential of the electron gass, where one assuming the electron total energy to be thermal, where applying mechanical pressure destroys Sc when it exceeds a certain critical value. However when the electron total energy is an assumed to be that of the free electron model and that the pressure is thermal and mechanical, the situation is different. The quantum expression for resistance shows that the increase of mechanical pressure increases the critical temperature. Such phenomenon is observed in high temperature cupper group.

Design consideration of a super-high speed high temperature superconductor maglev evacuated tube transport (I)

The super-high speed high temperature superconductor （HTS） maglev evacuated tube transport （ETT） is a promising transport mode for the future. As a key component of the HTS maglev vehicle, the permanent magnet guide- ways （PMGs） with different geometrical configurations and iron yoke widths are analyzed by finite element method （FEM）. The levitation force of a single onboard HTS maglev device over the designed PMG at different field cooling heights （FCH） is measured by magnetic levitation measurement system. Based on the designed PMG and experimental results, a preliminary scheme of subterranean super-high speed HTS maglev ETT is described in this paper. The HTS maglev ETT is mainly composed of an evacuated tube, HTS maglev vehicle, PMG, propulsion system, station, emergency rescue system, etc. In addition, a subterranean tube that consists of foundation tube and vacuum airproof layer is introduced. In order to convert the stress caused by the air pressure difference between inside and outside of the vehicle, a multi-circular vehicle body is designed. The vehicle is driven by a linear motor propulsion system under the control of a ground controlling system. The scheme of long-distance super-high speed passenger transportation is accomplished by the connection of different vehicles.

COMPOSITIONAL ANALYSIS OF HIGH-TEMPERATURE SUPERCONDUCTOR THIN FILMS BY HIGH ENERGY ELASTIC BACKSCATTERING OF HELIUM IONS

High energy ion backscattering can be used to enhance the sensitivity of oxygen analysis. At He++ ion energy of 8.8 MeV, the yield due to oxygen is about 25 times larger than that predicted by Rutherford formula. The elemental stoichiometry of some bulk and thin film superconductor samples was determined. The details of the measuring method are discribed.

Mass Transport of β-Diketonate Precursors for MOCVD of YBa_2Cu_3O_(7-δ) High T_c Superconducting Thin Films

Mass transport of Y(dpm)2 Ba(dpm)5· OH· 2Ho and Cu (dpm)2 by a carrier gas(argon) was theoretically considered and experimentally studied as a function of the system with operating parameters including temperature, carrier gas flow rate and system pressure. The experimental results are in a good agreement with the theoretical prediction. The mechanism of mass transport of these organometallic precursors and their use for YBCO film stoichiometry control and reproducibility are discussed.