The Chang＇an gold ore deposit in western Yunnan is located at the southern segment of the Ailaoshan metallogenic belt.The ore bodies are preserved in fractured Ordovician sedimentary clastic rocks.The gold-bearing mi...The Chang＇an gold ore deposit in western Yunnan is located at the southern segment of the Ailaoshan metallogenic belt.The ore bodies are preserved in fractured Ordovician sedimentary clastic rocks.The gold-bearing minerals occur dominantly in sulfide-quartz veins.Fluid inclusion analysis shows that the Chang＇an gold ore deposit is characterized by epithermal gold mineralization at temperatures between 200℃and 280℃at a shallow crustal level.The mineralizing fluids have intermediate to low salinity（6%-18%） and low densities（0.72-1.27 g/cm^3）.The ore minerals haveδ^（34）S in a range from -13‰to 3.57‰,concentrated from -2.06‰to 3.57‰with an average of 1.55‰.The ^（206）Pb/^（204）Pb,^（207）Pb/^（204）Pb and ^（208）Pb/^（204）Pb values are 18.9977-19.5748,15.7093-15.784,39.3814-40.2004 respectively.These isotope data suggest that the ore-forming elements were mainly derived from mixed crustal and mantle sources.The Chang＇an gold ore deposit and Tongchang Cu-Mo deposit are closely related to each other in their spatial distribution and age of formation.They have similar sources of mineralizing elements and identical ore-forming metal elements,and show a close relationship in physical and chemical conditions of mineralization.The two deposits constitute an epithermal-porphyry -skarn type Cu-Mo-Au mineralization system in the Tongchang-Chang＇an area,which is related to the Cenozoic high-K alkaline magmatism.展开更多
Subject Code:B01With the support by the National Natural Science Foundation of China,a creative study by the research group led by Prof.Chen Qianwang(陈乾旺)from the University of Science and Technology of China and H...Subject Code:B01With the support by the National Natural Science Foundation of China,a creative study by the research group led by Prof.Chen Qianwang(陈乾旺)from the University of Science and Technology of China and High Magnetic Field Laboratory,Hefei Institutes of Physical Science,Chinese Academy of展开更多
The stability of anion exchange membranes（AEMs） is an important feature of alkaline exchange membrane fuel cells（AEMFCs）, which has been extensively studied. However it remains a real challenge due to the harsh wo...The stability of anion exchange membranes（AEMs） is an important feature of alkaline exchange membrane fuel cells（AEMFCs）, which has been extensively studied. However it remains a real challenge due to the harsh working condition. Herein, we developed a novel type of polysulfone-based AEMs with three modified 1,2-dimethylbenzimidazoliums containing different substitutes at C4-and C7-position. The results showed that the introduction of the substitutes could obviously improve the dimensional and alkaline stabilities of the corresponding membranes. The swelling ratios of resultant AEMs were all lower than 10% after water immersion. The membrane with 4,7-dimethoxy-1,2-dimethylbenzimidazolium group exhibited the highest alkaline stability. Only 9.2% loss of hydroxide conductivity was observed after treating the membrane in 1 mol·L^（-1） KOH solution at 80 °C for 336 h. Furthermore, the density functional theory（DFT） study on the three functional group models showed that the substitutes at C4-and C7-position affected the lowest unoccupied molecular orbital（LUMO） energies of the different 1,2-dimethylbenzimidazolium groups.展开更多
基金supported by the National Key Basic Research and Development(973)Project (2009CB421001)China Geological Survey (1212010661311)+1 种基金Ministry of Land and Resources (200811008)the Ministry of Education,Project 111 (B07011)
文摘The Chang＇an gold ore deposit in western Yunnan is located at the southern segment of the Ailaoshan metallogenic belt.The ore bodies are preserved in fractured Ordovician sedimentary clastic rocks.The gold-bearing minerals occur dominantly in sulfide-quartz veins.Fluid inclusion analysis shows that the Chang＇an gold ore deposit is characterized by epithermal gold mineralization at temperatures between 200℃and 280℃at a shallow crustal level.The mineralizing fluids have intermediate to low salinity（6%-18%） and low densities（0.72-1.27 g/cm^3）.The ore minerals haveδ^（34）S in a range from -13‰to 3.57‰,concentrated from -2.06‰to 3.57‰with an average of 1.55‰.The ^（206）Pb/^（204）Pb,^（207）Pb/^（204）Pb and ^（208）Pb/^（204）Pb values are 18.9977-19.5748,15.7093-15.784,39.3814-40.2004 respectively.These isotope data suggest that the ore-forming elements were mainly derived from mixed crustal and mantle sources.The Chang＇an gold ore deposit and Tongchang Cu-Mo deposit are closely related to each other in their spatial distribution and age of formation.They have similar sources of mineralizing elements and identical ore-forming metal elements,and show a close relationship in physical and chemical conditions of mineralization.The two deposits constitute an epithermal-porphyry -skarn type Cu-Mo-Au mineralization system in the Tongchang-Chang＇an area,which is related to the Cenozoic high-K alkaline magmatism.
文摘Subject Code:B01With the support by the National Natural Science Foundation of China,a creative study by the research group led by Prof.Chen Qianwang(陈乾旺)from the University of Science and Technology of China and High Magnetic Field Laboratory,Hefei Institutes of Physical Science,Chinese Academy of
基金financially supported by the National Natural Science Foundation of China (No. 21404018)Fundamental Research Funds for the Central Universities (No. DUT16RC(4)79)+2 种基金Education Department of the Liaoning Province (No. LT2015007)Fundamental Research Funds for the Central Universities (No. DUT16TD19)Chang Jiang Scholar Program (No. T2012049)
文摘The stability of anion exchange membranes（AEMs） is an important feature of alkaline exchange membrane fuel cells（AEMFCs）, which has been extensively studied. However it remains a real challenge due to the harsh working condition. Herein, we developed a novel type of polysulfone-based AEMs with three modified 1,2-dimethylbenzimidazoliums containing different substitutes at C4-and C7-position. The results showed that the introduction of the substitutes could obviously improve the dimensional and alkaline stabilities of the corresponding membranes. The swelling ratios of resultant AEMs were all lower than 10% after water immersion. The membrane with 4,7-dimethoxy-1,2-dimethylbenzimidazolium group exhibited the highest alkaline stability. Only 9.2% loss of hydroxide conductivity was observed after treating the membrane in 1 mol·L^（-1） KOH solution at 80 °C for 336 h. Furthermore, the density functional theory（DFT） study on the three functional group models showed that the substitutes at C4-and C7-position affected the lowest unoccupied molecular orbital（LUMO） energies of the different 1,2-dimethylbenzimidazolium groups.
