In order to analyze the influence of the addition of yttrium and manganese on the soot combustion performance and high temperature stability of CeO_(2) catalyst,a series of Y/Mn-modified CeO_(2) catalysts were prepare...In order to analyze the influence of the addition of yttrium and manganese on the soot combustion performance and high temperature stability of CeO_(2) catalyst,a series of Y/Mn-modified CeO_(2) catalysts were prepared.The effects of structural properties,textural properties,oxygen vacancies,Ce^(3+),surface adsorbed oxygen species,reduction properties and desorption properties of oxygen species on the activity were analyzed by various characterization methods.The results of the activity test show that the addition of manganese is beneficial to enhancement of the activity,while the addition of yttrium increases the amount of reactive oxygen species,but decreases the activity.After aging at 700℃,the activity of the CeMn catalyst decreases most sharply,while the catalytic activity of the CeY catalyst can be maintained to a certain extent.Interestingly,the addition of yttrium and manganese at the same time can stabilize the activity.The fundamental reason is that yttrium and manganese move to the surface of the solid solution after aging,which increases the reduction performance of the catalyst,thus contributing to the increase of activity.Although the activity of CeYMn catalyst decreases after aging at 800℃,it is still higher than that of other catalysts aged at 700℃.展开更多
随着可再生能源接入电网比例的逐步增大,热力发电厂需要应对更加频繁、更大范围的负荷变化,给电厂的高阶大惯性过热汽温过程的控制带来严峻的挑战。为此,文中针对一类高阶大惯性过热汽温过程,提出一种基于相位补偿的自抗扰控制(phase co...随着可再生能源接入电网比例的逐步增大,热力发电厂需要应对更加频繁、更大范围的负荷变化,给电厂的高阶大惯性过热汽温过程的控制带来严峻的挑战。为此,文中针对一类高阶大惯性过热汽温过程,提出一种基于相位补偿的自抗扰控制(phase compensation based active disturbance rejection control,PC-ADRC)方法。首先,阐述过热汽温系统的工作原理和控制难点。然后,采用低频近似法详细推导相位补偿(phase compensation,PC)网络模型,提出采用PC网络对模型动态特性进行补偿,得到等效降阶模型的简化思路。为便于工程应用,给出PC-ADRC系统的简单实现方法和等效模型分析。最后,对PC-ADRC系统的稳定性和鲁棒性进行研究。理论分析和仿真结果表明,所提出的PC-ADRC系统能有效提升高阶过程控制系统的鲁棒性和快速响应能力。展开更多
基金Project supported by the National Natural Science Foundation of China(21962021)the Yunnan Fundamental Research Projects(202001AU070121)+1 种基金the National Natural Science Foundation of China(51908091)the Special Basic Cooperative Research Programs of Yunnan Provincial Undergraduate Universities'Association(202101BA070001-084)。
文摘In order to analyze the influence of the addition of yttrium and manganese on the soot combustion performance and high temperature stability of CeO_(2) catalyst,a series of Y/Mn-modified CeO_(2) catalysts were prepared.The effects of structural properties,textural properties,oxygen vacancies,Ce^(3+),surface adsorbed oxygen species,reduction properties and desorption properties of oxygen species on the activity were analyzed by various characterization methods.The results of the activity test show that the addition of manganese is beneficial to enhancement of the activity,while the addition of yttrium increases the amount of reactive oxygen species,but decreases the activity.After aging at 700℃,the activity of the CeMn catalyst decreases most sharply,while the catalytic activity of the CeY catalyst can be maintained to a certain extent.Interestingly,the addition of yttrium and manganese at the same time can stabilize the activity.The fundamental reason is that yttrium and manganese move to the surface of the solid solution after aging,which increases the reduction performance of the catalyst,thus contributing to the increase of activity.Although the activity of CeYMn catalyst decreases after aging at 800℃,it is still higher than that of other catalysts aged at 700℃.
文摘为解决当前常用煤矿氧气检测仪器易受交叉气体干扰且功耗大的问题,基于GD32F303RCT6微控制器和ADN8834热电冷却控制器,设计了一种软启动开关电路控制的垂直腔面发射激光器(Vertical-cavity Surface-emitting Laser,VCSEL)高精度驱动及温控电路。驱动电路中,高频正弦波信号和低频锯齿波信号叠加的二进制数据由微控制器产生,经信号发生电路、电压电流转换电路转化成VCSEL高精度驱动电流信号;温控电路中,设计基于比例积分微分(Proportional Integral Differential,PID)补偿电路和数模转换控制器(Digital to Analog Converter,DAC)目标温度控制电路实现激光器温度自动调节。测试结果表明:驱动电路的电流输出区间为0.680~1.360 mA;锯齿波频率误差小于0.5%,正弦波频率误差小于0.1%;氧气吸收峰扫描精度高达0.07 pm,对应电流扫描精度为0.12μA;温控电路的温度控制精度为±0.012℃。满足了可调谐半导体激光吸收光谱(Tunable Diode Laser Absorption Spectroscopy,TDLAS)煤矿氧气检测应用需求。
文摘随着可再生能源接入电网比例的逐步增大,热力发电厂需要应对更加频繁、更大范围的负荷变化,给电厂的高阶大惯性过热汽温过程的控制带来严峻的挑战。为此,文中针对一类高阶大惯性过热汽温过程,提出一种基于相位补偿的自抗扰控制(phase compensation based active disturbance rejection control,PC-ADRC)方法。首先,阐述过热汽温系统的工作原理和控制难点。然后,采用低频近似法详细推导相位补偿(phase compensation,PC)网络模型,提出采用PC网络对模型动态特性进行补偿,得到等效降阶模型的简化思路。为便于工程应用,给出PC-ADRC系统的简单实现方法和等效模型分析。最后,对PC-ADRC系统的稳定性和鲁棒性进行研究。理论分析和仿真结果表明,所提出的PC-ADRC系统能有效提升高阶过程控制系统的鲁棒性和快速响应能力。
