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Evaluation and Selection of High Biomass Rice (<i>Oryza sativa L.</i>) for Drought Tolerance 被引量:2
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作者 Aditi Kondhia Rodante Escleto Tabien Amir Ibrahim 《American Journal of Plant Sciences》 2015年第12期1962-1972,共11页
Biomass production is important in increasing yield not only for food but also for bio-fuel production that depends on high dry matter. Due to climate change, occurrence of drought may be prevalent and this affects bo... Biomass production is important in increasing yield not only for food but also for bio-fuel production that depends on high dry matter. Due to climate change, occurrence of drought may be prevalent and this affects both grain and biomass yields in crops including rice. The objectives of this study were to determine the performance of selected high biomass breeding rice lines to different levels of drought and use several drought tolerance indices to identify best genotypes that could be grown in unfavorable water stressed areas. A rainfed and flooded trial was conducted to evaluate 20 selected breeding lines for biomass production and ten entries from the same set were grown in the greenhouse at three different field capacities (FC, 50%, 75%, 100%). Most of the genotypes performed well under non-stressed conditions (flooded and 100% FC) but some genotypes performed well in water stressed condition. The plants had lower plant height, tiller plant-1, and total biomass at maturity under rainfed conditions and their flowering was delayed compared to flooded conditions. In the greenhouse, water stress slowed the rate of increase in height, and produced lower shoot and root weight, percent dry matter (% DM) and total biomass. However, drought enhanced the rate of tiller production. Two genotypes were found to more tolerant to drought stress and could be used for cultivation under water stress condition to get optimum biomass yields. These genotypes can be identified using drought tolerance indices, particularly stress tolerance index (STI), geometric mean productivity (GMP), mean productivity (MP) and harmonic mean (HARM), as these have a similar ability to separate drought sensitive and tolerant genotypes. Genetic and molecular analyses, and detailed characterization of these genotypes will help understand their inheritance pattern and the number of genes controlling the traits and determine specific leaves and root traits important in developing high biomass rice. 展开更多
关键词 high biomass RICE Water Stress Selection Indices
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“双碳”背景下废弃生物质的高值化利用研究
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作者 邵俊 郭丰艳 +2 位作者 刘建朋 包坤 郝斌 《山东化工》 CAS 2024年第2期232-235,238,共5页
以废弃棉花秸秆为原料,在500℃下热解制备了棉花秸秆活性炭(CSAC),并研究了对亚甲基蓝和酸性品红的吸附特性。同时,以CSAC为载体,采用水热法制备ZnO/CSAC,并初步探索其光催化特性。结果表明:室温下,投加量为6,25 g/L,吸附60,90 min时,C... 以废弃棉花秸秆为原料,在500℃下热解制备了棉花秸秆活性炭(CSAC),并研究了对亚甲基蓝和酸性品红的吸附特性。同时,以CSAC为载体,采用水热法制备ZnO/CSAC,并初步探索其光催化特性。结果表明:室温下,投加量为6,25 g/L,吸附60,90 min时,CSAC对200 mg/L模拟亚甲基蓝和酸性品红废水的脱色率分别为99.66%和78.20%。对两种染料的吸附过程都更符合准二级动力学,受化学吸附控制,且为放热过程。可见光照射下,ZnO/CSAC的投加量为1 g/L,2 h时对200 mg/L亚甲基蓝的降解率可以达到91.20%。ZnO/CSAC中纳米ZnO呈二维片状组装成绒球状长在CSAC表面,活性反应点位增多,光催化性能良好。 展开更多
关键词 废弃生物质 高值化 染料 光催化
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铁精矿内配某生物质高温高压热解及其还原行为研究
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作者 黄柱成 李屹鑫 舒阳 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第3期860-870,共11页
以生物质为还原剂,在温度为1 040℃、压力为30 kPa下对铁精矿内配生物质热解气化及其还原行为进行研究。研究结果表明:初期热解产生了酚类等大分子碳氢氧化合物液相,并与铁精矿形成了焦油包裹体,显著迟滞了生物质挥发分的释放;外配水和... 以生物质为还原剂,在温度为1 040℃、压力为30 kPa下对铁精矿内配生物质热解气化及其还原行为进行研究。研究结果表明:初期热解产生了酚类等大分子碳氢氧化合物液相,并与铁精矿形成了焦油包裹体,显著迟滞了生物质挥发分的释放;外配水和铁精矿中的晶格氧促进了大分子碳氢氧化合物逐步氧化为酮类、酸类化合物,并最终转化为CO和H_(2)等还原性气体;铁精矿还原生成了铁晶须,部分形成了碳铁化合物,实现了铁氧化物的高效快速还原,入炉50 min时,金属化率达96.72%。 展开更多
关键词 生物质 高温 高压 热解 直接还原
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高值化等鞭金藻固碳研究进展
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作者 蔡楠 方静平 +1 位作者 陈必链 何勇锦 《生物技术通报》 CAS CSCD 北大核心 2024年第6期68-80,共13页
工业生产和人类活动释放的大量CO2是造成全球性气候变暖的主要诱因。气候变暖往往伴随着极端恶劣天气的发生,对人类的生活、财产和基础设施构成严重威胁。为了减轻由此产生的负面影响和应对全球变暖,各国纷纷设定了碳达峰和碳减排目标,... 工业生产和人类活动释放的大量CO2是造成全球性气候变暖的主要诱因。气候变暖往往伴随着极端恶劣天气的发生,对人类的生活、财产和基础设施构成严重威胁。为了减轻由此产生的负面影响和应对全球变暖,各国纷纷设定了碳达峰和碳减排目标,并致力于对CO2进行固定和资源化利用。海洋等鞭金藻(Isochrysis galbana)具有生长速度快和固碳效率高的特点,集成废/污水处理和生物固碳,转化合成蛋白质、多不饱和脂肪酸等多种高值生物活性物质的等鞭金藻固碳技术,被认为是最有前途的碳捕获和资源高值化利用的技术之一。本文首先介绍和比较了常用的CO2捕获技术的优缺点,强调基于等鞭金藻的碳捕获技术的适用范围和固碳效率的优势。其次阐明了海洋等鞭金藻光合固碳机制及其与卡尔文循环、三羧酸循环等代谢通路的联系;探讨光和CO2对微藻固碳能力和胞内碳流分布的影响,探究培养条件、光生物反应器、基因工程/合成生物学技术改造藻株等影响等鞭金藻固碳效率的因素。最后,概述了等鞭金藻光合固碳与岩藻黄素、多不饱和脂肪酸、蛋白质等高值生物活性物质合成的关系,为精深加工、开发高值化等鞭金藻提供理论和实践依据,推动等鞭金藻固碳技术的发展和应用,协同推进节能减排,为助力实现“双碳”目标提供一条经济可行的新策略。 展开更多
关键词 碳中和 等鞭金藻 固碳 高值化生物质 碳代谢 效率 生物活性成分
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木质素光催化解聚研究进展
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作者 赵锡润 王丽云龙 +1 位作者 刘月 吕高金 《现代化工》 CAS CSCD 北大核心 2024年第2期42-46,共5页
综述了近年来用于木质素解聚的光催化剂种类,分析了木质素光催化解聚机理及策略,还对光催化与多种技术耦合的解聚方法进行了介绍,并展望了木质素光催化解聚研究领域所面临的挑战及发展方向。
关键词 生物质 木质素 解聚 光催化 高值化利用
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烟草废弃物资源综合利用研究进展
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作者 陈芊如 孟娜 +3 位作者 马斯琦 任婷婷 李义强 杜秀春 《江西农业学报》 CAS 2024年第1期146-153,共8页
在我国每年的烟叶种植与生产过程中可产生大量田间废弃物,如不加以处理不仅会严重威胁烟田生态环境,还会导致烟叶减产,因此,开展烟叶废弃物科学高效的资源化利用研究对烟草行业及其相关行业的可持续发展有着重要意义。综述了近些年高效... 在我国每年的烟叶种植与生产过程中可产生大量田间废弃物,如不加以处理不仅会严重威胁烟田生态环境,还会导致烟叶减产,因此,开展烟叶废弃物科学高效的资源化利用研究对烟草行业及其相关行业的可持续发展有着重要意义。综述了近些年高效利用烟草废弃物的主要途径及相关研究进展,包括茄尼醇、烟碱等高值化合物的提取和利用,有机堆肥的制备,生物质燃料制取,活性炭、纤维板和刨花板的制造等,旨在挖掘烟草剩余资源潜能并拓展其使用范围,以期实现烟草多用途高值利用的利益最大化,并推动烟草产业的健康发展。 展开更多
关键词 烟叶废弃物 资源利用 高值化合物 有机堆肥 生物质燃料
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重组亚胺还原酶工程菌快速高密度发酵研究
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作者 吴子蓥 李荣旭 +3 位作者 白少钰 胡浩轩 黄佳俊 卢宇靖 《食品与发酵工业》 CAS CSCD 北大核心 2024年第3期16-20,共5页
通过快速高密度发酵培养,以重组亚胺还原酶大肠杆菌工程菌的菌体生物量及酶活力作为评价标准,利用低成本的发酵培养基,在短时间内获得菌体的最大生物量和最佳酶活力。采用2 L发酵体系,对该工程菌的接种量和诱导条件进行优化。结果表明,... 通过快速高密度发酵培养,以重组亚胺还原酶大肠杆菌工程菌的菌体生物量及酶活力作为评价标准,利用低成本的发酵培养基,在短时间内获得菌体的最大生物量和最佳酶活力。采用2 L发酵体系,对该工程菌的接种量和诱导条件进行优化。结果表明,该菌株的快速高密度发酵最佳接种量为10%,当生物量OD_(600)值达到12时,发酵体系降温至20℃,加入0.4 mmol/L异丙基-β-D-硫代半乳糖苷,为最佳诱导条件,并以此条件进行20 L快速高密度发酵,诱导12 h酶活力最高,为4.56 U/g。该研究为进一步放大发酵体系以实现亚胺还原酶工业化快速高产量制备的生产奠定基础。 展开更多
关键词 亚胺还原酶 大肠杆菌 高密度发酵 生物量 酶活力
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生物质电厂灰作高性能混凝土掺合料的试验分析
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作者 唐宁 王正君 +1 位作者 乔伟毅 尹博鑫 《广东建材》 2024年第4期19-22,共4页
生物质电厂灰获取便利且具有一定火山灰活性。为测试生物质电厂灰作高性能混凝土掺合料的可行性和性能影响,本文对生物质电厂灰进行了理化特性分析,对灰样进行了预处理,制备了10%,20%和30%掺量的高性能混凝土试块进行了抗压强度试验和... 生物质电厂灰获取便利且具有一定火山灰活性。为测试生物质电厂灰作高性能混凝土掺合料的可行性和性能影响,本文对生物质电厂灰进行了理化特性分析,对灰样进行了预处理,制备了10%,20%和30%掺量的高性能混凝土试块进行了抗压强度试验和抗氯离子渗透性能测试,结果表明以处理后的生物质电厂灰作高性能混凝土的掺合料,随掺量增加,高性能混凝土试块抗压能力减小,但总体满足强度要求;掺入生物质电厂灰可以提高高性能混凝土抗氯离子侵蚀能力。 展开更多
关键词 生物质 电厂灰 高性能混凝土 废料利用
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生物质热解动力学模型研究进展
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作者 李亮 朱一萍 廖玉河 《能源环境保护》 2024年第2期67-80,共14页
生物质是地球上最丰富的可再生碳资源之一,在实现“双碳”战略目标方面扮演着重要作用。生物质热解是一项极具前景的生物质利用技术,其中热解形成的生物油有望取代传统化石能源,用于生产高值燃料或化学品。然而,生物质热解是一个十分复... 生物质是地球上最丰富的可再生碳资源之一,在实现“双碳”战略目标方面扮演着重要作用。生物质热解是一项极具前景的生物质利用技术,其中热解形成的生物油有望取代传统化石能源,用于生产高值燃料或化学品。然而,生物质热解是一个十分复杂的过程,该过程及热解产物分布受诸多因素影响。因此,发展生物质热解动力学模型对指导热解工艺生产十分重要。动力学模型的研究不仅可以揭示热解过程中所涉及的物理化学变化,还可以预测热解反应速率及主要产物分布。早期构建的全局动力学模型为热解机理的理解与更详细模型的发展奠定了基础。随着生物质热解的主要研究目标由最大化生物油产量转变为最大化高附加值化学品产量,包含更多热解机理信息和可预测更多单个产物产率的半详细和详细动力学模型开始出现。主要介绍了生物质热解动力学模型的研究现状,将动力学模型分为全局模型、半详细模型和详细模型,并对未来生物质热解动力学研究及详细模型的发展进行了展望。 展开更多
关键词 生物质 热解 动力学模型 高附加值
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生物质电厂高温输灰方案比较
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作者 邓飞飞 张凯 +1 位作者 仇学伟 蔡凌飞 《工程建设与设计》 2024年第11期101-103,共3页
概述气力输灰设备以及生物质电厂灰的特点,结合实际工程案例对仓泵直接气力输送和先用水冷刮板冷却再通过罗茨风机气力输送的两种输灰方案进行了对比。综合两种方案,建议以后新建项目采用稀相气力输送直接输送高温灰。
关键词 生物质电厂 高温灰 输灰
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生物质定向热解制备高附加值化学品研究进展
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作者 武刚 肖睿 张会岩 《能源环境保护》 2024年第2期43-56,共14页
石油化工产品是制备众多生活和生产用品,如化妆品、润滑油、塑料制品、合成纤维等的原材料,这使得人类对以石油为原料生产的各种化学品的依赖非常严重。基于此,以可再生生物质为原料生产高附加值平台化学品受到了广泛关注。生物质定向... 石油化工产品是制备众多生活和生产用品,如化妆品、润滑油、塑料制品、合成纤维等的原材料,这使得人类对以石油为原料生产的各种化学品的依赖非常严重。基于此,以可再生生物质为原料生产高附加值平台化学品受到了广泛关注。生物质定向热解可选择性地制备多种高附加值平台化学品,已成为目前全球研究的前沿和热点。对生物质定向热解制备多种常见的高附加值化学品进行了系统地概述,首先总结了热解原料、热解方式、预处理方式、反应温度、反应时间、催化剂等条件对目标高附加值产物的影响规律,然后分析了生物质定向热解制备目标产物的反应路径,最后对生物质定向热解制备平台化学品的未来发展方向进行了展望,为生物质的高效转化利用提供一定的依据和借鉴。 展开更多
关键词 生物质 定向热解 催化转化 高值化学品 反应机理
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A new horizontal in C1 chemistry: Highly selective conversion of syngas to light olefins by a novel OX-ZEO process 被引量:1
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作者 Ye Wang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2016年第2期167-168,共2页
The most challenging goal of C1 chemistry is the control of C–C coupling to produce chemicals or fuels from C1 feedstocks,in particular syngas(H2/CO),which can be derived from various carbon resources such as coal,... The most challenging goal of C1 chemistry is the control of C–C coupling to produce chemicals or fuels from C1 feedstocks,in particular syngas(H2/CO),which can be derived from various carbon resources such as coal,natural gas or shale gas,and biomass. 展开更多
关键词 challenging propylene chemicals shale highly biomass selectivity hydrocarbons currently naphtha
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Corrosion Behavior of TP316L of Superheater in Biomass Boiler with Simulated Atmosphere and Deposit 被引量:11
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作者 印佳敏 吴占松 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2009年第5期849-853,共5页
Corrosion behavior of TP316L was investigated with simulated atmosphere and ash deposition for the superheater in biomass boiler.Corrosion dynamic curves were plotted by mass gain.The results showed that the corrosion... Corrosion behavior of TP316L was investigated with simulated atmosphere and ash deposition for the superheater in biomass boiler.Corrosion dynamic curves were plotted by mass gain.The results showed that the corrosion was dependent on temperature and was greatly accelerated by ash deposition.The mass gain was distinctly reduced in the presence of SO2 with and without ash deposition on the specimens.Corrosion rates with ash deposit at different temperatures were calculated.Two feasible methods were provided to avoid serious high-temperature corrosion in the biomass boiler. 展开更多
关键词 腐蚀行为 生物质 过热器 模拟 锅炉 存款 大气 调查结果
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Growth traits and nitrogen assimilation-associated physiological parameters of wheat(Triticum aestivum L.) under low and high N conditions 被引量:5
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作者 ZHANG Fei-fei GAO Si +3 位作者 ZHAO Yuan-yuan ZHAO Xiao-lei LIU Xiao-man XIAO Kai 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2015年第7期1295-1308,共14页
In this study, 14 wheat cultivars with contrasting yield and N use efficiency (NUE) were used to investigate the agronomic and NUE-related traits, and the N assimilation-associated enzyme activities under low and hi... In this study, 14 wheat cultivars with contrasting yield and N use efficiency (NUE) were used to investigate the agronomic and NUE-related traits, and the N assimilation-associated enzyme activities under low and high N conditions. Under deficient-N, the cultivars with high N uptake efficiency (UpE) and high N utilization efficiency (UtE) exhibited higher plant biomass, yields, and N contents than those with medium and low NUEs. The high UpE cultivars accumulated more N than other NUE type cultivars. Under sufficient-N, the tested cultivars showed similar patterns in biomass, yield, and N content to those under deficient-N, but the varietal variations in above traits were smaller. In addition, the high UpE cultivars displayed much more of root biomass and larger of root length, surface area, and volume than other NUE type cultivars, indicating that the root morphological traits under N deprivation are closely associated with the plant biomass through its improvement of the N acquisition. The high UtE cultivars showed higher activities of nitrate reductase (NR), nitrite reductase (NIR), and gluta- mine synthetase (GS) at stages of seediling, heading and filling than other NUE type cultivars under both low and high N conditions. Moreover, the high UpE and UtE cultivars also displayed higher photosynthetic rate under deficient-N than the medium and low NUE cultivars. Together, our results indicated that the tested wheat cultivars possess dramatically genetic variations in biomass, yield, and NUE. The root morphological traits and the N assimilation enzymatic acitivities play critical roles in regulating N accumulation and internal N translocation under the N-starvation stress, respectively. They can be used as morphological and biochemical references for evaluation of UpE and UtE in wheat. 展开更多
关键词 wheat (Triticum aestivum L.) low and high N biomass yield nitrogen use efficiency root morphological traits N assimilzation-associated enzyme photosynthetic rate
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Sweet Sorghum Genotypes Testing in the High Latitude Rainfed Steppes of the Northern Kazakhstan (for Feed and Biofuel)
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作者 Rauan Zhapayev Kulyash Iskandarova +12 位作者 Kristina Toderich Irina Paramonova Abdullah Al-Dakheel Shoaib Ismail Srinivasa Rao Pinnamaneni Aiman Omarova Nina Nekrasova Darhan Balpanov Oleg Ten Erlan Ramanculov Yuriy Zelenskiy Aigul Akhmetova Muratbek Karabayev 《Journal of Environmental Science and Engineering(B)》 2015年第1期25-30,共6页
关键词 哈萨克斯坦 基因型检测 饲料产品质量 高纬度地区 甜高粱 生物燃料 草原 旱地
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Microorganisms in Small Patterned Ground Features and Adjacent Vegetated Soils along Topographic and Climatic Gradients in the High Arctic, Canada 被引量:1
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作者 Grizelle González Francisco J. Rivera-Figueroa +2 位作者 William A. Gould Sharon A. Cantrell José R. Pérez-Jiménez 《Open Journal of Soil Science》 2014年第1期47-55,共9页
In this study, we determine differences in total biomass of soil microorganisms and community structure (using the most probable number of bacteria (MPN) and the number of fungal genera) in patterned ground features (... In this study, we determine differences in total biomass of soil microorganisms and community structure (using the most probable number of bacteria (MPN) and the number of fungal genera) in patterned ground features (PGF) and adjacent vegetated soils (AVS) in mesic sites from three High Arctic islands in order to characterize microbial dynamics as affected by cryoturbation, and a broad bioclimatic gradient. We also characterize total biomass of soil microorganisms and the most probable number of bacteria along a topographic gradient within each bioclimatic subzone to evaluate whether differences in topography lead to differences in microbial dynamics at a smaller scale. We found total microbial biomass C, the most probable number of heterotrophic bacteria, and fungal genera vary along this bioclimatic gradient. Microbial biomass C decreased with increasing latitude. Overall, microbial biomass C, MPN and the number of fungal isolates were higher in AVS than in PGFs. The effects which topographic position had on microbial biomass C varied across the bioclimatic gradient as there was no effect of topographic position in Isachsen (subzone A) and Mould Bay (subzone B), when compared to Green Cabin (subzone C, warmer site).There was no effect of topographic position on MPN counts at Mould Bay and Green Cabin. However, in Isachsen, MPN counts were highest in the wet topographic position as compared to the mesic and dry. In conclusion, PGFs seem to decouple the effect climate that might have on the total biomass of soil microorganisms along the bioclimatic gradient;and influence gets ameliorated as latitude increases. Similarly, the effect of topography on the total microbial biomass is significant at the warmest bioclimatic zone of the gradient. Thus, climate and topographic effects on total microbial biomass increase with warmer climate. 展开更多
关键词 Soil MICROORGANISMS high Artic CANADA Patterned FEATURES MICROBIAL biomass
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Study of Alkali Metal Corrosion on Heating Surfaces and Bed Material Agglomerate in Biomass-fired Fluidized Bed Boiler
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作者 Tuo Chen Yanfen Liao +2 位作者 Shumei Wu Xiaoqian Ma Jinghui Song 《Energy and Power Engineering》 2013年第4期6-14,共9页
The bed material agglomeration and heating surface high-temperature Corrosion Problems of biomass-fired boiler in South China were studied in this work. The inner and outer surfaces of the corrosion sample were invest... The bed material agglomeration and heating surface high-temperature Corrosion Problems of biomass-fired boiler in South China were studied in this work. The inner and outer surfaces of the corrosion sample were investigated by scanning electron microscope (SEM) with Bruker EDX and XRD. Results showed that the outer side of the corrosion sample was mainly composed of alkali chloride deposited ash, sulphide and a small amount of eutectoid;while the inner side of the corrosion sample was still mainly made up of the composition of SUS316, but added with alkali metal, oxygen, chlorine and sulphur elements, appearing as the corrosion products and eutectoid. It was thought that alkali chloride deposit and the reaction with pipe metal to generate low melting point eutectoid on the outer surfaces, or the corrosion reaction through the alkali metal sulphatization process was the main reasons leading to the damage of metal surface oxide film. Chlorine plays a role as haptoreaction in the corrosion process, and transports metal material as the form of chloride from the inner side to the outer side of the pipe surfaces by diffusion, accelerating the corrosion process. Meanwhile, the slag was studied by scanning electron microscope (SEM) with Bruker EDX, and the transformation process of slage was computationally analyzed by FACTSAGE. Results showed that the amount of alkali metal in the agglomerates was little, however, caused a great impact on severe agglomerates. The increase of temperature enhanced the conversion process of alkali metal to molten oxide, especially when the temperature was higher than760℃, the amount of molten product increased sharply. Thus, the temperature control of fluidized bed plays an important role in solving the problem of alkali metal agglomerates;it also reliefs the volatile of alkali metal into gas phase, benefiting the control of heating surface corrosion. 展开更多
关键词 biomass COMBUSTION GENERATION high Temperature CORROSION AGGLOMERATE ALKALI Metal
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微波辅助炭基催化剂催化热解生物质的研究进展 被引量:1
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作者 李攀 胡秋辉 +4 位作者 胡俊豪 陈志勇 张永胜 方书起 常春 《工程科学学报》 EI CSCD 北大核心 2023年第9期1592-1601,共10页
炭基催化剂具有制备成本低、催化后处理简单等优点,但存在易积碳失活、产物选择性低等缺点,结合微波效应,可明显提高炭基催化剂的竞争力.本文对微波辅助炭基催化剂热解生物质的研究进展进行了现状综述.主要介绍了微波加热原理,吸波剂和... 炭基催化剂具有制备成本低、催化后处理简单等优点,但存在易积碳失活、产物选择性低等缺点,结合微波效应,可明显提高炭基催化剂的竞争力.本文对微波辅助炭基催化剂热解生物质的研究进展进行了现状综述.主要介绍了微波加热原理,吸波剂和催化剂对于微波热解的影响机制.分析了不同改性方法(金属负载法、化学法、磺化等)对炭基催化剂的孔隙结构、含氧官能团和酸性基团及催化反应产物特性的影响.总结了微波辅助改性炭基催化剂在焦油重整和改善生物质热解产物特性等方面的应用进展.本文对该研究方向存在的问题提出建议并进行展望,为基于微波催化热解作用下炭基催化剂的选择、改性和生物质高值化利用提供一定的参考. 展开更多
关键词 炭基催化剂 生物质 微波催化热解 改性 高值化利用
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改性HZSM-5催化玉米秸秆与HDPE共热解制轻质芳烃
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作者 李延吉 赵明 +1 位作者 李明泽 宋瑞雯 《太阳能学报》 EI CAS CSCD 北大核心 2023年第4期238-246,共9页
为提高生物质与聚乙烯共热解中苯、甲苯、乙苯、二甲苯和萘(简称)BTEXN和轻烯烃的产量,同时抑制C^(+)_(21)蜡的形成,通过TG-MS/FTIR和Py-GC/MS探究催化共热解中HZSM-5和改性HZSM-5对玉米秸秆和HDPE相互作用的影响,并对BTEXN进行定量分... 为提高生物质与聚乙烯共热解中苯、甲苯、乙苯、二甲苯和萘(简称)BTEXN和轻烯烃的产量,同时抑制C^(+)_(21)蜡的形成,通过TG-MS/FTIR和Py-GC/MS探究催化共热解中HZSM-5和改性HZSM-5对玉米秸秆和HDPE相互作用的影响,并对BTEXN进行定量分析。结果表明,在HZSM-5的催化共热解中,HZSM-5可促进玉米秸秆与HDPE之间的相互反应,芳烃和轻烃产率增加。相比HZSM-5,在改性HZSM-5的催化共热解中,改性HZSM-5可促进轻烯烃、C_(5)-C_(11)脂肪烃和芳烃的析出,并抑制C^(+)_(21)蜡的形成。Cu、Fe和Ce改性可促进单环芳烃的形成,同时提高BTEXN产量,相比HZSM-5分别提高20.99、25.43和20.89 mg/g,而P改性会抑制BTEXN形成。对于形成芳烃的Diels-Alder反应,Fe和Ce改性表现出较强的催化效果,而Cu改性对烃池反应催化效果较强。此外积碳分析表明,Fe和P改性具有较强的抗积碳能力。 展开更多
关键词 生物质 高密度聚乙烯类 热解 BTEXN HZSM-5
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高比表面积生物质多孔碳的制备及其电化学性能
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作者 金小青 汪秀雯 马志虎 《化工新型材料》 CAS CSCD 北大核心 2023年第5期249-254,共6页
以玉米秸秆为碳源(CS),经Na2CO3溶液浸泡预处理后,采用KOH活化,制备了多孔生物质碳材料(CS-ACs)。通过形貌、结构表征及电化学性能测试,发现生物质碳材料CS-AC-3具备多级孔道结构,比表面积可达3299m^(2)/g。三电极体系下,该材料在6mol/L... 以玉米秸秆为碳源(CS),经Na2CO3溶液浸泡预处理后,采用KOH活化,制备了多孔生物质碳材料(CS-ACs)。通过形貌、结构表征及电化学性能测试,发现生物质碳材料CS-AC-3具备多级孔道结构,比表面积可达3299m^(2)/g。三电极体系下,该材料在6mol/L NaOH和0.5mol/L Na_(2)SO_(4)电解液中,1A/g电流密度下,比电容分别为272F/g、220F/g,循环5000圈后(5A/g),其容量保持率为89%和80%;二电极体系中,以该材料组装的CS-AC-3//CS-AC-3对称电容器具有1.4V的宽电压窗口和较好的电容特性。作为一种可再生廉价碳材料,CS-ACs在实际应用中有好的应用前景。 展开更多
关键词 玉米秸秆 生物质碳 高比表面积 电容特性
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