High boron bearing steel, in which boron homogeneously distributed, wassuccessfully produced in the vacuum induction furnace. The microstructural observations of cast andhot rolled steels showed that the addition of t...High boron bearing steel, in which boron homogeneously distributed, wassuccessfully produced in the vacuum induction furnace. The microstructural observations of cast andhot rolled steels showed that the addition of titanium can eliminate the quantity of ferrous boridesprecipitated at the grain boundaries and break the net microstructure, as a result, its hotworkability is improved. The titanium boride TiB_2 homogeneously distributes in the matrix ofalpha-Fe. The parameters of hot rolling process, including preheated temperature, initial rollingtemperature, finished rolling temperature and the total deformation, have been optimized.展开更多
The effect of different tempering temperatures on the microstructure and mechanical properties of airquenched high boron white cast iron was studied.The results indicate that the high boron white cast iron comprises d...The effect of different tempering temperatures on the microstructure and mechanical properties of airquenched high boron white cast iron was studied.The results indicate that the high boron white cast iron comprises dendritic matrix and inter-dendritic M 2 B boride;and the matrix comprises martensite and pearlite.After quenching in the air,the matrix is changed into lath martensite;but only 1-μm-size second phase exists in the matrix.After tempering,another second phase of several tens of nanometers is found in the matrix,and the size and quantity increase with an increase in tempering temperature.The two kinds of second precipitation phase with different sizes in the matrix have the same chemical formula,but their forming stages are different.The precipitation phase with larger size forms during the austenitizing process,while the precipitation phase with smaller size forms during the tempering process.When tempered at different temperatures after quenching,the hardness decreases with an increase in the tempering temperature,but it increases a little at 450 ℃ due to the precipitation strengthening effect of the second phase,and it decreases greatly due to the martensite decomposition above 450 ℃.The impact toughness increases a little when tempered below 300 ℃,but it then decreases continuously owing to the increase in size and quantity of the secondary precipitate above 300 ℃.Considered comprehensively,the optimum tempering temperature is suggested at 300 ℃ to obtain a good combination of hardness and toughness.展开更多
Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitrid...Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitride films are limited to the size of growth chamber, which indicates a lower production efficiency. In this paper, the utilization efficiency of growth chamber is highly improved by alternately stacking multiple pieces of Cu foils and carbon fiber surface felt with porous structure. Uniform and continuous hexagonal boron nitride films are prepared on Cu foils through chemical vapor deposition utilizing ammonia borane as the precursor. This work develops a simple and practicable method for high-throughput preparation of hexagonal boron nitride films, which could contribute to the industrial application of hexagonal boron nitride. .展开更多
Influences of the tempering temperature on the microstructure, mechanical property and wear resistance of High-Boron High Speed Steel (HBHSS) roll materials were investigated by means of optical microscopy, scanning e...Influences of the tempering temperature on the microstructure, mechanical property and wear resistance of High-Boron High Speed Steel (HBHSS) roll materials were investigated by means of optical microscopy, scanning electron microscopy (SEM), X-ray diffraction, hardness measurement, impact tester, tensile tester and pin abrasion tester. The results show that the as-cast structure of HBHSS consists of a great amount of martensite and M2(B,C) and a few retained austenites and M23(B,C)6. After solution treated at 1,050 °C and followed by oil cooling, the amount of M23(B,C)6 carbo-borides in quenched HBHSS increases obviously and the macrohardness of the quenched HBHSS is 66 HRC, which is very close to the 65.8 HRC of as-cast HBHSS. On the whole, the hardness of HBHSS alloy shows a trend of slight decrease with increasing tempering temperature when tempered below 500 °C. While when above 500 °C, the hardness increases slightly as the tempering temperature increases and reaches a peak at 525 °C and then decreases obviously. The impact toughness of HBHSS has a tendency to increase as the tempering temperature increases. Tempering can improve the tensile strength and elongation of HBHSS, but a higher tempering temperature causes a slight decrease in both tensile strength and elongation. Excellent wear resistance can be obtained by tempering at 500 to 550 °C.展开更多
High-temperature mechanical properties of high-boron austenitic steels(HBASs) were studied at 850 °C using a dynamic thermal-mechanical simulation testing machine. In addition, the thermal fatigue properties of t...High-temperature mechanical properties of high-boron austenitic steels(HBASs) were studied at 850 °C using a dynamic thermal-mechanical simulation testing machine. In addition, the thermal fatigue properties of the alloys were investigated using the self-restraint Uddeholm thermal fatigue test, during which the alloy specimens were cycled between room temperature and 800°C. Stereomicroscopy and scanning electron microscopy were used to study the surface cracks and cross-sectional microstructure of the alloy specimens after the thermal fatigue tests. The effects of carbon content on the mechanical properties at room temperature and high-temperature as well as thermal fatigue properties of the HBASs were also studied. The experimental results show that increasing carbon content induces changes in the microstructure and mechanical properties of the HBASs. The boride phase within the HBAS matrix exhibits a round and smooth morphology, and they are distributed in a discrete manner. The hardness of the alloys increases from 239(0.19 wt.% C) to 302(0.29 wt.% C) and 312 HV(0.37 wt.% C); the tensile yield strength at 850 °C increases from 165.1 to 190.3 and 197.1 MPa; and the compressive yield strength increases from 166.1 to 167.9 and 184.4 MPa. The results of the thermal fatigue tests(performed for 300 cycles from room temperature to 800 °C) indicate that the degree of thermal fatigue of the HBAS with 0.29 wt.% C(rating of 2–3) is superior to those of the alloys with 0.19 wt.%(rating of 4–5) and 0.37 wt.%(rating of 3–4) carbon. The main cause of this difference is the ready precipitation of M23(C,B)6-type borocarbides in the alloys with high carbon content during thermal fatigue testing. The precipitation and aggregation of borocarbide particles at the grain boundaries result in the deterioration of the thermal fatigue properties of the alloys.展开更多
The fracture behaviour and morphologies of high-strength boron steel were investigated at different temperatures at a constant strain rate of 0.1 s-1 based on isothermal tensile tests. Fracture mechanisms were also an...The fracture behaviour and morphologies of high-strength boron steel were investigated at different temperatures at a constant strain rate of 0.1 s-1 based on isothermal tensile tests. Fracture mechanisms were also analyzed based on the relationship between microstructure transformation and continuous cooling transformation(CCT) curves. It is found that 1) fractures of the investigated steel at high temperatures are dimple fractures; 2) the deformation of high-strength boron steel at high temperatures accelerates diffusion transformations; thus, to obtain full martensite, a higher cooling rate is needed; and 3) the investigated steel has the best plasticity when the deformation temperature is 750 °C.展开更多
In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental...In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental results indicate that the boron alloyed high silicon cast steel comprises a dendritic matrix and interdendritic eutectic borides in as-cast condition. The dendritic matrix is made up of pearlite, ferrite, and the interdendritic eutectic boride is with a chemical formula of M2B (M represents Fe, Cr, Mn or Mo) which is much like that of carbide in high chromium white cast iron. Pure ausferrite structure that consists of bainitic ferrite and retained austenite can be obtained in the matrix by austempering treatment to the cast steel. No carbides precipitate in the ausferrite structure and the morphology of borides remains almost unchanged after austempering treatments. Secondary boride particles precipitate during the course of austenitizing. The hardness and tensile strength of the austempered cast steel decrease with the increase of the austempering temperature, from 250 oC to 400 oC. The impact toughness is 4-11 J?cm-2 at room temperature and the impact展开更多
The preparation process of amorphous nanometer boron powders through combustion synthesis was investigated, and the effects of the reactant ratio, the heating agent and the milling rate on the activity and particle si...The preparation process of amorphous nanometer boron powders through combustion synthesis was investigated, and the effects of the reactant ratio, the heating agent and the milling rate on the activity and particle size of amorphous boron powders were studied. The results show that the boron powders exist in the form of an amorphous phase which has the crystallinity lower than 30.4%, and the particle size of boron powder decreases with an increase of the high-energy ball milling rate. The purity of amorphous boron powder is 94.8% and particle sizes are much smaller than 100 nm when the mass ratio of B2O3/Mg/KClO3 is 100:105:17 and the ball milling time is 20 min with the milling rate of 300 r/min. At the same time, the amorphous boron nano-fibers appear in the boron powders.展开更多
The delayed fracture behavior of medium carbon high strength spring steel containing different amounts of boron (0. 000 5%, 0. 001 6 %) was studied using sustained load delayed fracture test. The results show that d...The delayed fracture behavior of medium carbon high strength spring steel containing different amounts of boron (0. 000 5%, 0. 001 6 %) was studied using sustained load delayed fracture test. The results show that delayed fracture resistance of boron containing steels is higher than that of conventional steel 60Si2MnA at the same strength level and it increases with the increase of boron eontent from 0. 000 5% to 0. 001 6%. The delayed fracture mode is mainly intergranular in the boron containing steels tempered at 350℃, which indicates that the addition of boron does not change the fracture character. However, the increase of boron content enlarges the size of the crack initia tion area. Further study of phase analysis indicates that most boron is in solid solution, and only a very small quantity of boron is in the M3 (C, B) phase.展开更多
Cubic boron nitride(c-BN) films were deposited on W6Mo5Cr4V2 high speed steel(HSS) substrate implanted with boron ion by RF-magnetron sputtering. The films were analyzed by the bending beam method, scratch test, XPS a...Cubic boron nitride(c-BN) films were deposited on W6Mo5Cr4V2 high speed steel(HSS) substrate implanted with boron ion by RF-magnetron sputtering. The films were analyzed by the bending beam method, scratch test, XPS and AFM. The experimental results show that the implantation of boron atom can reduce the internal stress and improve the adhesion strength of the films. The critical load of scratch test rises to 27.45 N, compared to 1.75 N of c-BN film on the unimplanted HSS. The AFM shows that the surface of the c-BN film on the implanted HSS is low in roughness and small in grain size. Then the composition of the boron implanted layer was analyzed by the XPS. And the influence of the boron implanted layer on the internal stress and adhesion strength of c-BN films were investigated.展开更多
基金This work was stLPPorted by the Foundation of Key Teacher Of State Education Min-istry, China.
文摘High boron bearing steel, in which boron homogeneously distributed, wassuccessfully produced in the vacuum induction furnace. The microstructural observations of cast andhot rolled steels showed that the addition of titanium can eliminate the quantity of ferrous boridesprecipitated at the grain boundaries and break the net microstructure, as a result, its hotworkability is improved. The titanium boride TiB_2 homogeneously distributes in the matrix ofalpha-Fe. The parameters of hot rolling process, including preheated temperature, initial rollingtemperature, finished rolling temperature and the total deformation, have been optimized.
文摘The effect of different tempering temperatures on the microstructure and mechanical properties of airquenched high boron white cast iron was studied.The results indicate that the high boron white cast iron comprises dendritic matrix and inter-dendritic M 2 B boride;and the matrix comprises martensite and pearlite.After quenching in the air,the matrix is changed into lath martensite;but only 1-μm-size second phase exists in the matrix.After tempering,another second phase of several tens of nanometers is found in the matrix,and the size and quantity increase with an increase in tempering temperature.The two kinds of second precipitation phase with different sizes in the matrix have the same chemical formula,but their forming stages are different.The precipitation phase with larger size forms during the austenitizing process,while the precipitation phase with smaller size forms during the tempering process.When tempered at different temperatures after quenching,the hardness decreases with an increase in the tempering temperature,but it increases a little at 450 ℃ due to the precipitation strengthening effect of the second phase,and it decreases greatly due to the martensite decomposition above 450 ℃.The impact toughness increases a little when tempered below 300 ℃,but it then decreases continuously owing to the increase in size and quantity of the secondary precipitate above 300 ℃.Considered comprehensively,the optimum tempering temperature is suggested at 300 ℃ to obtain a good combination of hardness and toughness.
文摘Chemical vapor deposition is considered as the most hopeful method for the synthesis of large-area high-quality hexagonal boron nitride on the substrate of catalytic metal. However, the size the hexagonal boron nitride films are limited to the size of growth chamber, which indicates a lower production efficiency. In this paper, the utilization efficiency of growth chamber is highly improved by alternately stacking multiple pieces of Cu foils and carbon fiber surface felt with porous structure. Uniform and continuous hexagonal boron nitride films are prepared on Cu foils through chemical vapor deposition utilizing ammonia borane as the precursor. This work develops a simple and practicable method for high-throughput preparation of hexagonal boron nitride films, which could contribute to the industrial application of hexagonal boron nitride. .
基金supported by the Scientific Plan Project of Beijing Education Committee (PXM2012- 014204-00-000136, PXM2012-014204-00-000156)the National Natural Science Foundation of China (Grant No. 51054008)Science and Technology Cooperating Project of Yunnan Province, China (Grant No.2010AD012)
文摘Influences of the tempering temperature on the microstructure, mechanical property and wear resistance of High-Boron High Speed Steel (HBHSS) roll materials were investigated by means of optical microscopy, scanning electron microscopy (SEM), X-ray diffraction, hardness measurement, impact tester, tensile tester and pin abrasion tester. The results show that the as-cast structure of HBHSS consists of a great amount of martensite and M2(B,C) and a few retained austenites and M23(B,C)6. After solution treated at 1,050 °C and followed by oil cooling, the amount of M23(B,C)6 carbo-borides in quenched HBHSS increases obviously and the macrohardness of the quenched HBHSS is 66 HRC, which is very close to the 65.8 HRC of as-cast HBHSS. On the whole, the hardness of HBHSS alloy shows a trend of slight decrease with increasing tempering temperature when tempered below 500 °C. While when above 500 °C, the hardness increases slightly as the tempering temperature increases and reaches a peak at 525 °C and then decreases obviously. The impact toughness of HBHSS has a tendency to increase as the tempering temperature increases. Tempering can improve the tensile strength and elongation of HBHSS, but a higher tempering temperature causes a slight decrease in both tensile strength and elongation. Excellent wear resistance can be obtained by tempering at 500 to 550 °C.
基金supported by the National Natural Science Foundation of China(No.50974080)
文摘High-temperature mechanical properties of high-boron austenitic steels(HBASs) were studied at 850 °C using a dynamic thermal-mechanical simulation testing machine. In addition, the thermal fatigue properties of the alloys were investigated using the self-restraint Uddeholm thermal fatigue test, during which the alloy specimens were cycled between room temperature and 800°C. Stereomicroscopy and scanning electron microscopy were used to study the surface cracks and cross-sectional microstructure of the alloy specimens after the thermal fatigue tests. The effects of carbon content on the mechanical properties at room temperature and high-temperature as well as thermal fatigue properties of the HBASs were also studied. The experimental results show that increasing carbon content induces changes in the microstructure and mechanical properties of the HBASs. The boride phase within the HBAS matrix exhibits a round and smooth morphology, and they are distributed in a discrete manner. The hardness of the alloys increases from 239(0.19 wt.% C) to 302(0.29 wt.% C) and 312 HV(0.37 wt.% C); the tensile yield strength at 850 °C increases from 165.1 to 190.3 and 197.1 MPa; and the compressive yield strength increases from 166.1 to 167.9 and 184.4 MPa. The results of the thermal fatigue tests(performed for 300 cycles from room temperature to 800 °C) indicate that the degree of thermal fatigue of the HBAS with 0.29 wt.% C(rating of 2–3) is superior to those of the alloys with 0.19 wt.%(rating of 4–5) and 0.37 wt.%(rating of 3–4) carbon. The main cause of this difference is the ready precipitation of M23(C,B)6-type borocarbides in the alloys with high carbon content during thermal fatigue testing. The precipitation and aggregation of borocarbide particles at the grain boundaries result in the deterioration of the thermal fatigue properties of the alloys.
基金Project(51305317)supported by the National Natural Science Foundation of ChinaProjects(WUT:2013-IV-092,WUT:2014-VII-002)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(IRT13087)supported by Innovative Research Team Development Program of Ministry of Education of China
文摘The fracture behaviour and morphologies of high-strength boron steel were investigated at different temperatures at a constant strain rate of 0.1 s-1 based on isothermal tensile tests. Fracture mechanisms were also analyzed based on the relationship between microstructure transformation and continuous cooling transformation(CCT) curves. It is found that 1) fractures of the investigated steel at high temperatures are dimple fractures; 2) the deformation of high-strength boron steel at high temperatures accelerates diffusion transformations; thus, to obtain full martensite, a higher cooling rate is needed; and 3) the investigated steel has the best plasticity when the deformation temperature is 750 °C.
基金supported by the National Natural Science Foundation of China(No.50974080)
文摘In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental results indicate that the boron alloyed high silicon cast steel comprises a dendritic matrix and interdendritic eutectic borides in as-cast condition. The dendritic matrix is made up of pearlite, ferrite, and the interdendritic eutectic boride is with a chemical formula of M2B (M represents Fe, Cr, Mn or Mo) which is much like that of carbide in high chromium white cast iron. Pure ausferrite structure that consists of bainitic ferrite and retained austenite can be obtained in the matrix by austempering treatment to the cast steel. No carbides precipitate in the ausferrite structure and the morphology of borides remains almost unchanged after austempering treatments. Secondary boride particles precipitate during the course of austenitizing. The hardness and tensile strength of the austempered cast steel decrease with the increase of the austempering temperature, from 250 oC to 400 oC. The impact toughness is 4-11 J?cm-2 at room temperature and the impact
基金Project(51002025) supported by the National Natural Science Foundation of China
文摘The preparation process of amorphous nanometer boron powders through combustion synthesis was investigated, and the effects of the reactant ratio, the heating agent and the milling rate on the activity and particle size of amorphous boron powders were studied. The results show that the boron powders exist in the form of an amorphous phase which has the crystallinity lower than 30.4%, and the particle size of boron powder decreases with an increase of the high-energy ball milling rate. The purity of amorphous boron powder is 94.8% and particle sizes are much smaller than 100 nm when the mass ratio of B2O3/Mg/KClO3 is 100:105:17 and the ball milling time is 20 min with the milling rate of 300 r/min. At the same time, the amorphous boron nano-fibers appear in the boron powders.
基金Item Sponsored by National Key Fundamental Research and Development Programme of China (2004CB619104)
文摘The delayed fracture behavior of medium carbon high strength spring steel containing different amounts of boron (0. 000 5%, 0. 001 6 %) was studied using sustained load delayed fracture test. The results show that delayed fracture resistance of boron containing steels is higher than that of conventional steel 60Si2MnA at the same strength level and it increases with the increase of boron eontent from 0. 000 5% to 0. 001 6%. The delayed fracture mode is mainly intergranular in the boron containing steels tempered at 350℃, which indicates that the addition of boron does not change the fracture character. However, the increase of boron content enlarges the size of the crack initia tion area. Further study of phase analysis indicates that most boron is in solid solution, and only a very small quantity of boron is in the M3 (C, B) phase.
基金National Natural Science Foundation ofChina(No.59971065)
文摘Cubic boron nitride(c-BN) films were deposited on W6Mo5Cr4V2 high speed steel(HSS) substrate implanted with boron ion by RF-magnetron sputtering. The films were analyzed by the bending beam method, scratch test, XPS and AFM. The experimental results show that the implantation of boron atom can reduce the internal stress and improve the adhesion strength of the films. The critical load of scratch test rises to 27.45 N, compared to 1.75 N of c-BN film on the unimplanted HSS. The AFM shows that the surface of the c-BN film on the implanted HSS is low in roughness and small in grain size. Then the composition of the boron implanted layer was analyzed by the XPS. And the influence of the boron implanted layer on the internal stress and adhesion strength of c-BN films were investigated.