It was found that the steel plate in the composite plate in the WJ-8 fastener used in high speed rail is rusty. The objective of this study is to test the zinc coating of the steel plate. A literature review was condu...It was found that the steel plate in the composite plate in the WJ-8 fastener used in high speed rail is rusty. The objective of this study is to test the zinc coating of the steel plate. A literature review was conducted to identify the zinc coating techniques, and the companies that can provide different coating service was identified. A salt fog chamber was built that was in compliance with the ANSI B117 code, and the steel plates that were coated by the identified companies were tested using the salt fog chamber. The results indicated that the coating technique that had the best performance in preventing corrosion was the Greenkote plates with passivation. The galvanized option had the roughest coating layer, and it was the most reactive in the salt water solution. This makes it non-ideal for the dynamic rail environment because the increased friction of the plate could damage the supports, especially during extreme temperatures that would cause the rail to expand or contract. Greenkote with Phosphate and ArmorGalv also provided increased corrosion prevention with a smooth, strong finish, but it had more rust on the surface area than the Greenkote with ELU passivation. The ArmorGalv sample had more rust on the surface area than the Greenkote samples. This may not be a weakness in the ArmorGalv process;rather, it likely was the result of this particular sample not having the added protection of a colored coating.展开更多
The effect of ferrovanadium inoculation on the microstructure and properties of high speed steel (HSS) used for rolls was studied. The results showed that the as-cast eutectic carbide network tends to be broken after ...The effect of ferrovanadium inoculation on the microstructure and properties of high speed steel (HSS) used for rolls was studied. The results showed that the as-cast eutectic carbide network tends to be broken after ferrovanadium inoculation, and the carbides are changed to rod-like or nodular shape. After heat treatment, the carbides in the inoculated HSS are spheroidized and distributed more uniformly in the matrix. The impact toughness of high speed steel with ferrovanadium inoculation is obviously improved. The action mechanism of ferrovanadium inoculation on the microstructure of the alloy is also discussed.展开更多
The as-cast microstructures of high carbon high speed steels (HC-HSS) made by sand casting, centrifugal casting and electromagnetic centrifugal casting, respectively, were studied by using of optical microscopy (OM...The as-cast microstructures of high carbon high speed steels (HC-HSS) made by sand casting, centrifugal casting and electromagnetic centrifugal casting, respectively, were studied by using of optical microscopy (OM) and D/max2200pc X-ray diffraction. The results show that the microstructure of as-cast HC- HSS is dominated by alloy carbides (W2C, VC, Cr7C3), martensite and austenite. The centrifugal casting and electromagnetic centrifugal casting apparently improve the solidification structure of HCoHSS. With the increase of magnetic intensity (B), the volume fraction of austenite in the HC-HSS solidification structure increases significantly while the eutectic ledeburite decreases. Moreover, the secondary carbides precipitated from the austenite are finer with more homogeneous distribution in the electromagnetic centrifugal castings. It has also been found that the lath of eutectic carbide in ledeburite becomes finer and carbide phase spacing in eutectic ledeburite increases along with the higher magnetic field strength.展开更多
The influence of rare earth metals and heat treatment on the microstructure and performance of M42 steel has been investigated by means of an optical microscope OM scanning electron microscope SEM energy dispersive sp...The influence of rare earth metals and heat treatment on the microstructure and performance of M42 steel has been investigated by means of an optical microscope OM scanning electron microscope SEM energy dispersive spectroscopy EDS transmission electron microscope TEM electron back-scatter diffraction EBSD and X-ray diffraction XRD . The results show that M2 C is the prevailing type of eutectic carbides in M42 steel. After modification with rare earth metals M2 C eutectic carbides change from the ordered lamellar structure into a circular structure.Despite different morphologies the two carbides present the same characteristics of microstructure and growth orientation.Compared with lamellar carbides M2 C carbides with the circular structure are much easier to decompose and spheroidize after heating which remarkably refines the carbide dimensions.The refined carbides improve the supersaturation of alloying elements in martensite and increase the hardness of M42 steel by 1.5 HRC.展开更多
The effects of rare earths(RE)-Mg-Ti compound modification on the structures and properties of high-carbon high speed steel(HSS) were researched.The impact toughness(α_k),the fracture toughness(K_(1c))and threshold o...The effects of rare earths(RE)-Mg-Ti compound modification on the structures and properties of high-carbon high speed steel(HSS) were researched.The impact toughness(α_k),the fracture toughness(K_(1c))and threshold of fatigue crack growth(ΔK_(th))are tested.The thermal fatigue test is done on a self-straining thermal fatigue tester,the wear test is done on a high temperature wear test machine.The results show that the matrix can be refined by the RE-Mg-Ti compound modification,the eutectic carbides are inclined to spheroidicize and are distributed evenly,the morphology and distribution of eutectic carbides are improved by appropriate RE-Mg-Ti complex modification.After RE-Mg-Ti compound modification,a little effects can be found on the strength,hardness and red hardness,but the fracture toughness(K_(1c)) and threshold of fatigue crack growth(△K_(th)) are improved in the meantime,the impact toughness (α_k) is increased by over one time,and the resistance to thermal fatigue and wear resistance at an elevated temperature are remarkably improved.展开更多
The influence of Ce on the solidification microstructures of M2 high speed steel was studied. The results show that Ce has the effect of alleviating the segregation of alloying elements such as W and Mo in high speed ...The influence of Ce on the solidification microstructures of M2 high speed steel was studied. The results show that Ce has the effect of alleviating the segregation of alloying elements such as W and Mo in high speed steel. With the addition of Ce, the amount of eutectic carbides is decreased and the flakes of the carbides are refined. Ce mainly segregates onto the interface between the eutectic carbide and austenite, and a Dart of Ce enters M2C carbide. Ce can also enhance the breaking and spheroidizing of the network eutectic carbides during high temperature heat treatment.展开更多
An industrial plant trial for optimizing the process parameters in a round billet continuous casting mold with electromagnetic stirring (M-EMS) was performed, in which the influences of stirring parameters with M-EM...An industrial plant trial for optimizing the process parameters in a round billet continuous casting mold with electromagnetic stirring (M-EMS) was performed, in which the influences of stirring parameters with M-EMS on the solidification macrostructure of high carbon steel were investigated. The results show that the billet quality is not well controlled under the condition of working current and frequency with EMS, in which the subsurface crack of grade 1.0-2.0 ups to 38.09%, the central pipe of grade 1.0-1.5 reaches to 14.28%, and the central porosity of grade 1.5 is 14.29%. The parameters of current 260 A and frequency 8 Hz as the final optimum scheme has a remarkable effect for improving the macroscopic quality of billet, in which the subsurface crack, central pipe and skin blowhole are all disappeared, and the central porosity and carbon segregation are also well improved.展开更多
The present work investigated the solidification microstructure of AISI M2 high speed steel manufactured by different casting technologies, namely iron mould casting and continuous casting. The results revealed that t...The present work investigated the solidification microstructure of AISI M2 high speed steel manufactured by different casting technologies, namely iron mould casting and continuous casting. The results revealed that the as-cast structure of the steel was composed of the iron matrix and the M2C eutectic carbide networks, which were greatly refined in the ingot made by continuous casting process, compared with that by the iron mould casting process. M2C eutectic carbides presented variation in their morphologies and growth characteristics in the ingots by both casting methods. In the ingot by iron mould casting, they have a plate-like morphology and grow anisotropically. However, in the ingot made by continuous casting, the carbides evolved into the fiber-like shape that exhibited little characteristics of anisotropic growth. It was noticed that the fiber-like M2C was much easier to decompose and spheroidize after heated, as a result, the carbides refined remarkably, compared with the case of plate-like carbides in the iron mould casting ingot.展开更多
High speed steel (HSS) rolls can replace traditional rolls such as alloyed cast iron rolls and powder metallurgical (PM) hard alloy rolls. The main reasons for the replacement are that the wear resistance of low-cost ...High speed steel (HSS) rolls can replace traditional rolls such as alloyed cast iron rolls and powder metallurgical (PM) hard alloy rolls. The main reasons for the replacement are that the wear resistance of low-cost alloyed cast iron rolls is poor and the cost of high-quality PM hard alloy rolls is very high. By means of centrifugal casting, HSS rolls having excellent wear resistance have been manufactured. The hardness of the HSS roll is 6.5~67 HRC, the range of variation is smaller than 2 HRC and its impact toughness is 15 J/cm^2. The wear rate of HSS rolls used in the pre-finishing stands of high-speed hot wire-rod rolling mill reaches 2.5×10^(-4)mm per ton steel. Furthermore, the manufacturing cost of HSS rolls is significantly lower than that of PM hard alloy rolls; it is only 30 percent of that of PM hard alloy rolls.展开更多
The microscopic structure change rule in high speed steel (HSS) after an additional cryogenic treatment was studied in this paper. Highly dispersed nano-carbide (η-Fe2 C) separated from tempering martensite was found...The microscopic structure change rule in high speed steel (HSS) after an additional cryogenic treatment was studied in this paper. Highly dispersed nano-carbide (η-Fe2 C) separated from tempering martensite was found distributed on twin planes of marten-site and dislocation places. Retained austenite was found sheared into martensite and nano-carbide separated at the same time. In addition, the tempering martensite was fine-grained. The stated changes of HSS evidently improve the lifespan of HSS cutter and fully show the advantages of nano-structure. The cryogenic treatment of HSS also improves the roughness of HSS cutter (decrease Ra number by about 50%) and greatly increases the wear resistance of HSS cutter. Further experiments on the wear characteristic of HSS cutter supported the findings mentioned above. The stated HSS treatment technology would implement nano-structure of traditional tool steel through phase change. It could be a new method to improve the performance of HSS cutter.展开更多
The effect of Cr/Mn segregation on the abnormal banded structure of high carbon bearing steel was studied by reheating and hot rolling.With the use of an optical microscope, scanning electron microscope, transmission ...The effect of Cr/Mn segregation on the abnormal banded structure of high carbon bearing steel was studied by reheating and hot rolling.With the use of an optical microscope, scanning electron microscope, transmission electron microscope, and electron probe microanalyzer, the segregation characteristics of alloying elements in cast billet and their relationship with hot-rolled plate banded structure were revealed.The formation causes of an abnormal banded structure and the elimination methods were analyzed.Results indicate the serious positive segregation of C, Cr, and Mn alloy elements in the billet.Even distribution of Cr/Mn elements could not be achieved after 10 h of heat preservation at 1200℃, and the spacing of the element aggregation area increased, but the segregation index of alloy elements decreased.Obvious alloying element segregation characteristics are present in the banded structure of the hot-rolled plate.This distinct white band is composed of martensitic phases.The formation of this abnormal pearlite–martensite banded structure is due to the interaction between the undercooled austenite transformation behavior of hot-rolled metal and the segregation of its alloying elements.Under the air cooling after rolling, controlling the segregation index of alloy elements can reduce or eliminate the abnormal banded structure.展开更多
The mechanical properties and microstructure characteristics of a high speed steel (HSS) for roll has been studied. As compared with the as-cast HSS, the spray-formed HSS have fine grain and segregation free microstru...The mechanical properties and microstructure characteristics of a high speed steel (HSS) for roll has been studied. As compared with the as-cast HSS, the spray-formed HSS have fine grain and segregation free microstructures. Carbides distribute uniformly. The morphology and types of the carbides in spray-formed HSS are different from those in as-cast HSS. The results of the high temperature tensile experiment show that, as to spray-formed HSS, there is a possibility of superplastic deformation in the range of 780-810℃.展开更多
The electrode configuration determines the thermophysical field during the electroslag remelting(ESR) process and affects the final microstructure of the ingot. In this work, ingot with a diameter of 400 mm was prepar...The electrode configuration determines the thermophysical field during the electroslag remelting(ESR) process and affects the final microstructure of the ingot. In this work, ingot with a diameter of 400 mm was prepared with two electrode configuration modes of single power ESR process, namely one electrode(OE) and two series-connected electrodes(TSCE). Finite element simulation was employed to calculate the electromagnetic field, flow field and temperature field of the ESR system. The results show that the temperature of the slag pool and the metal pool of the TSCE process is lower and more uniform than that of the OE process.The calculated temperature distribution of the ingot could be indirectly verified from the shape of the metal pool by the experiment. The experimental results show that the depth of the metal pool in the OE ingot is about 160 mm, while the depth of the TSCE ingot is nearly 40 mm shallower than that of the OE ingot. Microstructural comparisons indicate that coarse eutectic carbides are formed in the center of the OE ingot, whereas more even eutectic carbides appear in the center of the TSCE ingot. In general, compared with the OE process, the TSCE process is preferred to remelt high speed steel ingots.展开更多
The apparent morphologies of packet martensite in eight high carbon steels were researched by using optical microscope, scanning electron microscope, and transmission electron microscope. It was found that the apparen...The apparent morphologies of packet martensite in eight high carbon steels were researched by using optical microscope, scanning electron microscope, and transmission electron microscope. It was found that the apparent morphologies, substructures, and habit plane of packet martensite in high carbon steels are entirely different from that in low carbon steels; the substructures of packet martensite in high carbon steels possess fully twinned structure, while the substructures of individual coarse martensite plates in these steels bear both fully and partially twinned structures. The formation reason for apparent morphologies, substructures and two habit planes (i. e, { 111 }, and { 225}r) of high carbon martensite were discussed in detail.展开更多
Core filling process of cast high speed steel roll was simulated.Ductile iron was used as core material.The influences of filling parameters,such as core filling time and core filling temperature,on the filling proces...Core filling process of cast high speed steel roll was simulated.Ductile iron was used as core material.The influences of filling parameters,such as core filling time and core filling temperature,on the filling process were investigated.Based on the simulated results,optimal core filling parameters were determined.The predicted temperature fields show that the temperature at the roll shoulder is the lowest during the core filling process and usually causes binding defects there.Method for solving this problem was presented.展开更多
A high speed steel composite roll billet was fabricated, which is regular in shape, smooth in surface, slight in trace, compact in internal structure, free of slag inclusion, shrinkage cavity, cracks and other flaws, ...A high speed steel composite roll billet was fabricated, which is regular in shape, smooth in surface, slight in trace, compact in internal structure, free of slag inclusion, shrinkage cavity, cracks and other flaws, and good in macro quality of junction surface using a vertical continuous casting machine. The interface zone microstructure of bimetallic in billet of high speed steel composite roll was analyzed by metallurgical microscope(OM), X-ray diffractmeter(XRD), scanning electron microscopy(SEM) and energy-dispersive X-ray analysis(EDS). The results indicate that the microstructure of roll billet is composed of chilled solidified layer, dendrite zone, interfacial zone of bimetal and core material zone. The microstructure of outer shell material is composed of martensite + bainite + residual austenite + some small labyrinth-shape, small-short lath-shape, or dollop-shape eutectic carbides. The microstructure of core material is slice-shape pearlite and a little ferrite along boundary of cells. The interface region microstructure of bimetallic composite roll consists of diffusion region, chilled solidified layer and columnar grain region.展开更多
M2 cast high speed steel was inoculated by addition of rare earth(RE)-Al-N, network eutectic carbides were eliminated, matrix microstructures were refined and the segregation of tungsten and molybdenum elements was re...M2 cast high speed steel was inoculated by addition of rare earth(RE)-Al-N, network eutectic carbides were eliminated, matrix microstructures were refined and the segregation of tungsten and molybdenum elements was relieved. In the condition that the hardness does not decrease, impact toughness obviously increases. Quenching at 1180 ℃ and three-times tempering at 560 ℃, the hardness of M2 cast high speed steel is 65~66 HRC, and impact toughness reaches 21.3 (J·cm^(-2)). Modified M2 cast high speed steel has excellent thermal fatigue resistance and high temperature wear resistance. Roller made in modified M2 cast high speed steel has excellent service effect when it is used in slit rolling mill of hot rolling bar mill.展开更多
Manuscript received 30 July 1999 Abstract The shielded metal arc welding (SMAW) of a manganese steel part as a crossing of railway track to a carbon steel part as the rails of the railroad is the welding of dissimil...Manuscript received 30 July 1999 Abstract The shielded metal arc welding (SMAW) of a manganese steel part as a crossing of railway track to a carbon steel part as the rails of the railroad is the welding of dissimilar steel. It are was known that it is not possible to the the rail of railroad directly to the cross- ing of railway track made from a steel containing about 14% of manganese (wt. ) because of so many differences between the two kinds of steels such as composition, microstructure,mechanical properties and weldability.A method was used to solve the problem by presetting an intermediate layer on each side of the joint and other special procedures were used.The result of test indicated that a good weld joint was obtained.展开更多
A high speed steel (HSS) was studied for rollers in this work. The steel was quenched at 1150℃ and tempered at 520℃. The phase structures of the steel were determined by X-ray diffraction (XRD), and the hardness...A high speed steel (HSS) was studied for rollers in this work. The steel was quenched at 1150℃ and tempered at 520℃. The phase structures of the steel were determined by X-ray diffraction (XRD), and the hardness of specimens was measured. The volume fraction of carbides was counted by Image-Pro Plus software. The typical microstructures were observed by field emission scanning electron microscope (FESEM). Stable and meta-stable carbides were deduced by removing the existing phases one by one in the Fe-C equilibrium calculation. It is found that the precipitated carbides are bulk-like MC, long stripe-like M2C, fishbone-like M6C, and daisy-like M7C3 during the tempering process. The stable carbides are MC and M6C, but the meta-stable ones are M2C, M7C3, and M3C.展开更多
The present work employed the X-ray diffraction, scanning electron microscopy, electron backscattered diffraction, and electron probe microanalysis techniques to identify the microstructural evolution and mechanical a...The present work employed the X-ray diffraction, scanning electron microscopy, electron backscattered diffraction, and electron probe microanalysis techniques to identify the microstructural evolution and mechanical and abrasive behavior of high carbon steel during quenching-partitioning treatment with an aim to enhance the toughness and wear resistance of high carbon steel.Results showed that, with the increase in partitioning temperature from 250 to 400℃, the amount of retained austenite(RA) decreased resulting from the carbide precipitation effect after longer partitioning times.Moreover, the stability of RA generally increased because of the enhanced degree of carbon enrichment in RA.Given the factors affecting the toughness of high carbon steel, the stability of RA associated with size, carbon content, and morphology plays a significant role in determining the toughness of high carbon steel.The analysis of the wear resistance of samples with different mechanical properties shows that hardness is the primary factor affecting the wear resistance of high carbon steel, and the toughness is the secondary one.展开更多
文摘It was found that the steel plate in the composite plate in the WJ-8 fastener used in high speed rail is rusty. The objective of this study is to test the zinc coating of the steel plate. A literature review was conducted to identify the zinc coating techniques, and the companies that can provide different coating service was identified. A salt fog chamber was built that was in compliance with the ANSI B117 code, and the steel plates that were coated by the identified companies were tested using the salt fog chamber. The results indicated that the coating technique that had the best performance in preventing corrosion was the Greenkote plates with passivation. The galvanized option had the roughest coating layer, and it was the most reactive in the salt water solution. This makes it non-ideal for the dynamic rail environment because the increased friction of the plate could damage the supports, especially during extreme temperatures that would cause the rail to expand or contract. Greenkote with Phosphate and ArmorGalv also provided increased corrosion prevention with a smooth, strong finish, but it had more rust on the surface area than the Greenkote with ELU passivation. The ArmorGalv sample had more rust on the surface area than the Greenkote samples. This may not be a weakness in the ArmorGalv process;rather, it likely was the result of this particular sample not having the added protection of a colored coating.
文摘The effect of ferrovanadium inoculation on the microstructure and properties of high speed steel (HSS) used for rolls was studied. The results showed that the as-cast eutectic carbide network tends to be broken after ferrovanadium inoculation, and the carbides are changed to rod-like or nodular shape. After heat treatment, the carbides in the inoculated HSS are spheroidized and distributed more uniformly in the matrix. The impact toughness of high speed steel with ferrovanadium inoculation is obviously improved. The action mechanism of ferrovanadium inoculation on the microstructure of the alloy is also discussed.
基金supported by the special fund for basic scientifi c research of central colleges,Chang’an University (CHD2010JC015)the innovation fund of small and medium-sized enterprise of Science & Technology Ministry of China under grant no. 10C26213201139Beijing Education Committee patent outcome conversion item
文摘The as-cast microstructures of high carbon high speed steels (HC-HSS) made by sand casting, centrifugal casting and electromagnetic centrifugal casting, respectively, were studied by using of optical microscopy (OM) and D/max2200pc X-ray diffraction. The results show that the microstructure of as-cast HC- HSS is dominated by alloy carbides (W2C, VC, Cr7C3), martensite and austenite. The centrifugal casting and electromagnetic centrifugal casting apparently improve the solidification structure of HCoHSS. With the increase of magnetic intensity (B), the volume fraction of austenite in the HC-HSS solidification structure increases significantly while the eutectic ledeburite decreases. Moreover, the secondary carbides precipitated from the austenite are finer with more homogeneous distribution in the electromagnetic centrifugal castings. It has also been found that the lath of eutectic carbide in ledeburite becomes finer and carbide phase spacing in eutectic ledeburite increases along with the higher magnetic field strength.
基金The National Natural Science Foundation of China(No.51301038,51201031,51371050)the Industry-AcademiaResearch Cooperative Innovation Fund of Jiangsu Province(No.BY2014127-03)+1 种基金the Natural Science Foundation of Jiangsu Province(No.BK20141306)the Scientific and Technological Innovation Fund of Danyang(No.SY201305)
文摘The influence of rare earth metals and heat treatment on the microstructure and performance of M42 steel has been investigated by means of an optical microscope OM scanning electron microscope SEM energy dispersive spectroscopy EDS transmission electron microscope TEM electron back-scatter diffraction EBSD and X-ray diffraction XRD . The results show that M2 C is the prevailing type of eutectic carbides in M42 steel. After modification with rare earth metals M2 C eutectic carbides change from the ordered lamellar structure into a circular structure.Despite different morphologies the two carbides present the same characteristics of microstructure and growth orientation.Compared with lamellar carbides M2 C carbides with the circular structure are much easier to decompose and spheroidize after heating which remarkably refines the carbide dimensions.The refined carbides improve the supersaturation of alloying elements in martensite and increase the hardness of M42 steel by 1.5 HRC.
文摘The effects of rare earths(RE)-Mg-Ti compound modification on the structures and properties of high-carbon high speed steel(HSS) were researched.The impact toughness(α_k),the fracture toughness(K_(1c))and threshold of fatigue crack growth(ΔK_(th))are tested.The thermal fatigue test is done on a self-straining thermal fatigue tester,the wear test is done on a high temperature wear test machine.The results show that the matrix can be refined by the RE-Mg-Ti compound modification,the eutectic carbides are inclined to spheroidicize and are distributed evenly,the morphology and distribution of eutectic carbides are improved by appropriate RE-Mg-Ti complex modification.After RE-Mg-Ti compound modification,a little effects can be found on the strength,hardness and red hardness,but the fracture toughness(K_(1c)) and threshold of fatigue crack growth(△K_(th)) are improved in the meantime,the impact toughness (α_k) is increased by over one time,and the resistance to thermal fatigue and wear resistance at an elevated temperature are remarkably improved.
文摘The influence of Ce on the solidification microstructures of M2 high speed steel was studied. The results show that Ce has the effect of alleviating the segregation of alloying elements such as W and Mo in high speed steel. With the addition of Ce, the amount of eutectic carbides is decreased and the flakes of the carbides are refined. Ce mainly segregates onto the interface between the eutectic carbide and austenite, and a Dart of Ce enters M2C carbide. Ce can also enhance the breaking and spheroidizing of the network eutectic carbides during high temperature heat treatment.
基金supported by the Program for New Century Excellent Talents in University from the Ministry of Education of China (No.NCET-04-0285)
文摘An industrial plant trial for optimizing the process parameters in a round billet continuous casting mold with electromagnetic stirring (M-EMS) was performed, in which the influences of stirring parameters with M-EMS on the solidification macrostructure of high carbon steel were investigated. The results show that the billet quality is not well controlled under the condition of working current and frequency with EMS, in which the subsurface crack of grade 1.0-2.0 ups to 38.09%, the central pipe of grade 1.0-1.5 reaches to 14.28%, and the central porosity of grade 1.5 is 14.29%. The parameters of current 260 A and frequency 8 Hz as the final optimum scheme has a remarkable effect for improving the macroscopic quality of billet, in which the subsurface crack, central pipe and skin blowhole are all disappeared, and the central porosity and carbon segregation are also well improved.
基金supported by the Fund Project for Transformation of Scientific and Technological Achievements of Jiangsu Province,China(No.BA2010139)
文摘The present work investigated the solidification microstructure of AISI M2 high speed steel manufactured by different casting technologies, namely iron mould casting and continuous casting. The results revealed that the as-cast structure of the steel was composed of the iron matrix and the M2C eutectic carbide networks, which were greatly refined in the ingot made by continuous casting process, compared with that by the iron mould casting process. M2C eutectic carbides presented variation in their morphologies and growth characteristics in the ingots by both casting methods. In the ingot by iron mould casting, they have a plate-like morphology and grow anisotropically. However, in the ingot made by continuous casting, the carbides evolved into the fiber-like shape that exhibited little characteristics of anisotropic growth. It was noticed that the fiber-like M2C was much easier to decompose and spheroidize after heated, as a result, the carbides refined remarkably, compared with the case of plate-like carbides in the iron mould casting ingot.
文摘High speed steel (HSS) rolls can replace traditional rolls such as alloyed cast iron rolls and powder metallurgical (PM) hard alloy rolls. The main reasons for the replacement are that the wear resistance of low-cost alloyed cast iron rolls is poor and the cost of high-quality PM hard alloy rolls is very high. By means of centrifugal casting, HSS rolls having excellent wear resistance have been manufactured. The hardness of the HSS roll is 6.5~67 HRC, the range of variation is smaller than 2 HRC and its impact toughness is 15 J/cm^2. The wear rate of HSS rolls used in the pre-finishing stands of high-speed hot wire-rod rolling mill reaches 2.5×10^(-4)mm per ton steel. Furthermore, the manufacturing cost of HSS rolls is significantly lower than that of PM hard alloy rolls; it is only 30 percent of that of PM hard alloy rolls.
文摘The microscopic structure change rule in high speed steel (HSS) after an additional cryogenic treatment was studied in this paper. Highly dispersed nano-carbide (η-Fe2 C) separated from tempering martensite was found distributed on twin planes of marten-site and dislocation places. Retained austenite was found sheared into martensite and nano-carbide separated at the same time. In addition, the tempering martensite was fine-grained. The stated changes of HSS evidently improve the lifespan of HSS cutter and fully show the advantages of nano-structure. The cryogenic treatment of HSS also improves the roughness of HSS cutter (decrease Ra number by about 50%) and greatly increases the wear resistance of HSS cutter. Further experiments on the wear characteristic of HSS cutter supported the findings mentioned above. The stated HSS treatment technology would implement nano-structure of traditional tool steel through phase change. It could be a new method to improve the performance of HSS cutter.
文摘The effect of Cr/Mn segregation on the abnormal banded structure of high carbon bearing steel was studied by reheating and hot rolling.With the use of an optical microscope, scanning electron microscope, transmission electron microscope, and electron probe microanalyzer, the segregation characteristics of alloying elements in cast billet and their relationship with hot-rolled plate banded structure were revealed.The formation causes of an abnormal banded structure and the elimination methods were analyzed.Results indicate the serious positive segregation of C, Cr, and Mn alloy elements in the billet.Even distribution of Cr/Mn elements could not be achieved after 10 h of heat preservation at 1200℃, and the spacing of the element aggregation area increased, but the segregation index of alloy elements decreased.Obvious alloying element segregation characteristics are present in the banded structure of the hot-rolled plate.This distinct white band is composed of martensitic phases.The formation of this abnormal pearlite–martensite banded structure is due to the interaction between the undercooled austenite transformation behavior of hot-rolled metal and the segregation of its alloying elements.Under the air cooling after rolling, controlling the segregation index of alloy elements can reduce or eliminate the abnormal banded structure.
文摘The mechanical properties and microstructure characteristics of a high speed steel (HSS) for roll has been studied. As compared with the as-cast HSS, the spray-formed HSS have fine grain and segregation free microstructures. Carbides distribute uniformly. The morphology and types of the carbides in spray-formed HSS are different from those in as-cast HSS. The results of the high temperature tensile experiment show that, as to spray-formed HSS, there is a possibility of superplastic deformation in the range of 780-810℃.
基金financially surpported by the Foundation of Hebei Provincial Department of Education,China(Grant No.QN2018034 and QN2017051)
文摘The electrode configuration determines the thermophysical field during the electroslag remelting(ESR) process and affects the final microstructure of the ingot. In this work, ingot with a diameter of 400 mm was prepared with two electrode configuration modes of single power ESR process, namely one electrode(OE) and two series-connected electrodes(TSCE). Finite element simulation was employed to calculate the electromagnetic field, flow field and temperature field of the ESR system. The results show that the temperature of the slag pool and the metal pool of the TSCE process is lower and more uniform than that of the OE process.The calculated temperature distribution of the ingot could be indirectly verified from the shape of the metal pool by the experiment. The experimental results show that the depth of the metal pool in the OE ingot is about 160 mm, while the depth of the TSCE ingot is nearly 40 mm shallower than that of the OE ingot. Microstructural comparisons indicate that coarse eutectic carbides are formed in the center of the OE ingot, whereas more even eutectic carbides appear in the center of the TSCE ingot. In general, compared with the OE process, the TSCE process is preferred to remelt high speed steel ingots.
文摘The apparent morphologies of packet martensite in eight high carbon steels were researched by using optical microscope, scanning electron microscope, and transmission electron microscope. It was found that the apparent morphologies, substructures, and habit plane of packet martensite in high carbon steels are entirely different from that in low carbon steels; the substructures of packet martensite in high carbon steels possess fully twinned structure, while the substructures of individual coarse martensite plates in these steels bear both fully and partially twinned structures. The formation reason for apparent morphologies, substructures and two habit planes (i. e, { 111 }, and { 225}r) of high carbon martensite were discussed in detail.
文摘Core filling process of cast high speed steel roll was simulated.Ductile iron was used as core material.The influences of filling parameters,such as core filling time and core filling temperature,on the filling process were investigated.Based on the simulated results,optimal core filling parameters were determined.The predicted temperature fields show that the temperature at the roll shoulder is the lowest during the core filling process and usually causes binding defects there.Method for solving this problem was presented.
基金Project(200809123) supported by the National Natural Science Foundation of China
文摘A high speed steel composite roll billet was fabricated, which is regular in shape, smooth in surface, slight in trace, compact in internal structure, free of slag inclusion, shrinkage cavity, cracks and other flaws, and good in macro quality of junction surface using a vertical continuous casting machine. The interface zone microstructure of bimetallic in billet of high speed steel composite roll was analyzed by metallurgical microscope(OM), X-ray diffractmeter(XRD), scanning electron microscopy(SEM) and energy-dispersive X-ray analysis(EDS). The results indicate that the microstructure of roll billet is composed of chilled solidified layer, dendrite zone, interfacial zone of bimetal and core material zone. The microstructure of outer shell material is composed of martensite + bainite + residual austenite + some small labyrinth-shape, small-short lath-shape, or dollop-shape eutectic carbides. The microstructure of core material is slice-shape pearlite and a little ferrite along boundary of cells. The interface region microstructure of bimetallic composite roll consists of diffusion region, chilled solidified layer and columnar grain region.
文摘M2 cast high speed steel was inoculated by addition of rare earth(RE)-Al-N, network eutectic carbides were eliminated, matrix microstructures were refined and the segregation of tungsten and molybdenum elements was relieved. In the condition that the hardness does not decrease, impact toughness obviously increases. Quenching at 1180 ℃ and three-times tempering at 560 ℃, the hardness of M2 cast high speed steel is 65~66 HRC, and impact toughness reaches 21.3 (J·cm^(-2)). Modified M2 cast high speed steel has excellent thermal fatigue resistance and high temperature wear resistance. Roller made in modified M2 cast high speed steel has excellent service effect when it is used in slit rolling mill of hot rolling bar mill.
文摘Manuscript received 30 July 1999 Abstract The shielded metal arc welding (SMAW) of a manganese steel part as a crossing of railway track to a carbon steel part as the rails of the railroad is the welding of dissimilar steel. It are was known that it is not possible to the the rail of railroad directly to the cross- ing of railway track made from a steel containing about 14% of manganese (wt. ) because of so many differences between the two kinds of steels such as composition, microstructure,mechanical properties and weldability.A method was used to solve the problem by presetting an intermediate layer on each side of the joint and other special procedures were used.The result of test indicated that a good weld joint was obtained.
基金supported by the National Natural Science Foundation of China (No. 51271163)
文摘A high speed steel (HSS) was studied for rollers in this work. The steel was quenched at 1150℃ and tempered at 520℃. The phase structures of the steel were determined by X-ray diffraction (XRD), and the hardness of specimens was measured. The volume fraction of carbides was counted by Image-Pro Plus software. The typical microstructures were observed by field emission scanning electron microscope (FESEM). Stable and meta-stable carbides were deduced by removing the existing phases one by one in the Fe-C equilibrium calculation. It is found that the precipitated carbides are bulk-like MC, long stripe-like M2C, fishbone-like M6C, and daisy-like M7C3 during the tempering process. The stable carbides are MC and M6C, but the meta-stable ones are M2C, M7C3, and M3C.
基金supported by the Natural Science Foundation of Southwest University of Science and Technology (No.19zx7163)the National Natural Science Foundation of China (No.51975492)。
文摘The present work employed the X-ray diffraction, scanning electron microscopy, electron backscattered diffraction, and electron probe microanalysis techniques to identify the microstructural evolution and mechanical and abrasive behavior of high carbon steel during quenching-partitioning treatment with an aim to enhance the toughness and wear resistance of high carbon steel.Results showed that, with the increase in partitioning temperature from 250 to 400℃, the amount of retained austenite(RA) decreased resulting from the carbide precipitation effect after longer partitioning times.Moreover, the stability of RA generally increased because of the enhanced degree of carbon enrichment in RA.Given the factors affecting the toughness of high carbon steel, the stability of RA associated with size, carbon content, and morphology plays a significant role in determining the toughness of high carbon steel.The analysis of the wear resistance of samples with different mechanical properties shows that hardness is the primary factor affecting the wear resistance of high carbon steel, and the toughness is the secondary one.