Spontaneous combustion of oil shale is very common as a result of long-time exposure to the air in the Fushun West Open-Pit Mine and West Dump. The PAHs in the high-grade off shale and its spontaneous combustion produ...Spontaneous combustion of oil shale is very common as a result of long-time exposure to the air in the Fushun West Open-Pit Mine and West Dump. The PAHs in the high-grade off shale and its spontaneous combustion product were analyzed semiquantitatively by GC-MS in order to investigate their distribution in different states and their potential negative effects on the environment. Totally 57 and 60 PAHs and their alkyl homologues were identified in the two analyzed samples, among which the alkyl derivatives were predominant, taking up to about 65% in the total PAHs. Those low-molecular mass PAHs （3- or 4-ring） were the main compounds in the two samples. Ten of sixteen USEPA priority pollutant PAHs were detected in two samples, of which phenanthrene was the richest whose contents were 6.93% and 15.03%. Based on comparison of analysis results, the amount and contents of PAHs, except for triaromatic steroid group, were higher in the burning oil shale. So it can be determined that the effects caused by spontaneous combustion of oil shale would be more serious and that the effects of the Fushun oil shale and its spontaneous combustion on the environment should not be ignored in the future work.展开更多
Continental shale oil has two types, low-medium maturity and medium-high maturity, and they are different in terms of resource environment, potential, production methods and technologies, and industrial evaluation cri...Continental shale oil has two types, low-medium maturity and medium-high maturity, and they are different in terms of resource environment, potential, production methods and technologies, and industrial evaluation criteria. In addition, continental shale oil is different from the shale oil and tight oil in the United States. Scientific definition of connotations of these resource types is of great significance for promoting the exploration of continental shale oil from "outside source" into "inside source" and making it a strategic replacement resource in the future. The connotations of low-medium maturity and medium-high maturity continental shale oils are made clear in this study. The former refers to the liquid hydrocarbons and multiple organic matter buried in the continental organic-rich shale strata with a burial depth deeper than 300 m and a Ro value less than 1.0%. The latter refers to the liquid hydrocarbons present in organic-rich shale intervals with a burial depth that in the "liquid window" range of the Tissot model and a Ro value greater than 1.0%. The geological characteristics, resource potential and economic evaluation criteria of different types of continental shale oil are systematically summarized. According to evaluation, the recoverable resources of in-situ conversion technology for shale oil with low-medium maturity in China is about(700-900)×10^8 t, and the economic recoverable resources under medium oil price condition($ 60-65/bbl) is(150-200)×10^8 t. Shale oil with low-medium maturity guarantees the occurrence of the continental shale oil revolution. Pilot target areas should be optimized and core technical equipment should be developed according to the key parameters such as the cumulative production scale of well groups, the production scale, the preservation conditions, and the economics of exploitation. The geological resources of medium-high maturity shale oil are about 100×10^8 t, and the recoverable resources can to be determined after the daily production and cumulative production of a single well reach the economic threshold. Continental shale oil and tight oil are different in lithological combinations, facies distribution, and productivity evaluation criteria. The two can be independently distinguished and coexist according to different resource types. The determination of China’s continental shale oil types, resources potentials, and tight oil boundary systems can provide a reference for the upcoming shale oil exploration and development practices and help the development of China’s continental shale oil.展开更多
On the basis of the characterization of microscopic pore-throats in shale oil reservoirs by high-pressure mercury intrusion technique, a grading evaluation standard of shale oil reservoirs and a lower limit for reserv...On the basis of the characterization of microscopic pore-throats in shale oil reservoirs by high-pressure mercury intrusion technique, a grading evaluation standard of shale oil reservoirs and a lower limit for reservoir formation were established. Simultaneously, a new method for the classification of shale oil flow units based on logging data was established. A new classification scheme for shale oil reservoirs was proposed according to the inflection points and fractal features of mercury injection curves: microscopic pore-throats(less than 25 nm), small pore-throats(25-100 nm), medium pore-throats(100-1 000 nm) and big pore-throats(greater than 1 000 nm). Correspondingly, the shale reservoirs are divided into four classes, I, II, III and IV according to the number of microscopic pores they contain, and the average pore-throat radii corresponding to the dividing points are 150 nm, 70 nm and 10 nm respectively. By using the correlation between permeability and pore-throat radius, the permeability thresholds for the reservoir classification are determined at 1.00× 10^(-3) μm^2, 0.40×10^(-3) μm^2 and 0.05×10^(-3) μm^2 respectively. By using the exponential relationship between porosity and permeability of the same hydrodynamic flow unit, a new method was set up to evaluate the reservoir flow belt index and to identify shale oil flow units with logging data. The application in the Dongying sag shows that the standard proposed is suitable for grading evaluation of shale oil reservoirs.展开更多
The geochemical analysis and experimental simulation are comprehensively used to systematically study the hydrocarbon generation material,organic matter enrichment and hydrocarbon generation model of Paleogene source ...The geochemical analysis and experimental simulation are comprehensively used to systematically study the hydrocarbon generation material,organic matter enrichment and hydrocarbon generation model of Paleogene source rock in the Western Qaidam Depression,Qaidam Basin,NW China.Three main factors result in low TOC values of saline lacustrine source rock of the Qaidam Basin:relatively poor nutrient supply inhibits the algal bloom,too fast deposition rate causes the dilution of organic matter,and high organic matter conversion efficiency causes the low residual organic carbon.For this type of hydrogen-rich organic matter,due to the reduction of organic carbon during hydrocarbon generation,TOC needs to be restored based on maturity before evaluating organic matter abundance.The hydrocarbon generation of saline lacustrine source rocks of the Qaidam Basin is from two parts:soluble organic matter and insoluble organic matter.The soluble organic matter is inherited from organisms and preserved in saline lacustrine basins.It generates hydrocarbons during low-maturity stage,and the formed hydrocarbons are rich in complex compounds such as NOS,and undergo secondary cracking to form light components in the later stage;the hydrocarbon generation model of insoluble organic matter conforms to the traditional“Tissot”model,with an oil generation peak corresponding to Ro of 1.0%.展开更多
The Huadian Basin is an oil shale-bearing basin located in northeastern China. Thirteen oil shale layers deposited in this basin, and the characteristics of oil shale are different among these oil shale layers. Based ...The Huadian Basin is an oil shale-bearing basin located in northeastern China. Thirteen oil shale layers deposited in this basin, and the characteristics of oil shale are different among these oil shale layers. Based on the core observation and microscope identification, using the organic and inor- ganic data from borehole HD3 and outcrops, the formation conditions of different grade oil shale have been evaluated. Based on measuring oil yield （OY in short） of an oil shale to determine its grade, this paper classifies the oil shale as high grade （OY〉10%）, medium grade （10%〉OY〉5%） and low grade （5%〉OY〉3.5%）. The high grade oil shale is mainly in brown or dark brown, and the bulk density ranges from 1.59 to 1.81 g/cm3. The results of X-ray diffraction indicate the content of carbonate min- erals is 28.0%. The HI （hydrogen index）-Tmax, HI-OI （oxygen index） and S2-TOC （total organic carbon） diagrams indicate the kerogen types are I and II1. The high grade oil shale generally formed in the rela- tively arid paleoclimate, deposited in the brackish water, dysoxic environment, when the bioprodctivity is extremely high, and the information is mainly from the inorganic parameters diagrams of chemical index of alteration （CIA）, Sr/Ba and V/（V＋Ni）. The medium grade oil shale mainly shows grey-black or black-brown color and the bulk density ranges from 1.87 to 2.08 g/cm^3. The average content of carbon- ate minerals is 16.4%, far less than high grade oil shale and the kerogen type is mainly IIm. The inor- ganic parameters diagrams reflect the medium grade oil shale generally formed in the less humid pa- leoclimate, deposited in the brackish water, dysoxic to anoxic environment, when the bioproductivity is medium. The color of low grade oil shale is major in grey-black or dark grey and the bulk density ranges from 2.00 to 2.15 g/cm^3. The average content of carbonate minerals is sharply decreased and the kerogen type is mainly II1. The inorganic parameters diagrams indicate the low grade oil shale gener- ally formed in the relatively humid paleoclimate, deposited in the freshwater to brackish water, anoxic environment, when the bioproductivity is relatively low. Comprehensive study suggest the increasing precipitation caused by a relatively humid paleoclimate resulted in decreasing oxygen concentration and salinity in the bottom water, restrained the salinity stratification, and tended to form the low grade oil shale. The strong evaporation leading to relatively arid paleoclimate resulted in increasing oxygen concentration and salinity in the bottom water, and promoted the salinity stratification. The area with well preservation conditions caused by the relative high sedimentary rate and salinity stratification are favorable to high grade oil shale deposit. In summary, the bioproductivity and the paleoclimate are the main factors controlling the oil shale grade in the Huadian Basin, when the bioproductivity is relatively high and the paleoclimate is relatively arid, it is prone to form the high grade oil shale. However the low grade oil shale developed in the low bioproductivity and relatively humid paleoclimate.展开更多
文摘Spontaneous combustion of oil shale is very common as a result of long-time exposure to the air in the Fushun West Open-Pit Mine and West Dump. The PAHs in the high-grade off shale and its spontaneous combustion product were analyzed semiquantitatively by GC-MS in order to investigate their distribution in different states and their potential negative effects on the environment. Totally 57 and 60 PAHs and their alkyl homologues were identified in the two analyzed samples, among which the alkyl derivatives were predominant, taking up to about 65% in the total PAHs. Those low-molecular mass PAHs （3- or 4-ring） were the main compounds in the two samples. Ten of sixteen USEPA priority pollutant PAHs were detected in two samples, of which phenanthrene was the richest whose contents were 6.93% and 15.03%. Based on comparison of analysis results, the amount and contents of PAHs, except for triaromatic steroid group, were higher in the burning oil shale. So it can be determined that the effects caused by spontaneous combustion of oil shale would be more serious and that the effects of the Fushun oil shale and its spontaneous combustion on the environment should not be ignored in the future work.
基金Funded by National Science and Technology Major Project(2016ZX05046)China National Petroleum Corporation International Cooperation Project(2015D-4810-02).
文摘Continental shale oil has two types, low-medium maturity and medium-high maturity, and they are different in terms of resource environment, potential, production methods and technologies, and industrial evaluation criteria. In addition, continental shale oil is different from the shale oil and tight oil in the United States. Scientific definition of connotations of these resource types is of great significance for promoting the exploration of continental shale oil from "outside source" into "inside source" and making it a strategic replacement resource in the future. The connotations of low-medium maturity and medium-high maturity continental shale oils are made clear in this study. The former refers to the liquid hydrocarbons and multiple organic matter buried in the continental organic-rich shale strata with a burial depth deeper than 300 m and a Ro value less than 1.0%. The latter refers to the liquid hydrocarbons present in organic-rich shale intervals with a burial depth that in the "liquid window" range of the Tissot model and a Ro value greater than 1.0%. The geological characteristics, resource potential and economic evaluation criteria of different types of continental shale oil are systematically summarized. According to evaluation, the recoverable resources of in-situ conversion technology for shale oil with low-medium maturity in China is about(700-900)×10^8 t, and the economic recoverable resources under medium oil price condition($ 60-65/bbl) is(150-200)×10^8 t. Shale oil with low-medium maturity guarantees the occurrence of the continental shale oil revolution. Pilot target areas should be optimized and core technical equipment should be developed according to the key parameters such as the cumulative production scale of well groups, the production scale, the preservation conditions, and the economics of exploitation. The geological resources of medium-high maturity shale oil are about 100×10^8 t, and the recoverable resources can to be determined after the daily production and cumulative production of a single well reach the economic threshold. Continental shale oil and tight oil are different in lithological combinations, facies distribution, and productivity evaluation criteria. The two can be independently distinguished and coexist according to different resource types. The determination of China’s continental shale oil types, resources potentials, and tight oil boundary systems can provide a reference for the upcoming shale oil exploration and development practices and help the development of China’s continental shale oil.
基金Supported by the National Natural Science Foundation of China(41330313,41402122)China National Science and Technology Major Project(2017ZX05049004-003)+1 种基金Research Project Funded by the SINOPEC Corp.(P15028)Fundamental Research Funds for the Central Universities(15CX05046A,15CX07004A,17CX02074)
文摘On the basis of the characterization of microscopic pore-throats in shale oil reservoirs by high-pressure mercury intrusion technique, a grading evaluation standard of shale oil reservoirs and a lower limit for reservoir formation were established. Simultaneously, a new method for the classification of shale oil flow units based on logging data was established. A new classification scheme for shale oil reservoirs was proposed according to the inflection points and fractal features of mercury injection curves: microscopic pore-throats(less than 25 nm), small pore-throats(25-100 nm), medium pore-throats(100-1 000 nm) and big pore-throats(greater than 1 000 nm). Correspondingly, the shale reservoirs are divided into four classes, I, II, III and IV according to the number of microscopic pores they contain, and the average pore-throat radii corresponding to the dividing points are 150 nm, 70 nm and 10 nm respectively. By using the correlation between permeability and pore-throat radius, the permeability thresholds for the reservoir classification are determined at 1.00× 10^(-3) μm^2, 0.40×10^(-3) μm^2 and 0.05×10^(-3) μm^2 respectively. By using the exponential relationship between porosity and permeability of the same hydrodynamic flow unit, a new method was set up to evaluate the reservoir flow belt index and to identify shale oil flow units with logging data. The application in the Dongying sag shows that the standard proposed is suitable for grading evaluation of shale oil reservoirs.
基金Supported by the PetroChina Science and Technology Project(2021DJ1808).
文摘The geochemical analysis and experimental simulation are comprehensively used to systematically study the hydrocarbon generation material,organic matter enrichment and hydrocarbon generation model of Paleogene source rock in the Western Qaidam Depression,Qaidam Basin,NW China.Three main factors result in low TOC values of saline lacustrine source rock of the Qaidam Basin:relatively poor nutrient supply inhibits the algal bloom,too fast deposition rate causes the dilution of organic matter,and high organic matter conversion efficiency causes the low residual organic carbon.For this type of hydrogen-rich organic matter,due to the reduction of organic carbon during hydrocarbon generation,TOC needs to be restored based on maturity before evaluating organic matter abundance.The hydrocarbon generation of saline lacustrine source rocks of the Qaidam Basin is from two parts:soluble organic matter and insoluble organic matter.The soluble organic matter is inherited from organisms and preserved in saline lacustrine basins.It generates hydrocarbons during low-maturity stage,and the formed hydrocarbons are rich in complex compounds such as NOS,and undergo secondary cracking to form light components in the later stage;the hydrocarbon generation model of insoluble organic matter conforms to the traditional“Tissot”model,with an oil generation peak corresponding to Ro of 1.0%.
基金financially supported by the Ministry of Land Resources National Department Public Benefit Research Foundation(No.201211051-04)the National Natural Science Foundation of China(No.41302075)+2 种基金the Specialized Research Fund for the Doctoral Program of Higher Education(No.20110061110050)the Graduate Innovation Fund of Jilin University(No.2014027)the support of the Opening Foundation of Key Laboratory for Oil Shale and Paragenetic Energy Minerals,Jilin Province
文摘The Huadian Basin is an oil shale-bearing basin located in northeastern China. Thirteen oil shale layers deposited in this basin, and the characteristics of oil shale are different among these oil shale layers. Based on the core observation and microscope identification, using the organic and inor- ganic data from borehole HD3 and outcrops, the formation conditions of different grade oil shale have been evaluated. Based on measuring oil yield （OY in short） of an oil shale to determine its grade, this paper classifies the oil shale as high grade （OY〉10%）, medium grade （10%〉OY〉5%） and low grade （5%〉OY〉3.5%）. The high grade oil shale is mainly in brown or dark brown, and the bulk density ranges from 1.59 to 1.81 g/cm3. The results of X-ray diffraction indicate the content of carbonate min- erals is 28.0%. The HI （hydrogen index）-Tmax, HI-OI （oxygen index） and S2-TOC （total organic carbon） diagrams indicate the kerogen types are I and II1. The high grade oil shale generally formed in the rela- tively arid paleoclimate, deposited in the brackish water, dysoxic environment, when the bioprodctivity is extremely high, and the information is mainly from the inorganic parameters diagrams of chemical index of alteration （CIA）, Sr/Ba and V/（V＋Ni）. The medium grade oil shale mainly shows grey-black or black-brown color and the bulk density ranges from 1.87 to 2.08 g/cm^3. The average content of carbon- ate minerals is 16.4%, far less than high grade oil shale and the kerogen type is mainly IIm. The inor- ganic parameters diagrams reflect the medium grade oil shale generally formed in the less humid pa- leoclimate, deposited in the brackish water, dysoxic to anoxic environment, when the bioproductivity is medium. The color of low grade oil shale is major in grey-black or dark grey and the bulk density ranges from 2.00 to 2.15 g/cm^3. The average content of carbonate minerals is sharply decreased and the kerogen type is mainly II1. The inorganic parameters diagrams indicate the low grade oil shale gener- ally formed in the relatively humid paleoclimate, deposited in the freshwater to brackish water, anoxic environment, when the bioproductivity is relatively low. Comprehensive study suggest the increasing precipitation caused by a relatively humid paleoclimate resulted in decreasing oxygen concentration and salinity in the bottom water, restrained the salinity stratification, and tended to form the low grade oil shale. The strong evaporation leading to relatively arid paleoclimate resulted in increasing oxygen concentration and salinity in the bottom water, and promoted the salinity stratification. The area with well preservation conditions caused by the relative high sedimentary rate and salinity stratification are favorable to high grade oil shale deposit. In summary, the bioproductivity and the paleoclimate are the main factors controlling the oil shale grade in the Huadian Basin, when the bioproductivity is relatively high and the paleoclimate is relatively arid, it is prone to form the high grade oil shale. However the low grade oil shale developed in the low bioproductivity and relatively humid paleoclimate.
