Rice grain yield and quality are negatively impacted by high temperature stress.Irrigation water temperature significantly affects rice growth and development,thus influencing yield and quality.The role of cooler irri...Rice grain yield and quality are negatively impacted by high temperature stress.Irrigation water temperature significantly affects rice growth and development,thus influencing yield and quality.The role of cooler irrigation water in counteracting high temperature induced damages in rice grain yield and quality are not explored.Hence,in the present study two rice hybrids,Liangyoupeijiu(LYPJ)and IIyou 602(IIY602)were exposed to heat stress and irrigated with water having different temperatures in a splitsplit plot experimental design.The stress was imposed starting from heading until maturity under field-based heat tents,over two consecutive years.The maximum day temperature inside the heat tents was set at 38℃.For the irrigation treatments,two different water sources were used including belowground water with cooler water temperature and pond water with relatively higher water temperature.Daytime mean temperatures in the heat tents were increased by 1.2–2.0℃ across two years,while nighttime temperature remained similar at both within and outside the heat tents.Cooler belowground water irrigation did have little effect on air temperature at the canopy level but decreased soil temperature(0.2–1.4℃)especially under control.Heat stress significantly reduced grain yield(33%to 43%),panicles m^(-2)(9%to 10%),spikelets m^(-2)(15%to 22%),grain-filling percentage(13%to 26%)and 1000-grain weight(3%to 5%).Heat stress significantly increased chalkiness and protein content and decreased grain length and amylose content.Grain yield was negatively related to air temperature at the canopy level and soil temperature.Whereas grain quality parameters like chalkiness recorded a significantly positive association with both air and soil temperatures.Irrigating with cooler belowground water reduced the negative effect of heat stress on grain yield by 8.8%in LYPJ,while the same effect was not seen in IIY602,indicating cultivar differences in their response to irrigation water temperature.Our findings reveal that irrigating with cooler belowground water would not significantly mitigate yield loss or improve grain quality under realistic field condition.The outcome of this study adds to the scientific knowledge in understanding the interaction between heat stress and irrigation as a mitigation tool.Irrigation water temperature regulation at the rhizosphere was unable to counteract heat stress damages in rice and hence a more integrated management and genetic options at canopy levels should be explored in the future.展开更多
In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sour...In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sources,particle sizes of silica flour,and additions of silica fume,alumina,colloidal iron oxide and nano-graphene,were investigated.To simulate the environment of cementing geothermal wells and deep wells,cement slurries were directly cured at 50 MPa and 200?C.Mineral compositions(as determined by X-ray diffraction Rietveld refinement),water permeability,compressive strength and Young’s modulus were used to evaluate the qualities of the set cement.Short-term curing(2e30 d)test results indicated that the adoption of 6 m m ultrafine crystalline silica played the most important role in stabilizing the mechanical properties of oil well cement systems,while the addition of silica fume had a detrimental effect on strength stability.Long-term curing(2e180 d)test results indicated that nano-graphene could stabilize the Young’s modulus of oil well cement systems.However,none of the ad-mixtures studied here can completely prevent the strength retrogression phenomenon due to their inability to stop the conversion of amorphous to crystalline phases.展开更多
The kinetics of non-catalyzed decompositions of xylose and its decomposition product furfural in high temperature liquid water (HTLW) was studied for temperature from 180 to 220℃ and under pressure of 10MPa. The ma...The kinetics of non-catalyzed decompositions of xylose and its decomposition product furfural in high temperature liquid water (HTLW) was studied for temperature from 180 to 220℃ and under pressure of 10MPa. The main products of xylose decomposition were furfural and formic acid, and furfural further degraded to formic acid under HTLW condition. With the assumption of first order kinetics e.quation, the evaluated activation energy of xylose and furfural decomposition was 123.27kJ·mol^-1 and 58.84kJ·mol^-1, respectively.展开更多
To study the effect of high temperature, rice seedlings 20, 30, 40 and 50 d were kept at 5, 10, 15 and 20 cm water depth in a water pool. Meteorological findings indicated that water temperature varied up to 10 cm but...To study the effect of high temperature, rice seedlings 20, 30, 40 and 50 d were kept at 5, 10, 15 and 20 cm water depth in a water pool. Meteorological findings indicated that water temperature varied up to 10 cm but became stable below this depth. Deep water inflicted higher tiller mortality, minimal increase in dry weight of aerial parts and leaf area, decrease in root length, and decrease in root dry weight especially at 20 cm water depth and produced an unbalanced T/R ratio (top versus root dry weight). However, deep water tended to increase plant length. These parameters, however, excel in shallow water. Older seedlings, with the exception of root dry weight, could not perform well compared to young seedlings in all physiological and morphological aspects. The study revealed that seedlings, particularly young ones, stand well in shallow water and can cope with high temperature.展开更多
A finite element is established for analyzing the dynamical mechanics and deformation of steel frame at high temperature when it is rapidly cooled down by spray water in fire fighting, The simulation result shows that...A finite element is established for analyzing the dynamical mechanics and deformation of steel frame at high temperature when it is rapidly cooled down by spray water in fire fighting, The simulation result shows that remarkable mechanical coupling effects are produced in the process, and the sectional stress in rapid cooling down is found considerably larger than that in heating-up. Meanwhile, the stress and deformation of a beam mainly related to cooling rate and location are much larger than those of a column in rapid cooling, In fire fighting, the structure on the first or second floor was more dangerous than those on other floors in rapid cooling, These results could provide a theoretical reference for the design of steel structure and fire fighting.展开更多
High temperature liquid water(HTLW) has drawn increasing attention as an environmentally benign medium for organic chemical reactions,especially acid-/base-catalyzed reactions. Non-catalyzed hydrolyses of gallotannin ...High temperature liquid water(HTLW) has drawn increasing attention as an environmentally benign medium for organic chemical reactions,especially acid-/base-catalyzed reactions. Non-catalyzed hydrolyses of gallotannin and tara tannin in HTLW for the simultaneous preparation of gallic acid(GA) and pyrogallol(PY) are under investigation in our laboratory. In this study,the hydrolysis kinetics of gallotannin and tara tannin were determined. The reaction is indicated to be a typical consecutive first-order one in which GA has formed as a main intermediate and PY as the final product. Selective decomposition of tannin in HTLW was proved to be possible by adjusting reaction temperature and time. The present results provide an important basic data and reference for the green preparation of GA and PY.展开更多
Aiming at reducing the difficulty of cooling the interior of high-density motors,this study proposed the placement of a water cold plate cooling structure between the axial laminations of the motor stator.The effect o...Aiming at reducing the difficulty of cooling the interior of high-density motors,this study proposed the placement of a water cold plate cooling structure between the axial laminations of the motor stator.The effect of the cooling water flow,thickness of the plate,and motor loss density on the cooling effect of the water cold plate were studied.To compare the cooling performance of water cold plate and outer spiral water jacket cooling structures,a high-speed permanent magnet motor with a high loss density was used to establish two motor models with the two cooling structures.Consequently,the cooling effects of the two models were analyzed using the finite element method under the same loss density,coolant flow,and main dimensions.The results were as follows.(1)The maximum and average temperatures of the water cold plate structure were reduced by 25.5%and 30.5%,respectively,compared to that of the outer spiral water jacket motor;(2)Compared with the outer spiral water jacket structure,the water cold plate structure can reduce the overall mass and volume of the motor.Considering a 100 kW high-speed permanent magnet motor as an example,a water cold plate cooling system was designed,and the temperature distribution is analyzed,with the result indicating that the cooling structure satisfied the cooling requirements of the high loss density motor.展开更多
Two novel and environmentally benign solvent systems, organic acids-ennchea high temperature liquid water (HTLW) and NH3-enriched HTLW, were developed, which can enhance the reaction rate of acid/base-catalyzed orga...Two novel and environmentally benign solvent systems, organic acids-ennchea high temperature liquid water (HTLW) and NH3-enriched HTLW, were developed, which can enhance the reaction rate of acid/base-catalyzed organic reactions in HTLW. We investigated the decomposition of fructose in organic acids-enriched HTLW, hydrolysis of cinnamaldehyde and aldol condensation of phenylaldehyde with acetaldehyde in NH3-enriched HTLW. The experimental results demonstrated that organic acids-enriched or NH3-enriched HTLW can greatly accelerate acid/base-catalyzed organic reactions in HTLW.展开更多
An inconsecutive high frequency distribution with a"sandwich structure"pattern for high temperature warm water warmer than 29℃ in the western Pacific warm pool(WPWP) was found using Tropical Rainfall Measur...An inconsecutive high frequency distribution with a"sandwich structure"pattern for high temperature warm water warmer than 29℃ in the western Pacific warm pool(WPWP) was found using Tropical Rainfall Measuring Mission(TRMM) sea surface temperature(SST) data,a relatively high resolution data for space.This phenomenon only shows up in boreal summer(June to September),and becomes obvious when WPWP SST is higher than 29℃.As observed,East Asian summer monsoon(EASM) impinges on Philippine Islands in July,which has an important impact on the formation and maintenance of the "sandwich structure".Winds affect the distribution of SST in two ways:one by increasing the local latent heat flux and the other by transporting cold water towards the southeast of Philippine Islands.展开更多
To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines...To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines temperature effects on the rheological properties of two types of high-density water-based drilling fluids (fresh water-based and brine-based) under high temperature and high pressure (HTHP) with a Fann 50SL rheometer. On the basis of the water-based drilling fluid systems formulated in laboratory, this paper mainly describes the influences of different types and concentration of clay, the content of a colloid stabilizer named GHJ-1 and fluid density on the rheological parameters such as viscosity and shear stress. In addition, the effects of aging temperature and aging time of the drilling fluid on these parameters were also examined. Clay content and proportions for different densities of brine-based fluids were recommended to effectively regulate the rheological properties. Four theological models, the Bingham, power law, Casson and H-B models, were employed to fit the rheological parameters. It turns out that the H-B model was the best one to describe the rheological properties of the high-density drilling fluid under HTHP conditions and power law model produced the worst fit. In addition, a new mathematical model that describes the apparent viscosity as a function of temperature and pressure was established and has been applied on site.展开更多
The water wall is an important part of the passive natural circulation residual heat removal system in a high temperature gas-cooled reactor. The maximum temperatures of the pressure shell and the water wall are calcu...The water wall is an important part of the passive natural circulation residual heat removal system in a high temperature gas-cooled reactor. The maximum temperatures of the pressure shell and the water wall are calcu- lated using annular vertical closed cavity model. Fine particles can deposit on the water wall due to the thermophore- sis effect. This deposit can affect heat transfer. The thermophoretic deposit efficiency is calculated by using Batch and Shen’s formula fitted for both laminar flow and turbulent flow. The calculated results indicate that natural convection is turbulent in the closed cavity. The transient thermophoretic deposit efficiency rises with the increase of the pressure shell’s temperature. Its maximum value is 14%.展开更多
[Objective] The study aimed to find a possible way to combat or alleviate the negative effects caused by high temperature and water deficit at the growth stage of peak boll-setting.[Method] With Bt transgenic cotton G...[Objective] The study aimed to find a possible way to combat or alleviate the negative effects caused by high temperature and water deficit at the growth stage of peak boll-setting.[Method] With Bt transgenic cotton GK22 as the test cultivar,a potted experiment was carried out to investigate the effects of the regulation of external substances(the water solutions of pix,urea and their mixture) on the physiological parameters,insecticidal protein content,yield and yield component of cotton plants in artificial climate chambers treated with high temperature and water deficit.[Result] The application of external pix,urea or their mixture was effective in stabilizing the physiological parameters of cotton plants,insecticidal protein content,yield and yield components.Compared with the exclusive application of pix and urea,the mixture of pix and urea played the most effective role in stabilizing the content of chlorophyll,soluble sugar and insecticidal protein,alleviating the increase of the content of free amino acids and proline,and increasing boll number per plant,boll weight and seed cotton yield.[Conclusion] The water solutions of pix,urea or their mixtures can be used to combat or alleviate the stress of high temperature and water deficit if they are sprayed onto cotton plants prior to stress occurrence.展开更多
Aiming at the high temperature corrosion in a coal-fired boiler,the effect of H2S and SO2 on the corrosion of 12 CrlMoV under the water wall condition has been investigated by experiments.The results indicate that H2 ...Aiming at the high temperature corrosion in a coal-fired boiler,the effect of H2S and SO2 on the corrosion of 12 CrlMoV under the water wall condition has been investigated by experiments.The results indicate that H2 S can promote the corrosion significantly,and the coarse porous oxide film formed cannot stop the progress of corrosion.While SO2 presents little effect on the corrosion.The main composition of the surface of 12 CrlMoV corrosion products is Fe2 O3.With H2S in the atmosphere,the corrosion gradually develops into deeper layers by forming FeS,FeO and Fe2 O3 alternately.The corrosion rate is doubled for every 50℃ inerease in temperature at 400-500℃.展开更多
In order to ensure the safety of the non-heating gathering and transportation processes for high water fraction crude oil,the effect of temperature,water fraction,and flow rate on the flow characteristics of crude oil...In order to ensure the safety of the non-heating gathering and transportation processes for high water fraction crude oil,the effect of temperature,water fraction,and flow rate on the flow characteristics of crude oil with high water fraction was studied in a flow experimental system of the X Oilfield.Four distinct flow patterns were identified by the photographic and local sampling techniques.Especially,three new flow patterns were found to occur below the pour point of crude oil,including EW/O&W stratified flow with gel deposition,EW/O&W intermittent flow with gel deposition,and water single-phase flow with gel deposition.Moreover,two characteristic temperatures,at which the change rate of pressure drop had changed obviously,were found during the change of pressure drop.The characteristic temperature of the first congestion of gel deposition in the pipeline was determined to be the safe temperature for the non-heating gathering and transportation of high water cut crude oil,while the pressure drop reached the peak at this temperature.An empirical formula for the safe temperature was established for oil-water flow with high water fraction/low fluid production rate.The results can serve as a guide for the safe operation of the non-heating gathering and transportation of crude oil in high water fraction oilfields.展开更多
Tests were carried out to study the strength deterioration of concrete cooled in air or by water after sub-high temperature at different level and varying with cycles. It is proved that the cross-shaped cracks turned ...Tests were carried out to study the strength deterioration of concrete cooled in air or by water after sub-high temperature at different level and varying with cycles. It is proved that the cross-shaped cracks turned up and extended little by little on the surface of specimen subjected to repeat sub-high temperature, the splitting failure is characterized by cross-shaped cracks after 30 cycles, the concrete strengths decrease rapidly at early stage and to be steady subsequently with the increase of the temperature cycles, the splitting-tensile strength is more sensitive to temperature cycles than the compressive strength, the decline of concrete strength is mainly controlled by the maximum temperature having reached, the ultrasonic velocity in concrete is also declined. On the basis of test results, the mechanisms of sub-high temperature to the strength deterioration of concrete are analyzed.The formulas for calculating the compressive and splitting-tensile strength of concrete relating to the variation of temperature are proposed.展开更多
The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significa...The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significant contributing factor to the challenges faced is the inadequacy of existing soil mechanics experimental instruments in providing effective indicators,creating a bottleneck in comprehensively understanding the mechanisms of land subsidence.It is urgent to develop a multi-field and multi-functional soil mechanics experimental system to address this issue.Based soil mechanics theories,the existing manufacturing capabilities of triaxial apparatus and the practical demands of the test system,a set of multi-field coupled high-pressure triaxial system is developed tailored for testing deep soils(at depths of approximately 3000 m)and soft rock.This system incorporates specialized design elements such as high-pressure chamber and horizontal deformation testing devices.In addition to the conventional triaxial tester functions,its distinctive feature encompass a horizontal deformation tracking measuring device,a water release testing device and temperature control device for the sample.This ensemble facilitates testing of horizontal and vertical deformation water release and other parameters of samples under a specified stress conditions,at constant or varying temperature ranging from-40℃–90℃.The accuracy of the tested parameters meets the requirements of relevant current specifications.The test system not only provides scientifically robust data for revealing the deformation and failure mechanism of soil subjected to extreme temperature,but also offers critical data support for major engineering projects,deep exploration and mitigation efforts related to soil deformation-induced disaster.展开更多
基金provided by Science and Technology Plan Project of Hunan Province(2019RS1054)Open Research Fund of State Key Laboratory of Hybrid Rice provided by Hunan Hybrid Rice Research Center(2018KF05)+4 种基金Scientific Research Fund of Hunan Provincial Education Department(18B109)Scientific Research Funding for Crop Science(YXQN2018-6)Hundred Talents Program of the Hunan Provincethe grant support from Hong Kong Research Grants Council(GRF 12103219 and 12103220 and Ao E/M-403/16)a Scholarship from Hong Kong Scholars Program。
文摘Rice grain yield and quality are negatively impacted by high temperature stress.Irrigation water temperature significantly affects rice growth and development,thus influencing yield and quality.The role of cooler irrigation water in counteracting high temperature induced damages in rice grain yield and quality are not explored.Hence,in the present study two rice hybrids,Liangyoupeijiu(LYPJ)and IIyou 602(IIY602)were exposed to heat stress and irrigated with water having different temperatures in a splitsplit plot experimental design.The stress was imposed starting from heading until maturity under field-based heat tents,over two consecutive years.The maximum day temperature inside the heat tents was set at 38℃.For the irrigation treatments,two different water sources were used including belowground water with cooler water temperature and pond water with relatively higher water temperature.Daytime mean temperatures in the heat tents were increased by 1.2–2.0℃ across two years,while nighttime temperature remained similar at both within and outside the heat tents.Cooler belowground water irrigation did have little effect on air temperature at the canopy level but decreased soil temperature(0.2–1.4℃)especially under control.Heat stress significantly reduced grain yield(33%to 43%),panicles m^(-2)(9%to 10%),spikelets m^(-2)(15%to 22%),grain-filling percentage(13%to 26%)and 1000-grain weight(3%to 5%).Heat stress significantly increased chalkiness and protein content and decreased grain length and amylose content.Grain yield was negatively related to air temperature at the canopy level and soil temperature.Whereas grain quality parameters like chalkiness recorded a significantly positive association with both air and soil temperatures.Irrigating with cooler belowground water reduced the negative effect of heat stress on grain yield by 8.8%in LYPJ,while the same effect was not seen in IIY602,indicating cultivar differences in their response to irrigation water temperature.Our findings reveal that irrigating with cooler belowground water would not significantly mitigate yield loss or improve grain quality under realistic field condition.The outcome of this study adds to the scientific knowledge in understanding the interaction between heat stress and irrigation as a mitigation tool.Irrigation water temperature regulation at the rhizosphere was unable to counteract heat stress damages in rice and hence a more integrated management and genetic options at canopy levels should be explored in the future.
基金Financial support comes from China National Natural Science Foundation(Grant No.51974352)as well as from China University of Petroleum(East China)(Grant Nos.2018000025 and 2019000011)。
文摘In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sources,particle sizes of silica flour,and additions of silica fume,alumina,colloidal iron oxide and nano-graphene,were investigated.To simulate the environment of cementing geothermal wells and deep wells,cement slurries were directly cured at 50 MPa and 200?C.Mineral compositions(as determined by X-ray diffraction Rietveld refinement),water permeability,compressive strength and Young’s modulus were used to evaluate the qualities of the set cement.Short-term curing(2e30 d)test results indicated that the adoption of 6 m m ultrafine crystalline silica played the most important role in stabilizing the mechanical properties of oil well cement systems,while the addition of silica fume had a detrimental effect on strength stability.Long-term curing(2e180 d)test results indicated that nano-graphene could stabilize the Young’s modulus of oil well cement systems.However,none of the ad-mixtures studied here can completely prevent the strength retrogression phenomenon due to their inability to stop the conversion of amorphous to crystalline phases.
基金Supported by the National Natural Science Foundation of China (No.20476089) and the Project of the Ministry of Science and Technology of China (No.2004CCA05500).
文摘The kinetics of non-catalyzed decompositions of xylose and its decomposition product furfural in high temperature liquid water (HTLW) was studied for temperature from 180 to 220℃ and under pressure of 10MPa. The main products of xylose decomposition were furfural and formic acid, and furfural further degraded to formic acid under HTLW condition. With the assumption of first order kinetics e.quation, the evaluated activation energy of xylose and furfural decomposition was 123.27kJ·mol^-1 and 58.84kJ·mol^-1, respectively.
文摘To study the effect of high temperature, rice seedlings 20, 30, 40 and 50 d were kept at 5, 10, 15 and 20 cm water depth in a water pool. Meteorological findings indicated that water temperature varied up to 10 cm but became stable below this depth. Deep water inflicted higher tiller mortality, minimal increase in dry weight of aerial parts and leaf area, decrease in root length, and decrease in root dry weight especially at 20 cm water depth and produced an unbalanced T/R ratio (top versus root dry weight). However, deep water tended to increase plant length. These parameters, however, excel in shallow water. Older seedlings, with the exception of root dry weight, could not perform well compared to young seedlings in all physiological and morphological aspects. The study revealed that seedlings, particularly young ones, stand well in shallow water and can cope with high temperature.
基金supported by the National Natural Science Foundation of China (51478002)
文摘A finite element is established for analyzing the dynamical mechanics and deformation of steel frame at high temperature when it is rapidly cooled down by spray water in fire fighting, The simulation result shows that remarkable mechanical coupling effects are produced in the process, and the sectional stress in rapid cooling down is found considerably larger than that in heating-up. Meanwhile, the stress and deformation of a beam mainly related to cooling rate and location are much larger than those of a column in rapid cooling, In fire fighting, the structure on the first or second floor was more dangerous than those on other floors in rapid cooling, These results could provide a theoretical reference for the design of steel structure and fire fighting.
基金Project supported by the National Natural Science Foundation ofChina (No. 20674068)the Natural Science Foundation of Zheji-ang Province, China (No. Y405157)
文摘High temperature liquid water(HTLW) has drawn increasing attention as an environmentally benign medium for organic chemical reactions,especially acid-/base-catalyzed reactions. Non-catalyzed hydrolyses of gallotannin and tara tannin in HTLW for the simultaneous preparation of gallic acid(GA) and pyrogallol(PY) are under investigation in our laboratory. In this study,the hydrolysis kinetics of gallotannin and tara tannin were determined. The reaction is indicated to be a typical consecutive first-order one in which GA has formed as a main intermediate and PY as the final product. Selective decomposition of tannin in HTLW was proved to be possible by adjusting reaction temperature and time. The present results provide an important basic data and reference for the green preparation of GA and PY.
基金supported by the National Natural Science Foundation of China(51920105011)Natural Science Foundation of Liaoning Province(2021-YQ-09)Liaoning Bai Qian Wan Talents Program,China.
文摘Aiming at reducing the difficulty of cooling the interior of high-density motors,this study proposed the placement of a water cold plate cooling structure between the axial laminations of the motor stator.The effect of the cooling water flow,thickness of the plate,and motor loss density on the cooling effect of the water cold plate were studied.To compare the cooling performance of water cold plate and outer spiral water jacket cooling structures,a high-speed permanent magnet motor with a high loss density was used to establish two motor models with the two cooling structures.Consequently,the cooling effects of the two models were analyzed using the finite element method under the same loss density,coolant flow,and main dimensions.The results were as follows.(1)The maximum and average temperatures of the water cold plate structure were reduced by 25.5%and 30.5%,respectively,compared to that of the outer spiral water jacket motor;(2)Compared with the outer spiral water jacket structure,the water cold plate structure can reduce the overall mass and volume of the motor.Considering a 100 kW high-speed permanent magnet motor as an example,a water cold plate cooling system was designed,and the temperature distribution is analyzed,with the result indicating that the cooling structure satisfied the cooling requirements of the high loss density motor.
基金The authors are grateful for the financial support of the National Natural Science Foundation of China(20476089,20176054)Project of the Ministry of Science and Technology of China (No.2004CCA0500) Zhejing Provincial Natural Science Foundation of China(ZE0214).
文摘Two novel and environmentally benign solvent systems, organic acids-ennchea high temperature liquid water (HTLW) and NH3-enriched HTLW, were developed, which can enhance the reaction rate of acid/base-catalyzed organic reactions in HTLW. We investigated the decomposition of fructose in organic acids-enriched HTLW, hydrolysis of cinnamaldehyde and aldol condensation of phenylaldehyde with acetaldehyde in NH3-enriched HTLW. The experimental results demonstrated that organic acids-enriched or NH3-enriched HTLW can greatly accelerate acid/base-catalyzed organic reactions in HTLW.
基金National Natural Science Foundation of China (40975038, 40830106)National Basic Research Program of China (973 Program:2012CB955604)+1 种基金Program from China Meteorological Administration (GYHY200906008)Project 111 (B07036)
文摘An inconsecutive high frequency distribution with a"sandwich structure"pattern for high temperature warm water warmer than 29℃ in the western Pacific warm pool(WPWP) was found using Tropical Rainfall Measuring Mission(TRMM) sea surface temperature(SST) data,a relatively high resolution data for space.This phenomenon only shows up in boreal summer(June to September),and becomes obvious when WPWP SST is higher than 29℃.As observed,East Asian summer monsoon(EASM) impinges on Philippine Islands in July,which has an important impact on the formation and maintenance of the "sandwich structure".Winds affect the distribution of SST in two ways:one by increasing the local latent heat flux and the other by transporting cold water towards the southeast of Philippine Islands.
文摘To maintain tight control over rheological properties of high-density water-based drilling fluids, it is essential to understand the factors influencing the theology of water-based drilling fluids. This paper examines temperature effects on the rheological properties of two types of high-density water-based drilling fluids (fresh water-based and brine-based) under high temperature and high pressure (HTHP) with a Fann 50SL rheometer. On the basis of the water-based drilling fluid systems formulated in laboratory, this paper mainly describes the influences of different types and concentration of clay, the content of a colloid stabilizer named GHJ-1 and fluid density on the rheological parameters such as viscosity and shear stress. In addition, the effects of aging temperature and aging time of the drilling fluid on these parameters were also examined. Clay content and proportions for different densities of brine-based fluids were recommended to effectively regulate the rheological properties. Four theological models, the Bingham, power law, Casson and H-B models, were employed to fit the rheological parameters. It turns out that the H-B model was the best one to describe the rheological properties of the high-density drilling fluid under HTHP conditions and power law model produced the worst fit. In addition, a new mathematical model that describes the apparent viscosity as a function of temperature and pressure was established and has been applied on site.
基金Supported by the Special Funds for Major State Basic Research Projects of China (No.2002CB211604) and the National Key Projects in the Ninth Five –Year Plan (96-G01-02-05).
文摘The water wall is an important part of the passive natural circulation residual heat removal system in a high temperature gas-cooled reactor. The maximum temperatures of the pressure shell and the water wall are calcu- lated using annular vertical closed cavity model. Fine particles can deposit on the water wall due to the thermophore- sis effect. This deposit can affect heat transfer. The thermophoretic deposit efficiency is calculated by using Batch and Shen’s formula fitted for both laminar flow and turbulent flow. The calculated results indicate that natural convection is turbulent in the closed cavity. The transient thermophoretic deposit efficiency rises with the increase of the pressure shell’s temperature. Its maximum value is 14%.
基金Supported by the National Natural Science Foundation of China(3077127231171483)+1 种基金the Priority Academic Program Development of Jiangsu Higher Education Institutions,Jiangsu Innovation Project for Agriculture Science and Technology [cx(11)2054 ]Jiangsu Agriculture Science and Technology Support Program(SBE2010307)
文摘[Objective] The study aimed to find a possible way to combat or alleviate the negative effects caused by high temperature and water deficit at the growth stage of peak boll-setting.[Method] With Bt transgenic cotton GK22 as the test cultivar,a potted experiment was carried out to investigate the effects of the regulation of external substances(the water solutions of pix,urea and their mixture) on the physiological parameters,insecticidal protein content,yield and yield component of cotton plants in artificial climate chambers treated with high temperature and water deficit.[Result] The application of external pix,urea or their mixture was effective in stabilizing the physiological parameters of cotton plants,insecticidal protein content,yield and yield components.Compared with the exclusive application of pix and urea,the mixture of pix and urea played the most effective role in stabilizing the content of chlorophyll,soluble sugar and insecticidal protein,alleviating the increase of the content of free amino acids and proline,and increasing boll number per plant,boll weight and seed cotton yield.[Conclusion] The water solutions of pix,urea or their mixtures can be used to combat or alleviate the stress of high temperature and water deficit if they are sprayed onto cotton plants prior to stress occurrence.
基金supported by the National Key Research and Development Plan of China (No. 2018YFB0604203)
文摘Aiming at the high temperature corrosion in a coal-fired boiler,the effect of H2S and SO2 on the corrosion of 12 CrlMoV under the water wall condition has been investigated by experiments.The results indicate that H2 S can promote the corrosion significantly,and the coarse porous oxide film formed cannot stop the progress of corrosion.While SO2 presents little effect on the corrosion.The main composition of the surface of 12 CrlMoV corrosion products is Fe2 O3.With H2S in the atmosphere,the corrosion gradually develops into deeper layers by forming FeS,FeO and Fe2 O3 alternately.The corrosion rate is doubled for every 50℃ inerease in temperature at 400-500℃.
基金financially supported by the National Natural Science Foundation of China (Grant No.51674281)the Opening Fund of Shandong Provincial Key Laboratory of Oil&Gas Storage (Study on low temperature flow characteristics of oil and water in gathering pipeline)the Transportation Safety and the Fundamental Research Funds for the Central Universities
文摘In order to ensure the safety of the non-heating gathering and transportation processes for high water fraction crude oil,the effect of temperature,water fraction,and flow rate on the flow characteristics of crude oil with high water fraction was studied in a flow experimental system of the X Oilfield.Four distinct flow patterns were identified by the photographic and local sampling techniques.Especially,three new flow patterns were found to occur below the pour point of crude oil,including EW/O&W stratified flow with gel deposition,EW/O&W intermittent flow with gel deposition,and water single-phase flow with gel deposition.Moreover,two characteristic temperatures,at which the change rate of pressure drop had changed obviously,were found during the change of pressure drop.The characteristic temperature of the first congestion of gel deposition in the pipeline was determined to be the safe temperature for the non-heating gathering and transportation of high water cut crude oil,while the pressure drop reached the peak at this temperature.An empirical formula for the safe temperature was established for oil-water flow with high water fraction/low fluid production rate.The results can serve as a guide for the safe operation of the non-heating gathering and transportation of crude oil in high water fraction oilfields.
基金Funded by Outstanding Youth Science Foundation of Henan Province of China (No. 04120002300)
文摘Tests were carried out to study the strength deterioration of concrete cooled in air or by water after sub-high temperature at different level and varying with cycles. It is proved that the cross-shaped cracks turned up and extended little by little on the surface of specimen subjected to repeat sub-high temperature, the splitting failure is characterized by cross-shaped cracks after 30 cycles, the concrete strengths decrease rapidly at early stage and to be steady subsequently with the increase of the temperature cycles, the splitting-tensile strength is more sensitive to temperature cycles than the compressive strength, the decline of concrete strength is mainly controlled by the maximum temperature having reached, the ultrasonic velocity in concrete is also declined. On the basis of test results, the mechanisms of sub-high temperature to the strength deterioration of concrete are analyzed.The formulas for calculating the compressive and splitting-tensile strength of concrete relating to the variation of temperature are proposed.
基金supported by National Natural Science Foundation(No.41272301 and No.42007171)Nature Fund of Hebei(No.D2021504034)Chinese Academy of Geological Sciences(No.YYWF201628).
文摘The increasing severity of ground subsidence,ground fissure and other disasters caused by the excessive exploitation of deep underground resources has highlighted the pressing need for effective management.A significant contributing factor to the challenges faced is the inadequacy of existing soil mechanics experimental instruments in providing effective indicators,creating a bottleneck in comprehensively understanding the mechanisms of land subsidence.It is urgent to develop a multi-field and multi-functional soil mechanics experimental system to address this issue.Based soil mechanics theories,the existing manufacturing capabilities of triaxial apparatus and the practical demands of the test system,a set of multi-field coupled high-pressure triaxial system is developed tailored for testing deep soils(at depths of approximately 3000 m)and soft rock.This system incorporates specialized design elements such as high-pressure chamber and horizontal deformation testing devices.In addition to the conventional triaxial tester functions,its distinctive feature encompass a horizontal deformation tracking measuring device,a water release testing device and temperature control device for the sample.This ensemble facilitates testing of horizontal and vertical deformation water release and other parameters of samples under a specified stress conditions,at constant or varying temperature ranging from-40℃–90℃.The accuracy of the tested parameters meets the requirements of relevant current specifications.The test system not only provides scientifically robust data for revealing the deformation and failure mechanism of soil subjected to extreme temperature,but also offers critical data support for major engineering projects,deep exploration and mitigation efforts related to soil deformation-induced disaster.