A series of poly[（methylsilylene ethynylenephenyleneethynylene）-co-（dimethylsilylene ethynylenephenyleneethynylene）]s were synthesized by the incorporation of various ratios of methylsilylene to dimethylsilylene u...A series of poly[（methylsilylene ethynylenephenyleneethynylene）-co-（dimethylsilylene ethynylenephenyleneethynylene）]s were synthesized by the incorporation of various ratios of methylsilylene to dimethylsilylene units into the polymer chain backbone. The resultant copolymers were soluble in a variety of common organic solvents at room temperature. The copolymers were characterized by FT-IR, ^1H-NMR, GPC, rheological analysis, differential scanning calorimetry （DSC） and thermogravimetric analysis （TGA）. The results showed that the copolymers exhibited good processability and cured at low temperatures like 200℃. The curing reactions involved in hydrosilylation of Si-H and alkyne groups and the polymerization of alkynes. Td5 （5% weight loss） of the cured copolymers ranged from 629℃ to 686℃, and the decomposition residues of cured copolymers at 1000℃ ranged from 88.1% to 90.9% under nitrogen. Thermal stability of the copolymers increased with the introduction of methylsilylene traits into polymer chains. The cured copolymers were sintered at 1450℃, and the results of X-ray diffraction analysis showed that β-SIC was formed in the sintered products.展开更多
A modified silicon-containing arylacetylene resin with a well-defined organic-inorganic POSS functionality was successfully synthesized by Huisgen azide-alkyne 1,3-dipolar cycloaddition. The POSS hybridized resin exhi...A modified silicon-containing arylacetylene resin with a well-defined organic-inorganic POSS functionality was successfully synthesized by Huisgen azide-alkyne 1,3-dipolar cycloaddition. The POSS hybridized resin exhibits excellent thermal properties which were characterized by differential scanning calorimetry （DSC） and thermogravimetric analyses （TGA）. Scanning electron microscope （SEM） was used to characterize fracture surface of the hybridized polymer. The results show that phase separation occurs. The POSS moieties are aggregated each other in the polymer to form 200-400 nm domains.展开更多
基金supported by the National High Technology Research and Development Program of China (No.2002-305205)the Special Material Project Program of China(No.51312)Key Project of Science and Technology Foundation of China(9140-12011308)
文摘A series of poly[（methylsilylene ethynylenephenyleneethynylene）-co-（dimethylsilylene ethynylenephenyleneethynylene）]s were synthesized by the incorporation of various ratios of methylsilylene to dimethylsilylene units into the polymer chain backbone. The resultant copolymers were soluble in a variety of common organic solvents at room temperature. The copolymers were characterized by FT-IR, ^1H-NMR, GPC, rheological analysis, differential scanning calorimetry （DSC） and thermogravimetric analysis （TGA）. The results showed that the copolymers exhibited good processability and cured at low temperatures like 200℃. The curing reactions involved in hydrosilylation of Si-H and alkyne groups and the polymerization of alkynes. Td5 （5% weight loss） of the cured copolymers ranged from 629℃ to 686℃, and the decomposition residues of cured copolymers at 1000℃ ranged from 88.1% to 90.9% under nitrogen. Thermal stability of the copolymers increased with the introduction of methylsilylene traits into polymer chains. The cured copolymers were sintered at 1450℃, and the results of X-ray diffraction analysis showed that β-SIC was formed in the sintered products.
文摘A modified silicon-containing arylacetylene resin with a well-defined organic-inorganic POSS functionality was successfully synthesized by Huisgen azide-alkyne 1,3-dipolar cycloaddition. The POSS hybridized resin exhibits excellent thermal properties which were characterized by differential scanning calorimetry （DSC） and thermogravimetric analyses （TGA）. Scanning electron microscope （SEM） was used to characterize fracture surface of the hybridized polymer. The results show that phase separation occurs. The POSS moieties are aggregated each other in the polymer to form 200-400 nm domains.
