Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition o...Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition on the bulk density, crushing strength, and oxidation resistance was analyzed. The mierostructure of carbon anodes was investigated by scanning electron microscopy （SEM）, and the mechanism of producing carbon anodes by high-temperature mould pressing was analyzed. The results show that when the anodes are produced by high-temperature mould pressing, coal pitch can expand into the coke particles and fill the pores inside the particles, which is beneficial for improving the quality of prebaked anodes. The bulk density of carbon anodes is 1.64-1.66 g/cm3, which is 0.08-0.12 g/cm3 higher than that of industrial anodes, and the oxidation resistance of carbon anodes is also significantly improved.展开更多
Pressure allows the precise tuning of a fundamental parameter, the interatomic distance, which controls the electronic structure and virtually all interatomic interactions that determine material properties. Hence, pr...Pressure allows the precise tuning of a fundamental parameter, the interatomic distance, which controls the electronic structure and virtually all interatomic interactions that determine material properties. Hence, pressure tuning is an effective tool in the search for new materials with enhanced properties. To realize pressure tuning on matter, large-volume press （LVP） apparatuses have been widely used not only to synthesize novel materials but also to implement the in situ measurement of physical properties. Herein, we introduce the LVP apparatuses, including belt-type, cubic anvil, and 6-8 type multi-anvil, that will be constructed at the Synergetic Extreme Condition User Facility （SECUF） at Jilin University. Typically, cell volumes of 1000 mm3 can be obtained at 20 GPa in a belt-type apparatus that is significantly larger than that obtained in a 6-8 type multi-anvil apparatus at the same pressure. Furthermore, the in situ measurement of physical prop- erties, including thermological, electrical, and mechanical behaviors, is coupled to these LVP apparatuses. Some typical results of both synthetic experiments and in situ measurements obtained from the LVP apparatuses are also reviewed.展开更多
A new method to calculate and counterbalance the inertia force of slider-crank mechanisms in high-speed mechanical presses was put forward. By analyzing the kinematic characteristics of a center-located slider-crank m...A new method to calculate and counterbalance the inertia force of slider-crank mechanisms in high-speed mechanical presses was put forward. By analyzing the kinematic characteristics of a center-located slider-crank mechanism whose crank rotates at a constant angular velocity,the kinematic parameters of the slide,connecting rod and crank were formulated approximately. On the basis of the results above,three inertia forces and the input moment in the mechanism during its idle running were investigated and formulated by dynamic analysis. A verification experiment was performed on a slider-crank mechanism at a high-speed press machine. The forces derived from the established formulas were compared respectively with those obtained by the ADAMS software and the classical method of connecting rod mass substitution. It was experimentally found that the proposed formulas have an improved performance over related earlier techniques. By use of these results,a 1 000 kN 1 250 rpm four-point high-speed press machine was designed and manufactured. The slide of this press is driven by four sets of slider-crank mechanisms with symmetrical layout and opposite rotation directions to counterbalance the horizontal inertia forces. Four eccentric counterbalance blocks were designed to counterbalance the vertical force after their mass and equivalent eccentric radius were formulated. The high-speed press machine designed by the proposed counterbalance method has worked with satisfactory performance and good dynamic balance for more than four years in practical production.展开更多
ZrB2 ceramics were prepared by self-propagating high-temperature synthesis（SHS） and were sintered by hot pressing（HP）.The effects of the granularities and doses of raw materials in Zr-B2O3-Mgon SHS process and pro...ZrB2 ceramics were prepared by self-propagating high-temperature synthesis（SHS） and were sintered by hot pressing（HP）.The effects of the granularities and doses of raw materials in Zr-B2O3-Mgon SHS process and product were investigated.XRD and combustion temperature curves prove that the ideal SHS reactants of Zr-B2O3-Mg are 50μm Zr powder,75μm B2O3 powder and 400μm Mg powder with 45% excessive.The particle sizes of SHS product,acid-leached product,sintered product are 2-5μm,0.5-2μm,2-10μm respectively.Chemical analysis indicates that the acid-leached product consists of ZrB2（94.59%）,ZrO2（3.87%）,and H3BO3（1.54%）,The sintered product has a relative density of 95.4%.展开更多
FeAl intermetallic compound with different contents of rare earth oxide La2O3 addition was prepared by hot pressing the mechanically alloyed powders.Effect of La2O3 on microstructure and high-temperature wear property...FeAl intermetallic compound with different contents of rare earth oxide La2O3 addition was prepared by hot pressing the mechanically alloyed powders.Effect of La2O3 on microstructure and high-temperature wear property of the sintered FeAl samples was investigated in this paper.The results showed that 1 wt.% La2O3 addition could refine the microstructure and increase the density of the FeAl intermetallic compound,and correspondingly improved the high-temperature wear resistance.SEM and EDS analyses of the wo...展开更多
The NiAl-28Cr-5.85Mo-0.15Hf alloy was prepared by high-pressure die casting (HPDC) and subsequent hot isostatic pressing(HIP), and tested for compressible strength and fracture behavior at 300-1 373 K. The results sho...The NiAl-28Cr-5.85Mo-0.15Hf alloy was prepared by high-pressure die casting (HPDC) and subsequent hot isostatic pressing(HIP), and tested for compressible strength and fracture behavior at 300-1 373 K. The results show that the elevated temperature 0.2% compressible yield strength as well as the room-temperature compressible fracture strain of as-HIP alloy are larger than those of the same alloy prepared by directional solidification (DS). It suggests that the fine structures with a homogeneous distribution of fine Cr (Mo) and Hf-rich phase created by high-pressure die casting lead to these improvements.展开更多
基金Project(090302012)supported by the Fundamental Research Funds for the Central Universities,ChinaProject(50934005)supported by the National Natural Science Foundation of China
文摘Laboratory-scale carbon anodes were produced by a new method of high temperature mould pressing, and their physico-chemical properties were studied. The influence of mould pressing conditions and coal pitch addition on the bulk density, crushing strength, and oxidation resistance was analyzed. The mierostructure of carbon anodes was investigated by scanning electron microscopy （SEM）, and the mechanism of producing carbon anodes by high-temperature mould pressing was analyzed. The results show that when the anodes are produced by high-temperature mould pressing, coal pitch can expand into the coke particles and fill the pores inside the particles, which is beneficial for improving the quality of prebaked anodes. The bulk density of carbon anodes is 1.64-1.66 g/cm3, which is 0.08-0.12 g/cm3 higher than that of industrial anodes, and the oxidation resistance of carbon anodes is also significantly improved.
文摘Pressure allows the precise tuning of a fundamental parameter, the interatomic distance, which controls the electronic structure and virtually all interatomic interactions that determine material properties. Hence, pressure tuning is an effective tool in the search for new materials with enhanced properties. To realize pressure tuning on matter, large-volume press （LVP） apparatuses have been widely used not only to synthesize novel materials but also to implement the in situ measurement of physical properties. Herein, we introduce the LVP apparatuses, including belt-type, cubic anvil, and 6-8 type multi-anvil, that will be constructed at the Synergetic Extreme Condition User Facility （SECUF） at Jilin University. Typically, cell volumes of 1000 mm3 can be obtained at 20 GPa in a belt-type apparatus that is significantly larger than that obtained in a 6-8 type multi-anvil apparatus at the same pressure. Furthermore, the in situ measurement of physical prop- erties, including thermological, electrical, and mechanical behaviors, is coupled to these LVP apparatuses. Some typical results of both synthetic experiments and in situ measurements obtained from the LVP apparatuses are also reviewed.
基金supported by the National Natural Science Foundation of China (No.50575175)
文摘A new method to calculate and counterbalance the inertia force of slider-crank mechanisms in high-speed mechanical presses was put forward. By analyzing the kinematic characteristics of a center-located slider-crank mechanism whose crank rotates at a constant angular velocity,the kinematic parameters of the slide,connecting rod and crank were formulated approximately. On the basis of the results above,three inertia forces and the input moment in the mechanism during its idle running were investigated and formulated by dynamic analysis. A verification experiment was performed on a slider-crank mechanism at a high-speed press machine. The forces derived from the established formulas were compared respectively with those obtained by the ADAMS software and the classical method of connecting rod mass substitution. It was experimentally found that the proposed formulas have an improved performance over related earlier techniques. By use of these results,a 1 000 kN 1 250 rpm four-point high-speed press machine was designed and manufactured. The slide of this press is driven by four sets of slider-crank mechanisms with symmetrical layout and opposite rotation directions to counterbalance the horizontal inertia forces. Four eccentric counterbalance blocks were designed to counterbalance the vertical force after their mass and equivalent eccentric radius were formulated. The high-speed press machine designed by the proposed counterbalance method has worked with satisfactory performance and good dynamic balance for more than four years in practical production.
文摘ZrB2 ceramics were prepared by self-propagating high-temperature synthesis（SHS） and were sintered by hot pressing（HP）.The effects of the granularities and doses of raw materials in Zr-B2O3-Mgon SHS process and product were investigated.XRD and combustion temperature curves prove that the ideal SHS reactants of Zr-B2O3-Mg are 50μm Zr powder,75μm B2O3 powder and 400μm Mg powder with 45% excessive.The particle sizes of SHS product,acid-leached product,sintered product are 2-5μm,0.5-2μm,2-10μm respectively.Chemical analysis indicates that the acid-leached product consists of ZrB2（94.59%）,ZrO2（3.87%）,and H3BO3（1.54%）,The sintered product has a relative density of 95.4%.
基金supported by the National Natural Science Foundation of China (50575034)
文摘FeAl intermetallic compound with different contents of rare earth oxide La2O3 addition was prepared by hot pressing the mechanically alloyed powders.Effect of La2O3 on microstructure and high-temperature wear property of the sintered FeAl samples was investigated in this paper.The results showed that 1 wt.% La2O3 addition could refine the microstructure and increase the density of the FeAl intermetallic compound,and correspondingly improved the high-temperature wear resistance.SEM and EDS analyses of the wo...
基金Project (05YB31) supported by the Scientific Research Initial Foundation for Doctor of Shenyang Institute of Aeronautical Engineering,China
文摘The NiAl-28Cr-5.85Mo-0.15Hf alloy was prepared by high-pressure die casting (HPDC) and subsequent hot isostatic pressing(HIP), and tested for compressible strength and fracture behavior at 300-1 373 K. The results show that the elevated temperature 0.2% compressible yield strength as well as the room-temperature compressible fracture strain of as-HIP alloy are larger than those of the same alloy prepared by directional solidification (DS). It suggests that the fine structures with a homogeneous distribution of fine Cr (Mo) and Hf-rich phase created by high-pressure die casting lead to these improvements.
