1 Introduction In contrast,1experimental geochemistry is a young subject,but in recent years,the research on experiment of high temperature and high pressure has become an important branch in the parallel subjects of ...1 Introduction In contrast,1experimental geochemistry is a young subject,but in recent years,the research on experiment of high temperature and high pressure has become an important branch in the parallel subjects of traditional mineralogy,petrology,geochemistry and geophysics.It is not only an important and essential way and window to understand geological processes in depth and geological展开更多
The pressure-induced structural transitions of ZnTe are investigated at pressures up to 59.2 GPa in a diamond anvil cell by using synchrotron powder x-ray diffraction method. A phase transition from the initial zinc b...The pressure-induced structural transitions of ZnTe are investigated at pressures up to 59.2 GPa in a diamond anvil cell by using synchrotron powder x-ray diffraction method. A phase transition from the initial zinc blende (ZB, ZnTe-Ⅰ) structure to a cinnabar phase (ZnTe-Ⅱ) is observed at 9.6 GPa, followed by a high pressure orthorhombic phase (ZnTe-Ⅲ) with Cmcm symmetry at 12.1 GPa. The ZB, cinnabar (space group P3121), Cmcm, P31 and rock salt structures of ZnTe are investigated by using density functional theory calculations. Based on the experiments and calculations, the ZnTe-Ⅱ phase is determined to have a cinnabar structure rather than a P3 1 symmetry.展开更多
Center for Analysis and Prediction, China Seismological Bureau, Beijing 100036, China 2) Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China
The transitional pressure of quartz coesite under the differential stress and highly strained conditions is far from the pressure of the stable field under the static pressure. Therefore, the effect of the different...The transitional pressure of quartz coesite under the differential stress and highly strained conditions is far from the pressure of the stable field under the static pressure. Therefore, the effect of the differential stress should be considered when the depth of petrogenesis is estimated about ultrahigh pressure metamorphic (UHPM) rocks. The rheological strength of typical ultrahigh pressure rocks in continental subduction zone was derived from the results of the laboratory experiments. The results indicate the following three points. (1) The rheological strength of gabbro, similar to that of eclogite, is smaller than that of clinopyroxenite on the same condition. (2) The calculated strength of rocks (gabbro, eclogite and clinopyroxenite) related to UHPM decreases by nearly one order of magnitude with the temperature rising by 100 ℃ in the range between 600 and 900 ℃. The calculated strength is far greater than the faulting strength of rocks at 600 ℃, and is in several hundred to more than one thousand mega pascals at 700-800 ℃, which suggests that those rocks are located in the brittle deformation region at 600 ℃, but are in the semi brittle to plastic deformation region at 700-800 ℃. Obviously, the 700 ℃ is a brittle plastic transition boundary. (3) The calculated rheological strength in the localized deformation zone on a higher strain rate condition (1.6×10 -12 s -l ) is 2-5 times more than that in the distributed deformation zone on a lower strain rate condition (1.6×10 -14 s -1 ). The average rheological stress (1 600 MPa) at the strain rate of 10 -12 s -1 stands for the ultimate differential stress of UHPM rocks in the semi brittle flow field, and the average rheological stress (550-950 MPa) at the strain rate of l0 -14 - 10 -13 s -l stands for the ultimate differential stress of UHPM rocks in the plastic flow field, suggesting that the depth for the formation of UHPM rocks is more than 20-60 km below the depth estimated under static pressure condition due to the effect of the differential stress.展开更多
Hydrous minerals are important water carriers in the crust and the mantle, especially in the subduction zone. With the recent development of the experimental technique, studies of the electrical conductivity of hydrou...Hydrous minerals are important water carriers in the crust and the mantle, especially in the subduction zone. With the recent development of the experimental technique, studies of the electrical conductivity of hydrous silicate minerals under controlled temperature, pressure and oxygen fugacity, have helped to constrain the water distribution in the Earth's interior. This paper introduces high pressure and temperature experimental study of electrical conductivity measurement of hydrous minerals such as serpentine, talc, brucite, phase A, super hydrous phase B and phase D, and assesses the data quality of the above minerals. The dehydration effect and the pressure effect on the bulk conductivity of the hydrous minerals are specifically emphasized. The conduction mechanism of hydrous minerals and the electrical structure of the subduction zone are discussed based on the available conductivity data. Finally, the potential research fields of the electrical conductivity of hydrous minerals is presented.展开更多
Jadeite quartzite, essentially a two-phase rock made up of jadeite and quartz, is one of the most important UHP lithologies occur- ring in the Dabie Mountain ultrahigh pressure metamorphic belt and forms layers in bio...Jadeite quartzite, essentially a two-phase rock made up of jadeite and quartz, is one of the most important UHP lithologies occur- ring in the Dabie Mountain ultrahigh pressure metamorphic belt and forms layers in biotite-plagioclase gneiss. High pressure- high temperature studies on natural albite from the country rock gneiss were undertaken to reveal the--in parts----complex mineralogical changes that occur in the jadeite quartzite during prograde metamorphism. Experiments were conducted at 800- 1200~C, in the pressure range of 2.0-3.5 GPa. One of the most intriguing results shows that the low pressure boundary of the jadeite+coesite stability field is located between about 3.2 GPa at 1000~C and 3.4 GPa at 1200~C, thus about (0.2-0.3)_+0.1 GPa higher than the quartz-coesite transition curve, given the uncertainty in the present study. Minor amounts of sodium and aluminum entering the structure of quartz and the intimate intergrowth texture of the run products may contribute to the ob- served pressure shift. Combined petrological and mineralogical studies on the run products and the natural rocks yield the fol- lowing prograde reaction sequence to have occurred: The protolith of the jadeite- quartzite from Dabie Mountain is an albitized siltstone/greywacke characterized by an albite+quartz assemblage. During prograde metamorphism albite breaks down to form jadeite+quartz and thus at this stage two types of quartz can be distinguished whereas type-I-quartz already existed in the pro- tolith, type-II-quartz represents a newly formed reaction product of albite. During further P-T-increase the pure type- I-quartz was transformed to coesite, whereas type-II-quartz (together with jadeite) was still present as a stable phase because of its im- purities of Na and A1. At a later stage during further subduction, type-II-quartz also decomposes to form coesite. These studies represent an important puzzlement for a better understanding of the evolution of jadeite- quartzite from the Dabie Mountain during continental crust subduction and thus contribute to a more complete knowledge of the formation of the Dabie Mountain UHP orogenic belt in general.展开更多
Precise determination of cation diffusivity in garnet can provide critical information for quantitatively understanding the timescales and thermodynamics of various geological processes,but very few studies have been ...Precise determination of cation diffusivity in garnet can provide critical information for quantitatively understanding the timescales and thermodynamics of various geological processes,but very few studies have been performed for Fe-Mn interdiffusion.In this study,Fe-Mn interdiffusion rates in natural single crystals of Mn-bearing garnet with 750 ppm H2O are determined at 6 GPa and 1273-1573 K in a Kawai-type multi-anvil apparatus.Diffusion profiles were acquired by electron microprobe and fitted using Boltzmann-Matano equation.The experimental results show that the Fe-Mn interdiffusion coefficient(DFe-Mn)slightly decreases with increasing XFe.The experimentally determined DFe-Mn in Mn-bearing garnet can be fitted by the Arrhenius equation:DFe-Mn(m2/s)=D0XFenexp(-E*/RT),where E*=(1-XFe)E*Mn+XFeE*Fe,D0=8.06-6.04+9.87×10-9 m2/s,E*Mn=248±27 KJ/mol,E*Fe=226±59 KJ/mol,n=-1.36±0.51.The comparing the present results with previous experimental data suggest that water can greatly enhance the DFe-Mn in garnet.Our results indicate that the time required for homogenization of the compositional zoning of a garnet is much shorter than previously thought.展开更多
A series of crystallization experiments have been carried out by using natural Emeishan Ti-rich hydrous basalts as starting materials at a pressure of 0.5 GPa and temperatures of 800-1000℃to constrain the origin of F...A series of crystallization experiments have been carried out by using natural Emeishan Ti-rich hydrous basalts as starting materials at a pressure of 0.5 GPa and temperatures of 800-1000℃to constrain the origin of Fe-Ti-V oxide ore deposits.Our experimental results demonstrate that the sandwich-and trellis-type ilmenite lamellae in titanomagnetite of layered intrusions can be formed by the reaction of earlier crystallized ilmenite and the evolved parental magma.During evolution of parental basaltic magma,the Fe-Ti oxide should be composed of titanomagnetite+ilmenite in the earlier stage,but changed to titanomagnetite+titanomagnetite-ilmenite intergrowth±ilmenite at the later stage.Accordingly,the Panzhihua Fe-Ti oxide ores,which are mainly composed of titanomagnetite,should be formed earlier than the adjacent gabbro,in which titanomagnetite-ilmenite intergrowth is the major form of the Fe-Ti oxide.展开更多
基金project was jointly funded by the Funds for the program of the National Natural Science Foundation (Noes. 41572060, U1133602)Projects of YM Lab (2011)Innovation Team of Yunnan province and KMUST (2008,2012)
文摘1 Introduction In contrast,1experimental geochemistry is a young subject,but in recent years,the research on experiment of high temperature and high pressure has become an important branch in the parallel subjects of traditional mineralogy,petrology,geochemistry and geophysics.It is not only an important and essential way and window to understand geological processes in depth and geological
基金Supported by the National Natural Science Foundation of China under Grant No 11474280the National Basic Research Program of China under Grant No 2011CB808200the Chinese Academy of Sciences under Grant Nos KJCX2-SW-N20 and KJCX2-SW-N03
文摘The pressure-induced structural transitions of ZnTe are investigated at pressures up to 59.2 GPa in a diamond anvil cell by using synchrotron powder x-ray diffraction method. A phase transition from the initial zinc blende (ZB, ZnTe-Ⅰ) structure to a cinnabar phase (ZnTe-Ⅱ) is observed at 9.6 GPa, followed by a high pressure orthorhombic phase (ZnTe-Ⅲ) with Cmcm symmetry at 12.1 GPa. The ZB, cinnabar (space group P3121), Cmcm, P31 and rock salt structures of ZnTe are investigated by using density functional theory calculations. Based on the experiments and calculations, the ZnTe-Ⅱ phase is determined to have a cinnabar structure rather than a P3 1 symmetry.
基金State Natural Science Foundation of China (10032040 and 49874013).
文摘Center for Analysis and Prediction, China Seismological Bureau, Beijing 100036, China 2) Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550002, China
文摘The transitional pressure of quartz coesite under the differential stress and highly strained conditions is far from the pressure of the stable field under the static pressure. Therefore, the effect of the differential stress should be considered when the depth of petrogenesis is estimated about ultrahigh pressure metamorphic (UHPM) rocks. The rheological strength of typical ultrahigh pressure rocks in continental subduction zone was derived from the results of the laboratory experiments. The results indicate the following three points. (1) The rheological strength of gabbro, similar to that of eclogite, is smaller than that of clinopyroxenite on the same condition. (2) The calculated strength of rocks (gabbro, eclogite and clinopyroxenite) related to UHPM decreases by nearly one order of magnitude with the temperature rising by 100 ℃ in the range between 600 and 900 ℃. The calculated strength is far greater than the faulting strength of rocks at 600 ℃, and is in several hundred to more than one thousand mega pascals at 700-800 ℃, which suggests that those rocks are located in the brittle deformation region at 600 ℃, but are in the semi brittle to plastic deformation region at 700-800 ℃. Obviously, the 700 ℃ is a brittle plastic transition boundary. (3) The calculated rheological strength in the localized deformation zone on a higher strain rate condition (1.6×10 -12 s -l ) is 2-5 times more than that in the distributed deformation zone on a lower strain rate condition (1.6×10 -14 s -1 ). The average rheological stress (1 600 MPa) at the strain rate of 10 -12 s -1 stands for the ultimate differential stress of UHPM rocks in the semi brittle flow field, and the average rheological stress (550-950 MPa) at the strain rate of l0 -14 - 10 -13 s -l stands for the ultimate differential stress of UHPM rocks in the plastic flow field, suggesting that the depth for the formation of UHPM rocks is more than 20-60 km below the depth estimated under static pressure condition due to the effect of the differential stress.
基金supported by the National Natural Science Foundation of China(Grant Nos.41590623&41472040)the Fundamental Research Funds for the Central Universities+2 种基金China University of Geosciences(Grant No.CUGL150801)Special Fund from the State Key Laboratory of Geological Processes and Mineral ResourcesChina University of Geosciences(Grant No.MSFGPMR201408)
文摘Hydrous minerals are important water carriers in the crust and the mantle, especially in the subduction zone. With the recent development of the experimental technique, studies of the electrical conductivity of hydrous silicate minerals under controlled temperature, pressure and oxygen fugacity, have helped to constrain the water distribution in the Earth's interior. This paper introduces high pressure and temperature experimental study of electrical conductivity measurement of hydrous minerals such as serpentine, talc, brucite, phase A, super hydrous phase B and phase D, and assesses the data quality of the above minerals. The dehydration effect and the pressure effect on the bulk conductivity of the hydrous minerals are specifically emphasized. The conduction mechanism of hydrous minerals and the electrical structure of the subduction zone are discussed based on the available conductivity data. Finally, the potential research fields of the electrical conductivity of hydrous minerals is presented.
基金supported by the Research Projects of China(Grants Nos.2009CB825003,41002068)the State Key Laboratory of GPMR(Grant No.MSF-GPMR 200911)China University of Geosciences(Grant No.CUGL090204)
文摘Jadeite quartzite, essentially a two-phase rock made up of jadeite and quartz, is one of the most important UHP lithologies occur- ring in the Dabie Mountain ultrahigh pressure metamorphic belt and forms layers in biotite-plagioclase gneiss. High pressure- high temperature studies on natural albite from the country rock gneiss were undertaken to reveal the--in parts----complex mineralogical changes that occur in the jadeite quartzite during prograde metamorphism. Experiments were conducted at 800- 1200~C, in the pressure range of 2.0-3.5 GPa. One of the most intriguing results shows that the low pressure boundary of the jadeite+coesite stability field is located between about 3.2 GPa at 1000~C and 3.4 GPa at 1200~C, thus about (0.2-0.3)_+0.1 GPa higher than the quartz-coesite transition curve, given the uncertainty in the present study. Minor amounts of sodium and aluminum entering the structure of quartz and the intimate intergrowth texture of the run products may contribute to the ob- served pressure shift. Combined petrological and mineralogical studies on the run products and the natural rocks yield the fol- lowing prograde reaction sequence to have occurred: The protolith of the jadeite- quartzite from Dabie Mountain is an albitized siltstone/greywacke characterized by an albite+quartz assemblage. During prograde metamorphism albite breaks down to form jadeite+quartz and thus at this stage two types of quartz can be distinguished whereas type-I-quartz already existed in the pro- tolith, type-II-quartz represents a newly formed reaction product of albite. During further P-T-increase the pure type- I-quartz was transformed to coesite, whereas type-II-quartz (together with jadeite) was still present as a stable phase because of its im- purities of Na and A1. At a later stage during further subduction, type-II-quartz also decomposes to form coesite. These studies represent an important puzzlement for a better understanding of the evolution of jadeite- quartzite from the Dabie Mountain during continental crust subduction and thus contribute to a more complete knowledge of the formation of the Dabie Mountain UHP orogenic belt in general.
基金supported by the National Natural Science Foundation of China (41973056,41773056)Key Research Program of Frontier Sciences of CAS (ZDBS-LY-DQC015)to B.Zhang+1 种基金the Fundamental Research Funds for the Central Universities (K20210168)Data presented as part of this study are available from Zenodo (https://doi.org/10.5281/zenodo.7080353).
文摘Precise determination of cation diffusivity in garnet can provide critical information for quantitatively understanding the timescales and thermodynamics of various geological processes,but very few studies have been performed for Fe-Mn interdiffusion.In this study,Fe-Mn interdiffusion rates in natural single crystals of Mn-bearing garnet with 750 ppm H2O are determined at 6 GPa and 1273-1573 K in a Kawai-type multi-anvil apparatus.Diffusion profiles were acquired by electron microprobe and fitted using Boltzmann-Matano equation.The experimental results show that the Fe-Mn interdiffusion coefficient(DFe-Mn)slightly decreases with increasing XFe.The experimentally determined DFe-Mn in Mn-bearing garnet can be fitted by the Arrhenius equation:DFe-Mn(m2/s)=D0XFenexp(-E*/RT),where E*=(1-XFe)E*Mn+XFeE*Fe,D0=8.06-6.04+9.87×10-9 m2/s,E*Mn=248±27 KJ/mol,E*Fe=226±59 KJ/mol,n=-1.36±0.51.The comparing the present results with previous experimental data suggest that water can greatly enhance the DFe-Mn in garnet.Our results indicate that the time required for homogenization of the compositional zoning of a garnet is much shorter than previously thought.
基金supported by funds from the National Key Research and Development Program of China (No.2016YFC0600204)the National Natural Science Foundation of China (Nos.41530211 and41872061)+1 种基金the National Key Basic Research Program of China (No.2015CB856101)the MOST Special Fund from the State Key Laboratory of GPMR (No.MSFGPMR02-2)
文摘A series of crystallization experiments have been carried out by using natural Emeishan Ti-rich hydrous basalts as starting materials at a pressure of 0.5 GPa and temperatures of 800-1000℃to constrain the origin of Fe-Ti-V oxide ore deposits.Our experimental results demonstrate that the sandwich-and trellis-type ilmenite lamellae in titanomagnetite of layered intrusions can be formed by the reaction of earlier crystallized ilmenite and the evolved parental magma.During evolution of parental basaltic magma,the Fe-Ti oxide should be composed of titanomagnetite+ilmenite in the earlier stage,but changed to titanomagnetite+titanomagnetite-ilmenite intergrowth±ilmenite at the later stage.Accordingly,the Panzhihua Fe-Ti oxide ores,which are mainly composed of titanomagnetite,should be formed earlier than the adjacent gabbro,in which titanomagnetite-ilmenite intergrowth is the major form of the Fe-Ti oxide.