The evaporation coefficients alpha(i) of impurity elements Al, Cu, Cr, Co, Fe, Ni, Si in liquid scandium metal of purity 99.9% were measured at 1550 degrees C and 6.7 x 10(-3) Pa. The separating coefficients beta(i) a...The evaporation coefficients alpha(i) of impurity elements Al, Cu, Cr, Co, Fe, Ni, Si in liquid scandium metal of purity 99.9% were measured at 1550 degrees C and 6.7 x 10(-3) Pa. The separating coefficients beta(i) and activity coefficients gamma(i)(o) of these impurity elements were calculated and the separation possibility between these impurity elements and Sc was discussed from thermodynamics. Then the new technology in preparation of high purity scandium metal was proposed and its purification mechanism was discussed.展开更多
文摘The evaporation coefficients alpha(i) of impurity elements Al, Cu, Cr, Co, Fe, Ni, Si in liquid scandium metal of purity 99.9% were measured at 1550 degrees C and 6.7 x 10(-3) Pa. The separating coefficients beta(i) and activity coefficients gamma(i)(o) of these impurity elements were calculated and the separation possibility between these impurity elements and Sc was discussed from thermodynamics. Then the new technology in preparation of high purity scandium metal was proposed and its purification mechanism was discussed.
