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Biodrying of municipal solid waste with high water content by combined hydrolytic-aerobic technology 被引量:10
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作者 ZHANG Dongqing HE Pinjing +2 位作者 SHAO Liming JIN Taifeng HAN Jingyao 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2008年第12期1534-1540,共7页
The high water content of municipal solid waste(MSW)will reduce the effciency of mechanical sorting,consequently unfavorable for beneficial utilization.In this study,a combined hydrolytic-aerobic biodrying technology ... The high water content of municipal solid waste(MSW)will reduce the effciency of mechanical sorting,consequently unfavorable for beneficial utilization.In this study,a combined hydrolytic-aerobic biodrying technology was introduced to remove water from MSW.The total water removals were proved to depend on the ventilation frequency and the temporal span in the hydrolytic stage. The ventilation frequency of 6 times/d was preferable in the hydrolytic stage.The hydrolytic span should not be prolonged more than ... 展开更多
关键词 BIODRYING high water content HYDROLYSIS AERATION municipal solid waste extracellular enzyme
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Analysis of evaporation of high-salinity phreatic water at a burial depth of 0 m in an arid area 被引量:1
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作者 JIA Rui-liang ZHOU Jin-long +1 位作者 LI Qiao LI Yang 《Journal of Groundwater Science and Engineering》 2015年第1期1-8,共8页
High-salinity phreatic water refers to which with total dissolved solids(TDS)>30 g/L. Previous studies have shown that high salinity phreatic water evaporation is different at different depths. High salinity phre... High-salinity phreatic water refers to which with total dissolved solids(TDS)>30 g/L. Previous studies have shown that high salinity phreatic water evaporation is different at different depths. High salinity phreatic water evaporation under 0 m depth is the basis of the high salinity phreatic water evaporation studies. In this study, evaporation of high-salinity phreatic water at a burial depth of 0 m in arid area was investigated. New insights were gained on evaporation mechanisms via experiments conducted on high-salinity phreatic water with TDS of 100 g/L at 0 m at the study site at Changji Groundwater Balance Experiment Site, Xinjiang Uygur Autonomous Region in China, where the lithology of the vadose(unsaturated zone) was silty clay. Comparison was made on the data of high-salinity phreatic water evaporation, water surface evaporation(EΦ20) and meteorological data obtained in two complete hydrological years from April 1, 2012 to March 31, 2014. The experiments demonstrated that when the lithology of the vadose zone is silty clay, the burial depth is 0 m and the TDS is 100 g/L, intra-annual variation of phreatic water evaporation is the opposite to the variation of atmospheric evaporation EΦ20 and air temperature. The salt crust formed by the evaporation of high-salinity phreatic water has a strong inhibitory effect on phreatic water evaporation. Large volumes of precipitation can reduce such an inhibitory effect. During freezing periods, surface snow cover can promote the evaporation of high-salinity phreatic water at 0 m; the thicker the snow cover, the more apparent this effect is. 展开更多
关键词 Arid area high-salinity phreatic water Phreatic water evaporation at the burial depth of 0m water evaporation
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Environmental Effect of Reservoirs Accumulating Highly Mineralized Oil-Field Waste Waters
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作者 Ilyusya M. Gabbasova Ruslan R. Suleymanov 《Journal of Water Resource and Protection》 2010年第4期309-313,共5页
The effect of oilfield waste water on the ground, the soil and the underground water has been studied. The reservoir is shown to be the source of environmental pollution due to the seepage of highly mineralized waste ... The effect of oilfield waste water on the ground, the soil and the underground water has been studied. The reservoir is shown to be the source of environmental pollution due to the seepage of highly mineralized waste water through the reservoir bed and walls. Increased water mineralization in the spring two kilometers downward from the reservoir is one indication of it. Desalinization of the water should be expected in 140 years’ time. Typical chernozem formed on the area under study 40 years after the contamination have be-come naturally desalinized and desolonized as a result of a washing water regime and a genetically high content of carbonates and gypsum in the profile and soil forming rocks. Moreover, they retain an increased content of water-soluble salts, exchangeable sodium and electrical resistance, which is typical for alkali soils and solonetzs. The humus accumulative horizons show hydrophobic behavior. Due to leaching carbonates content, cation exchange capacity, mobile nitrogen and phosphorus availability decrease. Soil contamination by OWW leads to the accumulation of toxic elements in the soil and vegetation. 展开更多
关键词 OILFIELD waste water salinIZATION TOXIC Elements Ground waterS Soil Properties
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Performance Simulation of H-TDS Unit of Fajr Industrial Wastewater Treatment Plant Using a Combination of Neural Network and Principal Component Analysis
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作者 Hamed Hasanlou Naser Mehrdadi +1 位作者 Mohammad Taghi Jafarzadeh Hamidreza Hasanlou 《Journal of Water Resource and Protection》 2012年第5期311-317,共7页
Nowadays, with regard to environmental issues, proper operation of wastewater treatment plants is of particular importance that in the case of inappropriate utilization, they will cause serious problems. Processes tha... Nowadays, with regard to environmental issues, proper operation of wastewater treatment plants is of particular importance that in the case of inappropriate utilization, they will cause serious problems. Processes that exist in environmental systems and environmental engineers are dealing with them mostly have two major characteristics: they are dependent on many variables;and there are complex relationships between its components which make them very difficult to analyze. Being familiar with characteristics of industrial town effluents from various wastewater treatment units, which have high qualitative and quantitative variations and more uncertainties compared to urban wastewaters, plays very effective role in governing them. In order to achieve a better and efficient control over the operation of an industrial wastewater treatment plant, powerful mathematical tool can be used that is based on recorded data from some basic parameters of wastewater during a period of treatment plant operation. In this study, the multilayer perceptron (MLP) feed forward neural network with a hidden layer and stop training method was used to predict quality parameters of the industrial effluent. Data of this study are related to the Fajr Industrial Wastewater Treatment Plant located in Mahshahr—Iran that qualitative and quantitative characteristics of its units were used for training, calibration and evaluation of the neural model. Also, Principal Component Analysis technique was applied to modify and improve performance of generated models of neural networks. The results of this model showed good accuracy of the model in estimating qualitative pro- file of wastewater. This model facilitates evaluating the performance of each treatment plant units through comparing the results of prediction model with the standard amount of output. 展开更多
关键词 Simulation Artificial NEURAL Network PCA Fajr Industrial waste water Treatment PLANT high TDS UNIT
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Evapotranspiration and Removal Performance in the Treatment of High Salinity LandfilI-Leachate Using HSF
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作者 Tokuo Yano Kazuhiro Yamada +3 位作者 Masatomo Nakayama Akiko Inoue-kohama Shinya Sato Keijiro Enari 《Journal of Environmental Science and Engineering(B)》 2016年第9期440-450,共11页
In this study, the water budget in the treatment of high salinity landfill-leachate was estimated and the influence of evapotranspiration (ET) on treatment performance was investigated. The salinity of the inside of... In this study, the water budget in the treatment of high salinity landfill-leachate was estimated and the influence of evapotranspiration (ET) on treatment performance was investigated. The salinity of the inside of horizontal subsurface flow constructed wetland (HSF) of the raw leachate inflow was 15.0± 3.4 g.Cl/L which was in the level of the salinity of the survival limit of reed, and that of the double diluted leachate inflow was 9.3 ± 1.9 g.CI7L. There were large differences in the vegetation between HSF of the raw leachate inflow and that of the double diluted leachate inflow. The dense vegetation bed of double diluted leachate inflow during the growing season (April-October) provided a high ET and a large water loss, which made great contributions to the reduction of the outflow load of COD and T-N. The HSF with die-back reeds in the non-growing season (November-March) provided a slight ET and a small water loss and made less of a contribution to pollutant removal compared to the HSF with dense vegetation bed during the growing season. However, the HSF with die-back reeds during the non-growing season exhibited higher removal performance than the unplanted HSF. 展开更多
关键词 EVAPOTRANSPIRATION HSF high salinity landfill-leachate removal performance water budget.
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Short Term Effects of Olive Mill Waste Water on Soil Chemical Properties under Semi Arid Mediterranean Conditions
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作者 Raja Dakhli Ridha Lamouri +1 位作者 Houcine Taamallah Mohamed Ouessar 《Journal of Life Sciences》 2013年第11期1209-1218,共10页
The aim of this work is to assess the short term effect of OMWW (olive mill waste water) application on chemical and biological soil properties. A field experiment was carried out in southern Tunisia. OMWW applicati... The aim of this work is to assess the short term effect of OMWW (olive mill waste water) application on chemical and biological soil properties. A field experiment was carried out in southern Tunisia. OMWW application was done at rates equivalent to 0, 15, 30 and 45 m^3/ha. Results showed that increasing rates of OMWW enhance the soil fertility due to its richness in organic matter such as N and P. A rapid increase of microbial biomass (during 14 days of incubation) of OMWW amended soils occurred. However, a high increase in salinity values and phenolic compounds concentrations was observed during this experiment. 展开更多
关键词 Olive mill waste water chemical properties biological activity phenolic compounds salinity
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High Water Content Material Based on Ba-Bearing Sulphoaluminate Cement 被引量:3
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作者 常钧 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2005年第3期88-90,共3页
A new type of high water content material which is made up of two pastes is prepared, one is refute from lime and gypsum, and another is based on Ba-bearing sulphoaluminate cement. It has excellent properties such as ... A new type of high water content material which is made up of two pastes is prepared, one is refute from lime and gypsum, and another is based on Ba-bearing sulphoaluminate cement. It has excellent properties such as slow single paste solidifing ,fust double pustes solidifing ,fast coagulating and hardening, high early strength, good suspeasion property at high W/C ratio and low cost. Meanwhile, the properties and hydration mechanism of the material were analyzed by using XRD, DTA- TG and SEM. The hydrated products of new type of high water content material are Ba-bearing ettringite, BaSO4 , aluminum gel and C-S-H gel. 展开更多
关键词 Ba- bearing sulphoaluminate cement high water content material filling material BAO barium industrial waste residue
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Frying Performance of High Oleic Oil Enriched in Biophenols during Discontinuos and Prolonged Thermal Treatment 被引量:1
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作者 R. Romano N. Manzo +2 位作者 L. Le Grottaglie A. Fiore V. Fogliano 《Food and Nutrition Sciences》 2013年第9期120-124,共5页
Biophenols are potent natural antioxidants that protect food quality by preventing oxidative deterioration of lipids. During heat treatment this protective rule prevents oxidation caused by many factors, as high tempe... Biophenols are potent natural antioxidants that protect food quality by preventing oxidative deterioration of lipids. During heat treatment this protective rule prevents oxidation caused by many factors, as high temperature reached, presence of oxygen and water contained in food matrix. The aim of this study was to evaluate the frying performance of high oleic oil enriched in biophenols, comparing its thermal stability with those of high oleic oil (control sample) during thermo-oxidation and deep fat frying process. Positive effects when biophenols were added to oil were found: lower acidity levels, lower TPC values during the first 16 hours of heat treatment, absence of short chain fatty acids (C8:0) until 24 h of thermo-oxidation treatment and detection of lower acrylamide content in French friesrespect to those fried in the control oil. 展开更多
关键词 Biophenols high Oleic OIL Deep FAT FRYING OLIVE MILL waste water
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Species distribution of arsenic in sediments after an unexpected emergent discharge of high-arsenic wastewater into a river 被引量:1
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作者 Ruiping LIU Wei XU +3 位作者 Kun WU Wenxin GONG Huijuan LIU Jiuhui QU 《Frontiers of Environmental Science & Engineering》 SCIE EI CAS CSCD 2013年第4期568-578,共11页
The unexpected emergent discharge of high- arsenic wastewater into water environments results in significantly increased levels of arsenic in water; however, the species distribution of arsenic in sediments has never ... The unexpected emergent discharge of high- arsenic wastewater into water environments results in significantly increased levels of arsenic in water; however, the species distribution of arsenic in sediments has never been reported before for such cases. This study focuses on an As pollution accident in the Dasha River, and uses sequential extraction procedures with deionized water, l mol-L-1 MgC12 at pH = 8, 1 mol.L-1 NaH2PO4 at pH = 5, and 1 mol. L-1 HC1 to investigate four binding phases of arsenic (i.e., water soluble, ion-exchangeable, strongly- bound, and precipitates) in sediments at different layers in different cross-sections along the fiver. The average ratio of arsenite (As(III)) to arsenate (As(V)) was found to decrease from 0.74:1 in fiver water to 0.48:1 in sediment, owing to its higher affinity toward As(V) than As(III). The content of arsenic in the sediments was relatively low and the maximum content was observed to be 36.3 mg-kg1 for As(IID and 97.5 mg.kg1 for As(V). As(III) and As(V) showed different binding phases in sediments, and the average fractions of these four species were determined to be 0.09, 0.11, 0.17, and 0.63 for As(III) and 0.03, 0.14, 0.63, and 0.20 for As(V), respectively. For all the sediment samples, the content of arsenic showed no relationship with the characteristics of the sediments such as the particle diameter, the content of organic carbon, Fe, and Mn, although a negative correlation with particle diameter was observed for the sediments in the uppermost 2-cm layer. The unexpected emergent As incident results in the high content of total arsenic in the surface sediment, which may be potential secondary source to the elevated As levels in surface water. 展开更多
关键词 river sediments ARSENIC species distribution binding phases unexpected discharge of high-As waste-water
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The Interpretation of Underground Water Physical Parameters of Housing in the Region of Asahan Indah Palm Oil Factory Area Rokan Hulu District
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作者 M. Juandi 《Open Journal of Modern Hydrology》 2018年第4期119-125,共7页
The research has been conducted to analyze the distribution of underground water physical parameters of the housing around Asahan Indah palm oil factory area Rokan Hulu District with radial method within ±300 met... The research has been conducted to analyze the distribution of underground water physical parameters of the housing around Asahan Indah palm oil factory area Rokan Hulu District with radial method within ±300 meters radius from the factory location. The levels of underground water physical parameters include conductivity, resistivity, and salinity measured based on coordinate points amounted of 50 points. The data obtained from the measurement results were then inputted into “surfer 11” software to be processed in order to obtain the contour map of underground water physical parameters level. The results of this research indicated that the highest conductivity level came from the ring well type with 5 meter depth;it was 0.0964 (1/ohm·m) exceeded the standard threshold of underground water quality standard and the lowest conductivity was 0.00342 (1/ohm·m) which came from a ring well type with 10 meter depth. The lowest resistivity level was 10.37 ohm·m which came from the ring well type with 5 meter depth and the highest was 292.4 ohm·m which came from the ring well with 10 meter depth. The highest salinity level was 448 mg/l which exceeded the baseline threshold of underground water quality which came from the ring well type with 5 meter depth and the lowest was 175 mg/l from the ring well with 10 meter depth. The results of this research found that underground water in wells with 5 meters depth has been polluted with palm oil waste and at the depth of 10 meters, it has not been contaminated. 展开更多
关键词 Conductivity RESISTIVITY salinity PALM FACTORY waste Underground water
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Influence of heating and water-exposure on the liquid limits of GMZ01 and MX80 bentonites
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作者 Yuemiao Liu 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE 2010年第2期188-192,共5页
Bentonite has been considered as a buffer material for embedding canisters with high-level radioactive waste(HLW) in deep geological repositories.GMZ bentonite deposit,located in Xinghe County,Inner Mongolia Autonom... Bentonite has been considered as a buffer material for embedding canisters with high-level radioactive waste(HLW) in deep geological repositories.GMZ bentonite deposit,located in Xinghe County,Inner Mongolia Autonomous Region,China was proposed as a buffer/backfill material for HLW repository in China.The liquid limits of natural Na-bentonite GMZ01 and commercial Na-bentonite MX80,which are previously heated at 80 ℃ and 95 ℃,respectively,and exposed to water for different times are measured.It is observed that the liquid limit of GMZ01 increases slightly at the beginning,and then decreases as the heating time increases,while the liquid limit of MX80 decreases with the heating time.The liquid limits of both GMZ01 and MX80 decrease with increasing water-exposure time.After the samples are heated at 80℃and 95 ℃ for several months,the mineralogical composition of GMZ01 does not exhibit evident change,whereas MX80 experiences some changes.In addition,the chemical composition,cation exchange capacity(CEC) and exchangeable cation of all the samples do not change significantly. 展开更多
关键词 high-level radioactive waste(HLW) deep geological disposal BENTONITE HEATING water-exposure liquid limit
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改良MVR蒸发器在煤矿超高矿化度浓水处理中的应用 被引量:3
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作者 贺江海 马宝祥 +2 位作者 符红军 杨晓中 张文艺 《工业水处理》 CAS CSCD 北大核心 2024年第2期194-200,共7页
反渗透工艺是目前处理高矿化度矿井水常用的工艺,该工艺浓缩分质后会产生超高矿化度的氯化钠、硫酸钠浓缩盐水。这种浓缩盐水只能蒸发结晶处理后方可排放,传统的蒸发结晶工艺由于能耗非常高限制了其应用。近来年,相对能耗较低的MVR蒸发... 反渗透工艺是目前处理高矿化度矿井水常用的工艺,该工艺浓缩分质后会产生超高矿化度的氯化钠、硫酸钠浓缩盐水。这种浓缩盐水只能蒸发结晶处理后方可排放,传统的蒸发结晶工艺由于能耗非常高限制了其应用。近来年,相对能耗较低的MVR蒸发结晶工艺在国内外得到较多应用。针对煤矿矿井水浓缩的超高矿化度特点,在MVR工艺的基础上对蒸发器进行改良,增设由高温超导材料制成的原液预热器,进一步提高传热效率。改良制造的MVR蒸发器(150 kg/h)应用于陕西小纪汗煤矿超高矿化度浓水的应用试验中,传热面积由2.80 m^(2)提高至4.89 m^(2),蒸汽消耗量由179.40 kg/h减少到149.85 kg/h,每小时节约30 kg蒸汽,折合标准煤约2.8 kg,节能及碳减排效益显著。 展开更多
关键词 高矿化度矿井水 蒸发结晶 蒸汽机械再压缩技术 能耗分析
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基于双极膜电渗析的膜集成技术的高矿化度矿井水资源化处理 被引量:2
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作者 刘兆峰 郭强 +7 位作者 王霄 唐佳伟 蒋斌斌 曹志国 张锁 闫祖喻 王群 李井峰 《煤炭学报》 EI CAS CSCD 北大核心 2024年第5期2462-2471,共10页
在当前煤矿矿井水“零排放”及煤炭与水资源逆向分布背景下,西部矿区的高矿化度矿井水如若不进行合理处置便直接排放,不仅对当地生态环境造成不可估量的破坏,而且造成严重的水资源浪费,最终将制约煤炭绿色开发与生态文明建设。传统的高... 在当前煤矿矿井水“零排放”及煤炭与水资源逆向分布背景下,西部矿区的高矿化度矿井水如若不进行合理处置便直接排放,不仅对当地生态环境造成不可估量的破坏,而且造成严重的水资源浪费,最终将制约煤炭绿色开发与生态文明建设。传统的高盐废水零排放技术主要是利用蒸发结晶技术将无机盐由溶液态转变为结晶态进行回收。从经济性方面分析,该技术受投资高、运行成本高、无机盐附加值低等问题制约。基于此,以西部某矿井水为原水,以矿井水资源化零排放利用及脱盐低碳化为目标进行膜集成工艺设计,并在此基础上重点探讨电渗析和双极膜电渗析工序不同操作条件(操作电压、进料液浓度、温度、酸碱度、电流密度等)对电渗析脱盐性能及双极膜电渗析制酸碱性能的影响规律,之后以实验数据及经济评估模型,探究其经济可行性,旨在探索出适用于西部矿区高矿化度矿井水处理的膜集成技术,为高矿化度矿井水绿色资源化处理工艺的开发提供新的研究思路。通过对电渗析−双极膜电渗析实验过程探究,发现双极膜系统进料液质量浓度应不超过80 g/L、适宜的操作电压为18 V、适宜的进料液温度为25℃、进料液pH保持中性、更适合采用恒电压操作。此外,证实了以双极膜电渗析为核心的膜集成系统可实现高矿化度矿井水绿色资源化处理,以电渗析系统进料液总含盐量20 g/L为例,总的净收益为18604299元/a,且在耦合光伏电力供应系统时具有明显的二氧化碳减排效应,二氧化碳减排将超过3162 t/a,具有良好的经济效益和社会效益。 展开更多
关键词 高矿化度矿井水 集成膜系统 零排放 双极膜电渗析技术 矿井水资源化
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大掺量固废混凝土的制备及性能研究 被引量:2
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作者 钱耀丽 刘远祥 王琼 《混凝土与水泥制品》 2024年第2期93-96,共4页
将粉煤灰、矿粉、不同类型的钢渣粉按不同质量比(mF∶mK∶mG分别为60∶32∶8、60∶28∶12、60∶24∶16、50∶40∶10、50∶35∶15、50∶30∶20)制备了三元复合掺合料,确定了最佳钢渣粉类型和mF∶mK∶mG。在此基础上,通过调整砂率、水胶... 将粉煤灰、矿粉、不同类型的钢渣粉按不同质量比(mF∶mK∶mG分别为60∶32∶8、60∶28∶12、60∶24∶16、50∶40∶10、50∶35∶15、50∶30∶20)制备了三元复合掺合料,确定了最佳钢渣粉类型和mF∶mK∶mG。在此基础上,通过调整砂率、水胶比、减水剂掺量等方式制备了大掺量固废混凝土(固废总量≥70%),研究了其工作性、力学及耐久性能。结果表明:综合考虑胶砂流动度、三元复合掺合料的活性指数、经济性和环境效益,推荐选用原状钢渣粉,并控制mF∶mK∶mG为60∶32∶8;制备的大掺量固废混凝土的工作性、力学及耐久性能均较好,满足相关设计要求,并推荐采用聚羧酸减水剂,不推荐采用以萘系减水剂与脂肪族减水剂复配而成的复合减水剂。 展开更多
关键词 复合掺合料 再生混凝土 减水剂 大掺量固废
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煤矿矿井水处理技术现状与展望
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作者 李福勤 王丛 +4 位作者 郑煚州 陈宇航 何绪文 代其彬 田莉 《工业水处理》 CAS CSCD 北大核心 2024年第9期1-8,共8页
煤矿矿井水是重要的非常规水源,矿井水的资源化利用对缓解矿区水资源短缺和环境保护具有重要意义。分析了矿井水的来源和水质特点,综述了含悬浮物、高矿化度、酸性和含特殊污染物等不同类型矿井水的主要处理技术,总结了各处理技术的特... 煤矿矿井水是重要的非常规水源,矿井水的资源化利用对缓解矿区水资源短缺和环境保护具有重要意义。分析了矿井水的来源和水质特点,综述了含悬浮物、高矿化度、酸性和含特殊污染物等不同类型矿井水的主要处理技术,总结了各处理技术的特点和存在问题。大部分矿井水都含有一定量悬浮物,且水质水量变化较大,应着力提高井下水仓和地面调节池的预沉作用,开发和完善矿井水井下处理技术,结合自动化、智能化,实现无人值守;随高矿化度矿井水数量不断增加,其处理技术已成为矿井水处理领域的研究重点,应强化预处理,开发高效除硅除硬技术,引入能量回收装置,结合新能源和可再生能源开发绿色节能耦合脱盐技术,整体优化零排放工艺,降低浓盐废水处理成本;酸性和含特殊污染物矿井水是目前矿井水处理中的难点,应采取分布式高效定向处理技术,探索耦合工艺和自然修复治理。在国家政策引领下,矿井水处理技术将朝着更加节能、高效、智能和环保的方向发展。 展开更多
关键词 矿井水 水质特点 含悬浮物矿井水 高矿化度矿井水
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页岩气返排水中的反硝化厌氧甲烷氧化微生物——群落结构与关键影响因子
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作者 李欣悦 卢培利 +3 位作者 刘俊 李仕康 侯争鸣 丁阿强 《中国环境科学》 EI CAS CSCD 北大核心 2024年第9期5303-5312,共10页
首次探究了高温高压高盐的页岩气返排水中DAMO(denitrifying anaerobic methane oxidation)微生物存在的证据及其与关键环境因子之间的关联性.结果表明,在所研究的7个页岩气井场返排水中均检测到了DAMO古菌与细菌的存在,且古菌的丰度远... 首次探究了高温高压高盐的页岩气返排水中DAMO(denitrifying anaerobic methane oxidation)微生物存在的证据及其与关键环境因子之间的关联性.结果表明,在所研究的7个页岩气井场返排水中均检测到了DAMO古菌与细菌的存在,且古菌的丰度远高于细菌,其16S rRNA基因拷贝数分别为4.32×10^(4)~5.83×10^(5)copies/L和1.16×10^(3)~6.00×10^(3)copies/L.DAMO古菌与细菌的功能基因mcrA与pomA同样在所有的样品中检出.页岩气返排水中共发现了4个DAMO细菌代表性OTU与1个DAMO古菌代表性OTU,虽然返排水中盐度很高,但检出的DAMO细菌与古菌与已报道的淡水环境中的DAMO微生物亲缘性更近.RDA相关性分析表明,返排水常规理化因子对DAMO微生物的影响并非体现在微生物的丰度上,而是体现在微生物的功能上,其中pmoA基因丰度与TOC含量呈正显著相关,而mcrA基因丰度则与NO_(3)^(-)、NH_(4)^(+)、PO_(4)^(3-)和Cl^(-)浓度呈正相关,Cl^(-)影响最大.研究结果拓展了关于DAMO微生物环境分布的认识,可为缓解返排水中逸散甲烷所导致的温室效应的控制提供理论基础,也有助于加深对深部页岩微生物过程的认知. 展开更多
关键词 反硝化厌氧甲烷氧化 页岩气返排水 高盐 环境因子 群落结构
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抗超高温220℃聚合物水基钻井液技术
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作者 刘锋报 孙金声 +2 位作者 刘敬平 黄贤斌 孟旭 《钻井液与完井液》 CAS 北大核心 2024年第2期148-154,共7页
我国深层油气资源丰富,其高效开发对保障国家能源安全具有重大意义。钻井液是深部地层钻探的关键,但目前常规聚合物钻井液的抗温能力普遍低于220℃,且盐会大幅降低钻井液性能,钻探过程中往往由于钻井液失效引发安全事故,对深层油气开发... 我国深层油气资源丰富,其高效开发对保障国家能源安全具有重大意义。钻井液是深部地层钻探的关键,但目前常规聚合物钻井液的抗温能力普遍低于220℃,且盐会大幅降低钻井液性能,钻探过程中往往由于钻井液失效引发安全事故,对深层油气开发造成重大损失。针对钻井液高温高盐条件下性能恶化的难题,合成了具有协同作用的抗高温两性离子聚合物和抗高温阴离子聚合物,通过高强度的网架结构调控钻井液流变性;合成抗超高温高效封堵剂来提高钻井液封堵性能和滤失性能,封堵泥饼和砂床,阻止压力传递。以抗高温两性离子聚合物、抗高温阴离子聚合物和抗超高温高效封堵剂为核心处理剂,构建了一套抗超高温220℃的聚合物水基钻井液体系,并评价了该钻井液的性能。实验结果表明,该钻井液具有良好的流变滤失性、沉降稳定性、封堵性和润滑性,其高温高压滤失量仅为9.6 mL,高温高压下仍保持黏度和切力稳定,直立老化72 h沉降因子仅为0.5113,砂床侵入深度仅为6 mm,老化后润滑系数和泥饼黏滞系数分别为0.1224和0.0875。该钻井液具有良好的抗温性能和稳定性,对深部油气的开发具有重要意义。 展开更多
关键词 水基钻井液 抗高温 抗高矿化度 聚合物 深部地层
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基于双极膜电渗析的矿井浓盐水资源化处理工艺研究 被引量:1
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作者 晋银佳 王绍曾 +2 位作者 郭栋 尤良洲 衡世权 《工业水处理》 CAS CSCD 北大核心 2024年第3期104-111,共8页
双极膜电渗析(BMED)工艺能够将矿井水膜浓缩系统产生的浓盐水转化为酸和碱,从而实现浓盐水的资源化处理。BMED系统的运行能耗较高,且其性能与系统的初始酸/碱浓度、电解质质量分数以及电流密度等参数密切相关,有必要对其进行优化研究,... 双极膜电渗析(BMED)工艺能够将矿井水膜浓缩系统产生的浓盐水转化为酸和碱,从而实现浓盐水的资源化处理。BMED系统的运行能耗较高,且其性能与系统的初始酸/碱浓度、电解质质量分数以及电流密度等参数密切相关,有必要对其进行优化研究,以降低系统运行成本。以某矿井水零排放处理系统产生的纳滤(NF)浓盐水和碟管式反渗透(DTRO)浓盐水为研究对象,采用BMED小试装置研究了不同初始酸/碱浓度、电解质质量分数以及电流密度工况下,BMED系统运行电压、酸/碱浓度、电流效率等变化情况。实验结果表明,实验条件下处理浓盐水,当初始酸/碱浓度为0.1 mol/L左右时,BMED产生的酸/碱浓度最高;BMED装置产生酸/碱的速度与电解质质量分数有关,电解质质量分数较低的工况下酸/碱浓度增加较快;此外,产生酸/碱的速度与电流密度呈正相关,而电流效率与电流密度呈负相关。对于NF浓盐水的处理,在初始酸/碱浓度为0.1 mol/L左右、电流密度控制在21 mA/cm^(2)时经济性最高。此外,根据BMED系统的运行参数进行浓盐水资源化处理的成本收益测算,结果表明,采用双极膜电渗析工艺处理NF浓盐水的运行成本低于DTRO-蒸发结晶工艺,具有经济可行性。 展开更多
关键词 矿井浓盐水 资源化处理 双极膜电渗析 经济分析
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磁性介孔碳负载纳米零价铁的制备及其去除高盐废水中Cr(Ⅲ)有机配合物 被引量:1
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作者 张元培 王家宏 +1 位作者 黄金明 胡智 《无机化学学报》 SCIE CAS CSCD 北大核心 2024年第9期1731-1742,共12页
采用液相还原法制备了磁性介孔碳(Fe_(3)O_(4)@C)负载纳米零价铁(nano zero-valent iron,nZVI)复合材料(Fe_(3)O_(4)@C-nZVI),并将其用于高盐水中Cr(Ⅲ)-EDTA(EDTA:乙二胺四乙酸)的去除。扫描电镜、透射电镜、X射线衍射等表征表明nZVI... 采用液相还原法制备了磁性介孔碳(Fe_(3)O_(4)@C)负载纳米零价铁(nano zero-valent iron,nZVI)复合材料(Fe_(3)O_(4)@C-nZVI),并将其用于高盐水中Cr(Ⅲ)-EDTA(EDTA:乙二胺四乙酸)的去除。扫描电镜、透射电镜、X射线衍射等表征表明nZVI成功负载且分散良好,可磁性分离,在碳层保护下nZVI稳定性强,有利于材料的重复利用。nZVI的加人大大提高了Fe_(3)O_(4)@C-nZVI对Cr(Ⅲ)-EDTA的吸附能力,在pH=4.0、反应温度为25℃时,Fe_(3)O_(4)@C-nZVI对Cr(Ⅲ)-EDTA的最大吸附量为10.24 mg·g^(-1),显著高于Fe_(3)O_(4)@C(4.31 mg·g^(-1))。吸附Cr(Ⅲ)-EDTA的过程更符合Langmuir模型和准二级动力学模型。Fe_(3)O_(4)@C-nZVI对Cr(Ⅲ)-EDTA的吸附能力随着溶液pH值的增加先增加后减小;低浓度络合剂(EDTA、柠檬酸)会促进Cr(Ⅲ)-EDTA的吸附,而络合剂浓度增加时则表现为抑制;高浓度阳离子(Na^(+)、K^(+)、Ca^(2+))会促进Cr(Ⅲ)-EDTA的吸附。Fe_(3)O_(4)@C-nZVI在盐和络合剂环境中对Cr(Ⅲ)-EDTA仍表现出显著的吸附效果。经过3次再生循环后,Fe_(3)O_(4)@C-nZVI对Cr(Ⅲ)-EDTA的吸附量达6.90 mg·g^(-1)。X射线光电子能谱分析表明,Fe_(3)O_(4)@C-nZVI通过表面Fe(Ⅲ)与Cr(Ⅲ)-EDTA之间的配位作用形成FedO-EDTA-Cr(Ⅲ)配合物从而将Cr(Ⅲ)-EDTA去除,随后通过离子置换作用将Cr(Ⅲ)置换出来,置换出的Cr(Ⅲ)会与表面氧化铁共沉淀为Cr_(x)Fe_(1-x)(OH)_(3),进而沉积在nZVI表面被去除。 展开更多
关键词 磁性介孔碳 纳米零价铁 Cr(Ⅲ) 高盐废水 吸附机制
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泥水盾构高含水率超高黏粒含量废弃泥浆絮凝脱水试验研究
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作者 豆留盼 王峻 +3 位作者 李海涛 吴东阳 张心源 魏力峰 《隧道建设(中英文)》 CSCD 北大核心 2024年第4期771-782,共12页
针对江阴第二过江通道工程中泥水盾构产生的高含水率超高黏粒含量废弃泥浆泥水分离困难、处理效率低的问题,采用阴离子型聚丙烯酰胺(APAM)、聚合氯化铝(PAC)和聚合氯化铝铁(PAFC)3种絮凝剂开展泥浆絮凝试验,研究不同絮凝剂的絮凝脱水效... 针对江阴第二过江通道工程中泥水盾构产生的高含水率超高黏粒含量废弃泥浆泥水分离困难、处理效率低的问题,采用阴离子型聚丙烯酰胺(APAM)、聚合氯化铝(PAC)和聚合氯化铝铁(PAFC)3种絮凝剂开展泥浆絮凝试验,研究不同絮凝剂的絮凝脱水效果,选取底泥等效含水率、界面沉降速率、上清液浊度、泥浆脱水率以及Zeta电位作为评价指标,分析絮凝剂类型、用量、复配形式等对絮凝效果的影响,并探讨不同絮凝剂的絮凝机制。试验结果表明:1)不同絮凝剂对应的泥浆脱水效果排序为APAM>PAFC+APAM≥PAC+APAM>PAFC≥PAC,上清液浊度去除效果排序为PAFC>PAC>PAFC+APAM>PAC+APAM>APAM;2)有机絮凝剂APAM的最适投加量与其分子量密切相关,且不同分子量APAM的极限脱水率不尽相同,药剂分子量保持在1200万~1400万时,脱水效果最佳;3)PAFC+APAM复配絮凝剂对本依托工程中高含水率超高黏粒含量废弃泥浆调理效果最好,PAFC溶液和APAM溶液的最适投加量分别为33 g·L^(-1)和233 g·L^(-1),对应的PAFC和APAM干物质投加量分别为1.6 g·L^(-1)和0.466 g·L^(-1),在此条件下,泥浆90 min脱水率为29.6%,上清液浊度可降低至62.0 NTU;4)复配絮凝剂的脱水效果主要由有机絮凝剂APAM长链的吸附架桥作用主导,对上清液浊度的去除主要与无机絮凝剂PAC和PAFC的电性中和作用相关。 展开更多
关键词 泥水盾构 絮凝 废弃泥浆 超高黏粒含量 高含水率 脱水性能
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