Monolayer two-dimensional(2D)semiconductors are emerging as top candidates for the channels of the future chip industry due to their atomically thin body and superior immunity to short channel effect.However,the low s...Monolayer two-dimensional(2D)semiconductors are emerging as top candidates for the channels of the future chip industry due to their atomically thin body and superior immunity to short channel effect.However,the low saturation current caused by the high contact resistance(R_(c))in monolayer MoS2 field-effect transistors(FETs)limits ultimate electrical performance at scaled contact lengths,which seriously hinders application of monolayer MoS_(2 )transistors.Here we present a scalable strategy with a clean end-bond contact scheme that leads to size-independent electrodes and ultralow contact resistance of 2.5 kΩ·μm to achieve record high performances of saturation current density of 730μA·μm^(-1)at 300 K and 960μA·μm^(-1)at 6 K.Our end-bond contact strategy in monolayer MoS2 FETs enables the great potential for atomically thin integrated circuitry.展开更多
The dependences of soft magnetic properties and microstructures of the sputtered FeCo (=Fe65Co35) films on Co underlayer thickness tCo, FeCo thickness tFeCo, substrate temperature Ts and taxget-substrate spacing dT-...The dependences of soft magnetic properties and microstructures of the sputtered FeCo (=Fe65Co35) films on Co underlayer thickness tCo, FeCo thickness tFeCo, substrate temperature Ts and taxget-substrate spacing dT-s are studied. FeCo single layer generally shows a high coercivity with no obvious magnetic anisotropy. Excellent soft magnetic properties with saturation magnetization μ0Ms of 2.35 T and hard axis coercivity Hch of 0.25 kA/m in FeCo films can be achieved by introducing a Co underlayer. It is shown that sandwiching a Co underlayer causes a change in orientation and reduction in grain size from 70 nm to about 10 nm in the FeCo layer. The magnetic softness can be explained by the Hoffmann's ripple theory due to the effect of grain size. The magnetic anisotropy can be controlled by changing dT-S, and a maximum of 14.3 kA/m for anisotropic field Hk is obtained with dT-S=18.0 cm.展开更多
We propose and demonstrate a Q-switched erbium-doped fiber laser (EDFL) using an erbium-doped zirconia-alumina silica glass-based fiber (Zr-EDF) as a saturable absorber. As a 16-cm-long Zr-EDF is incorporated into...We propose and demonstrate a Q-switched erbium-doped fiber laser (EDFL) using an erbium-doped zirconia-alumina silica glass-based fiber (Zr-EDF) as a saturable absorber. As a 16-cm-long Zr-EDF is incorporated into a ring EDFL cavity, a stable Q-switching pulse train operating at 1565?nm wavelength is successfully obtained. The repetition rate is tunable from 33.97?kHz to 71.23?kHz by increasing the pump power from the threshold of 26?mW to the maximum of 74?mW. The highest pulse energy of 26.67?nJ is obtained at the maximum pump power.展开更多
Phosphor-in-glass(PiG)film is a promising luminescent material in high-brightness laser lighting for its advantages of high efficiency,outstanding color quality,and low-cost preparation,which must bear high laser powe...Phosphor-in-glass(PiG)film is a promising luminescent material in high-brightness laser lighting for its advantages of high efficiency,outstanding color quality,and low-cost preparation,which must bear high laser power(LP)and laser power density(LPD)simultaneously to enable high-luminance light.Herein,laser spot associated high-saturation PiG film was proposed for transmissive and reflective high-brightness laser lighting.Two types of PiG films were prepared by printing and sintering La_(3)Si_(6)N_(11):Ce^(3+)(LSN)phosphor-borosilicate glass pastes on a sapphire substrate(PiG-S)and an AlN substrate(PiG-A),respectively.The PiG films with perfect crystal structure of phosphor were reliably bonded on the substrates.The effects of laser spot areas on the luminescence saturation of LP and LPD were investigated in the PiG films.With the increase of laser spot area from 0.5 to 2.5 mm^(2),the LP threshold of PiG films is gradually raised,while the LPD threshold of PiG films is decreased.The PiG-S withstands a high LP of 23.46 W and a high LPD of 20.64 W/mm^(2),enabling white light with a luminous flux of 3677 lm.The PiG-A withstands a high LP of 41.12 W and a high LPD of 35.56 W/mm^(2),enabling white light with a luminous flux of 2882 lm.Moreover,the PiG-A maintains lower working temperature compared with the PiG-S,and the temperatures reduce with the increasing laser spot area.The results demonstrate that the laser spot associated PiG films realize high saturation thresholds of LP and LPD simultaneously,and enable high luminance for laser lighting.展开更多
High-entropy alloys(HEAs),which are composed of 3d transition metals such as Fe,Co,and Ni,exhibit an exceptional combination of magnetic and other properties;however,the addition of non-ferromagnetic elements always n...High-entropy alloys(HEAs),which are composed of 3d transition metals such as Fe,Co,and Ni,exhibit an exceptional combination of magnetic and other properties;however,the addition of non-ferromagnetic elements always negatively affects the saturation magnetization strength(M s).Co_(4)Fe_(2)Al_(x)Mn_(y) alloys were designed and investigated in this study to develop a novel HEA with excellent soft magnetic properties.The Co_(4)Fe_(2)Al_(1.5)Mn_(1.5) HEA possesses the highest M s of 161.3 emu g^(-1) thus far reported for magnetic HEAs,a low coercivity of 1.9 Oe,a high electrical resistivity of 173μΩ cm,a superior thermal stability up to 600℃,which originates from the novel microstructure of B2 nanoparticles distributed in a DO_(3) matrix phase,and the crucial transition of Mn from antiferromagnetism to ferromagnetism with the assistance of Al.The Co_(4)Fe_(2_)Al_(1.5)Mn_(1.5) HEA was selected to produce micron-sized powder and soft magnetic powder cores(SMPCs)for application in the exploration field.The SMPCs exhibit a high stable effective perme-ability of 35.9 up to 1 MHz,low core loss of 38.1 mW cm^(-3)(@100 kHz,20 mT),and an excellent direct current(DC)bias performance of 87.7%at 100 Oe.This study paves the way for the development of soft magnetic HEAs with promising applications as magnetic functional materials.展开更多
We have investigated the transient characteristics of discrete Raman Amplifiers and found that the response time caused by gain saturation is dependent upon the wavelength, which corresponds to the effective length of...We have investigated the transient characteristics of discrete Raman Amplifiers and found that the response time caused by gain saturation is dependent upon the wavelength, which corresponds to the effective length of the pump light.展开更多
Monodispersed Fe nanospindles and nanoparticles were successfully synthesized through environmentfriendly reductive annealing ?-Fe OOH nanorods. Effects of annealing temperature and reaction atmosphere on microstruct...Monodispersed Fe nanospindles and nanoparticles were successfully synthesized through environmentfriendly reductive annealing ?-Fe OOH nanorods. Effects of annealing temperature and reaction atmosphere on microstructure, phase, and magnetic property of Fe nanostructures were investigated.The as-obtained pure Fe nanoparticles with mean size of 45 nm had a high saturation magnetization up to 207 emu/g, close to that of bulk material(218 emu/g), which exhibited high air stability. After exposing in air for 2 and 7 days, the as synthesized Fe nanoparticles still showed high magnetization of 182 and141 emu/g, respectively.展开更多
The pulse energy in the ultrafast soliton fiber laser oscillators is usually limited by the well-known wave-breaking phenomenon owing to the absence of a desirable real saturable absorber(SA) with high power tolerance...The pulse energy in the ultrafast soliton fiber laser oscillators is usually limited by the well-known wave-breaking phenomenon owing to the absence of a desirable real saturable absorber(SA) with high power tolerance and large modulation depth. Here, we report a type of microfiber-based MoTe_2 SA fabricated by the magnetron-sputtering deposition(MSD) method. High-energy wave-breaking free soliton pulses were generated with pulse duration/pulse energy/average output power of 229 fs/2.14 nJ/57 mW in the 1.5 μm regime and 1.3 ps/13.8 nJ/212 mW in the 2 μm regime, respectively. To our knowledge, the generated soliton pulses at 1.5 μm had the shortest pulse duration and the highest output power among the reported erbium-doped fiber lasers mode locked by transition metal dichalcogenides. Moreover, this was the first demonstration of a MoTe_2-based SA in fiber lasers in the 2 μm regime, and the pulse energy/output power are the highest in the reported thulium-doped fiber lasers mode locked by two-dimensional materials. Our results suggest that a microfiber-based MoTe_2 SA could be used as an excellent photonic device for ultrafast pulse generation, and the MSD technique opens a promising route to produce a high-performance SA with high power tolerance and large modulation depth, which are beneficial for high-energy wave-breaking free pulse generation.展开更多
As the consumption of fructose and saturated fatty acids(FAs) has greatly increased in western diets and is linked with an increased risk of metabolic syndrome,the aim of this study was to investigate the effects of a...As the consumption of fructose and saturated fatty acids(FAs) has greatly increased in western diets and is linked with an increased risk of metabolic syndrome,the aim of this study was to investigate the effects of a mod-erate(10 weeks) and a prolonged(30 weeks) high fructose and saturated fatty acid(HFS) diet on plasma FA com-position in rats.The effects of a few weeks of HFS diet had already been described,but in this paper we tried to es-tablish whether these effects persist or if they are modified after 10 or 30 weeks.We hypothesized that the plasma FA profile would be altered between 10 and 30 weeks of the HFS diet.Rats fed with either the HFS or a standard diet were tested after 10 weeks and again after 30 weeks.After 10 weeks of feeding,HFS-fed rats developed the metabolic syndrome,as manifested by an increase in fasting insulinemia,total cholesterol and triglyceride levels,as well as by impaired glucose tolerance.Furthermore,the plasma FA profile of the HFS group showed higher proportions of monounsaturated FAs like palmitoleic acid [16:1(n-7)] and oleic acid [18:1(n-9)],whereas the proportions of some polyunsaturated n-6 FAs,such as linoleic acid [18:2(n-6)] and arachidonic acid [20:4(n-6)],were lower than those in the control group.After 30 weeks of the HFS diet,we observed changes mainly in the levels of 16:1(n-7)(decreased) and 20:4(n-6)(increased).Together,our results suggest that an HFS diet could lead to an adaptive response of the plasma FA profile over time,in association with the development of the metabolic syndrome.展开更多
Structure,magnetic properties and ductile of melt-spun Fe_(83-x)Si_(4)B_(13-y)C_(y)Cu_(x)(x=0-1.7;y=0-8)alloys were investigated.The addition of 1.7 at.%Cu in a Fe_(83)Si_(4)B_(13) amorphous alloy generates abundantα...Structure,magnetic properties and ductile of melt-spun Fe_(83-x)Si_(4)B_(13-y)C_(y)Cu_(x)(x=0-1.7;y=0-8)alloys were investigated.The addition of 1.7 at.%Cu in a Fe_(83)Si_(4)B_(13) amorphous alloy generates abundantα-Fe crystals by providing nucleation sites,and further C doping promotes the growth of the crystals by suitable turning amorphous-forming ability,hence they increase saturation magnetic flux density(B_(s))and slightly worse magnetic softness of the as-spun alloys.The as-spun Fe_(81.3)Si_(4)B_(7)C_(6)Cu_(1.7) alloy possesses a combined structure of a fully amorphous layer in wheel side surface and predominating nanocrystalline structure with gradually enlargedα-Fe crystal,whose average size and volume fraction are determined as about 12 nm and 32%,respectively,therefore superior soft magnetic properties and ductile with a high B_(s)of 1.74 T,coercivity(H_(c))of 32.7 A/m,effective permeability(μ_(e),at 1 kHz)of 3200 and high relatively strain at fracture(ε_(f))of 3.61%can be achieved directly in this alloy by only using melt-spinning.The annealing at 578 K releases internal stress,promotes the growth of theα-Fe crystals and remains the amorphous layer of the Fe_(81.3)Si_(4)B_(7)C_(6)Cu_(1.7) alloy,then improves the soft magnetic properties and maintains the superior ductile with increasing the B_(s)andμ_(e)to 1.80 T and 14,100,respectively,lowering the H_(c)to9.4 A/m and slightly reducing theε_(f)to 2.39%.The combination of superior soft magnetic properties and ductile and simplified synthesis process entitles the Fe-Si-B-C-Cu nanocrystalline alloys great potentials in high performance electromagnetic applications.展开更多
The gelation properties of polyol acetal derivatives including 2,4-(3,4-dichlorobenzylidene)-D-sorbitol(DCBS), 1,3:2,4-di(3,4-dichlorobenzylidene)-D-sorbitol(DDCBS) and 1,3:2,5:4,6-tris(3,4-dichlorobenzyli...The gelation properties of polyol acetal derivatives including 2,4-(3,4-dichlorobenzylidene)-D-sorbitol(DCBS), 1,3:2,4-di(3,4-dichlorobenzylidene)-D-sorbitol(DDCBS) and 1,3:2,5:4,6-tris(3,4-dichlorobenzylidene)-D-mannitol(TDCBM) in 35 single solvents and 39 binary solvent mixtures have been studied. FTIR and XRD results suggest that the self-assembly patterns of the gelator will not change in either the single solvent component or the corresponding solvent mixtures, but the critical gelation concentration(CGC)will be influenced. The results of SEM and rheology showed that the formation of true gels at saturated concentrations. Improving the heating temperature may promote the dissolving of gelators which are even insoluble at the temperature of the solvent boiling point and change the gelation behaviors. FloryHuggins parameter(x) was used to predict the gelation behavior of DCBS in the mixed solvents, and it is shown that the x values for the mixed solvents that can be gelled by DCBS are either greater or smaller than those for the selected good solvents.展开更多
基金supported by the Natural Science Foundation of Beijing Municipality(No.Z180011)the National Natural Science Foundation of China(Nos.51991340,51991342,51527802,51972022,51722203,and 51672026)+2 种基金the Overseas Expertise Introduction Projects for Discipline Innovation(No.B14003)the National Key Research and Development Program of China(Nos.2016YFA0202701,and 2018YFA0703503)the Fundamental Research Funds for the Central Universities(No.FRF-TP-19-025A3).
文摘Monolayer two-dimensional(2D)semiconductors are emerging as top candidates for the channels of the future chip industry due to their atomically thin body and superior immunity to short channel effect.However,the low saturation current caused by the high contact resistance(R_(c))in monolayer MoS2 field-effect transistors(FETs)limits ultimate electrical performance at scaled contact lengths,which seriously hinders application of monolayer MoS_(2 )transistors.Here we present a scalable strategy with a clean end-bond contact scheme that leads to size-independent electrodes and ultralow contact resistance of 2.5 kΩ·μm to achieve record high performances of saturation current density of 730μA·μm^(-1)at 300 K and 960μA·μm^(-1)at 6 K.Our end-bond contact strategy in monolayer MoS2 FETs enables the great potential for atomically thin integrated circuitry.
文摘The dependences of soft magnetic properties and microstructures of the sputtered FeCo (=Fe65Co35) films on Co underlayer thickness tCo, FeCo thickness tFeCo, substrate temperature Ts and taxget-substrate spacing dT-s are studied. FeCo single layer generally shows a high coercivity with no obvious magnetic anisotropy. Excellent soft magnetic properties with saturation magnetization μ0Ms of 2.35 T and hard axis coercivity Hch of 0.25 kA/m in FeCo films can be achieved by introducing a Co underlayer. It is shown that sandwiching a Co underlayer causes a change in orientation and reduction in grain size from 70 nm to about 10 nm in the FeCo layer. The magnetic softness can be explained by the Hoffmann's ripple theory due to the effect of grain size. The magnetic anisotropy can be controlled by changing dT-S, and a maximum of 14.3 kA/m for anisotropic field Hk is obtained with dT-S=18.0 cm.
基金Supported by the Postgraduate Research of Malaysia under Grant No PG098-2014Bthe CSIR of Government of India
文摘We propose and demonstrate a Q-switched erbium-doped fiber laser (EDFL) using an erbium-doped zirconia-alumina silica glass-based fiber (Zr-EDF) as a saturable absorber. As a 16-cm-long Zr-EDF is incorporated into a ring EDFL cavity, a stable Q-switching pulse train operating at 1565?nm wavelength is successfully obtained. The repetition rate is tunable from 33.97?kHz to 71.23?kHz by increasing the pump power from the threshold of 26?mW to the maximum of 74?mW. The highest pulse energy of 26.67?nJ is obtained at the maximum pump power.
基金supported by the National Natural Science Foundation of China(51805196 and 51775219)National Key R&D Program of China(2022YFB3604803)Key Research and Development Program of Hubei Province(2021BAA213 and 2020BAB068).
文摘Phosphor-in-glass(PiG)film is a promising luminescent material in high-brightness laser lighting for its advantages of high efficiency,outstanding color quality,and low-cost preparation,which must bear high laser power(LP)and laser power density(LPD)simultaneously to enable high-luminance light.Herein,laser spot associated high-saturation PiG film was proposed for transmissive and reflective high-brightness laser lighting.Two types of PiG films were prepared by printing and sintering La_(3)Si_(6)N_(11):Ce^(3+)(LSN)phosphor-borosilicate glass pastes on a sapphire substrate(PiG-S)and an AlN substrate(PiG-A),respectively.The PiG films with perfect crystal structure of phosphor were reliably bonded on the substrates.The effects of laser spot areas on the luminescence saturation of LP and LPD were investigated in the PiG films.With the increase of laser spot area from 0.5 to 2.5 mm^(2),the LP threshold of PiG films is gradually raised,while the LPD threshold of PiG films is decreased.The PiG-S withstands a high LP of 23.46 W and a high LPD of 20.64 W/mm^(2),enabling white light with a luminous flux of 3677 lm.The PiG-A withstands a high LP of 41.12 W and a high LPD of 35.56 W/mm^(2),enabling white light with a luminous flux of 2882 lm.Moreover,the PiG-A maintains lower working temperature compared with the PiG-S,and the temperatures reduce with the increasing laser spot area.The results demonstrate that the laser spot associated PiG films realize high saturation thresholds of LP and LPD simultaneously,and enable high luminance for laser lighting.
基金supported by Youth Innovation Promotion Association CAS (Grant No.2021294)the S&T Innovation 2025 Major Special Program (Grant No.2021Z038)+1 种基金the 2022 Xinjiang Uygur Autonomous Region Postgraduate Innovation Research Program (Grand No.XJ2022G070)the Tianshan Innovation Team Program of Xinjiang Uygur Autonomous Region (Grand No.2020D14038).
文摘High-entropy alloys(HEAs),which are composed of 3d transition metals such as Fe,Co,and Ni,exhibit an exceptional combination of magnetic and other properties;however,the addition of non-ferromagnetic elements always negatively affects the saturation magnetization strength(M s).Co_(4)Fe_(2)Al_(x)Mn_(y) alloys were designed and investigated in this study to develop a novel HEA with excellent soft magnetic properties.The Co_(4)Fe_(2)Al_(1.5)Mn_(1.5) HEA possesses the highest M s of 161.3 emu g^(-1) thus far reported for magnetic HEAs,a low coercivity of 1.9 Oe,a high electrical resistivity of 173μΩ cm,a superior thermal stability up to 600℃,which originates from the novel microstructure of B2 nanoparticles distributed in a DO_(3) matrix phase,and the crucial transition of Mn from antiferromagnetism to ferromagnetism with the assistance of Al.The Co_(4)Fe_(2_)Al_(1.5)Mn_(1.5) HEA was selected to produce micron-sized powder and soft magnetic powder cores(SMPCs)for application in the exploration field.The SMPCs exhibit a high stable effective perme-ability of 35.9 up to 1 MHz,low core loss of 38.1 mW cm^(-3)(@100 kHz,20 mT),and an excellent direct current(DC)bias performance of 87.7%at 100 Oe.This study paves the way for the development of soft magnetic HEAs with promising applications as magnetic functional materials.
文摘We have investigated the transient characteristics of discrete Raman Amplifiers and found that the response time caused by gain saturation is dependent upon the wavelength, which corresponds to the effective length of the pump light.
基金the National Basic Research Program of China, under grant No. 2014CB643702the National Natural Science Foundation of China, under grant Nos. 51422106, 51401228, 61428403+2 种基金the Ningbo City Scientific and Technological Project under grant No. 2012B81001the Scientific and Technological Project of Zhejiang Province under grant No. 2013TD08the China Postdoctoral Science Foundation under grant No. 2014M561524 for financial support
文摘Monodispersed Fe nanospindles and nanoparticles were successfully synthesized through environmentfriendly reductive annealing ?-Fe OOH nanorods. Effects of annealing temperature and reaction atmosphere on microstructure, phase, and magnetic property of Fe nanostructures were investigated.The as-obtained pure Fe nanoparticles with mean size of 45 nm had a high saturation magnetization up to 207 emu/g, close to that of bulk material(218 emu/g), which exhibited high air stability. After exposing in air for 2 and 7 days, the as synthesized Fe nanoparticles still showed high magnetization of 182 and141 emu/g, respectively.
基金National Natural Science Foundation of China(NSFC)(11704260,61405126,61605122,61775146)Shenzhen Science and Technology Project(JCY20150324141711695,JCYJ20160427105041864,JSGG20160429114438287,KQJSCX20160226194031,JCYJ20160422103744090)+1 种基金Beijing University of Posts and Telecommunications(BUPT)(IPOC2015B003)Natural Science Foundation of Guangdong Province(2016A030310049,2016A030310059)
文摘The pulse energy in the ultrafast soliton fiber laser oscillators is usually limited by the well-known wave-breaking phenomenon owing to the absence of a desirable real saturable absorber(SA) with high power tolerance and large modulation depth. Here, we report a type of microfiber-based MoTe_2 SA fabricated by the magnetron-sputtering deposition(MSD) method. High-energy wave-breaking free soliton pulses were generated with pulse duration/pulse energy/average output power of 229 fs/2.14 nJ/57 mW in the 1.5 μm regime and 1.3 ps/13.8 nJ/212 mW in the 2 μm regime, respectively. To our knowledge, the generated soliton pulses at 1.5 μm had the shortest pulse duration and the highest output power among the reported erbium-doped fiber lasers mode locked by transition metal dichalcogenides. Moreover, this was the first demonstration of a MoTe_2-based SA in fiber lasers in the 2 μm regime, and the pulse energy/output power are the highest in the reported thulium-doped fiber lasers mode locked by two-dimensional materials. Our results suggest that a microfiber-based MoTe_2 SA could be used as an excellent photonic device for ultrafast pulse generation, and the MSD technique opens a promising route to produce a high-performance SA with high power tolerance and large modulation depth, which are beneficial for high-energy wave-breaking free pulse generation.
文摘As the consumption of fructose and saturated fatty acids(FAs) has greatly increased in western diets and is linked with an increased risk of metabolic syndrome,the aim of this study was to investigate the effects of a mod-erate(10 weeks) and a prolonged(30 weeks) high fructose and saturated fatty acid(HFS) diet on plasma FA com-position in rats.The effects of a few weeks of HFS diet had already been described,but in this paper we tried to es-tablish whether these effects persist or if they are modified after 10 or 30 weeks.We hypothesized that the plasma FA profile would be altered between 10 and 30 weeks of the HFS diet.Rats fed with either the HFS or a standard diet were tested after 10 weeks and again after 30 weeks.After 10 weeks of feeding,HFS-fed rats developed the metabolic syndrome,as manifested by an increase in fasting insulinemia,total cholesterol and triglyceride levels,as well as by impaired glucose tolerance.Furthermore,the plasma FA profile of the HFS group showed higher proportions of monounsaturated FAs like palmitoleic acid [16:1(n-7)] and oleic acid [18:1(n-9)],whereas the proportions of some polyunsaturated n-6 FAs,such as linoleic acid [18:2(n-6)] and arachidonic acid [20:4(n-6)],were lower than those in the control group.After 30 weeks of the HFS diet,we observed changes mainly in the levels of 16:1(n-7)(decreased) and 20:4(n-6)(increased).Together,our results suggest that an HFS diet could lead to an adaptive response of the plasma FA profile over time,in association with the development of the metabolic syndrome.
基金financially supported by the National Key Research and Development Program of China(No.2016YFB0300500)the Youth Innovation Promotion Association CAS(No.2021294)+1 种基金the National Natural Science Foundation of China(No.51571047)Ningbo Major Special Projects of the Plan"Science and Technology Innovation 2025"(No.2018B10084)。
文摘Structure,magnetic properties and ductile of melt-spun Fe_(83-x)Si_(4)B_(13-y)C_(y)Cu_(x)(x=0-1.7;y=0-8)alloys were investigated.The addition of 1.7 at.%Cu in a Fe_(83)Si_(4)B_(13) amorphous alloy generates abundantα-Fe crystals by providing nucleation sites,and further C doping promotes the growth of the crystals by suitable turning amorphous-forming ability,hence they increase saturation magnetic flux density(B_(s))and slightly worse magnetic softness of the as-spun alloys.The as-spun Fe_(81.3)Si_(4)B_(7)C_(6)Cu_(1.7) alloy possesses a combined structure of a fully amorphous layer in wheel side surface and predominating nanocrystalline structure with gradually enlargedα-Fe crystal,whose average size and volume fraction are determined as about 12 nm and 32%,respectively,therefore superior soft magnetic properties and ductile with a high B_(s)of 1.74 T,coercivity(H_(c))of 32.7 A/m,effective permeability(μ_(e),at 1 kHz)of 3200 and high relatively strain at fracture(ε_(f))of 3.61%can be achieved directly in this alloy by only using melt-spinning.The annealing at 578 K releases internal stress,promotes the growth of theα-Fe crystals and remains the amorphous layer of the Fe_(81.3)Si_(4)B_(7)C_(6)Cu_(1.7) alloy,then improves the soft magnetic properties and maintains the superior ductile with increasing the B_(s)andμ_(e)to 1.80 T and 14,100,respectively,lowering the H_(c)to9.4 A/m and slightly reducing theε_(f)to 2.39%.The combination of superior soft magnetic properties and ductile and simplified synthesis process entitles the Fe-Si-B-C-Cu nanocrystalline alloys great potentials in high performance electromagnetic applications.
基金the financial support of the National Natural Science Foundation of China(No. 21476164)Tianjin Science and Technology Innovation Platform Program(No. 14TXGCCX00017)
文摘The gelation properties of polyol acetal derivatives including 2,4-(3,4-dichlorobenzylidene)-D-sorbitol(DCBS), 1,3:2,4-di(3,4-dichlorobenzylidene)-D-sorbitol(DDCBS) and 1,3:2,5:4,6-tris(3,4-dichlorobenzylidene)-D-mannitol(TDCBM) in 35 single solvents and 39 binary solvent mixtures have been studied. FTIR and XRD results suggest that the self-assembly patterns of the gelator will not change in either the single solvent component or the corresponding solvent mixtures, but the critical gelation concentration(CGC)will be influenced. The results of SEM and rheology showed that the formation of true gels at saturated concentrations. Improving the heating temperature may promote the dissolving of gelators which are even insoluble at the temperature of the solvent boiling point and change the gelation behaviors. FloryHuggins parameter(x) was used to predict the gelation behavior of DCBS in the mixed solvents, and it is shown that the x values for the mixed solvents that can be gelled by DCBS are either greater or smaller than those for the selected good solvents.