N-2000 is an admixture for concrete, with a low slump loss, high range water-reducing ratio and long-time retarding. The N-2000 is made up of naphthalene-sulfonic-maldehyde polycondensation (NSMP) and ATMP. Its charac...N-2000 is an admixture for concrete, with a low slump loss, high range water-reducing ratio and long-time retarding. The N-2000 is made up of naphthalene-sulfonic-maldehyde polycondensation (NSMP) and ATMP. Its characteristic results from the synergistic effects of NSMP and ATMP. The results show that when 0.7%-1.2% of N-2000 is added to concrete (by mass of cement), the water reducing ratio is up to 20%-30%, and the slump of fresh concrete can be retained for 2 hours without significant loss. N-2000 can not only improve the workability of fresh concrete but also increase the strength of the hardened concrete, especially early strength. It is also proved to have a good compatibility with various cements.展开更多
The primary objective of this research was to determine optimum dosage of mixing concrete containing plasticizers and fly ash, consistent with desirable structural grade concrete properties. Factorial tests were also ...The primary objective of this research was to determine optimum dosage of mixing concrete containing plasticizers and fly ash, consistent with desirable structural grade concrete properties. Factorial tests were also conducted to investigate the four main factors： water-cementing materials ratio, water content, content of superplasticizers （SP） and fly ash content. It was found that the requirement for setting time played the dominant role in shrinkage and anti-cracking, and fly ash played a critical role in workability and reducing heat of hydration but showed insignificant effects on slump, early strength and initial setting time of concrete.展开更多
A new kind of polycarboxylate superplasticizer with high slump loss resistance was obtained by designing scheduled molecular structure.The number average molecular mass of the polymer was characterized by the gel perm...A new kind of polycarboxylate superplasticizer with high slump loss resistance was obtained by designing scheduled molecular structure.The number average molecular mass of the polymer was characterized by the gel permeation chromatography measurements.And chemical structure of the polymer was observed by the Fourier transform infrared spectroscopy(FT-IR).The results show that the good workable maintaining of self-compacting concrete could be achieved through direct adjustment of number average molecular mass and different unsaturated monomer in synthetic process.The FT-IR analysis illustrated that the high slump loss resistance of polycarboxylate superplasticizers with ester and carboxyl group and expectations of molecular structure were designed.展开更多
渗透和扩散是污染物在防渗屏障中迁移的重要方式,当前对低固结压力下土–膨润土防渗墙渗透系数和扩散系数测试是否必须采用柔性壁渗透仪、是否必须对试样进行固结尚无统一看法。按土–膨润土防渗墙施工工艺制备填料,使用柔性壁渗透仪测...渗透和扩散是污染物在防渗屏障中迁移的重要方式,当前对低固结压力下土–膨润土防渗墙渗透系数和扩散系数测试是否必须采用柔性壁渗透仪、是否必须对试样进行固结尚无统一看法。按土–膨润土防渗墙施工工艺制备填料,使用柔性壁渗透仪测试了30,50和100 k Pa有效固结压力下填料渗透系数,进行刚性壁土柱渗透–扩散试验测试了10 k Pa固结压力下填料渗透系数和扩散系数,基于加速沥出试验原理提出快速测定高塌落度填料有效扩散系数的透析试验方法。柔性壁渗透试验结果表明,填料流入和流出渗透系数均随水力梯度增大而增大,存在起始水力梯度,柔性壁渗透试验的起始水力梯度在6.82~8,随固结压力由30 k Pa增至100 k Pa,渗透系数由5.21×10^(-8)降至3.78×10^(-8) cm/s。10 k Pa固结压力下,刚性壁渗透–扩散试验测得起始水力梯度为5.67,渗透系数为7.14×10^(-8) cm/s,试验不存在侧壁渗漏,填料中Cl^-有效扩散系数为3.12×10^(-6) cm^2/s。透析试验填料未经固结,测得有效扩散系数为4.45×10^(-6) cm^2/s。掺入6.02%膨润土后,粉土渗透系数降低约4个数量级,有效扩散系数仅降低约一半,扩散将是膨润土系防渗墙中污染物迁移的主要方式。展开更多
基金Key Science and Technology Development Fund Project of Hubei Province.China(No.941PO106).
文摘N-2000 is an admixture for concrete, with a low slump loss, high range water-reducing ratio and long-time retarding. The N-2000 is made up of naphthalene-sulfonic-maldehyde polycondensation (NSMP) and ATMP. Its characteristic results from the synergistic effects of NSMP and ATMP. The results show that when 0.7%-1.2% of N-2000 is added to concrete (by mass of cement), the water reducing ratio is up to 20%-30%, and the slump of fresh concrete can be retained for 2 hours without significant loss. N-2000 can not only improve the workability of fresh concrete but also increase the strength of the hardened concrete, especially early strength. It is also proved to have a good compatibility with various cements.
基金Funded by the National Natural Science Foundation of China(51409202)the Fundamental Research Funds for the Central Universities(2013-IV-36)the Jiangxi Provincial Project of Science and Technology(20132GGB70107)
文摘The primary objective of this research was to determine optimum dosage of mixing concrete containing plasticizers and fly ash, consistent with desirable structural grade concrete properties. Factorial tests were also conducted to investigate the four main factors： water-cementing materials ratio, water content, content of superplasticizers （SP） and fly ash content. It was found that the requirement for setting time played the dominant role in shrinkage and anti-cracking, and fly ash played a critical role in workability and reducing heat of hydration but showed insignificant effects on slump, early strength and initial setting time of concrete.
文摘A new kind of polycarboxylate superplasticizer with high slump loss resistance was obtained by designing scheduled molecular structure.The number average molecular mass of the polymer was characterized by the gel permeation chromatography measurements.And chemical structure of the polymer was observed by the Fourier transform infrared spectroscopy(FT-IR).The results show that the good workable maintaining of self-compacting concrete could be achieved through direct adjustment of number average molecular mass and different unsaturated monomer in synthetic process.The FT-IR analysis illustrated that the high slump loss resistance of polycarboxylate superplasticizers with ester and carboxyl group and expectations of molecular structure were designed.
文摘渗透和扩散是污染物在防渗屏障中迁移的重要方式,当前对低固结压力下土–膨润土防渗墙渗透系数和扩散系数测试是否必须采用柔性壁渗透仪、是否必须对试样进行固结尚无统一看法。按土–膨润土防渗墙施工工艺制备填料,使用柔性壁渗透仪测试了30,50和100 k Pa有效固结压力下填料渗透系数,进行刚性壁土柱渗透–扩散试验测试了10 k Pa固结压力下填料渗透系数和扩散系数,基于加速沥出试验原理提出快速测定高塌落度填料有效扩散系数的透析试验方法。柔性壁渗透试验结果表明,填料流入和流出渗透系数均随水力梯度增大而增大,存在起始水力梯度,柔性壁渗透试验的起始水力梯度在6.82~8,随固结压力由30 k Pa增至100 k Pa,渗透系数由5.21×10^(-8)降至3.78×10^(-8) cm/s。10 k Pa固结压力下,刚性壁渗透–扩散试验测得起始水力梯度为5.67,渗透系数为7.14×10^(-8) cm/s,试验不存在侧壁渗漏,填料中Cl^-有效扩散系数为3.12×10^(-6) cm^2/s。透析试验填料未经固结,测得有效扩散系数为4.45×10^(-6) cm^2/s。掺入6.02%膨润土后,粉土渗透系数降低约4个数量级,有效扩散系数仅降低约一半,扩散将是膨润土系防渗墙中污染物迁移的主要方式。
