The low voltage powerline is becoming a powerful solution to home network, building automation, and internet access as a result of its wide distribution, easy access and little maintenance. The character of powerline ...The low voltage powerline is becoming a powerful solution to home network, building automation, and internet access as a result of its wide distribution, easy access and little maintenance. The character of powerline channel is very complicated because it is an open net. This article analysed the character of the powerline channel,introduced the basics of OFDM(Orthogonal Frequency Division Multiplexing), and studied the OFDM applied into powerline high speed digital communication.展开更多
Modified polyimides(MPIs)show great potential towards 5G communication applications,due to its excellent thermal stability,mechanical property and chemical stability as compared to most of polymers.Introducing fluorid...Modified polyimides(MPIs)show great potential towards 5G communication applications,due to its excellent thermal stability,mechanical property and chemical stability as compared to most of polymers.Introducing fluoride groups or porous structure is favorable to ultra-low dielectric constant(D_(k))and dielectric loss(D_(f)).However,the cost of the fluorinated MPIs is high and their synthetic processes are complicated,and porous MPIs suffer poor mechanical properties.Also,increasing the fraction of free volume is a very effective way to lower D_(k)through introducing more ultra-low-D_(k)air component.However,most of this kind of MPIs lag far behind the fluorinated MPIs and the porous MPIs in terms of ultra-low D_(f),hindering the application of MPIs in high-speed communication devices.Thus,it is highly desirable to develop intrinsic ultra-low-D_(k)/D_(f)MPIs at high frequency with less fluoric groups and nonporous structure.Herein,we introduce a facile and effective strategy to lower D_(k)and D_(f)through introducing rigid and large sterically hindered aromatic groups into MPIs.On the one hand,their large steric hindrance effect leads to low D_(k)by increasing intrinsic free volume.On the other hand,the resulting highly stiff polymer chain and strong intermolecular interaction are favorable to reduce D_(f)by inhibiting dipole orientations.Based on this strategy,the spirobifluorene groups are preferred.The as-prepared MPIs show excellent dielectric performance with low D_(k)of 2.74–2.76 and low D_(f)of 0.00599 at 10 GHz,to some extent,exceeding the multiple fluorinated MPI with D_(k)/D_(f)of 2.67/0.00663 at 10 GHz.展开更多
文摘The low voltage powerline is becoming a powerful solution to home network, building automation, and internet access as a result of its wide distribution, easy access and little maintenance. The character of powerline channel is very complicated because it is an open net. This article analysed the character of the powerline channel,introduced the basics of OFDM(Orthogonal Frequency Division Multiplexing), and studied the OFDM applied into powerline high speed digital communication.
基金Key-Area Research and Development Program of Guangdong Province(No.2020B010182001)the National Natural Science Foundation of China(Nos.U20A20340 and 52001068)+3 种基金National Key R&D Program of China(No.2020YFB0408100)Guangdong Innovative and Entrepreneurial Research Team Program(No.2016ZT06C412)the“One-Hundred Young Talents”of Guangdong University of Technology(No.220413236)Foshan Introducing Innovative and Entrepreneurial Teams(No.1920001000108)。
文摘Modified polyimides(MPIs)show great potential towards 5G communication applications,due to its excellent thermal stability,mechanical property and chemical stability as compared to most of polymers.Introducing fluoride groups or porous structure is favorable to ultra-low dielectric constant(D_(k))and dielectric loss(D_(f)).However,the cost of the fluorinated MPIs is high and their synthetic processes are complicated,and porous MPIs suffer poor mechanical properties.Also,increasing the fraction of free volume is a very effective way to lower D_(k)through introducing more ultra-low-D_(k)air component.However,most of this kind of MPIs lag far behind the fluorinated MPIs and the porous MPIs in terms of ultra-low D_(f),hindering the application of MPIs in high-speed communication devices.Thus,it is highly desirable to develop intrinsic ultra-low-D_(k)/D_(f)MPIs at high frequency with less fluoric groups and nonporous structure.Herein,we introduce a facile and effective strategy to lower D_(k)and D_(f)through introducing rigid and large sterically hindered aromatic groups into MPIs.On the one hand,their large steric hindrance effect leads to low D_(k)by increasing intrinsic free volume.On the other hand,the resulting highly stiff polymer chain and strong intermolecular interaction are favorable to reduce D_(f)by inhibiting dipole orientations.Based on this strategy,the spirobifluorene groups are preferred.The as-prepared MPIs show excellent dielectric performance with low D_(k)of 2.74–2.76 and low D_(f)of 0.00599 at 10 GHz,to some extent,exceeding the multiple fluorinated MPI with D_(k)/D_(f)of 2.67/0.00663 at 10 GHz.