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Product Development of High Strength and Toughness Spring Flat Steel
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作者 Jianxin Wang Chunhui Zhang 《Frontiers of Metallurgical Industry》 2024年第1期15-18,共4页
With the continuous development of mechanical industry,higher requirements are put forward for the comprehensive properties of spring steel.The chemical composition and production process of spring flat steel are desi... With the continuous development of mechanical industry,higher requirements are put forward for the comprehensive properties of spring steel.The chemical composition and production process of spring flat steel are designed to meet the requirements of high strength and high toughness of spring flat steel,through the test,the product surface quality and internal quality all meet the national standards,the performance indicators to meet user requirements. 展开更多
关键词 spring flat steel mechanical properties high strength high toughness
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Constructing high-toughness polyimide binder with robust polarity and ion-conductive mechanisms ensuring long-term operational stability of silicon-based anodes
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作者 Yongjun Kang Nanxi Dong +5 位作者 Fangzhou Liu Daolei Lin Bingxue Liu Guofeng Tian Shengli Qi Dezhen Wu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期580-591,I0014,共13页
Silicon-based materials have demonstrated remarkable potential in high-energy-density batteries owing to their high theoretical capacity.However,the significant volume expansion of silicon seriously hinders its utiliz... Silicon-based materials have demonstrated remarkable potential in high-energy-density batteries owing to their high theoretical capacity.However,the significant volume expansion of silicon seriously hinders its utilization as a lithium-ion anode.Herein,a functionalized high-toughness polyimide(PDMI) is synthesized by copolymerizing the 4,4'-Oxydiphthalic anhydride(ODPA) with 4,4'-oxydianiline(ODA),2,3-diaminobenzoic acid(DABA),and 1,3-bis(3-aminopropyl)-tetramethyl disiloxane(DMS).The combination of rigid benzene rings and flexible oxygen groups(-O-) in the PDMI molecular chain via a rigidness/softness coupling mechanism contributes to high toughness.The plentiful polar carboxyl(-COOH) groups establish robust bonding strength.Rapid ionic transport is achieved by incorporating the flexible siloxane segment(Si-O-Si),which imparts high molecular chain motility and augments free volume holes to facilitate lithium-ion transport(9.8 × 10^(-10) cm^(2) s^(-1) vs.16 × 10^(-10) cm^(2) s~(-1)).As expected,the SiO_x@PDMI-1.5 electrode delivers brilliant long-term cycle performance with a remarkable capacity retention of 85% over 500 cycles at 1.3 A g^(-1).The well-designed functionalized polyimide also significantly enhances the electrochemical properties of Si nanoparticles electrode.Meanwhile,the assembled SiO_x@PDMI-1.5/NCM811 full cell delivers a high retention of 80% after 100 cycles.The perspective of the binder design strategy based on polyimide modification delivers a novel path toward high-capacity electrodes for high-energy-density batteries. 展开更多
关键词 Polyimide binder high toughness Robust ionic transport Silicon-based anodes Lithium-ion batteries
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Ultrahigh strength and improved electrical conductivity in an aging strengthened copper alloy processed by combination of equal channel angular pressing and thermomechanical treatment
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作者 WANG Xu LI Zhou +1 位作者 MENG Xiang-peng XIAO Zhu 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第6期1823-1837,共15页
In this paper,equal channel angular pressing and thermomechanical treatment was employed to improve the strength and electrical conductivity of an aging strengthened Cu-Ti-Cr-Mg alloy,and the microstructure and proper... In this paper,equal channel angular pressing and thermomechanical treatment was employed to improve the strength and electrical conductivity of an aging strengthened Cu-Ti-Cr-Mg alloy,and the microstructure and properties of the alloy were investigated in detail.The results showed that the samples deformed by the combination of cryogenic equal channel angular pressing(ECAP)and rolling had good comprehensive properties after aging at 400℃.The tensile strength of the peak-aged and over-aged samples was 1120 MPa and 940 MPa,with their corresponding electrical conductivity of 14.7%IACS and 22.1%IACS,respectively.ECAP and cryogenic rolling introduced high density dislocations,leading to the inhibition of the softening effects and refinement of the grains.After a long time aging at 400℃,the alloy exhibited ultra-high strength with obvious increasing electrical conductivity.The high strength was attributed to the synergistic effect of work hardening,grain refinement strengthening and precipitation strengthening.The precipitation of a large amount of Ti atoms from the matrix led to the high electrical conductivity of the over-aged sample. 展开更多
关键词 Cu-Ti alloy equal channel angular pressing ROLLING aging treatment high strength
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Development of a High Early Strength Non-fuorine and Non-alkaline Flash Setting Admixture and Flash Mechanism
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作者 SUN Guowen YANG Xinyu +2 位作者 WANG Fengjuan WANG Jinshuo LIU Zhiyong 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第6期1518-1527,共10页
To solve the problems of high rebound rate and strength reversion of shotcrete,a non-fluorine and non-alkaline liquid flash setting admixture(FSN)with low rebound and high early strength was synthesized under 60-65℃w... To solve the problems of high rebound rate and strength reversion of shotcrete,a non-fluorine and non-alkaline liquid flash setting admixture(FSN)with low rebound and high early strength was synthesized under 60-65℃water bath environment through orthogonal test design and taking setting time and compressive strength as indicators.The experimental results show that the optimum mass ratio of FSN is aluminum sulfate:diethanolamine:triethanolamine:pseudo-boehmite:lithium carbonate:water=57%:8%:0.05%:2%:2%:31%.When FSN is added with 7%of the mass of portland cement,the cement paste can be initially set in 3 min and finally set in 5 min.The compressive strength of mortar is 1.2 MPa at 6 h,18.0 MPa at 1 d,and more than 100%at 28 days;The microscopic analysis shows that the rapid release of Li^(+),NH^(4+),and CO_(3)^(2-)ions by FSN in the paste solution effectively shortens the induction period of high C_(3)S content in Portland cement,directly forms early coagulation AFt crystals in FSN and CH dominated by Al_(2)(SO_(4))_(3),and forms a large number of C-S-H gels in the later stage,so that the cement can quickly coagulate and harden,and the strength in the later stage is not retracted. 展开更多
关键词 SHOTCRETE flash setting admixture aluminum sulfate high early strength flash mechanism
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Effect of B_(2)O_(3) enrichment on microstructural inhomogeneity of high strength steel weldments
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作者 Joydeep Roy Pritam Das 《China Welding》 CAS 2024年第3期25-32,共8页
The present work attributes the role of boron on the high strength steel submerged arc weld using an undermatching filler wire.Mild steel filler wire was used for welding in constant machine parameters setting to eval... The present work attributes the role of boron on the high strength steel submerged arc weld using an undermatching filler wire.Mild steel filler wire was used for welding in constant machine parameters setting to evaluate the joint strength due to the enrichment of boron.To change the chemical composition of the weld metal,boron trioxide powder was blended with virgin flux in various proportions(2.5%−12.5%),which led to an increase in boron weight percentage in the range of 0−0.0065.The results show that weld metals(WM)optical micrographs depict the various types of ferrites,pearlites and secondary phases like martensite-austenite(M-A).Acicular ferrite content was influenced by the boron trioxide addition.Heat affected zone(HAZ)micrographs were not showing appreciable changes with oxide enrichment.Hardness and toughness of weld metals showed the mixed trend with B_(2)O_(3) enrichment whereas,small reduction in ultimate tensile strength(UTS)and yield strength(YS)was observed. 展开更多
关键词 high strength steel B_(2)O_(3) flux microstructure HARDNESS toughness ultimate tensile strength
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Anisotropic strength,deformation and failure of gneiss granite under high stress and temperature coupled true triaxial compression
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作者 Hongyuan Zhou Zaobao Liu +2 位作者 Fengjiao Liu Jianfu Shao Guoliang Li 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2024年第3期860-876,共17页
The anisotropic mechanical behavior of rocks under high-stress and high-temperature coupled conditions is crucial for analyzing the stability of surrounding rocks in deep underground engineering.This paper is devoted ... The anisotropic mechanical behavior of rocks under high-stress and high-temperature coupled conditions is crucial for analyzing the stability of surrounding rocks in deep underground engineering.This paper is devoted to studying the anisotropic strength,deformation and failure behavior of gneiss granite from the deep boreholes of a railway tunnel that suffers from high tectonic stress and ground temperature in the eastern tectonic knot in the Tibet Plateau.High-temperature true triaxial compression tests are performed on the samples using a self-developed testing device with five different loading directions and three temperature values that are representative of the geological conditions of the deep underground tunnels in the region.Effect of temperature and loading direction on the strength,elastic modulus,Poisson’s ratio,and failure mode are analyzed.The method for quantitative identification of anisotropic failure is also proposed.The anisotropic mechanical behaviors of the gneiss granite are very sensitive to the changes in loading direction and temperature under true triaxial compression,and the high temperature seems to weaken the inherent anisotropy and stress-induced deformation anisotropy.The strength and deformation show obvious thermal degradation at 200℃due to the weakening of friction between failure surfaces and the transition of the failure pattern in rock grains.In the range of 25℃ 200℃,the failure is mainly governed by the loading direction due to the inherent anisotropy.This study is helpful to the in-depth understanding of the thermal-mechanical behavior of anisotropic rocks in deep underground projects. 展开更多
关键词 Anisotropic strength and deformation True triaxial compression Thermal mechanical coupling Deep rock mechanics high temperature rock mechanics
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Effect of casting process on the inner-wall band segregation of high-strength antisulfur pipes
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作者 LUO Ming ZHANG Zhonghua 《Baosteel Technical Research》 CAS 2024年第1期27-36,共10页
Controlling inner-wall band segregation is one of the difficulties in the production of high-strength antisulfur pipes.Comparative tests were carried out on different casting processes(superheat,mold electromagnetic s... Controlling inner-wall band segregation is one of the difficulties in the production of high-strength antisulfur pipes.Comparative tests were carried out on different casting processes(superheat,mold electromagnetic stirring,end electromagnetic stirring,casting speed and soft reduction)for the smelting of high-strength antisulfur pipes.The microstructures of continuous-casting billets and hot-rolled or tempered pipes were analyzed using a metallographic microscope and scanning electron microscope.The mechanism and evolution law regarding the inner-wall band segregation of high-strength antisulfur pipes were studied,and the influence of different casting processes was explored. 展开更多
关键词 high strength antisulfur pipe casting process spot segregation band segregation
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Effect of microstructure on the low temperature toughness of high strength pipeline steels 被引量:10
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作者 Yan-ping Zeng Peng-yu Zhu Ke Tong 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2015年第3期254-261,共8页
Microstructure observations and drop-weight tear test were performed to study the microstructures and mechanical properties of two kinds of industrial X70 and two kinds of industrial X80 grade pipeline steels. The eff... Microstructure observations and drop-weight tear test were performed to study the microstructures and mechanical properties of two kinds of industrial X70 and two kinds of industrial X80 grade pipeline steels. The effective grain size and the fraction of high angle grain boundaries in the pipeline steels were investigated by electron backscatter diffraction analysis. It is found that the low temperature toughness of the pipeline steels depends not only on the effective grain size, but also on other microstructural factors such as martensite-austenite (MA) constituents and precipitates. The morphology and size of MA constituents significantly affect the mechanical properties of the pipeline steels. Nubby MA constituents with large size have significant negative effects on the toughness, while smaller granular MA constituents have less harmful effects. Similarly, larger Ti-rich nitrides with sharp corners have a strongly negative effect on the toughness, while fine, spherical Nb-rich carbides have a less deleterious effect. The low temperature toughness of the steels is independent of the fraction of high angle grain boundaries. 展开更多
关键词 high strength pipe steels microstrucmre low temperature toughness influencing factors
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Design of a low-alloy high-strength and high-toughness martensitic steel 被引量:8
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作者 Yan-jun Zhao Xue-ping Ren +1 位作者 Wen-chao Yang Yue Zang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2013年第8期733-740,共8页
To develop a high strength low alloy (HSLA) steel with high strength and high toughness, a series of martensitic steels were studied through alloying with various elements and thermodynamic simulation. The microstru... To develop a high strength low alloy (HSLA) steel with high strength and high toughness, a series of martensitic steels were studied through alloying with various elements and thermodynamic simulation. The microstructure and mechanical properties of the designed steel were investigated by optical microscopy, scanning electron microscopy, tensile testing and Charpy impact test. The results show that cementite exists between 500℃ and 700℃, M7C3 exits below 720℃, and they are much lower than the austenitizing temperature of the designed steel. Furthermore, the Ti(C,N) precipitate exists until 1280℃, which refines the microstructure and increases the strength and toughness. The optimal alloying components are 0.19% C, 1.19% Si, 2.83% Mn, 1.24% Ni, and 0.049% Ti; the tensile strength and the V notch impact toughness of the designed steel are more than 1500 MPa and 100 J, respectively. 展开更多
关键词 high strength steel martensitic steel alloy design THERMODYNAMICS alloying elements microstructuremechanical properties
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Flexural response of reinforced concrete beams strengthened with post-poured ultra high toughness cementitious composites layer 被引量:6
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作者 王楠 徐世烺 《Journal of Central South University》 SCIE EI CAS 2011年第3期932-939,共8页
Four-point bending tests were conducted up to failure on eleven reinforced concrete (RC) beams and strengthening beams to study the effectiveness of externally pouring ultra high toughness cementitious composites (UHT... Four-point bending tests were conducted up to failure on eleven reinforced concrete (RC) beams and strengthening beams to study the effectiveness of externally pouring ultra high toughness cementitious composites (UHTCC) on improving the flexural behavior of existing RC beams.The strengthening materials included UHTCC and high strength grade concrete.The parameters,such as thickness and length of strengthening layer and reinforcement in post-poured layer,were analyzed.The flexural behavior,failure mode and crack propagation of composite beams were investigated.The test results show that the strengthening layer improves the cracking and ultimate load by increasing the cross section area.Introducing UHTCC material into strengthening not only improves the bearing capacity of the original specimens,but also disperses larger cracks in upper concrete into multiple tightly-spaced fine cracks,thus prolonging the appearance of harm surface cracks and increasing the durability of existing structures.Compared with post-poured concrete,UHTCC is more suitable for working together with reinforcement.The load?deflection plots obtained from three-dimensional finite-element model (FEM) analyses are compared with those obtained from the experimental results,and show close correlation. 展开更多
关键词 ultra high toughness cementitious composities strengthening beams flexural behavior post-poured layer
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Mechanical properties and grain refinement by acicular ferrite in high strength high toughness weld metal 被引量:2
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作者 雷玄威 王红鸿 +1 位作者 吴开明 于磊 《China Welding》 EI CAS 2016年第1期71-76,共6页
The volume fraction and morphology of acicular ferrite evolution in a high strength high toughness weld metal were studied and the mechanical properties of weld metal under heat input of 21 kJ/cm with and without fast... The volume fraction and morphology of acicular ferrite evolution in a high strength high toughness weld metal were studied and the mechanical properties of weld metal under heat input of 21 kJ/cm with and without fast cooling were tested. The results show the weld metal can obtain a large proportion of acicular ferrite during a wide range of cooling rate and the sizes of acicular ferrite in length and thickness decrease with cooling rate increasing. The weld metal exhibited high tensile strength (895 MPa and 870 MPa) and good low temperature toughness (average AKv-30℃ 104 J and 79. 2 J). The higher tensile strength and better low temperature toughness of the weld metal under fast cooling are due to the more refined grain of acicular ferrite. 展开更多
关键词 acicular ferrite high toughness weld metal mechanical properties
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EFFECT OF WELDING THERMAL CYCLE ON THE MICROSTRUCTURE AND TOUGHNESS OF LOW ALLOY HIGH STRENGTH STEEL 被引量:1
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作者 C.S.Hu1,2) and Y.X.Gu3) 1) Department of Mechanical Engineering ,Fushun Petroleum Institute,Fushun 113001 ,China 2) State Key Laboratory for Corrosion and Protection ,Institute of Corrosion and Protection of Metal, The Chi nese Academy of Science,She 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1999年第4期626-629,共4页
Weldingthermalcyclicsimulated techniquesisemployed in thestudy. By meansof analysismetalloscope, fracture morphology and impact toughness test of the sample, the effect ofweldingthermalcycle peak temperature and dualt... Weldingthermalcyclicsimulated techniquesisemployed in thestudy. By meansof analysismetalloscope, fracture morphology and impact toughness test of the sample, the effect ofweldingthermalcycle peak temperature and dualthermal cycle on the micro structure and toughnessoflow alloy high strength steel HQ100 isinvestigated.Inner fine martensitic andbainitic microstrctureisobservedby TEM.Theresultsshow that withtheincreaseof peaktem perature, grain sizesbecomelarger,theimpacttoughness drop down .Ifthermalcycleisim posed twiceand dualthermalcyclicpeaktemperatureis1275 ℃+ 750 ℃,theimpacttoughnessisatthelowest value.Alsotheimpacttoughnessagrees withthefracture morphology. 展开更多
关键词 thermalcycle peaktemperature high strengthsteel MICROSTRUCTURE and toughness
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Dynamic fracture toughness of high strength metals under impact loading:increase or decrease 被引量:5
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作者 Ze-Jian Xu Yu-Long Li 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2011年第4期559-566,共8页
An elusive phenomenon is observed in previous investigations on dynamic fracture that the dynamic fracture toughness (DFT) of high strength metals always increases with the loading rate on the order of TPa.m1/2.s-1.... An elusive phenomenon is observed in previous investigations on dynamic fracture that the dynamic fracture toughness (DFT) of high strength metals always increases with the loading rate on the order of TPa.m1/2.s-1. For the purpose of verification, variation of DFT with the loading rate for two high strength steels commonly used in the aviation industry, 30CrMnSiA and 40Cr, is studied in this work. Results of the experiments are compared, which were conducted on the modified split Hopkinson pressure bar (SHPB) apparatus, with striker velocities ranging from 9.2 to 24.1 m/s and a constant value of 16.3 m/s for 30CrMnSiA and 40Cr, respectively. It is observed that for 30CrMnSiA, the crack tip loading rate increases with the increase of the striker velocity, while the fracture initiation time and the DFT simultaneously decrease. However, in the tests of 40Cr, there is also an increasing tendency of DFT, similar to other reports. Through an in-depth investigation on the relationship between the dynamic stress intensity factor (DSIF) and the loading rate, it is concluded that the generally increasing tendency in previous studies could be false, which is induced from a limited striker velocity domain and the errors existing in the experimental and numerical processes. To disclose the real dependency of DFT on the loading rate, experimentsneed to be performed in a comparatively large striker velocity range. 展开更多
关键词 Dynamic fracture. Fracture toughness Loadingrate effect - Hopkinson pressure bar high strength metal
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Effect of Plastic Deformation and H_2S on Dynamic Fracture Toughness of High Strength Casing Steel 被引量:1
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作者 曾德智 ZHANG Naiyan +3 位作者 TIAN Gang HU Junying ZHANG Zhi SHI Taihe 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS 2015年第2期397-403,共7页
The effects of plastic deformation and H2 S on fracture toughness of high strength casing steel(C110 steel) were investigated. The studied casing specimens are as follows: original casing, plastic deformation(PD)... The effects of plastic deformation and H2 S on fracture toughness of high strength casing steel(C110 steel) were investigated. The studied casing specimens are as follows: original casing, plastic deformation(PD) casing and PD casing after being immersed in NACE A solution saturated with H2S(PD+H2S). Instrumented impact method was employed to evaluate the impact behaviors of the specimens, meanwhile, dynamic fracture toughness(JId) was calculated by using Rice model and Schindler model. The experimental results show that dynamic fracture toughness of the casing decreases after plastic deformation. Compared with that of the original casing and PD casing, the dynamic fracture toughness decreases further when the PD casing immersed in H2 S, moreover, there are ridge-shaped feature and many secondary cracks present on the fracture surface of the specimens. Impact fracture mechanism of the casing is proposed as follows: the plastic deformation results in the increase of defect density of materials where the atomic hydrogen can accumulate in reversible or irreversible traps and even recombine to form molecular hydrogen, subsequently, the casing material toughness decreases greatly. 展开更多
关键词 sour gas fields high strength casing C110 steel plastic deformation H2S fracture toughness
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Low temperature impact toughness of laser hybrid welded joint of high strength low alloy steel
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作者 倪加明 李铸国 +2 位作者 黄坚 倪慧峰 吴毅雄 《China Welding》 EI CAS 2011年第3期1-5,共5页
High strength low alloy steel with 16 mm thickness was welded by using high power laser hybrid welding. Microstrueture was characterized by using optical microscopy, scanning electron microscopy ( SEM ) , transmissi... High strength low alloy steel with 16 mm thickness was welded by using high power laser hybrid welding. Microstrueture was characterized by using optical microscopy, scanning electron microscopy ( SEM ) , transmission electron microscopy (TEM) and selected area electron diffraction (SAED). Low temperature impact toughness was estimated by using Charpy V-notch impact samples selected from the upper part and the lower part at the same heterogeneous joint. Results show that the low temperature impact absorbed energies of weld metal are (202,180,165 J) of upper samples and (178,145,160 J) of lower samples, respectively. All of them increase compared to base metal. The embrittlement of HAZ does not occur. Weld metal primarily consists of refined carbide free bainite and a little granular bainite since laser hybrid welding owns the character of low heat input. Retained austenite constituent film "locates among the lath structure of bainitie ferrite. Refined bainitic ferrite lath and retained austenite constituent film provide better low temperature impact toughness compared to base metal. 展开更多
关键词 laser hybrid welding high strength low alloy steel low temperature impact toughness carbide free bainite retained austenite constituent film
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Thermal Activation Analyses of Dynamic FractureToughness of High Strength Low Alloy Steels
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作者 Cunjian LI and Shaohua LI Welding Research Department, Central Iron & Steel Research Institute, Beijing 100081, China Yuqing DENG State Administration of Metallurgical Industry, Beijing 100711, China 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2001年第2期215-218,共4页
A formula is derived for determining the influence of temperature and loading rate on dynamic fracture toughness of a high strength low alloy steel (HQ785C) from thermal activation analysis of the experimental results... A formula is derived for determining the influence of temperature and loading rate on dynamic fracture toughness of a high strength low alloy steel (HQ785C) from thermal activation analysis of the experimental results of three-point bend specimens as well as introducing an Arrhenius formula. It is shown that the results obtained by the given formula are in good agreement with the experimental ones in the thermal activation region. The present method is also valuable to describe the relationship between dynamic fracture toughness and temperature and loading rate of other high strength low alloy steels. 展开更多
关键词 TEST GB Thermal Activation Analyses of Dynamic Fracturetoughness of high strength Low Alloy Steels
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A New Method for Determining J_(IC) of High StrengthHigh Fracture Toughness Steels by SingleThree Point Bend Specimen
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作者 Ping GENG M.K.Tseng and Cunfu QIAN (College of Science, Northeastern University, Shenyang 110006, China) 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 1998年第4期377-379,共3页
A single three point bend specimen compliance method for determining JIC of high strength high fracture toughness steels is presented and a formula for calculatinff J-integral is proposed as follows.It is simple and v... A single three point bend specimen compliance method for determining JIC of high strength high fracture toughness steels is presented and a formula for calculatinff J-integral is proposed as follows.It is simple and valid for high strength high fracture toughness steels. The values of JIC and KIC measured by this method are in good agreement with those measured by standard test method. 展开更多
关键词 of high strengthhigh Fracture toughness Steels by SingleThree Point Bend Specimen A New Method for Determining J IC
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Designing new low alloyed Mg-RE alloys with high strength and ductility via high-speed extrusion 被引量:6
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作者 Jinshu Xie Zhi Zhang +6 位作者 Shujuan Liu Jinghuai Zhang Jun Wang Yuying He Liwei Lu Yunlei Jiao Ruizhi Wu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第1期82-91,共10页
Two new low-alloyed Mg-2RE-0.8Mn-0.6Ca-0.5Zn(wt%,RE=Sm or Y)alloys are developed,which can be produced on an in-dustrial scale via relatively high-speed extrusion.These two alloys are not only comparable to commercial... Two new low-alloyed Mg-2RE-0.8Mn-0.6Ca-0.5Zn(wt%,RE=Sm or Y)alloys are developed,which can be produced on an in-dustrial scale via relatively high-speed extrusion.These two alloys are not only comparable to commercial AZ31 alloy in extrudability,but also have superior mechanical properties,especially in terms of yield strength(YS).The excellent extrudability is related to less coarse second-phase particles and high initial melting point of the two as-cast alloys.The high strength-ductility mainly comes from the formation of fine grains,nano-spaced submicron/nano precipitates,and weak texture.Moreover,it is worth noting that the YS of the two alloys can maintain above 160 MPa at elevated temperature of 250°C,significantly higher than that of AZ31 alloy(YS:45 MPa).The Zn/Ca solute segregation at grain boundaries,the improved heat resistance of matrix due to addition of RE,and the high melting points of strengthening particles(Mn,MgZn_(2),and Mg-Zn-RE/Mg-Zn-RE-Ca)are mainly responsible for the excellent high-temperature strength. 展开更多
关键词 magnesium alloys high-speed extrusion high strength high ductility solute segregation
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Towards designing high mechanical performance low-alloyed wrought magnesium alloys via grain boundary segregation strategy:A review
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作者 Zhi Zhang Jinshu Xie +2 位作者 Jinghuai Zhang Xu-Sheng Yang Ruizhi Wu 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第5期1774-1791,共18页
Low-alloyed magnesium(Mg)alloys have emerged as one of the most promising candidates for lightweight materials.However,their further application potential has been hampered by limitations such as low strength,poor pla... Low-alloyed magnesium(Mg)alloys have emerged as one of the most promising candidates for lightweight materials.However,their further application potential has been hampered by limitations such as low strength,poor plasticity at room temperature,and unsatisfactory formability.To address these challenges,grain refinement and grain structure control have been identified as crucial factors to achieving high performance in low-alloyed Mg alloys.An effective way for regulating grain structure is through grain boundary(GB)segregation.This review presents a comprehensive summary of the distribution criteria of segregated atoms and the effects of solute segregation on grain size and growth in Mg alloys.The analysis encompasses both single element segregation and multi-element co-segregation behavior,considering coherent interfaces and incoherent interfaces.Furthermore,we introduce the high mechanical performance low-alloyed wrought Mg alloys that utilize GB segregation and analyze the potential impact mechanisms through which GB segregation influences materials properties.Drawing upon these studies,we propose strategies for the design of high mechanical performance Mg alloys with desirable properties,including high strength,excellent ductility,and good formability,achieved through the implementation of GB segregation.The findings of this review contribute to advancing the understanding of grain boundary engineering in Mg alloys and provide valuable insights for future alloy design and optimization. 展开更多
关键词 Magnesium alloys Grain boundary segregation high strength high plasticity high formability
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Various admixtures to mitigate the long-term strength retrogression of Portland cement cured under high pressure and high temperature conditions 被引量:2
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作者 Jiankun Qin Xueyu Pang +2 位作者 Ashok Santra Guodong Cheng Hailong Li 《Journal of Rock Mechanics and Geotechnical Engineering》 SCIE CSCD 2023年第1期191-203,共13页
In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sour... In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sources,particle sizes of silica flour,and additions of silica fume,alumina,colloidal iron oxide and nano-graphene,were investigated.To simulate the environment of cementing geothermal wells and deep wells,cement slurries were directly cured at 50 MPa and 200?C.Mineral compositions(as determined by X-ray diffraction Rietveld refinement),water permeability,compressive strength and Young’s modulus were used to evaluate the qualities of the set cement.Short-term curing(2e30 d)test results indicated that the adoption of 6 m m ultrafine crystalline silica played the most important role in stabilizing the mechanical properties of oil well cement systems,while the addition of silica fume had a detrimental effect on strength stability.Long-term curing(2e180 d)test results indicated that nano-graphene could stabilize the Young’s modulus of oil well cement systems.However,none of the ad-mixtures studied here can completely prevent the strength retrogression phenomenon due to their inability to stop the conversion of amorphous to crystalline phases. 展开更多
关键词 high pressure and high temperature(HPHT) strength retrogression Young’s modulus Water permeability Rietveld method
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