Various admixtures to mitigate the long-term strength retrogression of Portland cement cured under high pressure and high temperature conditions

In order to investigate the problem of long-term strength retrogression in oil well cement systems exposed to high pressure and high temperature(HPHT)curing conditions,various influencing factors,including cement sources,particle sizes of silica flour,and additions of silica fume,alumina,colloidal iron oxide and nano-graphene,were investigated.To simulate the environment of cementing geothermal wells and deep wells,cement slurries were directly cured at 50 MPa and 200?C.Mineral compositions(as determined by X-ray diffraction Rietveld refinement),water permeability,compressive strength and Young’s modulus were used to evaluate the qualities of the set cement.Short-term curing(2e30 d)test results indicated that the adoption of 6 m m ultrafine crystalline silica played the most important role in stabilizing the mechanical properties of oil well cement systems,while the addition of silica fume had a detrimental effect on strength stability.Long-term curing(2e180 d)test results indicated that nano-graphene could stabilize the Young’s modulus of oil well cement systems.However,none of the ad-mixtures studied here can completely prevent the strength retrogression phenomenon due to their inability to stop the conversion of amorphous to crystalline phases.

Relation between Modulus of Elasticity and Compressive Strength of Ultrahigh-Strength Mortar with Mixed Silicon Carbide as Fine Aggregate

Ultrahigh-strength mortar mixed surface-oxidized silicon carbide as a fine aggregate was prepared by means of press-casting followed by curing in an autoclave. The relation between modulus of elssticity up to 111 GPa and compressive strength up to 360 MPa of mortar mixed silicon carbide was discussed and it was revealed that the contributions of the aggregate hardness and of the interfacial strength between the aggregate and the cement paste on the elasticity of mortar were imporant.

Freezing and Thawing Durability of Ultra High Strength Concrete

Resistance to freezing and thawing of two UHSC （ultra high strength concrete） mixtures was evaluated in accordance with ASTM C 666 Procedure A. The two mixtures （plain and fiber reinforced） were developed using materials local to southern New Mexico, USA. Three different curing regimens were investigated for the mixture with fibers and one curing regimen was studied for the mixture without fibers. All curing regimens included 24 h of ambient curing followed by four days of wet curing at 50 ℃, and then two days dry curing at 200 ℃. At an age of seven days, one batch of fiber reinforced specimens was air cured at ambient conditions for the following six days and then placed in a water bath at 4.4 ℃ for 24 h prior to initiating freezing and thawing cycles. The second batch was air cured from day seven to day 12, and then wet cured for one day at 23 ℃ prior to being placed in the 4.4 ℃ water bath. The final batch was wet cured at 23 ℃ from the seventh day to an age of 13 days and then placed in the 4.4 ℃ water bath. The mixture with no fibers was air cured from the seventh day to an age of 12 days and then wet cured for one day at 23 ℃ prior to being placed in the 4.4 ℃ water bath. Higher moisture levels during curing produced greater initial dynamic elastic modulus values and durability factors at the end of the freezing and thawing tests, with the greatest durability factor being 87.5. Steel fibers were observed to improve both compressive strength and durability factor for UHSC.

Study on High Strength Concrete Confined by Continuous Carbon Fiber Sheet

Eight high strength concrete (HSC) prisms strengthened with continuous carbon fiber sheet(CFS)were tested.As a result of the confinement provided by CFS,the concrete would fail at a greater strain than the unconfined and then a significant increase in ductility can be achieved.The lateral pressure exerted by CFS would increase the compressive strength of the concrete,resulting in higher load bearing capacity.This paper proposes the stress strain curve of this kind of hybrid specimen,which agrees well with the test results.Based on the stress strain relationship and the assumptions proposed in this paper,a computer program was developed to analyze HSC columns,confined by CFS,which were subjected to axial compression and biaxial bending.The results shown in this paper indicate that the ductility of HSC column is significantly improved and the strength is also increased by some degree.

Experimental investigation of axially loaded steel fiber reinforced high strength concrete-filled steel tube columns

An experimental study on the compressive behavior of steel fiber reinforced concrete-filled steel tube columns is presented. Specimens were tested to investigate the effects of the concrete strength, the thickness of steel tube and the steel fiber volume fraction on the ultimate strength and the ductility. The experimental results indicate that the addition of steel fibers in concrete can significantly improve the ductility and the energy dissipation capacity of the concrete-filled steel tube columns and delay the local buckling of the steel tube, but has no obvious effect on the failure mode. It has also been found that the addition of steel fibers is a more effective method than using thicker steel tube in enhancing the ductility, and more advantageous in the case of higher strength concrete. An analytical model to estimate the load capacity is proposed for steel tube columns filled with both plain concrete and steel fiber reinforced concrete. The predicted results are in good agreement with the experimental ones obtained in this work and literatures.

Stability of fiber laser-MIG hybrid welding of high strength aluminum alloy

The effect of fiber laser on MIG arc was investigated with 8 mm 7075-T6 high strength aluminum alloy as base material.The arc shape,droplet transfer form and electrical signal in the process of MIG welding and laser-MIG hybrid welding were analyzed.The stability of the hybrid welding process was evaluated by standard deviation analysis.The results show that with the increase of laser power,a large number of laser-induced plasma enters the arc column area,providing more conductive channels,which makes the heat of MIG arc more concentrated and the short circuit transition disappear.Due to the continuous effect of laser,the keyhole becomes a continuous electron emission source,and a stable cathode spot will be formed near the keyhole,which enhances the stability of MIG arc at the base current state.By using the method of standard deviation analysis,the voltage standard deviation of single MIG welding arc and laser-MIG hybrid arc within 4 seconds was calculated.The standard deviation of single MIG arc voltage was 1.05,and the standard deviation of MIG arc voltage in laser-MIG hybrid welding was 0.71–0.86,so the hybrid welding process was more stable.

Detection of Thermophysical Properties for High Strength Concrete after Exposure to High Temperature

Using the detection principle of infrared thermal imaging technique and the detection principle of DRH thermal conductivity tester laboratory,we investigated the infrared thermal image inspection,coefficient of thermal conductivity,apparent density,and compressive strength test on C80 high-strength concrete（HSC） in the presence and absence of polypropylene fibers under completely heated conditions.Only slight damages were detected below 400 ℃,whereas more and more severe deterioration events were expected when the temperature was above 500 ℃.The results show that the elevated temperature through infrared images generally exhibits an upward trend with increasing temperature,while the coefficient of thermal conductivity and apparent density decrease gradually.Additionally,the addition of polypropylene fibers with appropriate length,diameter,and quantity contributes to the improvement of the high-temperature resistance of HSC.

Mechanism of improving ductility of high strength concrete T-section beam confined by CFRP sheet subjected to flexural loading

For the purpose of inventing a new seismic retrofitting method for the reinforced high strength concrete （HSC） T-section beam using carbon fiber reinforced polymer （CFRP） sheet, three series, a total of twelve T-section beams with nine specimens confined by CFRP sheet in the plastic zone and three control beams were conducted up to failure under four-point bending test. The effectiveness of confining CFRP sheet on improving the flexural ductility of tmstrengthened T-section beams was studied. The parameters such as the width and the thickness of CFRP sheet and the type of T-section were analyzed. The experimental results show that ductility and rotation capacity of plastic hinge can be improved by the confinement of CFRP sheet, and the ductility indices increase with the increment of width and thickness of CFRP sheet. A plastic rotation model considering the width of CFRP sheet and the effect of flange of T-section beam is proposed on the basis of the model of BAKER, and the test results show a good agreement with the perdicted results. The relevant construction suggestions for seismic retrofitting design of beam-slabs system in cast-in-place framework structure are presented.

Charactersitics of Stress-strain Curve of High Strength Steel Fiber Reinforced Concrete under Uniaxial Tension

A whole of 110 specimens divided into 22 groups were tested with varying the volume fraction of steel fibers and the matrix strength of these specimens. The stress-strain behaviors of four types of steel fiber reinforced concrete （SFRC） under uniaxial tension were studied experimentally. When the matrix strength and the fiber content increase, the tensile stress and tensile strain vary differently according to the fiber type. The mechanisms of reinforcing effect for different types of fiber were analyzed and the stress-strain curves of the specimens were plotted. Some experimental factors for stress or strain of SFRC were given. A tensile toughness modulus Re0.5 was introduced to evaluate the toughness characters of SFRC under uniaxial tension. Moreover, the formula of the tensile stress-strain curve of SFRC was regressed. The theoretical curve and the experimental ones fit well, which can be used for references in construction.

Structural Behavior of Continuous Prestressed Steel Fiber Reinforced High Strength Concrete Beam

The flexural behaviors of continuous fully and partially prestressed steel fiber reinforced high strength concrete beams are studied by experiment and nonlinear finite element analysis. Three levels of partial prestress ratio （PPR） are considered, and three pairs of two-span continuous beams with box sections varying in size are designed. The major parameters involved in the study include the PPR and the fiber location. It is concluded that the prestressed high strength concrete beam exhibits satisfactory ductility; the influences of steel fiber on the crack behaviors for partially prestressed beams are not as obvious as those for fully prestressed ones; steel fibers can improve the structural stiffness after cracking for fully prestressed high strength concrete beams; the moment redistribution from mid-span to intermediate support in the first stage should be mainly considered in practical design.

Influence of shrinkage-reducing admixture on drying shrinkage and mechanical properties of high-performance concrete

High-performance concrete （HPC） has specific performance advantages over conventional concrete in strength and durability. HPC mixtures are usually produced with water/binder mass ratios （mW/mB） in the range of 0.2-0.4, so volume changes of concrete as a result of drying, chemical reactions, and temperature change cannot be avoided. For these reasons, shrinkage and cracking are frequent phenomena. It is necessary to add some types of admixture for reduction of shrinkage and cracking of HPC. This study used a shrinkage-reducing admixture （SRA） for that purpose. Concrete was prepared with two different mW/mB （0.22 and 0.40） and four different mass fractions of SRA to binder （w（SRA） = 0%, 1%, 2%, and 4%）. The mineral admixtures used for concrete mixes were： 25% fly ash （FA） and 25% slag by mass of binder for the mixture with mW/mB = 0.40, and 15% silica fume （SF） and 25% FA for the mixture with mW/mB = 0.22. Tests were conducted on 24 prismatic specimens, and shrinkage strains were measured through 120 days of drying. Compressive strength, splitting strength, and static modulus of elasticity were also determined. The results show that the SRA effectively reduces some mechanical properties of HPC. The reductions in compressive strength, splitting tensile strength, and elastic modulus of the concrete were 7%-24%, 9%-19%, and 5%-12%, respectively, after 90 days, compared to concrete mixtures without SRA. SRA can also help reduce drying shrinkage of concrete. The shrinkage strains of HPC with SRA were only as high as 41% of the average free shrinkage of concrete without SRA after 120 days of drying.

Design of Eco-friendly Ultra-high Performance Concrete with Supplementary Cementitious Materials and Coarse Aggregate

Aiming to investigate the mix design of eco-friendly UHPC with supplementary cementitious materials and coarser aggregates, we comprehensively studied the workability, microstructure, porosity, compressive strength, flexural strength, and Young’s modulus of UHPC. Relationship between compressive strength and Young’s modulus was obtained eventually. It is found that the compressive strength, flexural strength, and Young’s modulus of UHPC increase by 19.01%, 10.81%, and 5.99%, respectively, when 40 wt% cement is replaced with supplementary cementitious materials. The relationship between compressive strength and Young’s modulus of UHPC is an exponential form.

Bending Modulus Measurement of Single High Performance Fiber

The bending modulus property of high performance fiber is an important property for both polymer science and engineering. The measurement of the bending performance is, however, difficult because of the thin size of the fiber. We have measured this property by the axial compression bending method where single fiber with suitable slenderness is compressed in the fiber axial direction to obtain the peak point of the force-displacement curve. Then the bending modulus and the flexural rigidity can be calculated by measuring the protruding length and diameter of fiber needles and the critical force, Pcr. The measured data show that the bending characteristics of all kinds of high performance fiber are dissimilar evidently.

Spalling and Mechanical Properties of Fiber Reinforced High-performance Concrete Subjected to Fire

Spalling and mechanical properties of FRHPC subjected to fire were tested on notched beams. The results confirm that the internal vapor pressure is the leading reason for spalling of high-performance concrete （HPC）. At the same time, the temperature-increasing velocity and constrained conditions of concrete element also play significant roles in spalling. Steel fibers cannot reduce the risk of spalling, although they have obvious beneficial effects on the mechanical properties of concrete before and after exposure to fire. Polypropylene （PP） fibers are very useful in preventing HPC from spalling, however, they have negative effects on the strengths. By using hybrid fibers （steel fibers＋PP fibers）, both good anti-spalling performance and improved mechanical properties come true, which may provide necessary safe guarantee for the rescue work and structure repair after fire disaster.

CT Image-based Analysis on the Defect of Polypropylene Fiber Reinforced High-Strength Concrete at High Temperatures

With the application of X-ray computed tomography（CT） technology of C80 high-strength concrete with polypropylene fiber at elevated temperatures, the microscopic damage evolution process observation and image building could be obtained, based on the statistics theory and numerical analysis of the combination of concrete internal defects extension and evolution regularity of microscopic structure. The expermental results show that the defect rate has changed at different temperatures and can determine the concrete degradation threshold temperatures. Also, data analysis can help to establish the evolution equation between the defect rate and the effect of temperature damage, and identify that the addition of polypropylene fibers in the high strength concrete at high temperature can improve cracking resistance.

Properties of High Strength Steel Fiber Reinforced Concrete under Compression

This paper mainly discusses the properties of high strength steel fiber reinforced concrete under compression. Steel fibers with volume content of 1% do not display significant effect on the strain at peak stress and the area of the ascending portion of

Flexural Behaviour of High－Strength Steel Fiber－Reinforced Concrete Beams

This paper presents the research results of twelve high strength concrete beams reinforced with steel fibers and bars. Fiber type I and II reduce the deflection by more than 25% and increase the ultimate load by about 10% compared to high strength concr

Optimization of Multigrain Premix for High Protein and Dietary Fibre Biscuits Using Response Surface Methodology (RSM)

In order to improve the nutritional quality of biscuits, a multigrain premix (MGP) was developed by using whole barley, sorghum, chickpea, pea and defatted soya flour, each at 20% level. The developed MGP had 26.28% protein, 10.13% insoluble dietary fiber and 7.38% soluble dietary fiber. The experiment was designed to optimise the MGP and wheat flour concentration for the development of multigrain biscuits with high protein, dietary fibre and to maximize the acceptability by the application of central composite rotatable design (CCRD) of Response Surface Methodology (RSM). The levels of incorporation of MGP and wheat flour were taken as variables whereas protein, soluble, insoluble fibers, biscuit dough hardness, breaking strength and overall acceptability (OAA) as responses. The optimum level of MGP and wheat flour obtained using numerical optimization was found to be 40 g and 60 g respectively. The biscuits prepared using these had 16.61% protein, 2.57% soluble fibre, and 6.67% insoluble fibre which is significantly (p ≤ 0.05) higher than control biscuit.

Effects of fibers on mechanical properties of high-performance concrete subjected to elevated temperatures

The compressive strength and ilexural toughness as well as fracture energy of fiber reinforced highperformance concrete （FRHPC） subjected to different high temperatures were studied. The results showed that after exposure at 300,600 and 900℃, the concrete mixes retained 88.1% , 41.3% and 10.2% of the original compressive strength on average, respectively. Steel fiber and polypropylene （PP） fiber were both effective in minimizing the damage effect of high temperatures on the compressive strength. The HPC reinforced with steel fibers showed higher flexural toughness and fracture energy before and after the high-temperature exposures. In comparison, PP fibers had minor beneficial effects on the flexural toughness and fracture energy. The mechanical properties of HPC reinforced with hybrid fibers （steel fiber ＋ PP fiber） were equivalent to or better than those of HPC reinforced with steel fibers alone. In addition, the failure pattern of FRHPC beams changed from pull-out of steel fibers at lower temperatures （20, 300 and 600℃） to tensile failure of steel fibers at higher temperature （900 ℃）.

Analysis on the Bonding Failure Mechanism of High Modulus Carbon Fiber Composites

In order to explore the bonding failure mechanism of high modulus carbon fiber composite materials,the tensile experiment and finite element numerical simulation for single-lap and bevel-lap joints of unidirectional laminates are carried out,and the stress distributions,the failure modes,and the damage contours are analyzed. The analysis shows that the main reason for the failure of the single-lap joint is that the stress concentration of the ply adjacent to the adhesive layer is serious owing to the modulus difference,and the stress cannot be effectively transmitted along the thickness direction of the laminate. When the tensile stress of the ply exceeds its ultimate strength in the loading process,the surface fiber will fail. Compared with the single-lap joint,the bevel-lap joint optimizes the stress transfer path along the thickness direction,allows each layer of the laminate to share the load,avoids the stress concentration of the surface layer,and improves the bearing capacity of the bevel-lap joint. The improved bearing capacity of the bevellap joint is twice as much as that of the single-lap joint. The research in this paper provides a new idea for the subsequent study of mechanical properties of adhesively bonded composite materials.