The delayed fracture behavior of medium carbon high strength spring steel containing different amounts of boron (0. 000 5%, 0. 001 6 %) was studied using sustained load delayed fracture test. The results show that d...The delayed fracture behavior of medium carbon high strength spring steel containing different amounts of boron (0. 000 5%, 0. 001 6 %) was studied using sustained load delayed fracture test. The results show that delayed fracture resistance of boron containing steels is higher than that of conventional steel 60Si2MnA at the same strength level and it increases with the increase of boron eontent from 0. 000 5% to 0. 001 6%. The delayed fracture mode is mainly intergranular in the boron containing steels tempered at 350℃, which indicates that the addition of boron does not change the fracture character. However, the increase of boron content enlarges the size of the crack initia tion area. Further study of phase analysis indicates that most boron is in solid solution, and only a very small quantity of boron is in the M3 (C, B) phase.展开更多
A high-building multi-directional pipe joint(HBMDPJ)was fabricated by wire and arc additive manufacturing using high-strength low-alloy(HSLA)steel.The microstructure characteristics and transformation were observed an...A high-building multi-directional pipe joint(HBMDPJ)was fabricated by wire and arc additive manufacturing using high-strength low-alloy(HSLA)steel.The microstructure characteristics and transformation were observed and analyzed.The results show that the forming part includes four regions.The solidification zone solidifies as typical columnar crystals from a molten pool.The complete austenitizing zone forms from the solidification zone heated to a temperature greater than 1100℃,and the typical columnar crystals in this zone are difficult to observe.The partial austenitizing zone forms from the completely austenite zone heated between Ac1(austenite transition temperature)and1100℃,which is mainly equiaxed grains.After several thermal cycles,the partial austenitizing zone transforms to the tempering zone,which consistes of fully equiaxed grains.From the solidification zone to the tempering zone,the average grain size decreases from 75 to20μm.The mechanical properties of HBMDPJ satisfies the requirement for the intended application.展开更多
The micro structure and mechanical properties of new kind of hot-rolled high strength and high elongation steels with retained austenite were studied by discussing the influence of different carbon content. The resear...The micro structure and mechanical properties of new kind of hot-rolled high strength and high elongation steels with retained austenite were studied by discussing the influence of different carbon content. The research results indicate that carbon content has a significant effect on retaining austenite and consequently resulting in high elongation. Besides, new findings about relationship between carbon content and retained austenite as well as properties were discussed in the paper.展开更多
The effect of fast cooling rate on the microstructure and mechanical properties of low-carbon high-strength steel annealed in the intercritical region was investigated using a Gleeble 1500 thermomechanical simulator a...The effect of fast cooling rate on the microstructure and mechanical properties of low-carbon high-strength steel annealed in the intercritical region was investigated using a Gleeble 1500 thermomechanical simulator and a continuous annealing thermomeehanical simulator. The results showed that the microstructure consisted of ferrite and bainite as the main phases with a small amount of retained austenite and martensite islands at cooling rate of 5 and 50 ℃/s, respectively. Fast cooling after continuous annealing affected all constituents of the microstructure. The mechanical properties were improved considerably. Ultimate tensile strength (U-TS) increased and total elongation (TEL) decreased with increasing cooling rate in all specimens. The specimen 1 at a cooling rate of 5 ℃/s exhibited the maximum TEL and UTSxTEL (20% and 27 200 MPa%, respectively) because of the competition between weakening by presence of the retained austenite plus the carbon indigence by carbide precipitation, and strengthening by martensitic islands and precipitation. The maximum UTS and YS (1 450 and 951 MPa, respectively) were obtained for specimen 2 at a cooling rate of 50 ℃/s. This is attributed to the effect of dispersion strengthening of finer martensite islands and the effect of precipitation strengthening of carbide precipitates.展开更多
The existing problems in the manufacture of SWRH82B high carbon steel wire were discussed by sampling and testing the microstructure and properties of the steel from the workshop. To solve the problems, the experiment...The existing problems in the manufacture of SWRH82B high carbon steel wire were discussed by sampling and testing the microstructure and properties of the steel from the workshop. To solve the problems, the experimental parameters for thermal simulation were optimized, and the thermal simulating experiments were carded out on a Gleeblel500 thermal simulator. The process parameters for the manufacture were optimized after analysis of the data, and the productive experiments were performed after the water box in front of the no-twist blocks was reconstructed, to control the temperature of the loop layer. The results from the productive experiments showed that the cooling rate of 10-15℃/s was reasonable before phase transformation, about 5℃/s during phase transformation, and 600-620℃ was the suitable starting temperature for phase transformation. The ultimate strength of the Ф11.0 mm wire was increased to 1150-1170 MPa with an increase of 20-30 MPa, the percentage reduction of section was to 34%-36% with an increase of 1%-3% by testing the finished products after reconstruction.展开更多
The effect of RE-modifier on the microstructure and mechanical properties of high carbon-medium manganese steel has been investigated in present work.The results showed that the RE-modifier can refine the crystalline ...The effect of RE-modifier on the microstructure and mechanical properties of high carbon-medium manganese steel has been investigated in present work.The results showed that the RE-modifier can refine the crystalline grain of high-carbon medium-manganese steel.The shape and distribution of carbides are improved and the columnar grains and phosphide in grain boundary are eliminated.Consequently,the impact toughness of the steel is increased by more than one time,compared with no addition of RE-modifier.展开更多
Over the past twenty years, significant advances have been made in the field of microalloying and associated applications, among which one of the most successful application cases is HTP practice for heavy gauge, high...Over the past twenty years, significant advances have been made in the field of microalloying and associated applications, among which one of the most successful application cases is HTP practice for heavy gauge, high strength pipeline steels. Combined the strengthening effects of TMCP and retardation effects of austenite recrystallization with increasing Nb in austenite region, HTP conception with low carbon and high niobium alloy design has been successfully applied to develop X80 coil with a thickness of 18.4 mm used for China's Second West-East pipeline. During this process, big efforts were made to further develop and enrich the application of microalloying technology, and at the same time the strengthening effects of Nb have been completely unfolded and fully utilized with improved metallurgical quality and quantitative analysis of microstructure. In this paper, the existing status and strengthening effect of Nb during reheating, rolling and cooling have been analyzed and characterized based on mass production samples and laboratory analysis. As confirmed, grain refinement remains the most basic strengthening measure to reduce the microstructure gradient along the thickness, which in turn enlarges the processing window to improve upon low temperature toughness, and finally make it possible to develop heavy gauge, high strength pipeline steels with more challenging fracture toughness requirements. As stated by a good saying that practice makes perfect. Based on application practice and theoretical analysis, HTP has been extended to develop heavy gauge and high strength pipeline steels with increasing requirements, including X80 SSAW pipe with a thickness of 22.0 mm and above, X80 LSAW pipe combining heavy gauge and large diameter, heavy gauge X80 LSAW pipe with low temperature requirements, as well as X90 steels. In this paper, alloy design, production processing, as well as mechanical properties and microstructure used for these products would be illustrated.展开更多
Samples of medium carbon steel were examined after heating between 900℃ - 980℃ and soaked for 45 minutes in a muffle furnace before quenching in palm oil and water separately. The mechanical behavior of the samples ...Samples of medium carbon steel were examined after heating between 900℃ - 980℃ and soaked for 45 minutes in a muffle furnace before quenching in palm oil and water separately. The mechanical behavior of the samples was investigated using universal tensile testing machine for tensile test and Vickers pyramid method for hardness testing. The microstructure of the quenched samples was studied using optical microscope. The tensile strength and hardness values of the quenched samples were relatively higher than those of the ascast samples, suggesting improved mechanical properties. However, samples quenched in palm oil displayed better properties compared with that of water-quenched samples. This behavior was traced to the fact that the carbon particles in palm oil quenched samples were more uniform and evenly distributed, indicating the formation of more pearlite structure, than those quenched in water and the as-received samples.展开更多
We investigated phase transition and precipitation of ultra-high strength steel(UHSS)in a new "short process" with controlled rolling and controlled cooling.Thermalexpansion test combined with metallographic obser...We investigated phase transition and precipitation of ultra-high strength steel(UHSS)in a new "short process" with controlled rolling and controlled cooling.Thermalexpansion test combined with metallographic observation was used to research the continuous cooling transformation(CCT)curve.Moreover,the microstructuraltransformation and precipitation law was revealed by morphologicalobservation and alloying elements by electron probe micro-analyzer(EPMA).Transmission electron microscopy(TEM)was utilized to analyze the composition and grain orientation of microstructure.The study showed that the measured criticaltransformation temperatures of Ac1 and Ac3 were 746 and 868 ℃,respectively.The CCT curve indicated that the undercooled austenite was transformed into proeutectoid ferrite and bainite with HV 520 in a broad range of cooling rate 0.1^(-1) ℃·s^(-1).When subjected to a cooling rate of 1 ℃·s^(-1),the undercooled austenite was divided into small-sized blocks by formed martensite.With further increase of cooling rate,micro-hardness increased dramatically,the microstructure of specimen was mainly lathe bainite(LB),granular bainite(GB),lath martensite(LM)and residualaustenite.By diffraction test analysis,it was identified that there was K-S orientation relationship between martensite and austenite for {110}_α//{111}_γ,{111}_α//{101}_γ.EPMA clearly showed that carbon diffused adequately due to staying for a long time at high temperature with a lower cooling rate of 2 ℃·s-1.Phase transition drive force was lower and the residualaustenite existed in the block form of Martensite austenite island(M-A).With the increase of cooling rate to 10 ℃·s^(-1),the block residualaustenite reduced,the carbon content of residualaustenite increased and α phase around the residualaustenite formed into a low carbon bainite form.展开更多
This work investigated the evolution of multiphase microstructure and impact fracture behavior of medium carbon high silicon high strength steel subjected to the austempering treatment at 240,360,and400℃.The results ...This work investigated the evolution of multiphase microstructure and impact fracture behavior of medium carbon high silicon high strength steel subjected to the austempering treatment at 240,360,and400℃.The results show that martensite,bainite,and retained austenite(RA)are the main microstructural phases.The austempering treatments at 360 and 400℃ caused the formation of carbon-poor ferrite in the matrix,and the transformation of ultrafine bainite into coarse lath bainite and granular bainite,respectively.Thick filmy RA was distributed between bainite laths.The polygonal martensiteaustenite islands and blocky RA formed along the grain boundaries.The average carbon concentration in the matrix decreased with the temperature increase,while the impact toughness initially increased and then dropped with temperature.The quasi-cleavage brittle fracture dominated the impact fracture mechanism of the sample austempered at 240℃ by forming tearing surfaces and tearing steps.The microcracks disappeared in the RA on the prior austenite grain boundaries.On the other side,the fracture surface of the sample austempered at 360℃ exhibited ductile fracture with deep dimples and brittle fracture with cleavage river patterns.The polygonal martensite-austenite islands or blocky RA constrained the microcracks.After austempered at 400℃,the brittle fracture was dominant,showing river patterns,and the microcracks propagated through the granular bainite without any resistance.展开更多
基金Item Sponsored by National Key Fundamental Research and Development Programme of China (2004CB619104)
文摘The delayed fracture behavior of medium carbon high strength spring steel containing different amounts of boron (0. 000 5%, 0. 001 6 %) was studied using sustained load delayed fracture test. The results show that delayed fracture resistance of boron containing steels is higher than that of conventional steel 60Si2MnA at the same strength level and it increases with the increase of boron eontent from 0. 000 5% to 0. 001 6%. The delayed fracture mode is mainly intergranular in the boron containing steels tempered at 350℃, which indicates that the addition of boron does not change the fracture character. However, the increase of boron content enlarges the size of the crack initia tion area. Further study of phase analysis indicates that most boron is in solid solution, and only a very small quantity of boron is in the M3 (C, B) phase.
基金financially supported by the National Key R&D Program of China(No.2017YFB1103200)the Independent Innovation Research Fund Project of Huazhong University of Science and Technology(No.2018KFYXMPT002)。
文摘A high-building multi-directional pipe joint(HBMDPJ)was fabricated by wire and arc additive manufacturing using high-strength low-alloy(HSLA)steel.The microstructure characteristics and transformation were observed and analyzed.The results show that the forming part includes four regions.The solidification zone solidifies as typical columnar crystals from a molten pool.The complete austenitizing zone forms from the solidification zone heated to a temperature greater than 1100℃,and the typical columnar crystals in this zone are difficult to observe.The partial austenitizing zone forms from the completely austenite zone heated between Ac1(austenite transition temperature)and1100℃,which is mainly equiaxed grains.After several thermal cycles,the partial austenitizing zone transforms to the tempering zone,which consistes of fully equiaxed grains.From the solidification zone to the tempering zone,the average grain size decreases from 75 to20μm.The mechanical properties of HBMDPJ satisfies the requirement for the intended application.
文摘The micro structure and mechanical properties of new kind of hot-rolled high strength and high elongation steels with retained austenite were studied by discussing the influence of different carbon content. The research results indicate that carbon content has a significant effect on retaining austenite and consequently resulting in high elongation. Besides, new findings about relationship between carbon content and retained austenite as well as properties were discussed in the paper.
基金Sponsored by National Natural Science Foundation of China(No.51004037)Shenyang City Application Basic Research Project(No.F13-316-1-15)
文摘The effect of fast cooling rate on the microstructure and mechanical properties of low-carbon high-strength steel annealed in the intercritical region was investigated using a Gleeble 1500 thermomechanical simulator and a continuous annealing thermomeehanical simulator. The results showed that the microstructure consisted of ferrite and bainite as the main phases with a small amount of retained austenite and martensite islands at cooling rate of 5 and 50 ℃/s, respectively. Fast cooling after continuous annealing affected all constituents of the microstructure. The mechanical properties were improved considerably. Ultimate tensile strength (U-TS) increased and total elongation (TEL) decreased with increasing cooling rate in all specimens. The specimen 1 at a cooling rate of 5 ℃/s exhibited the maximum TEL and UTSxTEL (20% and 27 200 MPa%, respectively) because of the competition between weakening by presence of the retained austenite plus the carbon indigence by carbide precipitation, and strengthening by martensitic islands and precipitation. The maximum UTS and YS (1 450 and 951 MPa, respectively) were obtained for specimen 2 at a cooling rate of 50 ℃/s. This is attributed to the effect of dispersion strengthening of finer martensite islands and the effect of precipitation strengthening of carbide precipitates.
文摘The existing problems in the manufacture of SWRH82B high carbon steel wire were discussed by sampling and testing the microstructure and properties of the steel from the workshop. To solve the problems, the experimental parameters for thermal simulation were optimized, and the thermal simulating experiments were carded out on a Gleeblel500 thermal simulator. The process parameters for the manufacture were optimized after analysis of the data, and the productive experiments were performed after the water box in front of the no-twist blocks was reconstructed, to control the temperature of the loop layer. The results from the productive experiments showed that the cooling rate of 10-15℃/s was reasonable before phase transformation, about 5℃/s during phase transformation, and 600-620℃ was the suitable starting temperature for phase transformation. The ultimate strength of the Ф11.0 mm wire was increased to 1150-1170 MPa with an increase of 20-30 MPa, the percentage reduction of section was to 34%-36% with an increase of 1%-3% by testing the finished products after reconstruction.
文摘The effect of RE-modifier on the microstructure and mechanical properties of high carbon-medium manganese steel has been investigated in present work.The results showed that the RE-modifier can refine the crystalline grain of high-carbon medium-manganese steel.The shape and distribution of carbides are improved and the columnar grains and phosphide in grain boundary are eliminated.Consequently,the impact toughness of the steel is increased by more than one time,compared with no addition of RE-modifier.
文摘Over the past twenty years, significant advances have been made in the field of microalloying and associated applications, among which one of the most successful application cases is HTP practice for heavy gauge, high strength pipeline steels. Combined the strengthening effects of TMCP and retardation effects of austenite recrystallization with increasing Nb in austenite region, HTP conception with low carbon and high niobium alloy design has been successfully applied to develop X80 coil with a thickness of 18.4 mm used for China's Second West-East pipeline. During this process, big efforts were made to further develop and enrich the application of microalloying technology, and at the same time the strengthening effects of Nb have been completely unfolded and fully utilized with improved metallurgical quality and quantitative analysis of microstructure. In this paper, the existing status and strengthening effect of Nb during reheating, rolling and cooling have been analyzed and characterized based on mass production samples and laboratory analysis. As confirmed, grain refinement remains the most basic strengthening measure to reduce the microstructure gradient along the thickness, which in turn enlarges the processing window to improve upon low temperature toughness, and finally make it possible to develop heavy gauge, high strength pipeline steels with more challenging fracture toughness requirements. As stated by a good saying that practice makes perfect. Based on application practice and theoretical analysis, HTP has been extended to develop heavy gauge and high strength pipeline steels with increasing requirements, including X80 SSAW pipe with a thickness of 22.0 mm and above, X80 LSAW pipe combining heavy gauge and large diameter, heavy gauge X80 LSAW pipe with low temperature requirements, as well as X90 steels. In this paper, alloy design, production processing, as well as mechanical properties and microstructure used for these products would be illustrated.
文摘Samples of medium carbon steel were examined after heating between 900℃ - 980℃ and soaked for 45 minutes in a muffle furnace before quenching in palm oil and water separately. The mechanical behavior of the samples was investigated using universal tensile testing machine for tensile test and Vickers pyramid method for hardness testing. The microstructure of the quenched samples was studied using optical microscope. The tensile strength and hardness values of the quenched samples were relatively higher than those of the ascast samples, suggesting improved mechanical properties. However, samples quenched in palm oil displayed better properties compared with that of water-quenched samples. This behavior was traced to the fact that the carbon particles in palm oil quenched samples were more uniform and evenly distributed, indicating the formation of more pearlite structure, than those quenched in water and the as-received samples.
基金Funded by the Scientifi c and Technological Research Program of Chongqing Municipal Education Commission(No.KJ1501324)the General Project of Chongqing Frontier and Applied Basic Research Project(No.cstc2015jcyj A90005)the Research Foundation of Chongqing University of Science and Technology(Nos.CK2013Z16&CK2014Z20)
文摘We investigated phase transition and precipitation of ultra-high strength steel(UHSS)in a new "short process" with controlled rolling and controlled cooling.Thermalexpansion test combined with metallographic observation was used to research the continuous cooling transformation(CCT)curve.Moreover,the microstructuraltransformation and precipitation law was revealed by morphologicalobservation and alloying elements by electron probe micro-analyzer(EPMA).Transmission electron microscopy(TEM)was utilized to analyze the composition and grain orientation of microstructure.The study showed that the measured criticaltransformation temperatures of Ac1 and Ac3 were 746 and 868 ℃,respectively.The CCT curve indicated that the undercooled austenite was transformed into proeutectoid ferrite and bainite with HV 520 in a broad range of cooling rate 0.1^(-1) ℃·s^(-1).When subjected to a cooling rate of 1 ℃·s^(-1),the undercooled austenite was divided into small-sized blocks by formed martensite.With further increase of cooling rate,micro-hardness increased dramatically,the microstructure of specimen was mainly lathe bainite(LB),granular bainite(GB),lath martensite(LM)and residualaustenite.By diffraction test analysis,it was identified that there was K-S orientation relationship between martensite and austenite for {110}_α//{111}_γ,{111}_α//{101}_γ.EPMA clearly showed that carbon diffused adequately due to staying for a long time at high temperature with a lower cooling rate of 2 ℃·s-1.Phase transition drive force was lower and the residualaustenite existed in the block form of Martensite austenite island(M-A).With the increase of cooling rate to 10 ℃·s^(-1),the block residualaustenite reduced,the carbon content of residualaustenite increased and α phase around the residualaustenite formed into a low carbon bainite form.
基金financially supported by the National Key Research and Development Program of China(No.2016YFB0300105)the Fundamental Research Funds for the Central Universities(No.N180725021)the Fundamental Research Funds for the Central Universities(No.N2024005-4)。
文摘This work investigated the evolution of multiphase microstructure and impact fracture behavior of medium carbon high silicon high strength steel subjected to the austempering treatment at 240,360,and400℃.The results show that martensite,bainite,and retained austenite(RA)are the main microstructural phases.The austempering treatments at 360 and 400℃ caused the formation of carbon-poor ferrite in the matrix,and the transformation of ultrafine bainite into coarse lath bainite and granular bainite,respectively.Thick filmy RA was distributed between bainite laths.The polygonal martensiteaustenite islands and blocky RA formed along the grain boundaries.The average carbon concentration in the matrix decreased with the temperature increase,while the impact toughness initially increased and then dropped with temperature.The quasi-cleavage brittle fracture dominated the impact fracture mechanism of the sample austempered at 240℃ by forming tearing surfaces and tearing steps.The microcracks disappeared in the RA on the prior austenite grain boundaries.On the other side,the fracture surface of the sample austempered at 360℃ exhibited ductile fracture with deep dimples and brittle fracture with cleavage river patterns.The polygonal martensite-austenite islands or blocky RA constrained the microcracks.After austempered at 400℃,the brittle fracture was dominant,showing river patterns,and the microcracks propagated through the granular bainite without any resistance.