The corrosion behaviors of ultra-high strength steel 30CrMnSiNi2A in sodium chloride solution were studied by weight loss and electrochemical methods. The morphology of corrosion products was observed using scanning e...The corrosion behaviors of ultra-high strength steel 30CrMnSiNi2A in sodium chloride solution were studied by weight loss and electrochemical methods. The morphology of corrosion products was observed using scanning electron microscopy(SEM) and the composition was analyzed using an energy dispersive spectroscopy(EDS) and X-Ray diffraction (XRD). The experimental results showed that the corrosion came from pitting corrosion and the rust layer was composed of outer rust layer γ-FeOOH and inner rust layer Fe_2O_3 with a little β-FeOOH. The correlation between corrosion rate and test time accorded with exponential rule. The corrosion current measured by polarization methods was higher than that calculated by weight loss method after a long-time immersion, the main reason was that,β-FeOOH and γ-Fe_2O_3 transformed by γ-FeOOH led to overestimating corrosion rate. The processes of corrosion prophase were obtained from XRD and EIS results. The corrosion product, Fe(OH)_2 formed at the initial stage stayed at a non-steady state and then consequently transferred to γ-FeOOH, γ-Fe_2O_3 or β-FeOOH.展开更多
研究了不同热输入对30Cr Mn Si Ni2A超高强度钢电子束焊接接头组织与性能的影响。研究结果表明:不同热输入可以得到不同的焊缝截面形貌,焊态下焊缝区域组织以粗大的板条马氏体为主,并有少量的残余奥氏体,热输入对焊态下的组织形貌没有...研究了不同热输入对30Cr Mn Si Ni2A超高强度钢电子束焊接接头组织与性能的影响。研究结果表明:不同热输入可以得到不同的焊缝截面形貌,焊态下焊缝区域组织以粗大的板条马氏体为主,并有少量的残余奥氏体,热输入对焊态下的组织形貌没有明显的差异影响。经过900℃油淬和低温回火后,利用扫描电镜观察发现焊缝和热影响区的显微组织主要为回火马氏体和残余奥氏体,且随着热输入的增加导致晶粒尺寸稍微增大,焊缝和热影响区相比,组织细且均匀。同时进行了抗拉强度、冲击韧性和显微硬度检测,数据说明随着焊缝热输入的增加接头的强度、冲击韧性会随之降低且数值趋于稳定,显微硬度值有下降的趋势但不明显。展开更多
基金Funded by the National Natural Science Foundation of China(No.51171011)
文摘The corrosion behaviors of ultra-high strength steel 30CrMnSiNi2A in sodium chloride solution were studied by weight loss and electrochemical methods. The morphology of corrosion products was observed using scanning electron microscopy(SEM) and the composition was analyzed using an energy dispersive spectroscopy(EDS) and X-Ray diffraction (XRD). The experimental results showed that the corrosion came from pitting corrosion and the rust layer was composed of outer rust layer γ-FeOOH and inner rust layer Fe_2O_3 with a little β-FeOOH. The correlation between corrosion rate and test time accorded with exponential rule. The corrosion current measured by polarization methods was higher than that calculated by weight loss method after a long-time immersion, the main reason was that,β-FeOOH and γ-Fe_2O_3 transformed by γ-FeOOH led to overestimating corrosion rate. The processes of corrosion prophase were obtained from XRD and EIS results. The corrosion product, Fe(OH)_2 formed at the initial stage stayed at a non-steady state and then consequently transferred to γ-FeOOH, γ-Fe_2O_3 or β-FeOOH.
文摘研究了不同热输入对30Cr Mn Si Ni2A超高强度钢电子束焊接接头组织与性能的影响。研究结果表明:不同热输入可以得到不同的焊缝截面形貌,焊态下焊缝区域组织以粗大的板条马氏体为主,并有少量的残余奥氏体,热输入对焊态下的组织形貌没有明显的差异影响。经过900℃油淬和低温回火后,利用扫描电镜观察发现焊缝和热影响区的显微组织主要为回火马氏体和残余奥氏体,且随着热输入的增加导致晶粒尺寸稍微增大,焊缝和热影响区相比,组织细且均匀。同时进行了抗拉强度、冲击韧性和显微硬度检测,数据说明随着焊缝热输入的增加接头的强度、冲击韧性会随之降低且数值趋于稳定,显微硬度值有下降的趋势但不明显。