To solve the problems of high rebound rate and strength reversion of shotcrete,a non-fluorine and non-alkaline liquid flash setting admixture(FSN)with low rebound and high early strength was synthesized under 60-65℃w...To solve the problems of high rebound rate and strength reversion of shotcrete,a non-fluorine and non-alkaline liquid flash setting admixture(FSN)with low rebound and high early strength was synthesized under 60-65℃water bath environment through orthogonal test design and taking setting time and compressive strength as indicators.The experimental results show that the optimum mass ratio of FSN is aluminum sulfate:diethanolamine:triethanolamine:pseudo-boehmite:lithium carbonate:water=57%:8%:0.05%:2%:2%:31%.When FSN is added with 7%of the mass of portland cement,the cement paste can be initially set in 3 min and finally set in 5 min.The compressive strength of mortar is 1.2 MPa at 6 h,18.0 MPa at 1 d,and more than 100%at 28 days;The microscopic analysis shows that the rapid release of Li^(+),NH^(4+),and CO_(3)^(2-)ions by FSN in the paste solution effectively shortens the induction period of high C_(3)S content in Portland cement,directly forms early coagulation AFt crystals in FSN and CH dominated by Al_(2)(SO_(4))_(3),and forms a large number of C-S-H gels in the later stage,so that the cement can quickly coagulate and harden,and the strength in the later stage is not retracted.展开更多
采用湿喷工艺研究了高强喷射混凝土,发现设计的C50喷射混凝土强度严重降低,通过X射线衍射(XRD)、扫描电子显微镜(SEM)、水泥浆水化程度(Degree of hydration)试验分析了强度严重降低的原因。结果表明:喷射成型对混凝土的水化产物种类和...采用湿喷工艺研究了高强喷射混凝土,发现设计的C50喷射混凝土强度严重降低,通过X射线衍射(XRD)、扫描电子显微镜(SEM)、水泥浆水化程度(Degree of hydration)试验分析了强度严重降低的原因。结果表明:喷射成型对混凝土的水化产物种类和净浆的水化程度影响甚微,但对混凝土的密实度及水化产物的形貌影响较大。喷射混凝土密实度不够、材料间粘接不牢固导致喷射混凝土的微观结构疏松,是造成喷射混凝土强度严重降低的主要原因。改进验证试验表明,对高强喷射混凝土来说,喷射施工质量控制对于混凝土强度至关重要,材料体系应适应喷射施工设备与工艺。高强湿喷混凝土(C50及以上)宜采取0.8～0.9MPa的风压;喷射时需连续一次垂直喷射,不得出现间断或脉冲;倒筒时间宜控制在10s以内;水胶比选取0.32～0.36,混凝土砂率控制在50%～70%。改进后的喷射高强混凝土28d强度可达63.6MPa。展开更多
基金Funded by the National Key Research and Development Program of China(No.2021YFB2601200)the Natural Science Foundations of Hebei Province(No.E2022210103)。
文摘To solve the problems of high rebound rate and strength reversion of shotcrete,a non-fluorine and non-alkaline liquid flash setting admixture(FSN)with low rebound and high early strength was synthesized under 60-65℃water bath environment through orthogonal test design and taking setting time and compressive strength as indicators.The experimental results show that the optimum mass ratio of FSN is aluminum sulfate:diethanolamine:triethanolamine:pseudo-boehmite:lithium carbonate:water=57%:8%:0.05%:2%:2%:31%.When FSN is added with 7%of the mass of portland cement,the cement paste can be initially set in 3 min and finally set in 5 min.The compressive strength of mortar is 1.2 MPa at 6 h,18.0 MPa at 1 d,and more than 100%at 28 days;The microscopic analysis shows that the rapid release of Li^(+),NH^(4+),and CO_(3)^(2-)ions by FSN in the paste solution effectively shortens the induction period of high C_(3)S content in Portland cement,directly forms early coagulation AFt crystals in FSN and CH dominated by Al_(2)(SO_(4))_(3),and forms a large number of C-S-H gels in the later stage,so that the cement can quickly coagulate and harden,and the strength in the later stage is not retracted.
文摘采用湿喷工艺研究了高强喷射混凝土,发现设计的C50喷射混凝土强度严重降低,通过X射线衍射(XRD)、扫描电子显微镜(SEM)、水泥浆水化程度(Degree of hydration)试验分析了强度严重降低的原因。结果表明:喷射成型对混凝土的水化产物种类和净浆的水化程度影响甚微,但对混凝土的密实度及水化产物的形貌影响较大。喷射混凝土密实度不够、材料间粘接不牢固导致喷射混凝土的微观结构疏松,是造成喷射混凝土强度严重降低的主要原因。改进验证试验表明,对高强喷射混凝土来说,喷射施工质量控制对于混凝土强度至关重要,材料体系应适应喷射施工设备与工艺。高强湿喷混凝土(C50及以上)宜采取0.8～0.9MPa的风压;喷射时需连续一次垂直喷射,不得出现间断或脉冲;倒筒时间宜控制在10s以内;水胶比选取0.32～0.36,混凝土砂率控制在50%～70%。改进后的喷射高强混凝土28d强度可达63.6MPa。
