High P_T experiment with natural massive rock sample of garnet biotite plagioclase gneiss indicates that the metamorphic reaction involving melt (reaction between relic mineral phase and melt) is the most important re...High P_T experiment with natural massive rock sample of garnet biotite plagioclase gneiss indicates that the metamorphic reaction involving melt (reaction between relic mineral phase and melt) is the most important reaction in granulite_facies metamorphism and accompanies anatexis process.展开更多
Using nanoparticles of CeO2 and ZrO2 prepared by the chemical precipitation method as starting materials, the single-phase cubic Ce0.5Zr0.5O2 solid solution (c-Ce0.5Z0.5O2) has been synthesized under 3.1 GPa at 1073 K...Using nanoparticles of CeO2 and ZrO2 prepared by the chemical precipitation method as starting materials, the single-phase cubic Ce0.5Zr0.5O2 solid solution (c-Ce0.5Z0.5O2) has been synthesized under 3.1 GPa at 1073 K for the first time. The structure of the c-Ce0.5Zr0.5O2 has not been changed before and after annealing at 773 K for 1 h. Only an unknown EPR signal (g =1.990) has been observed in the c-Ce0.5Zr0.5O2 and not varied after annealing at 773 K for 1 h, which exhibited that there exists no Ce3+ in the c-Ce0.5Zr0.5O2 and the Ce4+ has not been reduced into Ce3+ after annealing. The transport mechanism is ionic for the c-Ce0.5Zr0.5O2. The bulk conductivity (a =1.2×10-5 S/cm at 823 K, σ=2.1 ×10-3 S/cm at 1123 K) is the same as that of CeO2, but smaller than that of Y2O3-stabilized ZrO2. A marked curvature at T = 823 K has been observed in the Arrhenius plot of the bulk conductivity. The activation energy below 823 K is lower than that above 823 K, and the reason has been discussed.展开更多
文摘High P_T experiment with natural massive rock sample of garnet biotite plagioclase gneiss indicates that the metamorphic reaction involving melt (reaction between relic mineral phase and melt) is the most important reaction in granulite_facies metamorphism and accompanies anatexis process.
基金This work was supported by the National Natural Science Foundation of China (Grant No. 19874023).
文摘Using nanoparticles of CeO2 and ZrO2 prepared by the chemical precipitation method as starting materials, the single-phase cubic Ce0.5Zr0.5O2 solid solution (c-Ce0.5Z0.5O2) has been synthesized under 3.1 GPa at 1073 K for the first time. The structure of the c-Ce0.5Zr0.5O2 has not been changed before and after annealing at 773 K for 1 h. Only an unknown EPR signal (g =1.990) has been observed in the c-Ce0.5Zr0.5O2 and not varied after annealing at 773 K for 1 h, which exhibited that there exists no Ce3+ in the c-Ce0.5Zr0.5O2 and the Ce4+ has not been reduced into Ce3+ after annealing. The transport mechanism is ionic for the c-Ce0.5Zr0.5O2. The bulk conductivity (a =1.2×10-5 S/cm at 823 K, σ=2.1 ×10-3 S/cm at 1123 K) is the same as that of CeO2, but smaller than that of Y2O3-stabilized ZrO2. A marked curvature at T = 823 K has been observed in the Arrhenius plot of the bulk conductivity. The activation energy below 823 K is lower than that above 823 K, and the reason has been discussed.