Thermal conductivity is one of the most significant criterion of three-dimensional carbon fiber-reinforced SiC matrix composites(3D C/SiC).Represent volume element(RVE)models of microscale,void/matrix and mesoscale pr...Thermal conductivity is one of the most significant criterion of three-dimensional carbon fiber-reinforced SiC matrix composites(3D C/SiC).Represent volume element(RVE)models of microscale,void/matrix and mesoscale proposed in this work are used to simulate the thermal conductivity behaviors of the 3D C/SiC composites.An entirely new process is introduced to weave the preform with three-dimensional orthogonal architecture.The 3D steady-state analysis step is created for assessing the thermal conductivity behaviors of the composites by applying periodic temperature boundary conditions.Three RVE models of cuboid,hexagonal and fiber random distribution are respectively developed to comparatively study the influence of fiber package pattern on the thermal conductivities at the microscale.Besides,the effect of void morphology on the thermal conductivity of the matrix is analyzed by the void/matrix models.The prediction results at the mesoscale correspond closely to the experimental values.The effect of the porosities and fiber volume fractions on the thermal conductivities is also taken into consideration.The multi-scale models mentioned in this paper can be used to predict the thermal conductivity behaviors of other composites with complex structures.展开更多
Composites that can rapidly self-healing their structure and function at room temperature have broad application prospects.However,in view of the complexity of composite structure and composition,its self-heal is faci...Composites that can rapidly self-healing their structure and function at room temperature have broad application prospects.However,in view of the complexity of composite structure and composition,its self-heal is facing challenges.In this article,supramolecular effect is proposed to repair the multistage structure,mechanical and thermal properties of composite materials.A stiff and tough supramolecular frameworks of 2-[[(butylamino)carbonyl]oxy]ethyl ester(PBA)–polydimethylsiloxane(PDMS)were established using a chain extender with double amide bonds in a side chain to extend prepolymers through copolymerization.Then,by introducing the copolymer into a folded graphene film(FGf),a highly thermally conductive composite of PBA–PDMS/FGf with self-healing capacity was fabricated.The ratio of crosslinking and hydrogen bonding was optimized to ensure that PBA–PDMS could completely self-heal at room temperature in 10 min.Additionally,PBA–PDMS/FGf exhibits a high tensile strength of 2.23±0.15 MPa at break and high thermal conductivity of 13±0.2 W m^(−1)K^(−1);of which the self-healing efficiencies were 100%and 98.65%at room temperature for tensile strength and thermal conductivity,respectively.The excellent self-healing performance comes from the efficient supramolecular interaction between polymer molecules,as well as polymer molecule and graphene.This kind of thermal conductive self-healing composite has important application prospects in the heat dissipation field of next generation electronic devices in the future.展开更多
The sintering technology of the AlN ceramics power were discussed. It is discussed that the compound sintering aids is consistent with the enhancement of the the thermal conductivity of AlN ceramics, and sintering tec...The sintering technology of the AlN ceramics power were discussed. It is discussed that the compound sintering aids is consistent with the enhancement of the the thermal conductivity of AlN ceramics, and sintering technics is helped to the improvement of density. It is analyzed how to sinter machinable AlN ceramics with high thermal conductivity. And the microstructure of compound ceramics based on AlN was studied.展开更多
Improving the thermal stability of diamond and other superhard materials has great significance in various applications. Here, we report the synthesis and characterization of bulk diamond–cBN–B4C–Si composites sint...Improving the thermal stability of diamond and other superhard materials has great significance in various applications. Here, we report the synthesis and characterization of bulk diamond–cBN–B4C–Si composites sintered at high pressure and high temperature（HPHT, 5.2 GPa, 1620–1680 K for 3–5 min）. The results show that the diamond, cBN, B4C,BxSiC, SiO2 and amorphous carbon or a little surplus Si are present in the sintered samples. The onset oxidation temperature of 1673 K in the as-synthesized sample is much higher than that of diamond, cBN, and B4C. The high thermal stability is ascribed to the covalent bonds of B–C, C–N, and the solid-solution of BxSiC formed during the sintering process. The results obtained in this work may be useful in preparing superhard materials with high thermal stability.展开更多
C/C composites are the emerging materials of choice for aero-engine hot-end components that will bear impact loading in thermal-oxidizing environments. For the components run for extended periods, the safe operation o...C/C composites are the emerging materials of choice for aero-engine hot-end components that will bear impact loading in thermal-oxidizing environments. For the components run for extended periods, the safe operation of components depends on how to evaluate damages under a dynamic load. In this study, Charpy impact tests at a temperature range of 25 to l 200 ＂C were carried out on C/C composites to verify the effects of temperature induced thermal expansion and oxidation on their impact performance. Below 800 ℃, oxidation was negligible and composites expanding played a leading role, resulting in the remarkable increase in fiber/ matrix interface strength and impact energy. However, when the temperature was above 800 ℃, the release of CO or CO2 due to oxidation resulted in a lower impact energy.展开更多
The coefficient of thermal expansion, thermal diffusivity and specific heat of C/C composites from room temperature to ultra high temperature were experimentally investigated. Thermal conductivity and thermal stress r...The coefficient of thermal expansion, thermal diffusivity and specific heat of C/C composites from room temperature to ultra high temperature were experimentally investigated. Thermal conductivity and thermal stress resistance of the composites were therefore computed based on experimental results. The results show that the composite has a very low thermal expansion coefficient. Thermal diffusivity decreases exponentially with temperature increase. The specific heat increases linearly as the temperature rises, and the variation trend of thermal conductivity is similar to that of thermal diffusivity. The thermal stress coefficient of C/C composite has little change with temperature variation, and thermal stress resistance of the composite at high temperature is stable.展开更多
To make better use of 2.5D C/SiC composites in industry, it is necessary to understand the mechanical properties. A finite element model＇of 2.5D composites is established, by considering the fiber undulation and the ...To make better use of 2.5D C/SiC composites in industry, it is necessary to understand the mechanical properties. A finite element model＇of 2.5D composites is established, by considering the fiber undulation and the porosity in 2.5D C/SiC composites. The fiber direction of warp is defined by cosine function to simulate the undulation of warp, and based on uniform strain assumption, analytical model of the elastic modulus and coefficient of thermal expansion （CTE） for 2.5D C/SiC composites were established by using dual- scale model. The result is found to correlate reasonably well with the predicted results and experimental results. The parametric study also demonstrates the effects of the fiber volume fraction, distance of warp yarn, and porosity in micro-scale on the mechanical properties and the coefficients of thermal expansion.展开更多
The ablation properties of C/C composites with four different needled preforms prepared by isothermal chemical vapor infiltration (ICVI),which are super-thin mat lay-up,0°/90° weftless fabric lay-up,0°/...The ablation properties of C/C composites with four different needled preforms prepared by isothermal chemical vapor infiltration (ICVI),which are super-thin mat lay-up,0°/90° weftless fabric lay-up,0°/45° weftless fabric lay-up and 0°/45° twill fabric lay-up,were quantitatively evaluated by performing the ablation tests with an engine torch.And their ablation discrepancies were analyzed according to the surface characteristic,porosity and thermal diffusivity.The results show that the 0°/45° weftless composite has a flat eroded surface with no obvious macroscopic pits.Its thickness and mass erosion rates are decreased by about 46.8% and 34.8%,25.0% and 27.5%,and 17.5% and 19.4% compared with those of the mat,the 0°/90° weftless and the 0°/45° twill composites,respectively.The ablation properties are mainly controlled by the thermo-chemical effect (oxidation),and a little by the thermo-mechanical effect (mechanical denudation).The needling fiber bundles play an important role in accelerating the ablation process and resulting in the heterogeneous ablation.展开更多
The tensile properties of three different carbonfiberreinforced carbon composites (C/C), mat C/C, 2D laminate and 4D C/C, were investigated under the combined influence of temperature and loading rate. From the experi...The tensile properties of three different carbonfiberreinforced carbon composites (C/C), mat C/C, 2D laminate and 4D C/C, were investigated under the combined influence of temperature and loading rate. From the experiments the following could be concluded: loading rate between 10-1-10 mm/min was valid; the fracture stress of the three kinds of C/C composites increased with increasing temperature in the range from room temperature to 1900, and the initial modulus of 2D laminate C/C composites increased with the increase of temperature up to 2000.展开更多
In this paper were studied the microstructure and properties of the non-barrier coating compo- sites fabricated by a new technology.The bonding between C and A1 in the composites is quite well, and the composites have...In this paper were studied the microstructure and properties of the non-barrier coating compo- sites fabricated by a new technology.The bonding between C and A1 in the composites is quite well, and the composites have excellent properties.The ion probe and X-ray analyses indicate that there is Al_4C_3 phase in the composites and its amount in the composites increases when the composites are exposed.In the case of exposure the strength of the composites is reduced because of increasing amount of Al_4C_3.展开更多
Carbon fiber-reinforced silicon carbonitride ceramic matrix composites （C/SiCN） were prepared by rapid electro-thermal pyrolysis CVD using liquid polymer hexamethyldisilazane （HMDS, （CH3）3SiNHSi（CH3）3） as prec...Carbon fiber-reinforced silicon carbonitride ceramic matrix composites （C/SiCN） were prepared by rapid electro-thermal pyrolysis CVD using liquid polymer hexamethyldisilazane （HMDS, （CH3）3SiNHSi（CH3）3） as precursor. Microstructure morphology and production technique of C/SiCN composites were investigated. Scanning electron microscopy and transmission electron microscopy were respectively employed to characterize microstructures of the as-received C/SiCN composites samples. The high temperature pyrolysis of HMDS results in destruction of molecular chain, fracture of bonds, as well as liquid-gas-solid conversion from polymer to ceramic. Microstructures observation indicates that there is a high degree of coalescence between SiCN matrix and C fiber. The deposition model of liquid precursor electro-thermal pyrolysis CVD is different from that of gas precursor isothermal chemical vapor infiltration. Rapid liquid flow and slow gas diffusion are key factors for the difference of two methods. Preparation of rapid electro-thermal pyrolysis CVD consists of four steps including liquid polymer infiltration, polymer pyrolysis, rapid deposition of pyrolyzed substances and rapid densification, respectively.展开更多
The electronic packaging shell with high silicon carbide aluminum-base composites was prepared by semi-solid thixoforming technique. The flow characteristic of the Si C particulate was analyzed. The microstructures of...The electronic packaging shell with high silicon carbide aluminum-base composites was prepared by semi-solid thixoforming technique. The flow characteristic of the Si C particulate was analyzed. The microstructures of different parts of the shell were observed by scanning electron microscopy and optical microscopy, and the thermophysical and mechanical properties of the shell were tested. The results show that there exists the segregation phenomenon between the Si C particulate and the liquid phase during thixoforming, the liquid phase flows from the shell, and the Si C particles accumulate at the bottom of the shell. The volume fraction of Si C decreases gradually from the bottom to the walls. Accordingly, the thermal conductivities of bottom center and walls are 178 and 164 W·m-1·K-1, the coefficients of thermal expansion(CTE) are 8.2×10-6 and 12.6×10-6 K-1, respectively. The flexural strength decreases slightly from 437 to 347 MPa. The microstructures and properties of the shell show gradient distribution.展开更多
基金Supported by Science Center for Gas Turbine Project of China (Grant No.P2022-B-IV-014-001)Frontier Leading Technology Basic Research Special Project of Jiangsu Province of China (Grant No.BK20212007)the BIT Research and Innovation Promoting Project of China (Grant No.2022YCXZ019)。
文摘Thermal conductivity is one of the most significant criterion of three-dimensional carbon fiber-reinforced SiC matrix composites(3D C/SiC).Represent volume element(RVE)models of microscale,void/matrix and mesoscale proposed in this work are used to simulate the thermal conductivity behaviors of the 3D C/SiC composites.An entirely new process is introduced to weave the preform with three-dimensional orthogonal architecture.The 3D steady-state analysis step is created for assessing the thermal conductivity behaviors of the composites by applying periodic temperature boundary conditions.Three RVE models of cuboid,hexagonal and fiber random distribution are respectively developed to comparatively study the influence of fiber package pattern on the thermal conductivities at the microscale.Besides,the effect of void morphology on the thermal conductivity of the matrix is analyzed by the void/matrix models.The prediction results at the mesoscale correspond closely to the experimental values.The effect of the porosities and fiber volume fractions on the thermal conductivities is also taken into consideration.The multi-scale models mentioned in this paper can be used to predict the thermal conductivity behaviors of other composites with complex structures.
基金financially supported by National Natural Science Foundation of China (Grant Nos. 52173078, 52130303, 51973158, 51803151, and 51973152)the Science Foundation for Distinguished Young Scholars in Tianjin (No. 19JCJQJC61700)Tianjin Postgraduate Scientific Research Innovation Project in 2019 (2019YJSB181)
文摘Composites that can rapidly self-healing their structure and function at room temperature have broad application prospects.However,in view of the complexity of composite structure and composition,its self-heal is facing challenges.In this article,supramolecular effect is proposed to repair the multistage structure,mechanical and thermal properties of composite materials.A stiff and tough supramolecular frameworks of 2-[[(butylamino)carbonyl]oxy]ethyl ester(PBA)–polydimethylsiloxane(PDMS)were established using a chain extender with double amide bonds in a side chain to extend prepolymers through copolymerization.Then,by introducing the copolymer into a folded graphene film(FGf),a highly thermally conductive composite of PBA–PDMS/FGf with self-healing capacity was fabricated.The ratio of crosslinking and hydrogen bonding was optimized to ensure that PBA–PDMS could completely self-heal at room temperature in 10 min.Additionally,PBA–PDMS/FGf exhibits a high tensile strength of 2.23±0.15 MPa at break and high thermal conductivity of 13±0.2 W m^(−1)K^(−1);of which the self-healing efficiencies were 100%and 98.65%at room temperature for tensile strength and thermal conductivity,respectively.The excellent self-healing performance comes from the efficient supramolecular interaction between polymer molecules,as well as polymer molecule and graphene.This kind of thermal conductive self-healing composite has important application prospects in the heat dissipation field of next generation electronic devices in the future.
文摘The sintering technology of the AlN ceramics power were discussed. It is discussed that the compound sintering aids is consistent with the enhancement of the the thermal conductivity of AlN ceramics, and sintering technics is helped to the improvement of density. It is analyzed how to sinter machinable AlN ceramics with high thermal conductivity. And the microstructure of compound ceramics based on AlN was studied.
基金supported by the National Natural Science Foundation of China(Grant No.51301075)the Project of Development and Reform Commission of Jilin Province,China(Grant No.2014Y136)
文摘Improving the thermal stability of diamond and other superhard materials has great significance in various applications. Here, we report the synthesis and characterization of bulk diamond–cBN–B4C–Si composites sintered at high pressure and high temperature（HPHT, 5.2 GPa, 1620–1680 K for 3–5 min）. The results show that the diamond, cBN, B4C,BxSiC, SiO2 and amorphous carbon or a little surplus Si are present in the sintered samples. The onset oxidation temperature of 1673 K in the as-synthesized sample is much higher than that of diamond, cBN, and B4C. The high thermal stability is ascribed to the covalent bonds of B–C, C–N, and the solid-solution of BxSiC formed during the sintering process. The results obtained in this work may be useful in preparing superhard materials with high thermal stability.
基金Funded by the National Natural Science Foundation of China(No.U1134102)
文摘C/C composites are the emerging materials of choice for aero-engine hot-end components that will bear impact loading in thermal-oxidizing environments. For the components run for extended periods, the safe operation of components depends on how to evaluate damages under a dynamic load. In this study, Charpy impact tests at a temperature range of 25 to l 200 ＂C were carried out on C/C composites to verify the effects of temperature induced thermal expansion and oxidation on their impact performance. Below 800 ℃, oxidation was negligible and composites expanding played a leading role, resulting in the remarkable increase in fiber/ matrix interface strength and impact energy. However, when the temperature was above 800 ℃, the release of CO or CO2 due to oxidation resulted in a lower impact energy.
文摘The coefficient of thermal expansion, thermal diffusivity and specific heat of C/C composites from room temperature to ultra high temperature were experimentally investigated. Thermal conductivity and thermal stress resistance of the composites were therefore computed based on experimental results. The results show that the composite has a very low thermal expansion coefficient. Thermal diffusivity decreases exponentially with temperature increase. The specific heat increases linearly as the temperature rises, and the variation trend of thermal conductivity is similar to that of thermal diffusivity. The thermal stress coefficient of C/C composite has little change with temperature variation, and thermal stress resistance of the composite at high temperature is stable.
基金Funded by the National Basic Research Program of China,National Natural Science Foundation of China(No.51075204)Aeronautical Science Foundation of China(No.2012ZB52026)+1 种基金Research Fund for the Doctoral Program of Higher Education of China(No.20070287039)NUAA Research Funding(No.NZ2012106)
文摘To make better use of 2.5D C/SiC composites in industry, it is necessary to understand the mechanical properties. A finite element model＇of 2.5D composites is established, by considering the fiber undulation and the porosity in 2.5D C/SiC composites. The fiber direction of warp is defined by cosine function to simulate the undulation of warp, and based on uniform strain assumption, analytical model of the elastic modulus and coefficient of thermal expansion （CTE） for 2.5D C/SiC composites were established by using dual- scale model. The result is found to correlate reasonably well with the predicted results and experimental results. The parametric study also demonstrates the effects of the fiber volume fraction, distance of warp yarn, and porosity in micro-scale on the mechanical properties and the coefficients of thermal expansion.
基金Project(200202AA305207) supported by the National High Technology Research and Development Program of China
文摘The ablation properties of C/C composites with four different needled preforms prepared by isothermal chemical vapor infiltration (ICVI),which are super-thin mat lay-up,0°/90° weftless fabric lay-up,0°/45° weftless fabric lay-up and 0°/45° twill fabric lay-up,were quantitatively evaluated by performing the ablation tests with an engine torch.And their ablation discrepancies were analyzed according to the surface characteristic,porosity and thermal diffusivity.The results show that the 0°/45° weftless composite has a flat eroded surface with no obvious macroscopic pits.Its thickness and mass erosion rates are decreased by about 46.8% and 34.8%,25.0% and 27.5%,and 17.5% and 19.4% compared with those of the mat,the 0°/90° weftless and the 0°/45° twill composites,respectively.The ablation properties are mainly controlled by the thermo-chemical effect (oxidation),and a little by the thermo-mechanical effect (mechanical denudation).The needling fiber bundles play an important role in accelerating the ablation process and resulting in the heterogeneous ablation.
文摘The tensile properties of three different carbonfiberreinforced carbon composites (C/C), mat C/C, 2D laminate and 4D C/C, were investigated under the combined influence of temperature and loading rate. From the experiments the following could be concluded: loading rate between 10-1-10 mm/min was valid; the fracture stress of the three kinds of C/C composites increased with increasing temperature in the range from room temperature to 1900, and the initial modulus of 2D laminate C/C composites increased with the increase of temperature up to 2000.
文摘In this paper were studied the microstructure and properties of the non-barrier coating compo- sites fabricated by a new technology.The bonding between C and A1 in the composites is quite well, and the composites have excellent properties.The ion probe and X-ray analyses indicate that there is Al_4C_3 phase in the composites and its amount in the composites increases when the composites are exposed.In the case of exposure the strength of the composites is reduced because of increasing amount of Al_4C_3.
基金Funded by the National Natural Science Foundation of China(No.50772089)the Program of Introducing Talents of Discipline in the Project of Advanced Materials and their Forming Technology(B08040)
文摘Carbon fiber-reinforced silicon carbonitride ceramic matrix composites （C/SiCN） were prepared by rapid electro-thermal pyrolysis CVD using liquid polymer hexamethyldisilazane （HMDS, （CH3）3SiNHSi（CH3）3） as precursor. Microstructure morphology and production technique of C/SiCN composites were investigated. Scanning electron microscopy and transmission electron microscopy were respectively employed to characterize microstructures of the as-received C/SiCN composites samples. The high temperature pyrolysis of HMDS results in destruction of molecular chain, fracture of bonds, as well as liquid-gas-solid conversion from polymer to ceramic. Microstructures observation indicates that there is a high degree of coalescence between SiCN matrix and C fiber. The deposition model of liquid precursor electro-thermal pyrolysis CVD is different from that of gas precursor isothermal chemical vapor infiltration. Rapid liquid flow and slow gas diffusion are key factors for the difference of two methods. Preparation of rapid electro-thermal pyrolysis CVD consists of four steps including liquid polymer infiltration, polymer pyrolysis, rapid deposition of pyrolyzed substances and rapid densification, respectively.
文摘The electronic packaging shell with high silicon carbide aluminum-base composites was prepared by semi-solid thixoforming technique. The flow characteristic of the Si C particulate was analyzed. The microstructures of different parts of the shell were observed by scanning electron microscopy and optical microscopy, and the thermophysical and mechanical properties of the shell were tested. The results show that there exists the segregation phenomenon between the Si C particulate and the liquid phase during thixoforming, the liquid phase flows from the shell, and the Si C particles accumulate at the bottom of the shell. The volume fraction of Si C decreases gradually from the bottom to the walls. Accordingly, the thermal conductivities of bottom center and walls are 178 and 164 W·m-1·K-1, the coefficients of thermal expansion(CTE) are 8.2×10-6 and 12.6×10-6 K-1, respectively. The flexural strength decreases slightly from 437 to 347 MPa. The microstructures and properties of the shell show gradient distribution.
