An accurate mapping and understanding of remaining oil distribution is very important for water control and stabilize oil production of mature oilfields in ultra-high water-cut stage.Currently,the Tuo-21 Fault Block o...An accurate mapping and understanding of remaining oil distribution is very important for water control and stabilize oil production of mature oilfields in ultra-high water-cut stage.Currently,the Tuo-21 Fault Block of the Shengtuo Oilfield has entered the stage of ultra-high water cut(97.2%).Poor adaptability of the well pattern,ineffective water injection cycle and low efficiency of engineering measures(such as workover,re-perforation and utilization of high-capacity pumps)are the significant problems in the ultra-high water-cut reservoir.In order to accurately describe the oil and water flow characteristics,relative permeability curves at high water injection multiple(injected pore volume)and a semiquantitative method is applied to perform fine reservoir simulation of the Sand group 3e7 in the Block.An accurate reservoir model is built and history matching is performed.The distribution characteristics of remaining oil in lateral and vertical directions are quantitatively simulated and analyzed.The results show that the numerical simulation considering relative permeability at high injection multiple can reflect truly the remaining oil distribution characteristics after water flooding in an ultrahigh water-cut stage.The distribution of remaining oil saturation can be mapped more accurately and quantitatively by using the‘four-points and five-types’classification method,providing a basis for potential tapping of various remaining oil types of oil reservoirs in late-stage of development with high water-cut.展开更多
CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fractio...CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fraction),while CO_(2) emulsion with high water cut has been rarely researched.In this paper,we carried out a comprehensive experimental study of using high water cut CO_(2)/H_(2)O emulsion for enhancing oil recovery.Firstly,a nonionic surfactant,alkyl glycosides(APG),was selected to stabilize CO_(2)/H_(2)O emulsion,and the corresponding morphology and stability were evaluated with a transparent PVT cell.Subsequently,plugging capacity and apparent viscosity of CO_(2)/H_(2)O emulsion were measured systematically by a sand pack displacement apparatus connected with a 1.95-m long capillary tube.Furthermore,a high water cut(40 vol%) CO_(2)/H_(2)O emulsion was selected for flooding experiments in a long sand pack and a core sample,and the oil recovery,the rate of oil recovery,and the pressure gradients were analyzed.The results indicated that APG had a good performance on emulsifying and stabilizing CO_(2) emulsion.An inversion from H_(2)O/CO_(2) emulsion to CO_(2)/H_(2)O emulsion with the increase in water cut was confirmed.CO_(2)/H_(2)O emulsions with lower water cuts presented higher apparent viscosity,while the optimal plugging capacity of CO_(2)/H_(2)O emulsion occurred at a certain water cut.Eventually,the displacement using CO_(2)/H_(2)O emulsion provided 18.98% and 13.36% additional oil recovery than that using pure CO_(2) in long sand pack and core tests,respectively.This work may provide guidelines for EOR using CO_(2) emulsions with high water cut.展开更多
In order to improve the effect of water control and oil stabilization during high water cut period, a mathematical model of five point method well group was established with the high water cut well group of an Oilfiel...In order to improve the effect of water control and oil stabilization during high water cut period, a mathematical model of five point method well group was established with the high water cut well group of an Oilfield as the target area, the variation law of water cut and recovery factor of different injection parameters was analyzed, and the optimization research of injection parameters of polymer enhanced foam flooding was carried out. The results show that the higher the injection rate, the lower the water content curve, and the higher the oil recovery rate. As the foam defoamed when encountering oil, when the injection time was earlier than 80% of water cut, the later the injection time was, the better the oil displacement effect would be. When the injection time was later than 80% of water cut, the later the injection time was, the worse the oil displacement effect would be. The larger the injection volume, the lower the water content curve and the higher the recovery rate. After the injection volume exceeded 0.2 PV, the amplitude of changes in water content and recovery rate slowed down. The optimal injection parameters of profile control agent for high water content well group in Oilfield A were: injection rate of 15 m<sup>3</sup>/d, injection timing of 80% water content, and injection volume of 0.2 PV.展开更多
In this study,acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization.The effects of the content of ...In this study,acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization.The effects of the content of acrylic acid on the properties of the resulting waterborne polyurethane-poly(acrylic acid)(WPU-PAA)dispersion and the films were systematically investigated.The results showed that the cross-linking density of the interpenetrating network polymers was increased and the interlocking structure of the soft and hard phase dislocations in the molecular segments of the double networks was tailored with increasing the content of acrylic acid,leading to enhancement of the mechanical properties and water resistance of WPU-PAA films.Notably,with the increase in content of acrylic acid,the tensile strength,Young’s modulus,and toughness of the WPU-PAA-110 film increased by 3 times,and 8 times,and 2.4 times compared with WPU-PAA-80,respectively.The WPU-PAA-100 film showed the best water resistance,and the water absorption rate at 96 h was only 3.27%.This work provided a new design scheme for constructing bio-based WPU materials with excellent properties.展开更多
The high water content of municipal solid waste(MSW)will reduce the effciency of mechanical sorting,consequently unfavorable for beneficial utilization.In this study,a combined hydrolytic-aerobic biodrying technology ...The high water content of municipal solid waste(MSW)will reduce the effciency of mechanical sorting,consequently unfavorable for beneficial utilization.In this study,a combined hydrolytic-aerobic biodrying technology was introduced to remove water from MSW.The total water removals were proved to depend on the ventilation frequency and the temporal span in the hydrolytic stage. The ventilation frequency of 6 times/d was preferable in the hydrolytic stage.The hydrolytic span should not be prolonged more than ...展开更多
Jinping traffic tunnel is one of the deepest traffic tunnels in the world with a maximum overburden of 2 375 m and the overburden over 73% of its total length is larger than 1 500 m. The tunnel is 17.5 km long and des...Jinping traffic tunnel is one of the deepest traffic tunnels in the world with a maximum overburden of 2 375 m and the overburden over 73% of its total length is larger than 1 500 m. The tunnel is 17.5 km long and designed to provide a shortcut road between two hydropower stations: Jinping I and Jinping II of the Jinping Hydropower Project, located on Yalong River, Liangshan State, Sichuan Province, China. The tunnel is so deep that building any shafts is impossible. The construction starts from both ends (east and west ends), and the construction length from the west end is 10 km with a blind heading. This paper deals with an overview of this project and analysis of the engineering features, as well as key technologies developed and applied during the construction, including geological prediction, rock burst prevention under a super high in-situ stress, sealing of groundwater with a high pressure and big flow rate, ventilation for a blind heading of 10 km, wet spraying of shotcrete at zones of rock burst and rich water, etc. The application of the new technologies to the construction achieved a high quality tunnel within the contract period.展开更多
A new type of high water content material which is made up of two pastes is prepared, one is refute from lime and gypsum, and another is based on Ba-bearing sulphoaluminate cement. It has excellent properties such as ...A new type of high water content material which is made up of two pastes is prepared, one is refute from lime and gypsum, and another is based on Ba-bearing sulphoaluminate cement. It has excellent properties such as slow single paste solidifing ,fust double pustes solidifing ,fast coagulating and hardening, high early strength, good suspeasion property at high W/C ratio and low cost. Meanwhile, the properties and hydration mechanism of the material were analyzed by using XRD, DTA- TG and SEM. The hydrated products of new type of high water content material are Ba-bearing ettringite, BaSO4 , aluminum gel and C-S-H gel.展开更多
Layer regrouping is to divide all the layers into several sets of production series according to the physical properties and recovery percent of layers at high water-cut stage, which is an important technique to impro...Layer regrouping is to divide all the layers into several sets of production series according to the physical properties and recovery percent of layers at high water-cut stage, which is an important technique to improve oil recovery for high water-cut multilayered reservoirs. Dif- ferent regroup scenarios may lead to different production performances. Based on unstable oil-water flow theory, a multilayer commingled reservoir simulator is established by modifying the production split method. Taking into account the differences of layer properties, including per- meability, oil viscosity, and remaining oil saturation, the pseudo flow resistance contrast is proposed to serve as a characteristic index of layer regrouping for high water-cut multilayered reservoirs. The production indices of multi- layered reservoirs with different pseudo flow resistances are predicted with the established model in which the data are taken from the Shengtuo Oilfield. Simulation results show that the pseudo flow resistance contrast should be less than 4 when the layer regrouping is implemented. The K-means clustering method, which is based on the objec- tive function, is used to automatically carry out the layer regrouping process according to pseudo flow resistances. The research result is applied to the IV-VI sand groups of the second member of the Shahejie Formation in the Shengtuo Oilfield, a favorable development performance is obtained, and the oil recovery is enhanced by 6.08 %.展开更多
Some crude oils with high water cut have the capability to flow below the oil gel point, while the oil particles adhere to the pipe wall in the form of paste, also called "wall sticking". Wall sticking is a ...Some crude oils with high water cut have the capability to flow below the oil gel point, while the oil particles adhere to the pipe wall in the form of paste, also called "wall sticking". Wall sticking is a serious problem during the pipeline transportation, leading to partial or total blockage of the pipeline and energy wastage. In this paper, a series of laboratory flow loop experiments were conducted to observe the wall sticking characteristics of crude oil with high water cut, high viscosity and high gel point at low transportation temperatures. The effects of shear stress and water cut on the wall sticking rate and occurrence temperature were investigated. Experimental results indicated that the wall sticking rate and occurrence temperature were lower under stronger shear stress and higher water cut conditions. A criterion of wall sticking occurrence temperature(WSOT) and a regression model of wall sticking rate were then established. Finally, the software was developed to calculate the pressure drop along the pipelines of crude oils with high water-cut. It was able to predict the wall sticking thickness of gelled oil and then calculate the pressure drop along the pipelines. A typical case study indicated that the prediction results obtained from the software were in agreement with actual measured values.展开更多
The oil production predicted by means of the conventional water-drive characteristic curve is typically affected by large deviations with respect to the actual value when the so-called high water-cut stage is entered....The oil production predicted by means of the conventional water-drive characteristic curve is typically affected by large deviations with respect to the actual value when the so-called high water-cut stage is entered.In order to solve this problem,a new characteristic relationship between the relative permeability ratio and the average water saturation is proposed.By comparing the outcomes of different matching methods,it is verified that it can well reflect the variation characteristics of the relative permeability ratio curve.Combining the new formula with a reservoir engineering method,two new formulas are derived for the water flooding characteristic curve in the high water-cut stage.Their practicability is verified by using the production data of Mawangmiao and Xijiakou blocks.The results show that the error between the predicted cumulative oil production and production data of the two new water drive characteristic curves is less than the error between the B-type water drive characteristic curve and the other two water drive characteristic curves.It is concluded that the two new characteristic curves can be used to estimate more accurately the recoverable reserves,the final recovery and to estimate the effects of water flooding.展开更多
In order to ensure the safety of the non-heating gathering and transportation processes for high water fraction crude oil,the effect of temperature,water fraction,and flow rate on the flow characteristics of crude oil...In order to ensure the safety of the non-heating gathering and transportation processes for high water fraction crude oil,the effect of temperature,water fraction,and flow rate on the flow characteristics of crude oil with high water fraction was studied in a flow experimental system of the X Oilfield.Four distinct flow patterns were identified by the photographic and local sampling techniques.Especially,three new flow patterns were found to occur below the pour point of crude oil,including EW/O&W stratified flow with gel deposition,EW/O&W intermittent flow with gel deposition,and water single-phase flow with gel deposition.Moreover,two characteristic temperatures,at which the change rate of pressure drop had changed obviously,were found during the change of pressure drop.The characteristic temperature of the first congestion of gel deposition in the pipeline was determined to be the safe temperature for the non-heating gathering and transportation of high water cut crude oil,while the pressure drop reached the peak at this temperature.An empirical formula for the safe temperature was established for oil-water flow with high water fraction/low fluid production rate.The results can serve as a guide for the safe operation of the non-heating gathering and transportation of crude oil in high water fraction oilfields.展开更多
A new method using high water content material to mechanically fill cross roadways to form artificial bottom for coal faces was introduced. The reasonable determination of filling range, the optimization of the compou...A new method using high water content material to mechanically fill cross roadways to form artificial bottom for coal faces was introduced. The reasonable determination of filling range, the optimization of the compounding ratio of high water content material, and the filling technique were discussed in detail. This new method has been spread after industrial testing in Baodian Colliery. Compared with the traditional method, the manual wooden chock method, the new one decreases about 40% of the filling range and cost in dealing every one set of cross roadway in the testing condition.展开更多
To explore the variation of permeability and deformation behaviors of a fractured rock mass in high water pressure,a high pressure permeability test(HPPT),including measuring sensors of pore water pressure and displ...To explore the variation of permeability and deformation behaviors of a fractured rock mass in high water pressure,a high pressure permeability test(HPPT),including measuring sensors of pore water pressure and displacement of the rock mass,was designed according to the hydrogeological condition of Heimifeng pumped storage power station.With the assumption of radial water flow pattern in the rock mass during the HPPT,a theoretical formula was presented to estimate the coefficient of permeability of the rock mass using water pressures in injection and measuring boreholes.The variation in permeability of the rock mass with the injected water pressure was studied according to the suggested formula.By fitting the relationship between the coefficient of permeability and the injected water pressure,a mathematical expression was obtained and used in the numerical simulations.For a better understanding of the relationship between the pore water pressure and the displacement of the rock mass,a 3D numerical method based on a coupled hydro-mechanical theory was employed to simulate the response of the rock mass during the test.By comparison of the calculated and measured data of pore water pressure and displacement,the deformation behaviors of the rock mass were analyzed.It is shown that the variation of displacement in the fractured rock mass is caused by water flow passing through it under high water pressure,and the rock deformation during the test could be calculated by using the coupled hydro-mechanical model.展开更多
Through analyzing the effects of water consumption, diameter of solid particle, and flow vefority on the fluidity of high water content material slurry, the relatinnship among the fluidity, the isotropy of the slurry,...Through analyzing the effects of water consumption, diameter of solid particle, and flow vefority on the fluidity of high water content material slurry, the relatinnship among the fluidity, the isotropy of the slurry, and the pumping facilities applied in getway-side backfilling has been found. And the requirment of fluidity of high water content material for the design of getway-side back filling technique is put forward in the paper.展开更多
With the production of strong bottom water reservoir, it will soon enter the ultra-high water cut stage. After entering the ultra-high water cut period, the main means of stable production is liquid extraction. Large ...With the production of strong bottom water reservoir, it will soon enter the ultra-high water cut stage. After entering the ultra-high water cut period, the main means of stable production is liquid extraction. Large liquid volume has a certain impact on the physical property distribution and fluid seepage law of the oilfield. The relative permeability curve measured according to the industry standard is not used for the prediction of development indicators and the understanding of the dynamic law of the oilfield. In order to understand the characteristics of water drive law in high water cut stage of water drive oilfield, starting from the water drive characteristic curve in high water cut stage, the method for calculating the relative permeability curve is deduced. Through numerical simulation verification and fitting the actual production data, it is confirmed that the obtained relative permeability curve is in line with the reality of the oilfield, It can provide some guiding significance for understanding the production law and water drive law of strong bottom water reservoir in ultra-high water cut stage.展开更多
As coal and gas outburst is one of the most serious mine disasters, it is very important to at least control it if not prevent it from occurring. Injecting cement slurry or grouting into the coal seam can strengthen t...As coal and gas outburst is one of the most serious mine disasters, it is very important to at least control it if not prevent it from occurring. Injecting cement slurry or grouting into the coal seam can strengthen the seam, increase its rigidity coefficient(f), and reduce the volumetric expansion due to gas energy release.This paper reports the results of laboratory experiments on cement-based high water content slurry having different water-cement ratios(W/C) to be used for coal injection. The results show that as the W/C increases, the mobility of the slurry and its setting time increase. The compressive strength and rupture strength, however, are reduced. Furthermore, high W/C grout shows early strength after 7 days, which can be 80% of its 14-day compressive strength. To achieve rapid setting and early strength, the addition of Na_2SiO_3has proven to give the best result, when the concentration of the additive is 3%. The initial and final setting times are 13 and 21 min shorter than samples without Na_2SiO_3, while the compressive strength is more than double. As a retarder, the initial setting time can be extended to 83 min when tartaric acid of 0.4% concentration is added. Through the orthogonal experiment, the optimum recipe of the new high water content slurry has been determined to be: W/C = 2, tartaric acid = 0.2%, Na_2SiO_3= 3%, and12% bentonite. Reinforcement by injection simulation experiments show that the grouting radius of the new slurry mix is 250 mm when the applied grouting pressure is 60 k Pa, 7-day rupture strength and compressive strength are 5.2 and 6.4 MPa, respectively, and are 37% and 88% higher than ordinary cement grout. It can be concluded that the newly developed slurry mix is more effective than the ordinary mix for reinforcing coal and controlling gas outburst.展开更多
In this article, information about the geographical location of the Karakir Lake in Bukhara region, high water plants, systematics and their distribution is presented. As a result of the research, Lake Karakir has 34 ...In this article, information about the geographical location of the Karakir Lake in Bukhara region, high water plants, systematics and their distribution is presented. As a result of the research, Lake Karakir has 34 species of high water plants belonging to 16 families. These plants were divided into ecological groups and analyzed.展开更多
This study aims to improve the performances of the high-pressure water descaling technology used in steel hot rolling processes.In particular,a 2050 mm hot rolling line is considered,and the problem is investigated by...This study aims to improve the performances of the high-pressure water descaling technology used in steel hot rolling processes.In particular,a 2050 mm hot rolling line is considered,and the problem is investigated by means of a fluid–structure interaction(FSI)method by which the descaling effect produced by rolling coils with different section sizes is examined.Assuming a flat fan-shaped nozzle at the entrance of the R1R2 roughing mill,the outflow field characteristics and the velocity distribution curve on the strike line(at a target distance of 30–120 mm)are determined.It is found that the velocity in the center region of the water jet with different target distances is higher than that in the boundary region.As the target distance increases,the velocity of the water jet in the central region decreases.Through comparison with experimental results,it is shown that the simulation model can accurately predict the impact position of the high-pressure water on the impact plate,thereby providing a computational scheme that can be used to optimize the nozzle space layout and improve the slabs’descent effect for different rolling specifications.展开更多
In order to clarify the danger of water breakout in the bottom plate of extra-thick coal seam mining, 2202 working face of a mine in the west is taken as the research object, and it is proposed to use the on-site moni...In order to clarify the danger of water breakout in the bottom plate of extra-thick coal seam mining, 2202 working face of a mine in the west is taken as the research object, and it is proposed to use the on-site monitoring means combining borehole peeping and microseismic monitoring, combined with the theoretical analysis to analyze the danger of water breakout in the bottom plate. The results show that: 1) the theoretically calculated maximum damage depth of the bottom plate is 27.5 m, and its layer is located above the Austrian ash aquifer, which has the danger of water breakout;2) the drill hole peeping at the bottom plate of the working face shows that the depth of the bottom plate fissure development reaches 26 m, and the integrity of the water barrier layer has been damaged, so there is the risk of water breakout;3) for the microseismic monitoring of the anomalous area, the bottom plate of the return air downstream channel occurs in the field with a one-week lag, which shows that microseismic monitoring events may reflect the water breakout of the underground. This shows that the microseismic monitoring events can reflect the changes of the underground flow field, which can provide a reference basis for the early warning of water breakout. The research results can provide reference for the prediction of sudden water hazard.展开更多
Balance of the groundwater and ecology is crucial for controlled discharge.However,regarding the segments of tunnel boring machines(TBMs)under high water pressure,the stability of the lining structure is often reduced...Balance of the groundwater and ecology is crucial for controlled discharge.However,regarding the segments of tunnel boring machines(TBMs)under high water pressure,the stability of the lining structure is often reduced by excessive drain holes required to achieve this balance.The large discharge of pinholes can easily have severe consequences,such as the lowering of the groundwater table,drying of springs,and vegetation wilting.Thus,in this study,according to the fluid-structure coupling theory,a new drainage design for TBM segments was developed by considering a mountain tunnel subject to a high water pressure as a case study.The evolution characteristics,including the external water pressure of the lining,discharge volume of the segment,and groundwater-table drawdown,were investigated via numerical modeling with drain holes and pinholes.The results indicated that the optimal design parameters of drainage segments for the project case were as follows:a circumferential spacing angle and longitudinal number on one side of a single ring of 51°and 2,respectively,for the drain holes and an inclination angle and length of 46.41°and 0.25 times the grouting thickness,respectively,for the pin holes.展开更多
基金funded by SINOPEC Science and Technology Project P18080by National Energy Administration Research and Development Center Project.
文摘An accurate mapping and understanding of remaining oil distribution is very important for water control and stabilize oil production of mature oilfields in ultra-high water-cut stage.Currently,the Tuo-21 Fault Block of the Shengtuo Oilfield has entered the stage of ultra-high water cut(97.2%).Poor adaptability of the well pattern,ineffective water injection cycle and low efficiency of engineering measures(such as workover,re-perforation and utilization of high-capacity pumps)are the significant problems in the ultra-high water-cut reservoir.In order to accurately describe the oil and water flow characteristics,relative permeability curves at high water injection multiple(injected pore volume)and a semiquantitative method is applied to perform fine reservoir simulation of the Sand group 3e7 in the Block.An accurate reservoir model is built and history matching is performed.The distribution characteristics of remaining oil in lateral and vertical directions are quantitatively simulated and analyzed.The results show that the numerical simulation considering relative permeability at high injection multiple can reflect truly the remaining oil distribution characteristics after water flooding in an ultrahigh water-cut stage.The distribution of remaining oil saturation can be mapped more accurately and quantitatively by using the‘four-points and five-types’classification method,providing a basis for potential tapping of various remaining oil types of oil reservoirs in late-stage of development with high water-cut.
基金The financial supports received from the National Natural Science Foundation of China(Nos.22178378,22127812)。
文摘CO_(2) emulsions used for EOR have received a lot of interest because of its good performance on CO_(2)mobility reduction.However,most of them have been focusing on the high quality CO_(2) emulsion(high CO_(2) fraction),while CO_(2) emulsion with high water cut has been rarely researched.In this paper,we carried out a comprehensive experimental study of using high water cut CO_(2)/H_(2)O emulsion for enhancing oil recovery.Firstly,a nonionic surfactant,alkyl glycosides(APG),was selected to stabilize CO_(2)/H_(2)O emulsion,and the corresponding morphology and stability were evaluated with a transparent PVT cell.Subsequently,plugging capacity and apparent viscosity of CO_(2)/H_(2)O emulsion were measured systematically by a sand pack displacement apparatus connected with a 1.95-m long capillary tube.Furthermore,a high water cut(40 vol%) CO_(2)/H_(2)O emulsion was selected for flooding experiments in a long sand pack and a core sample,and the oil recovery,the rate of oil recovery,and the pressure gradients were analyzed.The results indicated that APG had a good performance on emulsifying and stabilizing CO_(2) emulsion.An inversion from H_(2)O/CO_(2) emulsion to CO_(2)/H_(2)O emulsion with the increase in water cut was confirmed.CO_(2)/H_(2)O emulsions with lower water cuts presented higher apparent viscosity,while the optimal plugging capacity of CO_(2)/H_(2)O emulsion occurred at a certain water cut.Eventually,the displacement using CO_(2)/H_(2)O emulsion provided 18.98% and 13.36% additional oil recovery than that using pure CO_(2) in long sand pack and core tests,respectively.This work may provide guidelines for EOR using CO_(2) emulsions with high water cut.
文摘In order to improve the effect of water control and oil stabilization during high water cut period, a mathematical model of five point method well group was established with the high water cut well group of an Oilfield as the target area, the variation law of water cut and recovery factor of different injection parameters was analyzed, and the optimization research of injection parameters of polymer enhanced foam flooding was carried out. The results show that the higher the injection rate, the lower the water content curve, and the higher the oil recovery rate. As the foam defoamed when encountering oil, when the injection time was earlier than 80% of water cut, the later the injection time was, the better the oil displacement effect would be. When the injection time was later than 80% of water cut, the later the injection time was, the worse the oil displacement effect would be. The larger the injection volume, the lower the water content curve and the higher the recovery rate. After the injection volume exceeded 0.2 PV, the amplitude of changes in water content and recovery rate slowed down. The optimal injection parameters of profile control agent for high water content well group in Oilfield A were: injection rate of 15 m<sup>3</sup>/d, injection timing of 80% water content, and injection volume of 0.2 PV.
基金by the Research and Development Program in Key Areas of Guangdong Province(Grant No.2020B0202010008)Guangdong Province Science&Technology Program(2018B030306016)+1 种基金Guangdong Provincial Innovation Team for General Key Technologies in Modern Agricultural Industry(2019KJ133)Key Projects of Basic Research and Applied Basic Research of the Higher Education Institutions of Guangdong Province(2018KZDXM014).
文摘In this study,acrylic acid was used as a neutralizer to prepare bio-based WPU with an interpenetrating polymer network structure by thermally induced free radical emulsion polymerization.The effects of the content of acrylic acid on the properties of the resulting waterborne polyurethane-poly(acrylic acid)(WPU-PAA)dispersion and the films were systematically investigated.The results showed that the cross-linking density of the interpenetrating network polymers was increased and the interlocking structure of the soft and hard phase dislocations in the molecular segments of the double networks was tailored with increasing the content of acrylic acid,leading to enhancement of the mechanical properties and water resistance of WPU-PAA films.Notably,with the increase in content of acrylic acid,the tensile strength,Young’s modulus,and toughness of the WPU-PAA-110 film increased by 3 times,and 8 times,and 2.4 times compared with WPU-PAA-80,respectively.The WPU-PAA-100 film showed the best water resistance,and the water absorption rate at 96 h was only 3.27%.This work provided a new design scheme for constructing bio-based WPU materials with excellent properties.
基金supported by the National Key Technolo-gy R&D Program(No.2006BAC06B04,2006BAC02A03)the Key Grant Project of Shanghai Committee of Science and Technology(No.06dz12308).
文摘The high water content of municipal solid waste(MSW)will reduce the effciency of mechanical sorting,consequently unfavorable for beneficial utilization.In this study,a combined hydrolytic-aerobic biodrying technology was introduced to remove water from MSW.The total water removals were proved to depend on the ventilation frequency and the temporal span in the hydrolytic stage. The ventilation frequency of 6 times/d was preferable in the hydrolytic stage.The hydrolytic span should not be prolonged more than ...
文摘Jinping traffic tunnel is one of the deepest traffic tunnels in the world with a maximum overburden of 2 375 m and the overburden over 73% of its total length is larger than 1 500 m. The tunnel is 17.5 km long and designed to provide a shortcut road between two hydropower stations: Jinping I and Jinping II of the Jinping Hydropower Project, located on Yalong River, Liangshan State, Sichuan Province, China. The tunnel is so deep that building any shafts is impossible. The construction starts from both ends (east and west ends), and the construction length from the west end is 10 km with a blind heading. This paper deals with an overview of this project and analysis of the engineering features, as well as key technologies developed and applied during the construction, including geological prediction, rock burst prevention under a super high in-situ stress, sealing of groundwater with a high pressure and big flow rate, ventilation for a blind heading of 10 km, wet spraying of shotcrete at zones of rock burst and rich water, etc. The application of the new technologies to the construction achieved a high quality tunnel within the contract period.
文摘A new type of high water content material which is made up of two pastes is prepared, one is refute from lime and gypsum, and another is based on Ba-bearing sulphoaluminate cement. It has excellent properties such as slow single paste solidifing ,fust double pustes solidifing ,fast coagulating and hardening, high early strength, good suspeasion property at high W/C ratio and low cost. Meanwhile, the properties and hydration mechanism of the material were analyzed by using XRD, DTA- TG and SEM. The hydrated products of new type of high water content material are Ba-bearing ettringite, BaSO4 , aluminum gel and C-S-H gel.
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University(IRT1294)the China National Science and Technology Major Projects(Grant No:2016ZX05011)
文摘Layer regrouping is to divide all the layers into several sets of production series according to the physical properties and recovery percent of layers at high water-cut stage, which is an important technique to improve oil recovery for high water-cut multilayered reservoirs. Dif- ferent regroup scenarios may lead to different production performances. Based on unstable oil-water flow theory, a multilayer commingled reservoir simulator is established by modifying the production split method. Taking into account the differences of layer properties, including per- meability, oil viscosity, and remaining oil saturation, the pseudo flow resistance contrast is proposed to serve as a characteristic index of layer regrouping for high water-cut multilayered reservoirs. The production indices of multi- layered reservoirs with different pseudo flow resistances are predicted with the established model in which the data are taken from the Shengtuo Oilfield. Simulation results show that the pseudo flow resistance contrast should be less than 4 when the layer regrouping is implemented. The K-means clustering method, which is based on the objec- tive function, is used to automatically carry out the layer regrouping process according to pseudo flow resistances. The research result is applied to the IV-VI sand groups of the second member of the Shahejie Formation in the Shengtuo Oilfield, a favorable development performance is obtained, and the oil recovery is enhanced by 6.08 %.
基金the support from the projects of the National Natural Science Foundation of China(No.51374224)for this research
文摘Some crude oils with high water cut have the capability to flow below the oil gel point, while the oil particles adhere to the pipe wall in the form of paste, also called "wall sticking". Wall sticking is a serious problem during the pipeline transportation, leading to partial or total blockage of the pipeline and energy wastage. In this paper, a series of laboratory flow loop experiments were conducted to observe the wall sticking characteristics of crude oil with high water cut, high viscosity and high gel point at low transportation temperatures. The effects of shear stress and water cut on the wall sticking rate and occurrence temperature were investigated. Experimental results indicated that the wall sticking rate and occurrence temperature were lower under stronger shear stress and higher water cut conditions. A criterion of wall sticking occurrence temperature(WSOT) and a regression model of wall sticking rate were then established. Finally, the software was developed to calculate the pressure drop along the pipelines of crude oils with high water-cut. It was able to predict the wall sticking thickness of gelled oil and then calculate the pressure drop along the pipelines. A typical case study indicated that the prediction results obtained from the software were in agreement with actual measured values.
基金It is supported by the National Natural Science Foundation of China(No.51404037)supported by the Scientific and Technological Research Project of Sinopec Jianghan Oilfield Branch Company(No.ZKK0220006).
文摘The oil production predicted by means of the conventional water-drive characteristic curve is typically affected by large deviations with respect to the actual value when the so-called high water-cut stage is entered.In order to solve this problem,a new characteristic relationship between the relative permeability ratio and the average water saturation is proposed.By comparing the outcomes of different matching methods,it is verified that it can well reflect the variation characteristics of the relative permeability ratio curve.Combining the new formula with a reservoir engineering method,two new formulas are derived for the water flooding characteristic curve in the high water-cut stage.Their practicability is verified by using the production data of Mawangmiao and Xijiakou blocks.The results show that the error between the predicted cumulative oil production and production data of the two new water drive characteristic curves is less than the error between the B-type water drive characteristic curve and the other two water drive characteristic curves.It is concluded that the two new characteristic curves can be used to estimate more accurately the recoverable reserves,the final recovery and to estimate the effects of water flooding.
基金financially supported by the National Natural Science Foundation of China (Grant No.51674281)the Opening Fund of Shandong Provincial Key Laboratory of Oil&Gas Storage (Study on low temperature flow characteristics of oil and water in gathering pipeline)the Transportation Safety and the Fundamental Research Funds for the Central Universities
文摘In order to ensure the safety of the non-heating gathering and transportation processes for high water fraction crude oil,the effect of temperature,water fraction,and flow rate on the flow characteristics of crude oil with high water fraction was studied in a flow experimental system of the X Oilfield.Four distinct flow patterns were identified by the photographic and local sampling techniques.Especially,three new flow patterns were found to occur below the pour point of crude oil,including EW/O&W stratified flow with gel deposition,EW/O&W intermittent flow with gel deposition,and water single-phase flow with gel deposition.Moreover,two characteristic temperatures,at which the change rate of pressure drop had changed obviously,were found during the change of pressure drop.The characteristic temperature of the first congestion of gel deposition in the pipeline was determined to be the safe temperature for the non-heating gathering and transportation of high water cut crude oil,while the pressure drop reached the peak at this temperature.An empirical formula for the safe temperature was established for oil-water flow with high water fraction/low fluid production rate.The results can serve as a guide for the safe operation of the non-heating gathering and transportation of crude oil in high water fraction oilfields.
文摘A new method using high water content material to mechanically fill cross roadways to form artificial bottom for coal faces was introduced. The reasonable determination of filling range, the optimization of the compounding ratio of high water content material, and the filling technique were discussed in detail. This new method has been spread after industrial testing in Baodian Colliery. Compared with the traditional method, the manual wooden chock method, the new one decreases about 40% of the filling range and cost in dealing every one set of cross roadway in the testing condition.
文摘To explore the variation of permeability and deformation behaviors of a fractured rock mass in high water pressure,a high pressure permeability test(HPPT),including measuring sensors of pore water pressure and displacement of the rock mass,was designed according to the hydrogeological condition of Heimifeng pumped storage power station.With the assumption of radial water flow pattern in the rock mass during the HPPT,a theoretical formula was presented to estimate the coefficient of permeability of the rock mass using water pressures in injection and measuring boreholes.The variation in permeability of the rock mass with the injected water pressure was studied according to the suggested formula.By fitting the relationship between the coefficient of permeability and the injected water pressure,a mathematical expression was obtained and used in the numerical simulations.For a better understanding of the relationship between the pore water pressure and the displacement of the rock mass,a 3D numerical method based on a coupled hydro-mechanical theory was employed to simulate the response of the rock mass during the test.By comparison of the calculated and measured data of pore water pressure and displacement,the deformation behaviors of the rock mass were analyzed.It is shown that the variation of displacement in the fractured rock mass is caused by water flow passing through it under high water pressure,and the rock deformation during the test could be calculated by using the coupled hydro-mechanical model.
文摘Through analyzing the effects of water consumption, diameter of solid particle, and flow vefority on the fluidity of high water content material slurry, the relatinnship among the fluidity, the isotropy of the slurry, and the pumping facilities applied in getway-side backfilling has been found. And the requirment of fluidity of high water content material for the design of getway-side back filling technique is put forward in the paper.
文摘With the production of strong bottom water reservoir, it will soon enter the ultra-high water cut stage. After entering the ultra-high water cut period, the main means of stable production is liquid extraction. Large liquid volume has a certain impact on the physical property distribution and fluid seepage law of the oilfield. The relative permeability curve measured according to the industry standard is not used for the prediction of development indicators and the understanding of the dynamic law of the oilfield. In order to understand the characteristics of water drive law in high water cut stage of water drive oilfield, starting from the water drive characteristic curve in high water cut stage, the method for calculating the relative permeability curve is deduced. Through numerical simulation verification and fitting the actual production data, it is confirmed that the obtained relative permeability curve is in line with the reality of the oilfield, It can provide some guiding significance for understanding the production law and water drive law of strong bottom water reservoir in ultra-high water cut stage.
基金financial support of the National Natural Science Foundation of China (No. 51474017)the Natural Science Foundation of Xinjiang Uygur Autonomous Region of China (No. 2014211B013)
文摘As coal and gas outburst is one of the most serious mine disasters, it is very important to at least control it if not prevent it from occurring. Injecting cement slurry or grouting into the coal seam can strengthen the seam, increase its rigidity coefficient(f), and reduce the volumetric expansion due to gas energy release.This paper reports the results of laboratory experiments on cement-based high water content slurry having different water-cement ratios(W/C) to be used for coal injection. The results show that as the W/C increases, the mobility of the slurry and its setting time increase. The compressive strength and rupture strength, however, are reduced. Furthermore, high W/C grout shows early strength after 7 days, which can be 80% of its 14-day compressive strength. To achieve rapid setting and early strength, the addition of Na_2SiO_3has proven to give the best result, when the concentration of the additive is 3%. The initial and final setting times are 13 and 21 min shorter than samples without Na_2SiO_3, while the compressive strength is more than double. As a retarder, the initial setting time can be extended to 83 min when tartaric acid of 0.4% concentration is added. Through the orthogonal experiment, the optimum recipe of the new high water content slurry has been determined to be: W/C = 2, tartaric acid = 0.2%, Na_2SiO_3= 3%, and12% bentonite. Reinforcement by injection simulation experiments show that the grouting radius of the new slurry mix is 250 mm when the applied grouting pressure is 60 k Pa, 7-day rupture strength and compressive strength are 5.2 and 6.4 MPa, respectively, and are 37% and 88% higher than ordinary cement grout. It can be concluded that the newly developed slurry mix is more effective than the ordinary mix for reinforcing coal and controlling gas outburst.
文摘In this article, information about the geographical location of the Karakir Lake in Bukhara region, high water plants, systematics and their distribution is presented. As a result of the research, Lake Karakir has 34 species of high water plants belonging to 16 families. These plants were divided into ecological groups and analyzed.
基金The research was funded by Science and Technology Project of Hebei Education Department(Project Number:QN2022198).Y.C.received the grant.
文摘This study aims to improve the performances of the high-pressure water descaling technology used in steel hot rolling processes.In particular,a 2050 mm hot rolling line is considered,and the problem is investigated by means of a fluid–structure interaction(FSI)method by which the descaling effect produced by rolling coils with different section sizes is examined.Assuming a flat fan-shaped nozzle at the entrance of the R1R2 roughing mill,the outflow field characteristics and the velocity distribution curve on the strike line(at a target distance of 30–120 mm)are determined.It is found that the velocity in the center region of the water jet with different target distances is higher than that in the boundary region.As the target distance increases,the velocity of the water jet in the central region decreases.Through comparison with experimental results,it is shown that the simulation model can accurately predict the impact position of the high-pressure water on the impact plate,thereby providing a computational scheme that can be used to optimize the nozzle space layout and improve the slabs’descent effect for different rolling specifications.
文摘In order to clarify the danger of water breakout in the bottom plate of extra-thick coal seam mining, 2202 working face of a mine in the west is taken as the research object, and it is proposed to use the on-site monitoring means combining borehole peeping and microseismic monitoring, combined with the theoretical analysis to analyze the danger of water breakout in the bottom plate. The results show that: 1) the theoretically calculated maximum damage depth of the bottom plate is 27.5 m, and its layer is located above the Austrian ash aquifer, which has the danger of water breakout;2) the drill hole peeping at the bottom plate of the working face shows that the depth of the bottom plate fissure development reaches 26 m, and the integrity of the water barrier layer has been damaged, so there is the risk of water breakout;3) for the microseismic monitoring of the anomalous area, the bottom plate of the return air downstream channel occurs in the field with a one-week lag, which shows that microseismic monitoring events may reflect the water breakout of the underground. This shows that the microseismic monitoring events can reflect the changes of the underground flow field, which can provide a reference basis for the early warning of water breakout. The research results can provide reference for the prediction of sudden water hazard.
基金the National Natural Science Foundation of China(Grant No.41972276)the Natural Science Foundation of Fujian Province(No.2020J06013)the"Foal Eagle Program"Youth Top-notch Talent Project of Fujian Province(No.00387088),The financial support is gratefully acknowledged.
文摘Balance of the groundwater and ecology is crucial for controlled discharge.However,regarding the segments of tunnel boring machines(TBMs)under high water pressure,the stability of the lining structure is often reduced by excessive drain holes required to achieve this balance.The large discharge of pinholes can easily have severe consequences,such as the lowering of the groundwater table,drying of springs,and vegetation wilting.Thus,in this study,according to the fluid-structure coupling theory,a new drainage design for TBM segments was developed by considering a mountain tunnel subject to a high water pressure as a case study.The evolution characteristics,including the external water pressure of the lining,discharge volume of the segment,and groundwater-table drawdown,were investigated via numerical modeling with drain holes and pinholes.The results indicated that the optimal design parameters of drainage segments for the project case were as follows:a circumferential spacing angle and longitudinal number on one side of a single ring of 51°and 2,respectively,for the drain holes and an inclination angle and length of 46.41°and 0.25 times the grouting thickness,respectively,for the pin holes.