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Petrogenesis of Mesozoic High-Mg Diorites in Western Shandong: Evidence from Chronology and Petro-geochemistry 被引量:24
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作者 Yang Chenghai Xu Wenliang +3 位作者 Yang Debin Liu Changchun Liu Xiaoming Hu Zhaochu 《Journal of China University of Geosciences》 SCIE CSCD 2005年第4期297-308,共12页
The high-Mg diorites, widely occurring in western Shandong, have important implications in the study of the relationship between the Mesozoic magmatism and the nature of the lithosphere and its thinning period in the ... The high-Mg diorites, widely occurring in western Shandong, have important implications in the study of the relationship between the Mesozoic magmatism and the nature of the lithosphere and its thinning period in the eastern North China craton (NCC). The Tietonggou and Jinling intrusions are typically representatives. LA-ICP-MS zircon U-Pb dating, major and trace element and Sr-Nd isotopic compositions of the Mesozoic intrusive rocks from western Shandong, eastern China, were analyzed. The weighted mean 106^pb/ 238^U ages from LA-ICP-MS zircon U-Pb dating results for early norite-diorite, late pyroxene-diorite from the Tietonggou intrusion and biotite-diorite from the Jinling intrusion are (131.4±4.9) Ma(n=15), (134. 5±2.3) Ma(n=13), and (132.8±4. 2) Ma(n=12), respectively, implying that they were formed in the Early Cretaceous. The weighted mean 207^pb/ 204^Pb ages for round zircons from late pyroxene-diorite in the Tietonggou intrusion is ( 2 513 ± 54) Ma( n= 8), suggesting that the basement of the North China craton should exist in the research area. The high-Mg diorites are characterized by enrichment in MgO, Na20, and light rare earth elements (LREE), and they are poor in heavy rare earth elements (HREE) and high field strength elements (HFSE), being similar to adakite. The existence of the mantle peridotite xenoliths with a high-Mg feature for these intrusive rocks implies that their primary magma should be derived from the upper mantle. However, Sr-Nd isotopic composi- tions (Is: 0.704 75--0.707 15;ENd (130 Ma) values: --3.95 to -- 13.30), depletion in HFSE, and the occurrence of Archean inherited zircons suggest that crustal materials could be involved in the derivation of the primary magma. The compositional difference between the diorites from the Tietonggou and Jinling intrusions could be attributed to those of magma sources and degrees of partial melting. The Early Cretaceous high-Mg diorites are considered to have been formed by the mixed melting of the delaminated lithosphere (lithospheric mantle + crust) and asthenosphere, based on their geochemistry, the mantlederived xenoliths, and the Early Mesozoic lithospheric evolutionary history of the eastern North China craton. 展开更多
关键词 high-mg diorite CHRONOLOGY get chemistry MESOZOIC western Shandong.
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Rare Earths, Trace Element Characteristics of High-Mg Volcanic Rocks of Yixian Formation in Sihetun West Liaoning Province and Its Apocalypse 被引量:3
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作者 张宏 张旗 《Journal of Rare Earths》 SCIE EI CAS CSCD 2005年第4期502-506,共5页
The high-Mg volcanic rocks of the Yixian Formation in the Sihetun area have the obvious characteristics of mantie-derived lava in rare earth, trace element characteristics with high Mg # (62 - 70) and high content o... The high-Mg volcanic rocks of the Yixian Formation in the Sihetun area have the obvious characteristics of mantie-derived lava in rare earth, trace element characteristics with high Mg # (62 - 70) and high content of compatible elements. In the meantime, the volcanic rocks also have the obvious characteristics of Crust-source material in rare earth, trace element characteristics with high ∑ REE ( 158.78 × 10^-6 - 359.66 × 10^-6 ), high (La/Yb) N ( 14.61 - 29.60), high La/Nb(2.37 - 7.52) and high Ba/Nb (67.58- 205.96), obvious positive anomaly of Pb and negative anomaly of Nb, Ta in trace element spider-gram. In Sr-Nd-Pb isotope the (^87Sr/^86Sr)i ratio is higher than 0.706 and the εNd( t ) ratio is from - 3.4 to - 13, both reflect enriched Mantle characteristics. The characteristics above of the volcanic rocks combined with the content of Sr, Ba, Y, Yb and the ratio of Sr/Y show that the volcanic rocks have the property of the Sanukite rocks in Setouchi Japan beside subduction zone, and illuminate that the Sanukite rocks can be formed not only in island-arc near subduction zone but also in intro-plate. The analysis indicates that the high-Mg volcanic rocks in the Sihetun area result from the collective function of mantle-derived lava and crust-source materials. The result illuminates that the West Liaoning region is very special in tectonic geochemical background in Cretaceous in East China, and is an ideal region for us to further study the characteristics of magmatic activity as well as the process of Crust-Mantle interaction in Eastern China. 展开更多
关键词 Sanukite trace element characteristics high-mg volcanic rocks Yixian Formation Sihetun rare earths
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Geochemistry and Geochronology of the High-Mg Gabbro Dykes from Quanji Massif: Implications for the Amalgamation of Tarim Block in NW China and Assembly of the Rodinia Supercontinent
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作者 LIAO Fanxi CHEN Nengsong +3 位作者 M.Santosh SUN Min WANG Qinyan XU Yixian 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第S1期104-105,共2页
The Tarim Craton is one of the major continental blocks in China.Mafic dykes,ultra-mafic–mafic–carbonatite complex and ultra-mafic–mafic pluton of 0.82–0.75 Ga widely occur in Kuluktage,Aksu and Tieklik area along
关键词 high-mg gabbro dykes Geochemistry and geochronology Double-sided subduction Northwest China Supercontinent Rodinia
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Discovery and Geological Significance of Early Carboniferous High-Mg Diorite in the Balikun Area, Eastern Tianshan
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作者 LUO Jinglan WANG Chong 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2020年第S01期39-39,共1页
The granodiorites,monzogranites and diorites are widely developed in the Balikun area of Eastern Tianshan Orogen.Of which,LA–ICP–MS zircon U-Pb isotopic dating from the diorites revealed that they were emplaced at 3... The granodiorites,monzogranites and diorites are widely developed in the Balikun area of Eastern Tianshan Orogen.Of which,LA–ICP–MS zircon U-Pb isotopic dating from the diorites revealed that they were emplaced at 327~333 Ma,representing an important period of magmatism in the Early Carboniferous.Geochemically,they are characterized by moderate SiO2(51.33–62.48 wt%),high but variable MgO(2.04–11.16 wt%,average 5.35),higher Mg#(40–73)and TiO2(0.67–1.29 wt%),Na2O/K2O(1.39–2.95)as well as variable Cr(2.49–675 ppm)and Ni(1.31–174 ppm),showing a geochemistry similar to those of high-Mg diorites or sanukitoids.In addition,they are enriched in the LILE,poor HFSE with an evident negative Nb anomalies and a REE pattern of moderate fractionator between LREE and HREE without or weak negative Eu anomalies.TheirεHf(t)are positive(+3.63–+15.65),suggesting a source from the depleted mantle.In addition,they have high TiO2 and Pb,and large quantity of amphibolite and biotite,indicating that they were most likely derived from the partial melting of depleted mantle metasomatized by the slabderived melt under a hydrous condition.Consequently,combined with the contemporary volcanics and granitoids formed in the island arc settings,we proposed that the subduction was continued till Early Carboniferous in the Bogda-Harlik tectonic belt.After that,wide occurrence of the post-collisional A-type granites and mafic-ultramafic intrusions indicate this tectonic belt entered the post-collisional environment from Late Carboniferous to Permian. 展开更多
关键词 high-mg diorites U-Pb dating GEOCHEMISTRY PETROGENESIS Balikun area in eastern Tianshan
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Petrogenesis and Tectonic Significance of An Early Paleoproterozoic High-Mg Boninite-Norite-Diorite Suite of Rocks from the Bastar Craton, Central India
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作者 Rajesh K.Srivastava Gulab C.Gautam 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第S1期116-,共1页
Mafic/ultramafic rocks derived from high siliceous(high-Si)high magnesium(high-Mg)mantle melts are an important feature observed during early Precambrian.They provide much important geological and petrological
关键词 high Si Petrogenesis and Tectonic Significance of An Early Paleoproterozoic high-mg Boninite-Norite-Diorite Suite of Rocks from the Bastar Craton Central India
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Zircon U-Pb age,geochemical and Nd isotopic data of Middle Jurassic high-Mg dioritic dike in Liaodong Peninsula,NE China 被引量:3
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作者 LI Zhuang PEI Fuping MENG En 《Global Geology》 2014年第3期143-154,共12页
Zircon LA-ICP-MS U-Pb age,geochemical and Nd isotopic data are presented for a newly recognized high-Mg dioritic dike from Haicheng,Liaodong Peninsula,NE China,to constrain its petrogenesis. The zircons from the high-... Zircon LA-ICP-MS U-Pb age,geochemical and Nd isotopic data are presented for a newly recognized high-Mg dioritic dike from Haicheng,Liaodong Peninsula,NE China,to constrain its petrogenesis. The zircons from the high-Mg diorite exhibit striped absorption and oscillatory growth zoning in the cathodoluminescence( CL) images,and have high Th/U ratios( 0. 05--0. 9),indicating a magma origin. Zircon LA-ICP-MS U-Pb dating indicates that206 Pb /238 U ages of 12 spots of zircons are between 167 Ma and 178 Ma,yielding a weighted mean206 Pb /238 U age of 172 ± 2 Ma( MSWD = 4. 1),which represents the forming age of the high-Mg dioritic dike,i. e. Middle Jurassic. Geochemically,the samples have SiO2= 55. 4--60. 6 wt. %,Na2 O = 2. 2--2. 76 wt. %,K2 O = 1. 32--2. 02 wt. % and( Na2 O + K2O) = 3. 82--4. 47 wt. %,belonging to sub-alkaline series and displaying a calc-alkaline evolutionary trend. They are characterized by high MgO( 4. 75--6. 85 wt. %),Mg#( 55--61),Cr( 130--262 ppm),Ni( 63--130 ppm),Sr( 568--857 ppm),and Ba( 484--1 130 ppm) contents,with geochemical features analogous to those of high-Mg adakites. They show variable εNd( t) values(-1. 3 to- 3. 9),with a weighted value of- 2. 7,which plot intermediately between the field of the ancient continental crust and the depleted mantle source,indicating that both the lower crust and mantle source are necessary for the generation of the parent magma of the Haicheng high-Mg diorites. The Haicheng high-Mg dioritic dike in the Liaodong Peninsula and the Jurassic magmatism in the eastern North China Craton formed under a continental crustal thickening setting that may be related to subduction of the Paleo-Pacific oceanic plate. 展开更多
关键词 锆石U-Pb年龄 ND同位素 闪长岩脉 辽东半岛 地球化学 中侏罗世 高镁 中国
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Boninitic geochemical characteristics of high-Mg mafic dykes from the Singhbhum Granitoid Complex,Eastern India
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作者 Akhtar R.Mir Shabber H.Alvi V.Balaram 《Chinese Journal Of Geochemistry》 EI CAS CSCD 2015年第2期241-251,共11页
The high-Mg mafic dykes from the Singhbhum Granitoid Complex in East India have geochemical characteristics[e.g.,enrichment of the large ion lithophile elements and light rare earth elements(LREEs) relative to high fi... The high-Mg mafic dykes from the Singhbhum Granitoid Complex in East India have geochemical characteristics[e.g.,enrichment of the large ion lithophile elements and light rare earth elements(LREEs) relative to high field strength elements(HFSEs):high-MgO(>8%),high-SiO_2(>52%),low-TiO_2(<0.5%),and high CaO/Al_2O_3(>0.58)]similar to those found in boninitic/noritic rocks.Their high percentage of orthopyroxene as a mafic mineral and of plagioclase as a felsic mineral,and normative hypersthene content greater than diopside content are also indications of their boninitic/noritic affinity.On a triangular diagram of MgO-CaO-Al_2O_3 and on binary diagrams of Ti/V vs Ti/Sc and TiO_2 vs Zr,these samples show geochemical similarities with Phanerozoic boninites and Paleoproterozoic high-Mg norites.On major and trace element variation diagrams,these dykes show a normal crystallization trend and their Nb/La(<0.5) and Nb/Ce(<0.21) values lower than average bulk crust(0.69 and0.33,respectively) suggest no crustal contamination.Their low values of Rb/Sr(0.11-0.41) and Rb/Ba(0.10-0.27)also suggest little or no effect of post magmatic processes.Their TiO_2(0.27-0.50),Al_2O_3/TiO_2(19.30-42.48),CaO/TiO_2(12.96-32.52),and Ti/V(12-18) values indicate derivation from a depleted mantle source under oxidizing conditions such as a mantle wedge.Ni vs Zr modeling shows that the studied high-Mg dykes were generated by25-30%melting of a refractory mantle source.Enrichment of Rb,Th,U,Pb,Sr,and LREEs,and depletion of HFSEs—especially Nb,P,Ti,Zr—on primitive mantle—and chondrite-normalized spider diagrams,respectively,are clear signals that the slab-derived component played an important role in the formation of melts for these rocks in a supra-subduction zone setting. 展开更多
关键词 地球化学特征 镁铁质 花岗岩 高镁 印度 轻稀土元素 二氧化钛 大楼
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Petrogenesis of high-Mg# Cenozoic volcanic rocks of southern Qiangtang area, Tibetan Plateau: geochemical and Sr-Nd isotopic evidence
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作者 FAN Lefu CHI Xiaoguo +3 位作者 LIU Jianfeng ZHANG Rui WANG Limin SUN Wei 《Global Geology》 2015年第3期174-182,共9页
The Nadingcuo volcanic rock suite is the most voluminous Cenozoic volcanic suite in the southern Qiangtang area of the northern Tibetan Plateau. These high-K calc-alkaline volcanic rocks were formed between36 and 34 M... The Nadingcuo volcanic rock suite is the most voluminous Cenozoic volcanic suite in the southern Qiangtang area of the northern Tibetan Plateau. These high-K calc-alkaline volcanic rocks were formed between36 and 34 Ma,characterized by high Mg#values,high concentrations of Ti O2 and P2O5,87 Sr /86 Sr ratios of0. 704682--0. 706 112,and εNd( t) values of- 1. 2 to 1. 6. There is a lack of reasonable explanations for sourcing and origin of magmas that formed the rocks with high Mg#values and Ti O2 and P2O5enrichments,which makes the previous research results still controversial. This study reviews the geochemical characteristics of Nadingcuo volcanic rocks and the data we have newly found in our fieldwork. We give some new interpretation to the magmatic evolution of the basaltic magmas in the discussed area dominated by fractional crystallization.The geochemistry of trachyandesite and trachyte units in the studied area is indicative of formation from mantlederived magmas that mixed with crustal materials. The high values of Mg#and Ti O2 and P2O5enrichment in these units are evident to show the mixing between mantle-derived magmas with ~ 30--40 wt.% rhyolitic melt or assimilation of a similar amount of felsic rocks. The geochemistry of basaltic rocks in the area also suggests that the Nadingcuo basalts may have been derived from an ocean island basalt( OIB)-type source that contained and was mixed with ancient mantle wedge derived material,indicating that a 36--34 Ma asthenospheric upwelling event in the Qiangtang area may relate to the northward subduction of Indian lithospheric mantle and the southward subduction of Asian lithospheric mantle. This upwelling of asthenospheric material was centered in the southern Qiangtang area between 36 and 34 Ma,while the northward movement of the Indian Craton caused this upwelling mantle flow to continuously migrate northward,resulting in the current centering of this upwelling in the Hoh Xil-Kunlun region. 展开更多
关键词 新生代火山岩 地球化学特征 羌塘地区 SR-ND同位素 高镁 青藏高原 洋岛玄武岩 长英质岩石
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吉林红旗岭晚三叠世镁铁超镁铁质侵入体矿物化学和岩石地球化学特征:对镍铜成矿的启示
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作者 王建 杨言辰 +1 位作者 李爱 袁海齐 《地学前缘》 EI CAS CSCD 北大核心 2024年第2期249-269,共21页
吉林红旗岭镁铁超镁铁质侵入岩群位于中亚造山带东段南缘,由3个北西向岩带(I、II、III)组成,包括30多个小岩株,其中I-岩带的部分岩体伴有铜镍矿化,并且其1和7号岩体分别形成了中型和大型岩浆铜镍硫化物型矿床。矿床主要容矿岩石为辉橄... 吉林红旗岭镁铁超镁铁质侵入岩群位于中亚造山带东段南缘,由3个北西向岩带(I、II、III)组成,包括30多个小岩株,其中I-岩带的部分岩体伴有铜镍矿化,并且其1和7号岩体分别形成了中型和大型岩浆铜镍硫化物型矿床。矿床主要容矿岩石为辉橄岩、橄辉岩、斜方辉石岩、二辉石岩、苏长岩和辉长岩。主量元素方面,红旗岭岩群具有富镁(w(MgO)=20.7%~31.1%)、低钛(w(TiO_(2))=0.33%~0.79%)、低碱(w(K 2 O+Na 2 O)=0.60%~2.29%)和硅(w(SiO_(2))=40.0%~53.0%)变化范围大的特征;微量元素方面,红旗岭岩群呈现弱富集LREE和LILE(Th)以及亏损HREE和HFSE(Nb-Ta-Ti)。岩相学、地球化学和矿物(橄榄石、斜方辉石、单斜辉石、尖晶石、斜长石和角闪石)主微量元素特征表明,红旗岭岩群明显不同于洋岛型玄武岩、阿拉斯加型环状杂岩和科马提岩,但与岛弧玄武岩以及中亚造山带西段的“黄山西”和“黄山东”铜镍硫化物矿床的容矿超镁铁质岩相似,其母岩浆是一种富Mg、亏损Nb-Ta的岛弧拉斑玄武质熔体,形成于晚三叠世古亚洲洋闭合后伸展环境,演化过程中经历了地壳混染和分离结晶作用,含矿母岩浆可能经历了硫化物的“二次熔离”,最终形成了铂族元素(PGE)亏损型岩浆铜镍硫化物矿床。 展开更多
关键词 岩浆铜镍硫化物矿床 高镁拉斑玄武质母岩浆 硫化物熔离 铂族元素亏损 碰撞后伸展环境 红旗岭 中亚造山带
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高钙镁钛精矿沸腾氯化制备TiCl_(4)的热力学及动力学
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作者 朱福兴 马占山 +3 位作者 陈爱祥 李良 黄志鹏 彭卫星 《有色金属(冶炼部分)》 CAS 北大核心 2024年第6期42-52,共11页
针对高钙镁钛精矿难以满足沸腾氯化制备四氯化钛工艺问题,从热力学和动力学角度对高钙镁钛原料碳热还原—沸腾氯化制备TiCl_(4)工艺进行了深入研究。结果表明:钛精矿高温碳热还原历程为:FeTiO_(3)→TiO_(2)+Fe→Ti_(n)O_(2) n-1(n=4~9)... 针对高钙镁钛精矿难以满足沸腾氯化制备四氯化钛工艺问题,从热力学和动力学角度对高钙镁钛原料碳热还原—沸腾氯化制备TiCl_(4)工艺进行了深入研究。结果表明:钛精矿高温碳热还原历程为:FeTiO_(3)→TiO_(2)+Fe→Ti_(n)O_(2) n-1(n=4~9)+Fe→Ti_(3)O_(5)+Fe→Ti_(2)O_(3)+Fe→TiC_(x)O_(1-x)+Fe,碳氧钛生成的温度必须高于1400℃,此时钛精矿中的Ca、Mg、Al、Si、Mn等杂质元素在1800℃以内都不会被还原为对应的碳化物;高钙镁钛铁矿精矿碳热还原制备碳氧钛过程中,失重率随温度升高呈现4阶段上升,其中阶段1和3分别为受扩散控制生成金属Fe和碳氧钛的快速失重段,而阶段2和4分别为金属Fe和碳氧钛形核长大的缓慢失重阶段,4个阶段的表观活化能分别为49.84、-2.24、12.82、-2.53 kJ mol。沸腾氯化过程还原产物中的Fe、MgO和CaO均会优先被氯气氯化,但当存在TiO_(2)时,SiO_(2)和Al_(2)O_(3)则不易被氯化,碳氧钛较适宜沸腾氯化的温度为300~650℃,沸腾氯化前5分钟为还原产物中碳氧钛的快速氯化阶段,主要受表面化学反应的控制,而后5~20分钟为Ti_(2)O_(3)的缓慢氯化阶段,主要受颗粒内部扩散控制的影响。 展开更多
关键词 高钙镁钛精矿 沸腾氯化 四氯化钛 碳氧钛
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高温高压实验揭示俯冲带蛇纹岩熔融行为与高镁岩浆成因
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作者 胡佳森 张国良 《海洋地质与第四纪地质》 CAS CSCD 北大核心 2024年第2期157-170,共14页
近年来一些研究在岛弧岩浆中发现了蛇纹岩组分,这表明俯冲至弧下的蛇纹岩不仅为地幔楔提供流体,而且可以通过部分熔融参与岛弧岩浆形成。然而,蛇纹岩在地幔楔中的熔融行为及其在俯冲带物质循环中的作用仍未进行深入研究。因此,本研究选... 近年来一些研究在岛弧岩浆中发现了蛇纹岩组分,这表明俯冲至弧下的蛇纹岩不仅为地幔楔提供流体,而且可以通过部分熔融参与岛弧岩浆形成。然而,蛇纹岩在地幔楔中的熔融行为及其在俯冲带物质循环中的作用仍未进行深入研究。因此,本研究选择3种蛇纹岩样品:蚀变原岩分别为二辉橄榄岩(SE2)和方辉橄榄岩(SE3)的天然蛇纹岩,以及模拟含有大量滑石的合成蛇纹岩样品(SEQ),在700~1300℃和4 GPa的温度压力条件下进行了模拟实验,限定了蛇纹岩的熔融温度,分析了实验产生的熔体成分。研究发现,不同类型蛇纹岩的固相线存在显著差异,SE3、SEQ和SE2蛇纹岩的固相线分别为900~960℃、960~1100℃以及1150~1200℃。这3种蛇纹岩的固相线均高于俯冲板片上表面的温度,要求蛇纹岩通过底辟作用进入地幔楔以发生部分熔融。根据实验结果,本研究认为SE2和SEQ蛇纹岩可以在地幔楔底部相对较低的温度条件下(960~1100℃)即发生熔融,产生科马提质岩浆;而在上覆地幔楔更高温度条件下(>1200℃),SE2蛇纹岩可以发生更广泛、更高程度的部分熔融,产生玻安质岩浆。 展开更多
关键词 蛇纹岩 俯冲带 高温高压实验 高镁岩浆 科马提岩
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Geochemistry of high-Mg andesites from the early Cretaceous Yixian Formation, western Liaoning: Implications for lower crustal delamination and Sr/Y variations 被引量:19
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作者 WANG Xiaorui1, GAO Shan1,2, LIU Xiaoming1, YUAN Honglin1, HU Zhaochu1, ZHANG Hong1,3 & WANG Xuance4 1. State Key Laboratory of Continental Dynamics, Department of Geology, Northwest University, Xi`an 710069, China 2. State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan 430074, China +1 位作者 3. Shenyang Institute of Geology and Mineral Resources, Shenyang 110032, China 4. Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China 《Science China Earth Sciences》 SCIE EI CAS 2006年第9期904-914,共11页
85 volcanic rocks of the Yixian Formation from the Sihetun type section were collected and analyzed for geochemical and isotopic compositions. Major element compositions indicate that the Sihetun volcanic rocks are hi... 85 volcanic rocks of the Yixian Formation from the Sihetun type section were collected and analyzed for geochemical and isotopic compositions. Major element compositions indicate that the Sihetun volcanic rocks are high magnesium andesites with some basalts occurring at the bottom of section. The Sihetun high magnesium andesites (SiO2 = 52.82―59.31wt%, Al2O3 = 14.15―16.35wt%) show many characteristics of adakites such as depletion in heavy rare-earth elements (HREE; Yb = 1.03―1.88 μg/g) and Y(12―20 μg/g) and high Sr (620―1323 μg/g) and Sr/Y(32―88), with high LaN/YbN ratio (10―25). They share similar major and trace element characteristics to volcanic rocks from the Xinglonggou Formation except their lower Nd isotope ratios (143Nd/144Nd (130Ma) = 0.5118―0.5119, ε Nd (130Ma) = ?11.6―?13.8, 87Sr/86Sr (130 Ma) = 0.7058―0.7064. They were in- terpreted in a way that eclogite that formed at the base of thickened Archean lower crust of the North China craton foundered into the convecting mantle and subsequently melted and interacted with peridotite. However, compared to the Xinglonggou volcanic rocks, the source of the Sihetun magma contained more ancient continental crustal material in order to explain its evolved Nd isotopes. The age of the Sihetun Formation was 120 to 130 Ma, and this indicates that delamination lasted to the early Cretaceous period. The Sr contents and Sr/Y ratios of the Sihetun high-Mg andesites show sig- nificant negative correlations with SiO2 for samples with SiO2 > 56%. These suggest that the Sr and Sr/Y values were reduced due to fractional crystallization of plagioclase. Accordingly, the effect of crystallization on volcanic Sr and Sr/Y ratio has to be taken into account. 展开更多
关键词 high-mg andesite Adakite YIXIAN Formation North China Craton delamination.
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高镁磷尾矿作为矿物掺合料应用于混凝土性能研究
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作者 姜立龙 李剑秋 +1 位作者 杨林 张庆刚 《无机盐工业》 CAS CSCD 北大核心 2024年第1期90-95,共6页
高镁磷尾矿是磷矿反浮选过程产生的固体废弃物,主要矿物相为白云石、少量氟磷灰石和石英。将磷尾矿烘干粉磨后制成磷尾矿粉,分析了磷尾矿粉粒径分布、毒害性,参照GB/T51003—2014《矿物掺合料应用技术规范》测定了磷尾矿粉相关性能指标... 高镁磷尾矿是磷矿反浮选过程产生的固体废弃物,主要矿物相为白云石、少量氟磷灰石和石英。将磷尾矿烘干粉磨后制成磷尾矿粉,分析了磷尾矿粉粒径分布、毒害性,参照GB/T51003—2014《矿物掺合料应用技术规范》测定了磷尾矿粉相关性能指标。以水泥、磷尾矿粉、粉煤灰为凝胶材料,制备了不同强度等级C30、C40、C50及C60混凝土,测定了混凝土工作性能、力学性能,并分析了掺磷尾矿粉水泥浆不同水化龄期的矿物组成。结果表明,经过烘干粉磨后,磷尾矿粒径D_(90)由133.1μm降至63.4μm,烧失量为39%、28d活性指数为70%、亚甲蓝值小于1.4、流动度比大于100%。当磷尾矿粉占总凝胶材料10%时配制的C60混凝土,坍落度为230mm、28d强度为64.1MPa、90 d强度为78.6 MPa;在养护龄期为90 d时,磷尾矿粉水泥硬化体中出现新矿物相水滑石,有利于混凝土后期强度增长。磷尾矿粉可作为矿物掺合料用于制备混凝土。 展开更多
关键词 高镁磷尾矿 矿物掺合料 混凝土 毒害 水化产物
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FeCoNiCrCu高熵合金涂层对复合铸造Al/Mg双金属组织和性能的影响
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作者 徐远财 蒋文明 +3 位作者 李庆晴 牛言清 余令辉 樊自田 《精密成形工程》 北大核心 2024年第3期115-122,共8页
目的研究不同厚度的FeCoNiCrCu高熵合金涂层对Al/Mg双金属组织和力学性能的影响。方法通过超音速火焰喷涂工艺在A356嵌体表面喷涂不同厚度的FeCoNiCrCu高熵合金涂层,采用消失模复合铸造工艺制备Al/Mg双金属,利用扫描电镜、EDS能谱及XRD... 目的研究不同厚度的FeCoNiCrCu高熵合金涂层对Al/Mg双金属组织和力学性能的影响。方法通过超音速火焰喷涂工艺在A356嵌体表面喷涂不同厚度的FeCoNiCrCu高熵合金涂层,采用消失模复合铸造工艺制备Al/Mg双金属,利用扫描电镜、EDS能谱及XRD衍射仪、维氏硬度测试仪和万能试验机对Al/Mg双金属界面微观组织和力学性能进行测试和分析。结果未喷涂高熵合金涂层的Al/Mg双金属界面由共晶层和金属间化合物层组成,断裂位置主要位于金属间化合物层,裂纹从Al_(3)Mg_(2)扩展至共晶层结束,具有典型的脆性断裂特征,剪切强度仅为30.37MPa。当高熵合金涂层厚度为5μm时,Al/Mg双金属形成了Al_(3)Mg_(2)+Mg_(2)Si/AlxFeCoNiCrCu+FeCoNiCrCu+Al-Mg-Co-Ni混合相/δ-Mg+Al_(12)Mg_(17)共晶组织的复杂界面,断裂发生在高熵合金层与δ-Mg+Al_(12)Mg_(17)共晶组织的交界处,断裂面产生了一定程度的塑性变形,剪切强度为48.46MPa,相对于无涂层的Al/Mg双金属提高了59.56%。当高熵合金涂层厚度为20μm时,铝侧生成了AlxFeCoNiCrCu高熵合金,镁侧则只生成了少量Mg-Ni-Cu混合相,断裂发生在高熵合金涂层与镁基体交界处,剪切强度为39.69 MPa。结论高熵合金涂层可以有效阻碍Al、Mg元素之间的扩散,从而显著抑制或完全阻止Al-Mg脆性金属间化合物的产生,大幅度降低界面层厚度。金属间化合物的减少和混合相对裂纹扩展的阻碍作用显著提高了Al/Mg双金属界面的剪切强度。 展开更多
关键词 FeCoNiCrCu高熵合金涂层 Al/Mg双金属 超音速火焰喷涂 复合铸造 微观组织 力学性能
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主元素改变对Al-8Mg-xSi合金微观组织和力学性能的影响
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作者 朱清越 《世界有色金属》 2024年第4期87-89,共3页
本文在高镁铝合金的基础上设计了一系列成分,研究了Si含量对Al-8Mg-xSi合金显微组织和力学性能的影响。研究结果表明:随着Si含量的增加,晶界轮廓逐渐清晰,Mg_2Si强化相体积分数增加。当Si含量为2.6wt.%时合金的综合力学性能最佳,硬度、... 本文在高镁铝合金的基础上设计了一系列成分,研究了Si含量对Al-8Mg-xSi合金显微组织和力学性能的影响。研究结果表明:随着Si含量的增加,晶界轮廓逐渐清晰,Mg_2Si强化相体积分数增加。当Si含量为2.6wt.%时合金的综合力学性能最佳,硬度、抗拉强度和屈服强度分别达到了93.1、254.9MPa和232.5MPa,比添加1wt.%Si的合金分别提升了7.4、37.7MPa和26MPa。其中,断裂机制由混合断裂转变为脆性断裂。 展开更多
关键词 AL-MG-SI合金 高镁铝合金 微观组织 力学性能
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超高强铝合金研究进展与发展趋势
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作者 邢清源 臧金鑫 +2 位作者 陈军洲 杨守杰 戴圣龙 《航空材料学报》 CAS CSCD 北大核心 2024年第2期60-71,共12页
超高强铝合金具有密度低、比强度高等特点,广泛应用于航空、航天、核工业等领域。合金的极限强度已从第四代铝合金的600 MPa级,逐步发展到650~700 MPa级、750 MPa级,甚至800 MPa级及以上第五代铝合金。本文首先对超高强铝合金的发展历... 超高强铝合金具有密度低、比强度高等特点,广泛应用于航空、航天、核工业等领域。合金的极限强度已从第四代铝合金的600 MPa级,逐步发展到650~700 MPa级、750 MPa级,甚至800 MPa级及以上第五代铝合金。本文首先对超高强铝合金的发展历程和国内外发展现状进行概述;随后,从成分设计与优化、熔铸与均匀化技术、热变形技术、热处理技术、计算机辅助模拟计算共五个方面对近些年的研究进展和所遇到的问题进行了总结和讨论;最后,结合未来装备的发展需求和国内的技术现状,指出“深入研究基础理论,解决综合性能匹配等问题以及在特定应用场景下专用材料的推广应用”是超高强铝合金的发展趋势和重要方向。 展开更多
关键词 超高强铝合金 AL-ZN-MG-CU系合金 熔铸法 高合金化
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具有蜂窝薄片状高比表面积氢氧化镁的制备
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作者 郭彦彦 赵飒 《盐科学与化工》 CAS 2024年第4期30-34,共5页
文章以普通氢氧化镁为原料,采用溶剂热法,考察了水溶剂和非水溶剂对氢氧化镁热处理结果的影响。采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)和低温氮气吸附比表面积测定仪对氢氧化镁的形貌和晶体结构进行了表征。结果表明,以15 mL正丁... 文章以普通氢氧化镁为原料,采用溶剂热法,考察了水溶剂和非水溶剂对氢氧化镁热处理结果的影响。采用扫描电子显微镜(SEM)、X射线衍射仪(XRD)和低温氮气吸附比表面积测定仪对氢氧化镁的形貌和晶体结构进行了表征。结果表明,以15 mL正丁醇为溶剂,4 g氢氧化钠为矿化剂,加1 g氢氧化镁干粉,在150℃下维持5 h,制备出了蜂窝状有序排列的薄片氢氧化镁,比表面积高达108.13 m^(2)/g。以正丙醇和异丙醇为溶剂也可得到同样的氢氧化镁产品,所得产品比表面积分别为140.65 m^(2)/g和139.04 m^(2)/g。 展开更多
关键词 氢氧化镁 高比表面积 正丁醇
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工业试验Mg脱氧HSLA钢CGHAZ的夹杂物、组织及韧性的特征分析
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作者 杜海龙 张银辉 +2 位作者 杨健 张宇 张玉旗 《炼钢》 CAS 北大核心 2024年第2期89-94,共6页
Mg作为第三代氧化物冶金技术的关键脱氧剂有助于提升高强度低合金钢(HSLA)的组织韧性。利用夹杂物自动分析系统、金相显微镜、焊接热模拟试验机等研究了Mg脱氧对HSLA钢粗晶热影响区(CGHAZ)夹杂物、组织以及低温冲击韧性的影响。结果表明... Mg作为第三代氧化物冶金技术的关键脱氧剂有助于提升高强度低合金钢(HSLA)的组织韧性。利用夹杂物自动分析系统、金相显微镜、焊接热模拟试验机等研究了Mg脱氧对HSLA钢粗晶热影响区(CGHAZ)夹杂物、组织以及低温冲击韧性的影响。结果表明,在200 kJ/cm的大线能量焊接条件下,Mg脱氧钢CGHAZ中生成了大量Mg-Ti-Mn-S夹杂物,由于这种类型的夹杂物可以促进针状铁素体(IAF)组织的形成,所以在200 kJ/cm大线能量焊接后,Mg脱氧钢CGHAZ低温冲击韧性优异,-20℃冲击功为204 J,断裂方式为韧性断裂。本研究成果可为提高大线能量焊接厚板钢组织性能提供理论与试验依据。 展开更多
关键词 HSLA钢 Mg脱氧 大线能量焊接 焊接热影响区 低温冲击韧性
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Ca-Mg-Al-Si系高性能泡沫陶瓷的制备
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作者 董明堂 戚芳 +2 位作者 刘方波 唐紫娟 梁健 《中国陶瓷》 CAS CSCD 北大核心 2024年第2期36-44,共9页
通过对钢渣和菱镁矿配方组成的优化,采用高温发泡法制备的兼具高强度和低热导率的Ca-Mg-Al-Si系高性能泡沫陶瓷,其主要原料为红柱石与粉砂质页岩,发泡剂为碳化硅,助熔剂为锂辉石。在测试其气孔率,体积密度与抗折强度等性能的同时,也使用... 通过对钢渣和菱镁矿配方组成的优化,采用高温发泡法制备的兼具高强度和低热导率的Ca-Mg-Al-Si系高性能泡沫陶瓷,其主要原料为红柱石与粉砂质页岩,发泡剂为碳化硅,助熔剂为锂辉石。在测试其气孔率,体积密度与抗折强度等性能的同时,也使用Micro-CT、SEM、XRD、XRF等检测手段对泡沫陶瓷进行了表征。实验结果显示:当样品中加入11 wt%钢渣,7 wt%菱镁矿时综合性能最佳,此时抗折强度为11.15 MPa,热导率为0.091W/(m·K),总气孔率为61.02%,闭口气孔率为55.30%,体积密度为0.944 g/cm^(3)。 展开更多
关键词 高强度 低热导率 Ca-Mg-Al-Si系 泡沫陶瓷
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不同Mo含量对Al-Mg合金轧板微观组织和短时高温力学性能的影响
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作者 韩向楠 亓海全 +5 位作者 王为民 刘阳 李天然 刘安奇 郭春城 秦翔智 《材料科学与工艺》 CAS CSCD 北大核心 2024年第3期69-77,共9页
基于高强度耐火Al-Mg合金开发需求,设计并制备了6种Mo含量(质量分数)的Al-Mg合金,经变形热处理获得H3xx态轧板,结合光学显微镜、X射线衍射仪、拉伸试验机、带有能谱仪(EDS)的蔡司扫描电镜(SEM)等表征设备对各合金轧板微观组织和短时高... 基于高强度耐火Al-Mg合金开发需求,设计并制备了6种Mo含量(质量分数)的Al-Mg合金,经变形热处理获得H3xx态轧板,结合光学显微镜、X射线衍射仪、拉伸试验机、带有能谱仪(EDS)的蔡司扫描电镜(SEM)等表征设备对各合金轧板微观组织和短时高温力学性能进行检测分析,揭示了微量Mo对Al-Mg合金的强韧化机理。结果表明:Mo合金化H3xx态Al-Mg合金具有较高的力学性能,这主要归功于与铝基体呈半共格关系的Al12Mo弥散相起到的弥散强化效果和抑制再结晶作用,但过量的Mo易使Al-Mg合金形成较高Mg固溶度的难熔Al12Mo结晶相,不利于合金性能提升。Al12Mo弥散相具有一定的高温稳定性,高温状态下显著阻碍再结晶晶粒长大,进而提高Al-Mg合金高温性能。Mo含量为0.08%时的高温性能最佳,高温强度最大提升22.5%。随着Mo含量的增加,Al-Mg合金常温力学性能和短时高温力学性能都有所提高。 展开更多
关键词 AL-MG合金 Mo合金化 显微组织 第二相 高温强度
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