The Binchuan area of Yunnan is located in the western part of the Emeishan large igneous province in the western margin of the Yangtze Block. In the present study, the Wuguiqing profile in thickness of about 1440 m is...The Binchuan area of Yunnan is located in the western part of the Emeishan large igneous province in the western margin of the Yangtze Block. In the present study, the Wuguiqing profile in thickness of about 1440 m is mainly composed of high-Ti basalts, with minor picrites in the lower part and andesites, trachytes, and rhyolites in the upper part. The picrites have relatively higher platinum- group element （PGE） contents （PGE=16.3-28.2 ppb）, with high Cu/Zr and Pd/Zr ratios, and low S contents （5.03-16.9 ppm）, indicating the parental magma is S-unsaturated and generated by high degree of partial melting of the Emeishan large igneous province （ELIP） mantle source. The slightly high Cu/Pd ratios （11 000-24 000） relative to that of the primitive mantle suggest that 0.007% sulfides have been retained in the mantle source. The PGE contents of the high-Ti basalts exhibit a wider range （~PGE=0.517-30.8 ppb）. The samples in the middle and upper parts are depleted in PGE and have ~Nd （260 Ma） ratios ranging from -2.8 to -2.2, suggesting that crustal contamination of the parental magma during ascent triggered sulfur saturation and segregation of about 0.446%-0.554% sulfides, and the sulfide segregation process may also provide the ore-forming material for the magmatic Cu-Ni-PGE sulfide deposits close to the studied basalts. The samples in this area show Pt- Pd type primitive mantle-normalized PGE patterns, and the Pd/Ir ratios are higher than that of the primitive mantle （Pd/Ir=l）, indicating that the obvious differentiation between Ir-group platinum- group elements （IPGE） and Pd-group platinum-group elements （PPGE） are mainly controlled by olivine or chromites fractionation during magma evolution. The Pd/Pt ratios of most samples are higher than the average ratio of mantle （Pd/Pt=0.55）, showing that the differentiation happened between Pt and Pd. The differentiation in picrites may be relevant to Pt hosted in discrete refractory Pt-alloy phase in the mantle; whereas the differentiation in the high-Ti basalts is probably associated with the fractionation of Fe-Pt alloys, coprecipitating with Ir-Ru-Os alloys. Some high-Ti basalt samples exhibit negative Ru anomalies, possibly due to removal of laurite collected by the early crystallized chromites.展开更多
The Altay orogenic belt of Xinjiang in NW China represents one of the important sites of juvenile crustal growth during the Phanerozoic. However, some important issues, e.g., tectonic evolution and petrogenesis, still...The Altay orogenic belt of Xinjiang in NW China represents one of the important sites of juvenile crustal growth during the Phanerozoic. However, some important issues, e.g., tectonic evolution and petrogenesis, still remain controversial. The picrites in the south margin of the Altay orogenic belt were discovered in the lower part of marine volcanic-sedimentary sequences of the northwest-striking Middle Devonian Beitashan Formation (Fm.), which consists chiefly of intermediate-basic volcanic rocks intercalated minor carbonate, siltstone and siliceous rocks. The picrites are usually highly porphyritic, and contain abundant forsteritic olivine phenocrysts with minor clinopyroxene distributed in the groundmass, which consist of olivine, clinopyroxene and plagioclase with minor Fe-Ti oxides. The MgO contents of the picrites range from 14 wt% to 22 wt% with Mg# (atomic Mg/(Mg+Fe) ratio) of 0.75-0.80. They are characterized by slightly negative Ti anomalies, remarkably negative Nb and Ta anomalies and slightly positive P and Sm anomalies with the similar abundances of HFSE as MORB on the MORB-normalized trace element patterns, all of which characterize typical island arc magmas. In combing with the southwestward migration of the magmas of the Beitashan Fm., we propose that the magmas may result from the southwestward subduction of Junggar ocean plate. The Zr/Nb ratios (23-66) of both picrites and basalts resemble the MORB (10-66), suggesting that they were derived from the MORB-like sources. However, the basalts and picrites display some distinguishable element ratios and REE patterns, e.g., Ti/V (23-35) and Zr/Sm (18-23) ratios of basalts are higher than those of picrites (14-17 and 14-15 respectively), and the basalts display flat-type REE-chondrite patterns whereas the picrites are characterized by lower total REE concentrations ((26-34)×10^-6) and slight enrichment of light REE. These distinguished geochemical characteristics could be interpreted by different partial melting degrees and mantle sources, i.e., the basalts were generated by lower partial melting of amphibole-bearing spinel peridotite which was metasomatized by fluids released from subducted oceanic crust, and the picrites were resulted from the higher degree of partial melting of metasomatized garnet peridotite under high temperature. In contrast, the andesite with significant LREE and LILE enrichment may be resulted from the partial melting of eclogites.展开更多
Magmatic Ni-Cu-(PGE) sulfide and Fe-Ti oxide deposits in plume-related large igneous provinces(LIPs)are commonly related to low-Ti and high-Ti series magmas, respectively, but the major factors that control such a rel...Magmatic Ni-Cu-(PGE) sulfide and Fe-Ti oxide deposits in plume-related large igneous provinces(LIPs)are commonly related to low-Ti and high-Ti series magmas, respectively, but the major factors that control such a relationship of metallogenic types and magma compositions are unclear. Magma fOcontrols sulfur status and relative timing of Fe-Ti oxide saturation in mafic magmas, which may help clarify this issue. Taking the Emeishan LIP as a case, we calculated the magma fOof the high-Ti and low-Ti picrites based on the olivine-spinel oxygen barometer, and the partitioning of V in olivine. The obtained fOof the high-Ti series magma(FMQ + 1.1 to FMQ + 2.6) is higher than that of the low-Ti series magma(FMQ-0.5to FMQ + 0.5). The magma fOof the high-Ti and low-Ti picrites containing Fo > 90 olivine reveals that the mantle source of the high-Ti series is likely more oxidized than that of the low-Ti series. The results using the ’lambda REE’ approach show that the high-Ti series may have been derived from relatively oxidized mantle with garnet pyroxenite component. The S contents at sulfide saturation(SCSS) of the two series magmas were calculated based on liquid compositions obtained from the alpha Melts modeling, and the results show that the low-Ti series magma could easily attain the sulfide saturation as it has low fOwith S being dominantly as S. In contrast, the oxidized high-Ti series magma is difficult to attain the sulfide saturation, but could crystallize Fe-Ti oxides at magma MgO content of ~7.0 wt.%. Thus, contrasting magma fOof low-Ti and high-Ti series in plume-related LIPs may play an important role in producing two different styles of metallogeny.展开更多
1 Introduction Santanghu Basin is located between the Armantai and Karamaili suture zone,at the junction of the Siberia,Kazakhstan and Tarim plates(Chen and Jahn,2004;Xiao et al.,2008).As an important part of the Cent...1 Introduction Santanghu Basin is located between the Armantai and Karamaili suture zone,at the junction of the Siberia,Kazakhstan and Tarim plates(Chen and Jahn,2004;Xiao et al.,2008).As an important part of the Central Asian展开更多
本文对虎跳峡苦橄岩和玄武岩及金安玄武岩的地球化学特征进行了研究。结果表明其微量元素原始地幔标准化曲线、Sr-Nd-Pb同位素比值与OIB、丽江苦橄岩相似，表现为其大离子亲石元素相对高场强元素富集，并且不存在Nb、Ta和Ti的负异常，...本文对虎跳峡苦橄岩和玄武岩及金安玄武岩的地球化学特征进行了研究。结果表明其微量元素原始地幔标准化曲线、Sr-Nd-Pb同位素比值与OIB、丽江苦橄岩相似，表现为其大离子亲石元素相对高场强元素富集，并且不存在Nb、Ta和Ti的负异常，表明岩浆在上升过程中很少受到岩石圈地幔或地壳物质的混染。利用Klein and Langmuir（1987）的方法得出虎跳峡熔岩和金安玄武岩原始岩浆MgO含量分别为15.81%~20.89%和8.06%~13.84%，其相应的地幔温度分别为1493~1611℃和1055~1474℃。所得温度略高于正常软流圈地幔温度，低于丽江仕满苦橄岩的熔融温度（1630~1680℃），推测丽江地区可能是峨眉山地幔柱的中心部位。展开更多
基金supported by the National Basic Research Program of China(No.2007CB411401)the Knowledge Innovation Program of the Chinese Academy of Sciences(No.KZCX2-YW-136)the National Natural Science Formation of China(No.40873028)
文摘The Binchuan area of Yunnan is located in the western part of the Emeishan large igneous province in the western margin of the Yangtze Block. In the present study, the Wuguiqing profile in thickness of about 1440 m is mainly composed of high-Ti basalts, with minor picrites in the lower part and andesites, trachytes, and rhyolites in the upper part. The picrites have relatively higher platinum- group element （PGE） contents （PGE=16.3-28.2 ppb）, with high Cu/Zr and Pd/Zr ratios, and low S contents （5.03-16.9 ppm）, indicating the parental magma is S-unsaturated and generated by high degree of partial melting of the Emeishan large igneous province （ELIP） mantle source. The slightly high Cu/Pd ratios （11 000-24 000） relative to that of the primitive mantle suggest that 0.007% sulfides have been retained in the mantle source. The PGE contents of the high-Ti basalts exhibit a wider range （~PGE=0.517-30.8 ppb）. The samples in the middle and upper parts are depleted in PGE and have ~Nd （260 Ma） ratios ranging from -2.8 to -2.2, suggesting that crustal contamination of the parental magma during ascent triggered sulfur saturation and segregation of about 0.446%-0.554% sulfides, and the sulfide segregation process may also provide the ore-forming material for the magmatic Cu-Ni-PGE sulfide deposits close to the studied basalts. The samples in this area show Pt- Pd type primitive mantle-normalized PGE patterns, and the Pd/Ir ratios are higher than that of the primitive mantle （Pd/Ir=l）, indicating that the obvious differentiation between Ir-group platinum- group elements （IPGE） and Pd-group platinum-group elements （PPGE） are mainly controlled by olivine or chromites fractionation during magma evolution. The Pd/Pt ratios of most samples are higher than the average ratio of mantle （Pd/Pt=0.55）, showing that the differentiation happened between Pt and Pd. The differentiation in picrites may be relevant to Pt hosted in discrete refractory Pt-alloy phase in the mantle; whereas the differentiation in the high-Ti basalts is probably associated with the fractionation of Fe-Pt alloys, coprecipitating with Ir-Ru-Os alloys. Some high-Ti basalt samples exhibit negative Ru anomalies, possibly due to removal of laurite collected by the early crystallized chromites.
文摘The Altay orogenic belt of Xinjiang in NW China represents one of the important sites of juvenile crustal growth during the Phanerozoic. However, some important issues, e.g., tectonic evolution and petrogenesis, still remain controversial. The picrites in the south margin of the Altay orogenic belt were discovered in the lower part of marine volcanic-sedimentary sequences of the northwest-striking Middle Devonian Beitashan Formation (Fm.), which consists chiefly of intermediate-basic volcanic rocks intercalated minor carbonate, siltstone and siliceous rocks. The picrites are usually highly porphyritic, and contain abundant forsteritic olivine phenocrysts with minor clinopyroxene distributed in the groundmass, which consist of olivine, clinopyroxene and plagioclase with minor Fe-Ti oxides. The MgO contents of the picrites range from 14 wt% to 22 wt% with Mg# (atomic Mg/(Mg+Fe) ratio) of 0.75-0.80. They are characterized by slightly negative Ti anomalies, remarkably negative Nb and Ta anomalies and slightly positive P and Sm anomalies with the similar abundances of HFSE as MORB on the MORB-normalized trace element patterns, all of which characterize typical island arc magmas. In combing with the southwestward migration of the magmas of the Beitashan Fm., we propose that the magmas may result from the southwestward subduction of Junggar ocean plate. The Zr/Nb ratios (23-66) of both picrites and basalts resemble the MORB (10-66), suggesting that they were derived from the MORB-like sources. However, the basalts and picrites display some distinguishable element ratios and REE patterns, e.g., Ti/V (23-35) and Zr/Sm (18-23) ratios of basalts are higher than those of picrites (14-17 and 14-15 respectively), and the basalts display flat-type REE-chondrite patterns whereas the picrites are characterized by lower total REE concentrations ((26-34)×10^-6) and slight enrichment of light REE. These distinguished geochemical characteristics could be interpreted by different partial melting degrees and mantle sources, i.e., the basalts were generated by lower partial melting of amphibole-bearing spinel peridotite which was metasomatized by fluids released from subducted oceanic crust, and the picrites were resulted from the higher degree of partial melting of metasomatized garnet peridotite under high temperature. In contrast, the andesite with significant LREE and LILE enrichment may be resulted from the partial melting of eclogites.
基金supported by grants from the National Natural Science Foundation of China (Nos. 41902077, 41730423 and 41921003)China Postdoctoral Science Foundation Grant (No. 2019M653103)Science and Technology Planning of Guangdong Province, China (2020B1212060055)。
文摘Magmatic Ni-Cu-(PGE) sulfide and Fe-Ti oxide deposits in plume-related large igneous provinces(LIPs)are commonly related to low-Ti and high-Ti series magmas, respectively, but the major factors that control such a relationship of metallogenic types and magma compositions are unclear. Magma fOcontrols sulfur status and relative timing of Fe-Ti oxide saturation in mafic magmas, which may help clarify this issue. Taking the Emeishan LIP as a case, we calculated the magma fOof the high-Ti and low-Ti picrites based on the olivine-spinel oxygen barometer, and the partitioning of V in olivine. The obtained fOof the high-Ti series magma(FMQ + 1.1 to FMQ + 2.6) is higher than that of the low-Ti series magma(FMQ-0.5to FMQ + 0.5). The magma fOof the high-Ti and low-Ti picrites containing Fo > 90 olivine reveals that the mantle source of the high-Ti series is likely more oxidized than that of the low-Ti series. The results using the ’lambda REE’ approach show that the high-Ti series may have been derived from relatively oxidized mantle with garnet pyroxenite component. The S contents at sulfide saturation(SCSS) of the two series magmas were calculated based on liquid compositions obtained from the alpha Melts modeling, and the results show that the low-Ti series magma could easily attain the sulfide saturation as it has low fOwith S being dominantly as S. In contrast, the oxidized high-Ti series magma is difficult to attain the sulfide saturation, but could crystallize Fe-Ti oxides at magma MgO content of ~7.0 wt.%. Thus, contrasting magma fOof low-Ti and high-Ti series in plume-related LIPs may play an important role in producing two different styles of metallogeny.
文摘1 Introduction Santanghu Basin is located between the Armantai and Karamaili suture zone,at the junction of the Siberia,Kazakhstan and Tarim plates(Chen and Jahn,2004;Xiao et al.,2008).As an important part of the Central Asian
文摘本文对虎跳峡苦橄岩和玄武岩及金安玄武岩的地球化学特征进行了研究。结果表明其微量元素原始地幔标准化曲线、Sr-Nd-Pb同位素比值与OIB、丽江苦橄岩相似，表现为其大离子亲石元素相对高场强元素富集，并且不存在Nb、Ta和Ti的负异常，表明岩浆在上升过程中很少受到岩石圈地幔或地壳物质的混染。利用Klein and Langmuir（1987）的方法得出虎跳峡熔岩和金安玄武岩原始岩浆MgO含量分别为15.81%~20.89%和8.06%~13.84%，其相应的地幔温度分别为1493~1611℃和1055~1474℃。所得温度略高于正常软流圈地幔温度，低于丽江仕满苦橄岩的熔融温度（1630~1680℃），推测丽江地区可能是峨眉山地幔柱的中心部位。
