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Broadband high-efficiency dielectric metalenses based on quasi-continuous nanostrips 被引量:2
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作者 Xiaohu Zhang Qinmiao Chen +6 位作者 Dongliang Tang Kaifeng Liu Haimo Zhang Lintong Shi Mengyao He Yongcai Guo Shumin Xiao 《Opto-Electronic Advances》 SCIE EI CAS CSCD 2024年第5期43-51,共9页
Benefiting from the abrupt phase changes within subwavelength thicknesses,metasurfaces have been widely applied for lightweight and compact optical systems.Simultaneous broadband and high-efficiency characteristics ar... Benefiting from the abrupt phase changes within subwavelength thicknesses,metasurfaces have been widely applied for lightweight and compact optical systems.Simultaneous broadband and high-efficiency characteristics are highly attractive for the practical implementation of metasurfaces.However,current metasurface devices mostly adopt discrete micro/nano structures,which rarely realize both merits simultaneously.In this paper,dielectric metasurfaces composed of quasi-continuous nanostrips are proposed to overcome this limitation.Via quasi-continuous nanostrips metasurface,a normal focusing metalens and a superoscillatory lens overcoming the diffraction limit are designed and experimentally demonstrated.The quasi-continuous metadevices can operate in a broadband wavelength ranging from 450 nm to 1000nm and keep a high power efficiency.The average efficiency of the fabricated metalens reaches 54.24%,showing a significant improvement compared to the previously reported metalenses with the same thickness.The proposed methodology can be easily extended to design other metadevices with the advantages of broadband and high-efficiency in practical optical systems. 展开更多
关键词 BROADBAND high-efficiency metalens sub-diffraction QUASI-CONTINUOUS
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High-efficiency Carbonation Modification Methods of Recycled Coarse Aggregates
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作者 张美香 YANG Xiaolin +3 位作者 丁亚红 SUN Bo ZHANG Xianggang LÜXiuwen 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期386-398,共13页
To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put fo... To solve the problem of only surface carbonation and realize high-efficiency carbonation of recycled coarse aggregate,the method of carbonated recycled coarse aggregate with nano materials pre-soaking was first put forward.The carbonation effect of modified recycled coarse aggregate with three different carbonation methods was evaluated,and water absorption,apparent density and crush index of modified recycled coarse aggregate were measured.Combined with XRD,SEM,and MIP microscopic analysis,the high-efficiency carbonation strengthening mechanism of modified recycled coarse aggregate was revealed.The experimental results show that,compared with the non-carbonated recycled coarse aggregate,the physical and microscopic properties of carbonated recycled coarse aggregate are improved.The method of carbonation with nano-SiO_(2) pre-soaking can realize the high-efficiency carbonation of recycled coarse aggregate,for modified recycled coarse aggregate with the method,water absorption is reduced by 23.03%,porosity is reduced by 44.06%,and the average pore diameter is 21.82 nm.The high-efficiency carbonation strengthening mechanism show that the pre-socked nano-SiO_(2) is bound to the hydration product Ca(OH)_(2) of the old mortar with nano-scale C-S-H,which can improve the CO_(2) absorption rate,accelerate the carbonation reaction,generate more stable CaCO_(3) and nano-scale silica gel,and bond to the dense three-dimensional network structure to realize the bidirectional enhancement of nano-materials and pressurized carbonation.It is concluded that the method of carbonation with nano-SiO_(2) pre-soaking is a novel high-efficiency carbonation modification of recycled coarse aggregate. 展开更多
关键词 recycled coarse aggregate pressurized carbonation high-efficiency carbonation NANO-SIO2 strengthening mechanism
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Effect of Na_(2)CO_(3)Roasting Activation on Acid Leaching Property of Fly Ash
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作者 LIU Chenjia ZHAO Aichun +4 位作者 YE Xin ZHAO Zi ZHANG Tingan YANG Xiaorong QIN Yanmei 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第6期1613-1620,共8页
By using high-alumina fly ash as raw material,a process was proposed for activating the fly ash with Na_(2)CO_(3)calcination and extracting aluminum from activated clinker with sulfuric acid leaching.The feasibility o... By using high-alumina fly ash as raw material,a process was proposed for activating the fly ash with Na_(2)CO_(3)calcination and extracting aluminum from activated clinker with sulfuric acid leaching.The feasibility of roasting process of activated fly ash by Na_(2)CO_(3)was discussed based on thermodynamic analysis.The experimental results showed that Na_(2)CO_(3)gradually reactes with mullite over 700 K to produce NaAlSiO_(4).The optimal process conditions for the activation stage are:a material ratio of 1:1 between sodium carbonate and fly ash,a calcination temperature of 900℃,and a calcination time of 2.5 hours.Under these conditions,the leaching rate of aluminum is 90.3%.By comparing the SEM and XRD analysis of raw and clinker materials,it could be concluded that the mullite phase of fly ash is almost completely destroyed and transformed into sodium aluminosilicate with good acid solubility. 展开更多
关键词 fly ash calcination activation acid leaching ALUMINUM
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Hydrometallurgical processing of chalcopyrite:A review of leaching techniques
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作者 Darwin Michell Cheje Machaca Amilton Barbosa Botelho Junior +2 位作者 Thamyres Cardoso de Carvalho Jorge Alberto Soares Tenório Denise Crocce Romano Espinosa 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第12期2537-2555,共19页
Copper,an essential metal for the energy transition,is primarily obtained from chalcopyrite through hydrometallurgical and pyrometallurgical methods.The risks and harmful impacts of these processes pose significant co... Copper,an essential metal for the energy transition,is primarily obtained from chalcopyrite through hydrometallurgical and pyrometallurgical methods.The risks and harmful impacts of these processes pose significant concerns for environmental and human safety,highlighting the need for more efficient and eco-friendly hydrometallurgical methods.This review article emphasizes current pro-cesses such as oxidative leaching,bioleaching,and pressure leaching that have demonstrated efficiency in overcoming the complicated chalcopyrite network.Oxidative leaching operates under benign conditions within the leaching media;nevertheless,the introduction of oxidizing agents provides benefits and advantages.Bioleaching,a non-aggressive method,has shown a gradual increase in copper extrac-tion efficiency and has been explored using both primary and secondary sources.Pressure leaching,known for its effectiveness and se-lectivity in copper extraction,is becoming commercially more viable with increased research investments.This research also provides im-portant data for advancing future research in the field. 展开更多
关键词 chalcopyrite leaching BIOleaching ionic liquids CHLORIDE hydrogen peroxide
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Study on synergistic leaching of potassium and phosphorus from potassium feldspar and solid waste phosphogypsum via coupling reactions
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作者 Chao Li Shizhao Wang +3 位作者 Yunshan Wang Xuebin An Gang Yang Yong Sun 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第1期117-129,共13页
To achieve the resource utilization of solid waste phosphogypsum(PG)and tackle the problem of utilizing potassium feldspar(PF),a coupled synergistic process between PG and PF is proposed in this paper.The study invest... To achieve the resource utilization of solid waste phosphogypsum(PG)and tackle the problem of utilizing potassium feldspar(PF),a coupled synergistic process between PG and PF is proposed in this paper.The study investigates the features of P and F in PG,and explores the decomposition of PF using hydrofluoric acid(HF)in the sulfuric acid system for K leaching and leaching of P and F in PG.The impact factors such as sulfuric acid concentration,reaction temperature,reaction time,material ratio(PG/PF),liquid–solid ratio,PF particle size,and PF calcination temperature on the leaching of P and K is systematically investigated in this paper.The results show that under optimal conditions,the leaching rate of K and P reach more than 93%and 96%,respectively.Kinetics study using shrinking core model(SCM)indicates two significant stages with internal diffusion predominantly controlling the leaching of K.The apparent activation energies of these two stages are 11.92 kJ·mol^(-1)and 11.55 kJ·mol^(-1),respectively. 展开更多
关键词 PHOSPHOGYPSUM Potassium feldspar Coupling reaction leaching Waste treatment Kinetics
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Selective leaching of lithium from spent lithium-ion batteries using sulfuric acid and oxalic acid
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作者 Haijun Yu Dongxing Wang +6 位作者 Shuai Rao Lijuan Duan Cairu Shao Xiaohui Tu Zhiyuan Ma Hongyang Cao Zhiqiang Liu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第4期688-696,共9页
Traditional hydrometallurgical methods for recovering spent lithium-ion batteries(LIBs)involve acid leaching to simultaneously extract all valuable metals into the leachate.These methods usually are followed by a seri... Traditional hydrometallurgical methods for recovering spent lithium-ion batteries(LIBs)involve acid leaching to simultaneously extract all valuable metals into the leachate.These methods usually are followed by a series of separation steps such as precipitation,extraction,and stripping to separate the individual valuable metals.In this study,we present a process for selectively leaching lithium through the synergistic effect of sulfuric and oxalic acids.Under optimal leaching conditions(leaching time of 1.5 h,leaching temperature of 70°C,liquid-solid ratio of 4 mL/g,oxalic acid ratio of 1.3,and sulfuric acid ratio of 1.3),the lithium leaching efficiency reached89.6%,and the leaching efficiencies of Ni,Co,and Mn were 12.8%,6.5%,and 21.7%.X-ray diffraction(XRD)and inductively coupled plasma optical emission spectrometer(ICP-OES)analyses showed that most of the Ni,Co,and Mn in the raw material remained as solid residue oxides and oxalates.This study offers a new approach to enriching the relevant theory for selectively recovering lithium from spent LIBs. 展开更多
关键词 selective leaching oxalic acid sulfuric acid spent lithium-ion batteries
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Effect of Saline Water on Soil Acidity, Alkalinity and Nutrients Leaching in Sandy Loamy Soil in Rwamagana Bella Flower Farm, Rwanda
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作者 Abel Mwubahaman Wali Umaru Garba +3 位作者 Hussein Bizimana Jean de Dieu Bazimenyera Eric Derrick Bugenimana Jean Nepomuscene Nsengiyumva 《Agricultural Sciences》 2024年第1期15-35,共21页
The necessity to saline and sodic waters is sometimes used for irrigating agricultural activities under certain circumstances, but it is important to note that the use of these waters comes with specific consideration... The necessity to saline and sodic waters is sometimes used for irrigating agricultural activities under certain circumstances, but it is important to note that the use of these waters comes with specific considerations and limitations. One way to decrease undesirable effects of sodic waters on the physical and chemical properties of soils is to apply organic and chemical amendments within the soil. This study aimed to assess the effectiveness of saline water on soil acidity, alkalinity and nutrients leaching in sandy loamy soil at Bella flower farm, in Rwamagana District, Rwanda. The water used was from the Muhazi Lake which is classified as Class I (Saline water quality). Column leaching experiments using treated soils were then conducted under saturated conditions. The soil under experimental was first analyzed for its textural classification, soil properties and is classified as sandy loamy soil. The t-test was taken at 1%, 5% and 10% levels of statistical significance compared to control soil. The results indicated that the application of saline water to soils caused an increase in some soil nutrients like increase of Phosphorus (P), Potassium (K<sup>+</sup>), Magnesium (Mg2<sup>+</sup>), Sulphur (S), CN ratio and Sodium (Na<sup>+</sup>) and decreased soil texture, physical and chemical properties and remained soil nutrients. Consequently, the intensive addition of saline water leachates to soil in PVC pipes led to decreased of soil EC through leaching and a raiser Soluble Sodium Percentage (SSP). The rate of saline water application affected the increase accumulation of SAR and Na% in the top soil layers. The study indicated that saline water is an inefficient amendment for sandy soil with saline water irrigation. The study recommends further studies with similar topic with saline water irrigation, as it accentuated the alkalinity levels. 展开更多
关键词 NUTRIENTS leaching Saline Water Soil Acidity Soil Alkalinity
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Experimental investigation of dynamic characteristics of leaching tubing for solution mining of salt cavern carbon and energy storage
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作者 Yin-Ping Li Xin-Bo Ge +1 位作者 Xi-Lin Shi Hong-Ling Ma 《Petroleum Science》 SCIE EI CAS CSCD 2024年第4期2703-2722,共20页
Salt caverns are extensively utilized for storing various substances such as fossil energy,hydrogen,compressed air,nuclear waste,and industrial solid waste.In China,when the salt cavern is leached through single-well ... Salt caverns are extensively utilized for storing various substances such as fossil energy,hydrogen,compressed air,nuclear waste,and industrial solid waste.In China,when the salt cavern is leached through single-well water solution mining with oil as a cushion,engineering challenges arise with the leaching tubing,leading to issues like damage and instability.These problems significantly hinder the progress of cavern construction and the control of cavern shape.The primary cause of this is the flowinduced vibration instability of leaching tubing within a confined space,which results in severe bending or damage to the tubing.This study presents a model experimental investigation on the dynamic characteristics of leaching tubing using a self-developed liquid-solid coupling physical model experiment apparatus.The experiment utilizes a silicone-rubber pipe(SRP)and a polycarbonate pipe(PCP)to examine the effects of various factors on the dynamic stability of cantilevered pipes conveying fluid.These factors include external space constraint,flexural rigidity,medium outside the pipe,overhanging length,and end conditions.The experiments reveal four dynamic response phenomena:water hammer,static buckling,chaotic motion,and flutter instability.The study further demonstrates that the length of the external space constraint has a direct impact on the flutter critical flow velocity of the cantilevered pipe conveying fluid.Additionally,the flutter critical flow velocity is influenced by the end conditions and different external media. 展开更多
关键词 Salt cavern storage Solution mining leaching tubing Experimental investigation Flutter instability
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Extraction of Valuable Metals from Titanium-bearing Blast Furnace Slag by Acid Leaching
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作者 刘燕 CHEN Xuegui +2 位作者 MAO Shuaidong XIAO Yadong LI Jiacong 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第2期376-385,共10页
To realize the resource utilization of the valuable metals in the titanium-containing blast furnace slag,the process route of “hydrochloric acid leaching-electrolysis-carbonization and carbon dioxide capture-preparat... To realize the resource utilization of the valuable metals in the titanium-containing blast furnace slag,the process route of “hydrochloric acid leaching-electrolysis-carbonization and carbon dioxide capture-preparation of calcium carbonate” was proposed.In this study,the influences of process conditions on the leaching rates of calcium,magnesium,aluminum,and iron and the phases of the leaching residue were investigated for the leaching process.The experimental results show that the HCl solution could selectively leach the elements from the titanium-containing blast furnace slag.The better leaching conditions are the HCl solution concentration of 4 mol/L,the leaching time of 30 min,the ratio of liquid volume to solid gas of 10 mL/g,and the stirring paddle speed of 300 r/min.Under the conditions,the leaching rates of calcium,magnesium,aluminum,and iron can reach 85.87%,73.41%,81.35%,and 59.08%,and the leaching rate of titanium is 10.71%.The iron and the aluminum are removed from the leachate to obtain iron-aluminum water purification agents,and the magnesium is removed from the leachate to obtain magnesium hydroxide.The leaching residue phase is dominated by perovskite,followed by magnesium silicate and tricalcium aluminate,and the titaniumrich material could be obtained from the leaching residue by desiliconization. 展开更多
关键词 titanium-containing blast furnace slag acid leaching valuable metals comprehensive utilization
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Preparation of sodium molybdate from molybdenum concentrate by microwave roasting and alkali leaching
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作者 Fengjuan Zhang Chenhui Liu +2 位作者 Srinivasakannan Chandrasekar Yingwei Li Fuchang Xu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CSCD 2024年第1期91-105,共15页
The preparation process of sodium molybdate has the disadvantages of high energy consumption,low thermal efficiency,and high raw material requirement of molybdenum trioxide,in order to realize the green and efficient ... The preparation process of sodium molybdate has the disadvantages of high energy consumption,low thermal efficiency,and high raw material requirement of molybdenum trioxide,in order to realize the green and efficient development of molybdenum concentrate resources,this paper proposes a new process for efficient recovery of molybdenum from molybdenum concentrate and preparation of sodium molybdate by microwave-enhanced roasting and alkali leaching.Thermodynamic analysis indicated the feasibility of oxidation roasting of molybdenum concentrate.The effects of roasting temperature,holding time,and power-to-mass ratio on the oxidation product and leaching product sodium molybdate (Na_(2)MoO_(4)·2H_(2)O) were investigated.Under the optimal process conditions:roasting temperature of 700℃,holding time of 110 min,and power-to-mass ratio of 110 W/g,the molybdenum state of existence was converted from MoS_(2) to Mo O3.The process of preparing sodium molybdate by alkali leaching of molybdenum calcine was investigated,the optimal leaching conditions include a solution concentration of 2.5 mol/L,a liquid-to-solid ratio of 2 mL/g,a leaching temperature of 60℃,and leaching solution termination at pH 8.The optimum conditions result in a leaching rate of sodium molybdate of 96.24%.Meanwhile,the content of sodium molybdate reaches 94.08wt%after leaching and removing impurities.Iron and aluminum impurities can be effectively separated by adjusting the pH of the leaching solution with sodium carbonate solution.This research avoids the shortcomings of the traditional process and utilizes the advantages of microwave metallurgy to prepare high-quality sodium molybdate,which provides a new idea for the highvalue utilization of molybdenum concentrate. 展开更多
关键词 molybdenum metallurgy microwave oxidation roasting removing impurities sodium hydroxide leaching
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Recovery of Li, Ni, Co and Mn from spent lithium-ion batteries assisted by organic acids: Process optimization and leaching mechanism
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作者 Liuyi Ren Bo Liu +5 位作者 Shenxu Bao Wei Ding Yimin Zhang Xiaochuan Hou Chao Lin Bo Chen 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期518-530,共13页
The proper recycling of spent lithium-ion batteries(LIBs)can promote the recovery and utilization of valuable resources,while also negative environmental effects resulting from the presence of toxic and hazardous subs... The proper recycling of spent lithium-ion batteries(LIBs)can promote the recovery and utilization of valuable resources,while also negative environmental effects resulting from the presence of toxic and hazardous substances.In this study,a new environmentally friendly hydro-metallurgical process was proposed for leaching lithium(Li),nickel(Ni),cobalt(Co),and manganese(Mn)from spent LIBs using sulfuric acid with citric acid as a reductant.The effects of the concentration of sulfuric acid,the leaching temperature,the leaching time,the solid-liquid ratio,and the reducing agent dosage on the leaching behavior of the above elements were investigated.Key parameters were optimized using response surface methodology(RSM)to maximize the recovery of metals from spent LIBs.The maxim-um recovery efficiencies of Li,Ni,Co,and Mn can reach 99.08%,98.76%,98.33%,and 97.63%.under the optimized conditions(the sulfuric acid concentration was 1.16 mol/L,the citric acid dosage was 15wt%,the solid-liquid ratio was 40 g/L,and the temperature was 83℃ for 120 min),respectively.It was found that in the collaborative leaching process of sulfuric acid and citric acid,the citric acid initially provided strong reducing CO_(2)^(-),and the transition metal ions in the high state underwent a reduction reaction to produce transition metal ions in the low state.Additionally,citric acid can also act as a proton donor and chelate with lower-priced transition metal ions,thus speeding up the dissolution process. 展开更多
关键词 spent lithium-ion batteries leaching response surface methodology sulfuric acid citric acid
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Process engineering of demineralisation of moderate to high ash Indian coals through NaOH‑HCl leaching and HF leaching
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作者 Heena Dhawan D.K.Sharma 《International Journal of Coal Science & Technology》 EI CAS CSCD 2024年第2期111-122,共12页
Chemical leaching of coals would be required to produce cleaner coals for some special applications where physical benefi-ciation may not be effective enough.This would also help in recovering Li and rare earth metals... Chemical leaching of coals would be required to produce cleaner coals for some special applications where physical benefi-ciation may not be effective enough.This would also help in recovering Li and rare earth metals besides in the sequestration of CO_(2).About 20 Indian coals having complexly distributed moderate to high ash contents were sequentially treated with various alkali–acid such as NaOH-HCl,HF,HCl,HCl-HF,and NaOH-HCl-HF leaching.This aimed to establish and design the best stepwise sequential process for the highest degree of demineralisation through a chemical leaching process.Kinetics and process intensification studies were carried out.More than 80%demineralisation of Madhaipur and Neemcha coals was observed using the best sequential treatment designed presently.The repeated stepwise treatment of the alkali and the acid was also studied,which was found to significantly enhance the degree of demineralisation of coals.The integrated process of alkali–acid leaching followed by solvent extraction(Organo-refining)and vice versa of the treated coal was also studied for producing cleaner coals. 展开更多
关键词 Alkali–acid leaching DEMINERALISATION Integrated process Rare earth elements
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Study on metal recovery process and kinetics of oxidative leaching from spent LiFePO_(4)Li-batteries
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作者 Xiaoming Zhang Wen Xie +5 位作者 Xiaolei Zhou Wenjie Zhang Jiawei Wen Xin Wang Guoyong Huang Shengming Xu 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第4期94-102,共9页
A green environmental protection and enhanced leaching process was proposed to recover all elements from spent lithium iron phosphate(LiFePO_(4)) lithium batteries.In order to reduce the influence of Al impurity in th... A green environmental protection and enhanced leaching process was proposed to recover all elements from spent lithium iron phosphate(LiFePO_(4)) lithium batteries.In order to reduce the influence of Al impurity in the recovery process,NaOH was used to remove impurity.After impurity removal,the spent LiFePO_(4) cathode material was used as raw material under the H_(2)SO_(4) system,and the pressure oxidation leaching process was adopted to achieve the preferential leaching of lithium.The E-pH diagram of the Fe-P-Al-H_(2)O system can determine the stable region of each element in the recovery process of spent LiFePO_(4)Li-batteries.Under the optimal conditions(500 r·min^(-1),15 h,363.15 K,0.4 MPa,the liquid-solid ratio was 4:1 ml·g^(-1)and the acid-material ratio was 0.29),the leaching rate of Li was 99.24%,Fe,Al,and Ti were 0.10%,2.07%,and 0.03%,respectively.The Fe and P were precipitated and recovered as FePO_(4)·2H_(2)O.The kinetic analysis shows that the process of high-pressure acid leaching of spent LiFePO_(4) materials depends on the surface chemical reaction.Through the life cycle assessment(LCA)of the spent LiFePO_(4) whole recovery process,eight midpoint impact categories were selected to assess the impact of recovery process.The results can provide basic environmental information on production process for recycling industry. 展开更多
关键词 Spent LiFePO_(4)Li-batteries Oxidative leaching Kinetic study Life cycle assessment
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An insight on the mechanism of efficient leaching of vanadium from vanadium shale induced by microwave-generated hot spots 被引量:3
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作者 Sheng Li Yimin Zhang +1 位作者 Yizhong Yuan Pengcheng Hu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第2期293-302,共10页
Microwave heating can rapidly and uniformly raise the temperature and accelerate the reaction rate.In this paper,microwave heating was used to improve the acid leaching,and the mechanism was investigated via microscop... Microwave heating can rapidly and uniformly raise the temperature and accelerate the reaction rate.In this paper,microwave heating was used to improve the acid leaching,and the mechanism was investigated via microscopic morphology analysis and numerical simulation by COMSOL Multiphysics software.The effects of the microwave power,leaching temperature,CaF_(2) dosage,H_(2)SO_(4) concentration,and leaching time on the vanadium recovery were investigated.A vanadium recovery of 80.66%is obtained at a microwave power of 550 W,leaching temperature of 95℃,CaF_(2) dosage of 5wt%,H_(2)SO_(4) concentration of 20vol%,and leaching time of 2.5 h.Compared with conventional leaching technology,the vanadium recovery increases by 6.18%,and the leaching time shortens by 79.17%.More obvious pulverization of shale particles and delamination of mica minerals happen in the microwave-assisted leaching process.Numerical simulation results show that the temperature of vanadium shales increases with an increase in electric field(E-field).The distributions of E-field and temperature among vanadium shale particles are relatively uniform,except for the higher content at the contact position of the particles.The analysis results of scaleup experiments and leaching experiments indicate high-temperature hot spots in the process of microwave-assisted leaching,and the local high temperature destroys the mineral structure and accelerates the reaction rate. 展开更多
关键词 vanadium shale microwave-assisted leaching hot spots numerical simulation
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Comprehensive utilization of complex rubidium ore resources:Mineral dissociation and selective leaching of rubidium and potassium 被引量:2
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作者 Quankuang Zhang Baozhong Ma +2 位作者 Chengyan Wang Yongqiang Chen Wenjuan Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第5期857-867,共11页
Currently,the process of extracting rubidium from ores has attracted a great deal of attention due to the increasing application of rubidium in high-technology field.A novel process for the comprehensive utilization o... Currently,the process of extracting rubidium from ores has attracted a great deal of attention due to the increasing application of rubidium in high-technology field.A novel process for the comprehensive utilization of rubidium ore resources is proposed in this paper.The process consists mainly of mineral dissociation,selective leaching,and desilication.The results showed that the stable silicon–oxygen tetrahedral structure of the rubidium ore was completely disrupted by thermal activation and the mineral was completely dissociated,which was conducive to subsequent selective leaching.Under the optimal conditions,extractions of 98.67% Rb and 96.23%K were obtained by leaching the rubidium ore.Moreover,the addition of a certain amount of activated Al(OH)_(3) during leaching can effectively inhibit the leaching of silicon.In the meantime,the leach residue was sodalite,which was successfully synthesized to zeolite A by hydrothermal conversion.The proposed process provided a feasible strategy for the green extraction of rubidium and the sustainable utilization of various resources. 展开更多
关键词 RUBIDIUM mineral dissociation selective leaching zeolite A DESILICATION
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Occurrence,leaching behavior,and detoxification of heavy metal Cr in coal gasification slag 被引量:2
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作者 Jiangshan Qu Jianbo Zhang +7 位作者 Huiquan Li Shaopeng Li Da Shi Ruiqi Chang Wenfen Wu Ganyu Zhu Chennian Yang Chenye Wang 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第6期11-19,共9页
Coal gasification slag(CGS)is a type of solid waste produced during coal gasification,in which heavy metals severely restrict its resource utilization.In this work,the mineral occurrence and distribution of typical he... Coal gasification slag(CGS)is a type of solid waste produced during coal gasification,in which heavy metals severely restrict its resource utilization.In this work,the mineral occurrence and distribution of typical heavy metal Cr in CGS is investigated.The leaching behavior of Cr under different conditions is studied in detail.Acid leaching-selective oxidation-coprecipitation method is proposed based on the characteristics of Cr in CGS.The detoxification of Cr in CGS is realized,and the detoxification mechanism is clarified.Results show that Cr is highly enriched in CGS.The speciation of Cr is mainly residual fraction(74.47%-86.12%),which is combined with amorphous aluminosilicate.Cr^(3+)and Cr^(6+)account for 90.93%-94.82%and 5.18%-9.07%of total Cr,respectively.High acid concentration and high liquid-solid ratio are beneficial to destroy the lattice structure of amorphous aluminosilicate,thus improving the leaching efficiency of Cr,which can reach 97.93%under the optimal conditions.Acid leaching-selective oxidation-coprecipitation method can realize the detoxification of Cr in CGS.Under the optimal conditions,the removal rates of Fe^(3+)and Cr^(3+)in the leaching solution are 80.99%-84.79%and 70.58%-71.69%,respectively,while the loss rate of Al^(3+)is only 1.10%-3.35%.Detoxification slag exists in the form of Fe-Cr coprecipitation(Fe_(1-x)Cr_xOOH),which can be used for smelting.The detoxification acid leaching solution can be used to prepare inorganic polymer composite coagulant poly-aluminum chloride(PAC).This study can provide theoretical and data guidance for detoxification of heavy metal Cr in CGS and achieve resource utilization of coal gasification solid waste. 展开更多
关键词 Coal gasification slag Heavy metal DISTRIBUTIONS leaching DETOXIFICATION PRECIPITATION
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Recovery of Li_(2)CO_(3)and FePO_(4)from spent LiFePO_(4)by coupling technics of isomorphic substitution leaching and solvent extraction 被引量:2
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作者 Yong Niu Xiaowu Peng +4 位作者 Jinfeng Li Yuze Zhang Fugen Song Dong Shi Lijuan Li 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2023年第2期306-315,共10页
Efficient and low-cost recycling of spent lithium iron phosphate(LiFePO_(4),LFP)batteries has become an inevitable trend.In this study,an integrated closed-loop recycling strategy including isomorphic substitution lea... Efficient and low-cost recycling of spent lithium iron phosphate(LiFePO_(4),LFP)batteries has become an inevitable trend.In this study,an integrated closed-loop recycling strategy including isomorphic substitution leaching and solvent extraction process for spent LFP was proposed.An inexpensive FeCl_(3)was used as leaching agent to directly substitute Fe^(2+)from LFP.99%of Li can be rapidly leached in just 30 min,accompanied by 98%of FePO_(4)precipitated in lixivium.The tri-n-butyl phosphate(TBP)-sulfonated kerosene(SK)system was applied to extract Li from lixivium through a twelve-stage countercurrent process containing synchronous extraction and stepwise stripping of Li^(+)and Fe^(3+).80.81%of Li can be selectively enriched in stripping liquor containing 3.059 mol·L^(-1)of Li^(+)under optimal conditions.And the Fe stripping liquor was recovered for LFP re-leaching,of which,Fe^(2+)was oxidized to Fe^(3+)by appropriate H_(2)O_(2).Raffinate and lixivium were concentrated and entered into extraction process to accomplished closeloop recycling process.Overall,the results suggest that more than 99%of Li was recovered.FeCl_(3)holding in solution was directly regenerated without any pollutant emission.The sustainable mothed would be an alternative candidate for total element recycling of spent LFP batteries with industrial potential. 展开更多
关键词 Spent LiFePO_(4) leaching lithium Extraction STRIPPING RECOVERY
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Toward high-efficiency perovskite solar cells with one-dimensional oriented nanostructured electron transport materials 被引量:1
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作者 Yinhua Lv Bing Cai +3 位作者 Ruihan Yuan Yihui Wu Quinn Qiao Wen-Hua Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第7期66-87,I0003,共23页
The unique advantages of one-dimensional(1D)oriented nanostructures in light-trapping and chargetransport make them competitive candidates in photovoltaic(PV)devices.Since the emergence of perovskite solar cells(PSCs)... The unique advantages of one-dimensional(1D)oriented nanostructures in light-trapping and chargetransport make them competitive candidates in photovoltaic(PV)devices.Since the emergence of perovskite solar cells(PSCs),1D nanostructured electron transport materials(ETMs)have drawn tremendous interest.However,the power conversion efficiencies(PCEs)of these devices have always significantly lagged behind their mesoscopic and planar counterparts.High-efficiency PSCs with 1D ETMs showing efficiency over 22%were just realized in the most recent studies.It yet lacks a comprehensive review covering the development of 1D ETMs and their application in PSCs.We hence timely summarize the advances in 1D ETMs-based solar cells,emphasizing on the fundamental and optimization issues of charge separation and collection ability,and their influence on PV performance.After sketching the classification and requirements for high-efficiency 1D nanostructured solar cells,we highlight the applicability of 1D TiO_(2)nanostructures in PSCs,including nanotubes,nanorods,nanocones,and nanopyramids,and carefully analyze how the electrostatic field affects cell performance.Other kinds of oriented nanostructures,e.g.,ZnO and SnO_(2)ETMs,are also described.Finally,we discuss the challenges and propose some potential strategies to further boost device performance.This review provides a broad range of valuable work in this fast-developing field,which we hope will stimulate research enthusiasm to push PSCs to an unprecedented level. 展开更多
关键词 1D nanostructures Perovskite solar cells Electron transport materials Electrostatic field high-efficiency
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基于遗传算法和蚁群算法的LEACH改进协议
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作者 徐巍 钟宇超 余成成 《无线电工程》 2024年第1期199-205,共7页
针对无线传感器网络低功耗自适应集簇分层(Low Energy Adaptive Clustering Hierarchy,LEACH)路由协议因能耗不均衡导致节点过早死亡的问题,提出了一种基于遗传算法和蚁群算法改进的LEACH路由协议。在分簇阶段,通过遗传算法选举合理的... 针对无线传感器网络低功耗自适应集簇分层(Low Energy Adaptive Clustering Hierarchy,LEACH)路由协议因能耗不均衡导致节点过早死亡的问题,提出了一种基于遗传算法和蚁群算法改进的LEACH路由协议。在分簇阶段,通过遗传算法选举合理的簇头节点并根据节点的分布划分簇群;在数据传输阶段,通过蚁群算法使簇头节点尽可能选择能量充足且距离较短的路径进行数据传输。仿真结果表明,与传统的分簇路由协议LEACH和LEACH-C相比,改进算法可以使网络的能量消耗更加均衡,并延长网络的生命周期。 展开更多
关键词 低功耗自适应集簇分层协议 节点能耗 分簇 遗传算法 蚁群算法
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Reclamation of CO_(2) sodium silicate used sands by steam leaching 被引量:1
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作者 Ji-jun Lu Wei He +1 位作者 Lei Yang Hua-fang Wang 《China Foundry》 SCIE EI CAS CSCD 2023年第6期537-544,共8页
The bond film on the surface of the CO_(2) sodium silicate used sands is not easy to decompose,therefore,it is difficult to reclaim used sands.A new reclamation method of CO_(2) sodium silicate used sands was develope... The bond film on the surface of the CO_(2) sodium silicate used sands is not easy to decompose,therefore,it is difficult to reclaim used sands.A new reclamation method of CO_(2) sodium silicate used sands was developed by steam leaching,which can reduce the water consumption of reclamation and improve the removal effect of sodium silicate bond film.Firstly,the leaching effect of the sodium silicate sands after 20/200/400/600/800/1,000°C heat preservation treatment was simulated.Furthermore,the influence of the leaching time on the removal effect of the sodium silicate bond film was studied.Finally,the casting properties of the reclaimed sands after the leaching reclamation treatment were tested.The results show for simulated used sands after 30 min of steam leaching,the removal ratio of the alkali exceeds 84.1%,the removal ratio of silicate is 86.2%,and the removal ratio of carbonate is 93.6%.The removal rate of alkali,silicate and carbonate is relatively low in the leaching time of 30-50 min.Considering the reclamation effect and cost,the leaching time is controlled in 30 min.Water consumption is only 60%of the mass of used sands for 30 min steam leaching,while it is 200%for wet reclamation.Morphological analysis shows that most of the hazardous substances in the used sands are removed in 30 min steam leaching,and the reclaimed sands surface after steam leaching in 50 min is as smooth as new sands.After 30 min of steam leaching,the alkali removal effect of the factory used sands can reach 81.5%,the water consumption by the steam leaching reclamation is 58%of the mass of the used sand,which is similar to the result of simulated used sands.The performance of reclaimed sands obtained after 30 min steam leaching is better than that of new sands when the amount of sodium silicate added is 6%of the mass of the reclaimed sands and the CO_(2) blowing time is 15 s:the 24 h ultimate compressive strength of reclaimed sands is 5.6 MPa(equated with new sands),and the collapsibility compressive strength is 5.2 MPa,which is lower than the collapsibility compressive strength of new sands(7.7 MPa).This indicates that the reclamation of CO_(2) sodium silicate used sands by steam leaching is a feasible method. 展开更多
关键词 sodium silicate sands steam leaching simulated temperature RECLAMATION
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