The effect of SiO_(2) and B_(2)O_(3) on viscosity and surface tension of CaF_(2)-CaO-Al_(2)O_(3)-MgO-SiO_(2)-B_(2)O_(3) slag designed for electroslag remelting of rotor steel was investigated.The viscosity of the slag...The effect of SiO_(2) and B_(2)O_(3) on viscosity and surface tension of CaF_(2)-CaO-Al_(2)O_(3)-MgO-SiO_(2)-B_(2)O_(3) slag designed for electroslag remelting of rotor steel was investigated.The viscosity of the slag melts increases with increasing the SiO_(2) content from 0.37 to 8.03 mass%,and the viscous activation energy increases from 54.21 to 58.49 kJ/mol.Increasing B_(2)O_(3) content of the slag from 0 to 3.62 mass%exhibits a similar effect on the viscosity,and the activation energy increases from 47.30 to 55.71 kJ/mol.The increase in the viscosity and activation energy for viscous flow of slag is attributed to the enhanced polymerization degree of slag melts network with increasing either SiO_(2) or B_(2)O_(3) content.The surface tension of slag melts decreases with increasing temperature.The surface tension of slag melts decreases with increasing either SiO_(2) or B_(2)O_(3) content,which is originated from the increase in the polymerization degree and the decrease in the CaO content of the slag.展开更多
基金support by the National Natural Science Foundationof China (Grant Nos.52074027 and 51874026) is greatly acknowledged.
文摘The effect of SiO_(2) and B_(2)O_(3) on viscosity and surface tension of CaF_(2)-CaO-Al_(2)O_(3)-MgO-SiO_(2)-B_(2)O_(3) slag designed for electroslag remelting of rotor steel was investigated.The viscosity of the slag melts increases with increasing the SiO_(2) content from 0.37 to 8.03 mass%,and the viscous activation energy increases from 54.21 to 58.49 kJ/mol.Increasing B_(2)O_(3) content of the slag from 0 to 3.62 mass%exhibits a similar effect on the viscosity,and the activation energy increases from 47.30 to 55.71 kJ/mol.The increase in the viscosity and activation energy for viscous flow of slag is attributed to the enhanced polymerization degree of slag melts network with increasing either SiO_(2) or B_(2)O_(3) content.The surface tension of slag melts decreases with increasing temperature.The surface tension of slag melts decreases with increasing either SiO_(2) or B_(2)O_(3) content,which is originated from the increase in the polymerization degree and the decrease in the CaO content of the slag.
