The long-term performance of moderate heat Portland cement with double-expansive sources （DE cement） in the system of high MgO clinker and gypsum was studied by XRD, SEM/EDAX and test methods for strength and expans...The long-term performance of moderate heat Portland cement with double-expansive sources （DE cement） in the system of high MgO clinker and gypsum was studied by XRD, SEM/EDAX and test methods for strength and expansion of cement. Results indicate that the periclase particle, whose size was 5-7.5μm in DE cement clinker containing 4.8 % MgO, existed individually. The periclase hydration in hardened DE cement paste started at about 60 days and completed up to 2 000 days, and ettringite in the paste was stable from 3 days to 2 000 days. Under the conditions of 4.5%-5.0 % MgO in clinker and 2.8%-3.4 %SO3 in cement, ettringite expansion and brucite expansion in DE cement paste had a continuity, entirety and stability. At the ages of 90, 365,730 and 2 000 days the expansion of the paste reached 0.07%-0.11%, 0.16%-0.21%, 0.21%-0.27 %, and 0.29%-0.38%, respectively. The results suggest that by using this cement in mass concrete it may compensate its temperature shrinkage and autogenous shrinkage to some extent.展开更多
The properties of low-heat Portland cement concrete（LHC） were studied in detail. The experimental results show that the LHC concrete has characteristics of a higher physical mechanical behavior, deformation and dura...The properties of low-heat Portland cement concrete（LHC） were studied in detail. The experimental results show that the LHC concrete has characteristics of a higher physical mechanical behavior, deformation and durability. Compared with moderate-heat Portland cement（MHC）, the average hydration heat of LHC concrete is reduced by about 17.5%. Under same mixing proportion, the adiabatic temperature rise of LHC concrete was reduced by 2 ℃-3 ℃,and the limits tension of LHC concrete was increased by 10× 10^-6-15×10^-6 than that of MHC. Moreover, it is indicated that LHC concrete has a better anti-crack behavior than MHC concrete.展开更多
基金Funded by National Natural Science Foundation of China (No.59493604)Zhejiang Provincial Natural Science Foundation of China (No.597082)China Yangtze River Three Gorges General
文摘The long-term performance of moderate heat Portland cement with double-expansive sources （DE cement） in the system of high MgO clinker and gypsum was studied by XRD, SEM/EDAX and test methods for strength and expansion of cement. Results indicate that the periclase particle, whose size was 5-7.5μm in DE cement clinker containing 4.8 % MgO, existed individually. The periclase hydration in hardened DE cement paste started at about 60 days and completed up to 2 000 days, and ettringite in the paste was stable from 3 days to 2 000 days. Under the conditions of 4.5%-5.0 % MgO in clinker and 2.8%-3.4 %SO3 in cement, ettringite expansion and brucite expansion in DE cement paste had a continuity, entirety and stability. At the ages of 90, 365,730 and 2 000 days the expansion of the paste reached 0.07%-0.11%, 0.16%-0.21%, 0.21%-0.27 %, and 0.29%-0.38%, respectively. The results suggest that by using this cement in mass concrete it may compensate its temperature shrinkage and autogenous shrinkage to some extent.
基金the National Natural Science Foundation of China(No.50539010)
文摘The properties of low-heat Portland cement concrete（LHC） were studied in detail. The experimental results show that the LHC concrete has characteristics of a higher physical mechanical behavior, deformation and durability. Compared with moderate-heat Portland cement（MHC）, the average hydration heat of LHC concrete is reduced by about 17.5%. Under same mixing proportion, the adiabatic temperature rise of LHC concrete was reduced by 2 ℃-3 ℃,and the limits tension of LHC concrete was increased by 10× 10^-6-15×10^-6 than that of MHC. Moreover, it is indicated that LHC concrete has a better anti-crack behavior than MHC concrete.
