Sluggish storage kinetics is considered as the main bottleneck of cathode materials for fast-charging aqueous zinc-ion batteries(AZIBs).In this report,we propose a novel in-situ self-etching strategy to unlock the Pal...Sluggish storage kinetics is considered as the main bottleneck of cathode materials for fast-charging aqueous zinc-ion batteries(AZIBs).In this report,we propose a novel in-situ self-etching strategy to unlock the Palm tree-like vanadium oxide/carbon nanofiber membrane(P-VO/C)as a robust freestanding electrode.Comprehensive investigations including the finite element simulation,in-situ X-ray diffraction,and in-situ electrochemical impedance spectroscopy disclosed it an electrochemically induced phase transformation mechanism from VO to layered Zn_(x)V_(2)O_5·nH_(2)O,as well as superior storage kinetics with ultrahigh pseudocapacitive contribution.As demonstrated,such electrode can remain a specific capacity of 285 mA h g^(-1)after 100 cycles at 1 A g^(-1),144.4 mA h g^(-1)after 1500 cycles at 30 A g^(-1),and even 97 mA h g^(-1)after 3000 cycles at 60 A g^(-1),respectively.Unexpectedly,an impressive power density of 78.9 kW kg^(-1)at the super-high current density of 100 A g^(-1)also can be achieved.Such design concept of in-situ self-etching free-standing electrode can provide a brand-new insight into extending the pseudocapacitive storage limit,so as to promote the development of high-power energy storage devices including but not limited to AZIBs.展开更多
The Jiama porphyry copper deposit in Tibet is one of the proven supergiant copper deposits in the Qinghai-Tibet Plateau at present,with the reserves of geological resources equivalent to nearly 20×10^(6) t.Howeve...The Jiama porphyry copper deposit in Tibet is one of the proven supergiant copper deposits in the Qinghai-Tibet Plateau at present,with the reserves of geological resources equivalent to nearly 20×10^(6) t.However,it features wavy and steep terrain,leading to extremely difficult field operation and heavy interference.This study attempts to determine the effects of the tensor controlled-source audiomagnetotellurics(CSAMT)with high-power orthogonal signal sources(also referred to as the high-power tensor CSAMT)when it is applied to the deep geophysical exploration in plateaus with complex terrain and mining areas with strong interference.The test results show that the high current provided by the highpower tensor CSAMT not only greatly improved the signal-to-noise ratio but also guaranteed that effective signals were received in the case of a long transmitter-receiver distance.Meanwhile,the tensor data better described the anisotropy of deep geologic bodies.In addition,the tests also show that when the transmitting current reaches 60 A,it is still guaranteed that strong enough signals can be received in the case of the transmitter-receiver distance of about 25 km,sounding curves show no near field effect,and effective exploration depth can reach 3 km.The 2D inversion results are roughly consistent with drilling results,indicating that the high-power tensor CSAMT can be used to achieve nearly actual characteristics of underground electrical structures.Therefore,this method has great potential for application in deep geophysical exploration in plateaus and mining areas with complex terrain and strong interference,respectively.This study not only serves as important guidance on the prospecting in the Qinghai-Tibet Plateau but also can be used as positive references for deep mineral exploration in other areas.展开更多
Microwave pre-treatment is considered as a promising technique for alleviating cutter wear. This paper introduces a high-power microwave-induced fracturing system for hard rock. The test system consists of a high-powe...Microwave pre-treatment is considered as a promising technique for alleviating cutter wear. This paper introduces a high-power microwave-induced fracturing system for hard rock. The test system consists of a high-power microwave subsystem (100 kW), a true triaxial testing machine, a dynamic monitoring subsystem, and an electromagnetic shielding subsystem. It can realize rapid microwave-induced fracturing, intelligent tuning of impedance, dynamic feedback under strong microwave fields, and active control of microwave parameters by addressing the following issues: the instability and insecurity of the system, the discharge breakdown between coaxial lines during high-power microwave output, and a lack of feedback of rock-microwave response. In this study, microwave-induced surface and borehole fracturing tests under true triaxial stress were carried out. Experimental comparisons imply that high-power microwave irradiation can reduce the fracturing time of hard rock and that the fracture range (160 mm) of a 915-MHz microwave source is about three times that of 2.45 GHz. After microwave-induced borehole fracturing, many tensile cracks occur on the rock surface and in the borehole: the maximum reduction of the P-wave velocity is 12.8%. The test results show that a high-power microwave source of 915 MHz is more conducive to assisting mechanical rock breaking and destressing. The system can promote the development of microwave-assisted rock breaking equipment.展开更多
Impact of amplified spontaneous emission(ASE)noise on the stimulated Raman scattering(SRS)threshold of highpower fiber amplifiers is demonstrated numerically through a spectral evolution approach.The simulation result...Impact of amplified spontaneous emission(ASE)noise on the stimulated Raman scattering(SRS)threshold of highpower fiber amplifiers is demonstrated numerically through a spectral evolution approach.The simulation results confirm that ASE noise in the Raman wavelength band could reduce the SRS threshold of high-power fiber amplifiers significantly.As for ASE noise originated the main amplifier,it becomes stronger and reduces the SRS threshold at shorter operation wavelength below 1052 nm.As for ASE noise originated from the seed laser,it reduces the SRS threshold at different operation wavelength under the condition that the Raman ratio is over-90 dB in the seed laser.The theoretical method and results in this work could provide a well reference to extend the operation wavelength of high-power fiber lasers.展开更多
In this paper,we use the elementary methods,the properties of Dirichlet character sums and the classical Gauss sums to study the estimation of the mean value of high-powers for a special character sum modulo a prime,a...In this paper,we use the elementary methods,the properties of Dirichlet character sums and the classical Gauss sums to study the estimation of the mean value of high-powers for a special character sum modulo a prime,and derive an exact computational formula.It can be conveniently programmed by the“Mathematica”software,by which we can get the exact results easily.展开更多
基金financially supported by the Shenzhen Science and Technology Program (JCYJ20200109105805902,JCYJ20220818095805012)the National Natural Science Foundation of China (22208221,22178221,42377487)+2 种基金the Scientific and Technological Plan of Guangdong Province (2019B090905005,2019B090911004)the Natural Science Foundation of Guangdong Province (2021A1515110751)the Guangdong Basic and Applied Basic Research Foundation (2022A1515110477,2021B1515120004)。
文摘Sluggish storage kinetics is considered as the main bottleneck of cathode materials for fast-charging aqueous zinc-ion batteries(AZIBs).In this report,we propose a novel in-situ self-etching strategy to unlock the Palm tree-like vanadium oxide/carbon nanofiber membrane(P-VO/C)as a robust freestanding electrode.Comprehensive investigations including the finite element simulation,in-situ X-ray diffraction,and in-situ electrochemical impedance spectroscopy disclosed it an electrochemically induced phase transformation mechanism from VO to layered Zn_(x)V_(2)O_5·nH_(2)O,as well as superior storage kinetics with ultrahigh pseudocapacitive contribution.As demonstrated,such electrode can remain a specific capacity of 285 mA h g^(-1)after 100 cycles at 1 A g^(-1),144.4 mA h g^(-1)after 1500 cycles at 30 A g^(-1),and even 97 mA h g^(-1)after 3000 cycles at 60 A g^(-1),respectively.Unexpectedly,an impressive power density of 78.9 kW kg^(-1)at the super-high current density of 100 A g^(-1)also can be achieved.Such design concept of in-situ self-etching free-standing electrode can provide a brand-new insight into extending the pseudocapacitive storage limit,so as to promote the development of high-power energy storage devices including but not limited to AZIBs.
基金supported by the National Key Research and Development Program of China(2018YFC0604102)the project of China Geological Survey(DD20190015)。
文摘The Jiama porphyry copper deposit in Tibet is one of the proven supergiant copper deposits in the Qinghai-Tibet Plateau at present,with the reserves of geological resources equivalent to nearly 20×10^(6) t.However,it features wavy and steep terrain,leading to extremely difficult field operation and heavy interference.This study attempts to determine the effects of the tensor controlled-source audiomagnetotellurics(CSAMT)with high-power orthogonal signal sources(also referred to as the high-power tensor CSAMT)when it is applied to the deep geophysical exploration in plateaus with complex terrain and mining areas with strong interference.The test results show that the high current provided by the highpower tensor CSAMT not only greatly improved the signal-to-noise ratio but also guaranteed that effective signals were received in the case of a long transmitter-receiver distance.Meanwhile,the tensor data better described the anisotropy of deep geologic bodies.In addition,the tests also show that when the transmitting current reaches 60 A,it is still guaranteed that strong enough signals can be received in the case of the transmitter-receiver distance of about 25 km,sounding curves show no near field effect,and effective exploration depth can reach 3 km.The 2D inversion results are roughly consistent with drilling results,indicating that the high-power tensor CSAMT can be used to achieve nearly actual characteristics of underground electrical structures.Therefore,this method has great potential for application in deep geophysical exploration in plateaus and mining areas with complex terrain and strong interference,respectively.This study not only serves as important guidance on the prospecting in the Qinghai-Tibet Plateau but also can be used as positive references for deep mineral exploration in other areas.
基金support from the Na-tional Natural Science Foundation of China(Grant No.41827806)the liaoning Revitalization Talent Program of China(Grant No.XLYCYSZX1902).
文摘Microwave pre-treatment is considered as a promising technique for alleviating cutter wear. This paper introduces a high-power microwave-induced fracturing system for hard rock. The test system consists of a high-power microwave subsystem (100 kW), a true triaxial testing machine, a dynamic monitoring subsystem, and an electromagnetic shielding subsystem. It can realize rapid microwave-induced fracturing, intelligent tuning of impedance, dynamic feedback under strong microwave fields, and active control of microwave parameters by addressing the following issues: the instability and insecurity of the system, the discharge breakdown between coaxial lines during high-power microwave output, and a lack of feedback of rock-microwave response. In this study, microwave-induced surface and borehole fracturing tests under true triaxial stress were carried out. Experimental comparisons imply that high-power microwave irradiation can reduce the fracturing time of hard rock and that the fracture range (160 mm) of a 915-MHz microwave source is about three times that of 2.45 GHz. After microwave-induced borehole fracturing, many tensile cracks occur on the rock surface and in the borehole: the maximum reduction of the P-wave velocity is 12.8%. The test results show that a high-power microwave source of 915 MHz is more conducive to assisting mechanical rock breaking and destressing. The system can promote the development of microwave-assisted rock breaking equipment.
基金the National Natural Science Foundation of China(Grant Nos.62005313 and 62061136013).
文摘Impact of amplified spontaneous emission(ASE)noise on the stimulated Raman scattering(SRS)threshold of highpower fiber amplifiers is demonstrated numerically through a spectral evolution approach.The simulation results confirm that ASE noise in the Raman wavelength band could reduce the SRS threshold of high-power fiber amplifiers significantly.As for ASE noise originated the main amplifier,it becomes stronger and reduces the SRS threshold at shorter operation wavelength below 1052 nm.As for ASE noise originated from the seed laser,it reduces the SRS threshold at different operation wavelength under the condition that the Raman ratio is over-90 dB in the seed laser.The theoretical method and results in this work could provide a well reference to extend the operation wavelength of high-power fiber lasers.
文摘In this paper,we use the elementary methods,the properties of Dirichlet character sums and the classical Gauss sums to study the estimation of the mean value of high-powers for a special character sum modulo a prime,and derive an exact computational formula.It can be conveniently programmed by the“Mathematica”software,by which we can get the exact results easily.
