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Experimental and Finite Element Analysis of Corroded High-Pressure Pipeline Repaired by Laminated Composite
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作者 Seyed Mohammad Reza Abtahi Saeid Ansari Sadrabadi +4 位作者 Gholam Hosein Rahimi Gaurav Singh Hamid Abyar Daniele Amato Luigi Federico 《Computer Modeling in Engineering & Sciences》 SCIE EI 2024年第8期1783-1806,共24页
Repairs of corroded high-pressure pipelines are essential for fluids transportation under high pressure.One of the methods used in their repairs is the use of layered composites.The composite used must have the necess... Repairs of corroded high-pressure pipelines are essential for fluids transportation under high pressure.One of the methods used in their repairs is the use of layered composites.The composite used must have the necessary strength.Therefore,the experiments and analytical solutions presented in this paper are performed according to the relevant standards and codes,including ASME PCC-2,ASME B31.8S,ASME B31.4,ISO 24817 and ASME B31.G.In addition,the experimental tests are replicated numerically using the finite element method.Setting the strain gauges at different distances from the defect location,can reduce the nonlinear effects,deformation,and fluctuations due to the high pressure.The direct relationship between the depth of an axial defect and the stress concentration is observed at the inner side edges of the defect.Composite reparation reduces the non-linearities related to the sharp variation of the geometry and a more reliable numerical simulation could be performed. 展开更多
关键词 high-pressure pipeline composite repair ASME PCC-2 ISO 24817
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A study of hydrate plug formation in a subsea natural gas pipeline using a novel high-pressure flow loop 被引量:12
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作者 Li Wenqing Gong Jing +3 位作者 Lü Xiaofang Zhao Jiankui Feng Yaorong Yu Da 《Petroleum Science》 SCIE CAS CSCD 2013年第1期97-105,共9页
The natural gas pipeline from Platform QKI8-1 in the southwest of Bohai Bay to the onshore processing facility is a subsea wet gas pipeline exposed to high pressure and low temperature for a long distance. Blockages i... The natural gas pipeline from Platform QKI8-1 in the southwest of Bohai Bay to the onshore processing facility is a subsea wet gas pipeline exposed to high pressure and low temperature for a long distance. Blockages in the pipeline occur occasionally. To maintain the natural gas flow in the pipeline, we proposed a method for analyzing blockages and ascribed them to the hydrate formation and agglomeration. A new high-pressure flow loop was developed to investigate hydrate plug formation and hydrate particle size, using a mixture of diesel oil, water, and natural gas as experimental fluids. The influences of pressure and initial flow rate were also studied. Experimental results indicated that when the flow rate was below 850 kg/h, gas hydrates would form and then plug the pipeline, even at a low water content (10%) of a water/oil emulsion. Furthermore, some practical suggestions were made for daily management of the subsea pipeline. 展开更多
关键词 Natural gas hydrate BLOCKAGE flow assurance high-pressure loop water cut flow rate
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Gas Film Disturbance Characteristics Analysis of High-Speed and High-Pressure Dry Gas Seal 被引量:12
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作者 CHEN Yuan JIANG Jinbo PENG Xudong 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2016年第6期1226-1233,共8页
The dry gas seal(DGS) has been widely used in high parameters centrifugal compressor, but the intense vibrations of shafting, especially in high-speed condition, usually result in DGS's failure. So the DGS's abili... The dry gas seal(DGS) has been widely used in high parameters centrifugal compressor, but the intense vibrations of shafting, especially in high-speed condition, usually result in DGS's failure. So the DGS's ability of resisting outside interference has become a determining factor of the further development of centrifugal compressor. However, the systematic researches of which about gas film disturbance characteristics of high parameters DGS are very little. In order to study gas film disturbance characteristics of high-speed and high-pressure spiral groove dry gas seal(S-DGS) with a flexibly mounted stator, rotor axial runout and misalignment are taken into consideration, and the finite difference method and analytical method are used to analyze the influence of gas film thickness disturbance on sealing performance parameters, what's more, the effects of many key factors on gas film thickness disturbance are systematically investigated. The results show that, when sealed pressure is 10.1MPa and seal face average linear velocity is 107.3 m/s, gas film thickness disturbance has a significant effect on leakage rate, but has relatively litter effect on open force; Excessively large excitation amplitude or excessively high excitation frequency can lead to severe gas film thickness disturbance; And it is beneficial to assure a smaller gas film thickness disturbance when the stator material density is between 3.1 g/cm3 to 8.4 g/cm3; Ensuring sealing performance while minimizing support axial stiffness and support axial damping can help to improve dynamic tracking property of dry gas seal. The proposed research provides the instruction to optimize dynamic tracking property of the DGS. 展开更多
关键词 high-speed and high-pressure dry gas seal gas film thickness disturbance dynamic tracking property
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Numerical Simulation Analysis of the Transformer Fire Extinguishing Process with a High-Pressure Water Mist System under Different Conditions
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作者 Haowei Yao Youxin Li +7 位作者 Kefeng Lv Dong Wang Jinguang Zhang Zhenyu Zhan Zhenyu Wang Huaitao Song Xiaoge Wei Hengjie Qin 《Computer Modeling in Engineering & Sciences》 SCIE EI 2023年第7期733-747,共15页
To thoroughly study the extinguishing effect of a high-pressure water mist fire extinguishing system when a transformer fire occurs,a 3D experimental model of a transformer is established in this work by employing Fir... To thoroughly study the extinguishing effect of a high-pressure water mist fire extinguishing system when a transformer fire occurs,a 3D experimental model of a transformer is established in this work by employing Fire Dynamics Simulator(FDS)software.More specifically,by setting different parameters,the process of the highpressure water mist fire extinguishing system with the presence of both diverse ambient temperatures and water mist sprinkler laying conditions is simulated.In addition,the fire extinguishing effect of the employed high-pressure water mist system with the implementation of different strategies is systematically analyzed.The extracted results show that a fire source farther away fromthe centerline leads to a lower local temperature distribution.In addition,as the ambient temperature increases,the temperature above the fire source decreases,while the temperature and the concentrationof theupperflue gas layer bothdecrease.Interestingly,after thehigh-pressurewatermist sprinkler begins to operate,both the temperature distribution above the fire source and the concentration of the flue gas decrease,which indicates that the high-pressure water mist system plays the role of cooling and dust removal.By comparing various sprinkler laying methods,it is found that the lower sprinkler height has a better effect on the temperature above the fire source,the temperature of the upper flue gas layer,and the concentration of the flue gas.Moreover,when the sprinkler is spread over thewhole transformer,the cooling effect on both the temperature above the fire source and the temperature of the upper flue gas layer is good,whereas the change in the concentration of the flue gas above the fire source is not obvious compared to the case where the sprinkler is not fully spread. 展开更多
关键词 Transformer fire high-pressure water mist TEMPERATURE flue gas concentration
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Geochemistry and origins of hydrogen-containing natural gases in deep Songliao Basin,China:Insights from continental scientific drilling 被引量:1
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作者 Shuang-Biao Han Chao-Han Xiang +3 位作者 Xin Du Lin-Feng Xie Jie Huang Cheng-Shan Wang 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期741-751,共11页
The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantl... The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen gas.The gas composition and stable isotope characteristics vary significantly,but the origin analysis of different gas types has previously been weak.Based on the geochemical parameters of gas samples from different depths and the analysis of geological settings,this research covers the diverse origins of natural gas in different strata.The gas components are mainly methane with a small amount of C_(2+),and non-hydrocarbon gases,including nitrogen(N_(2)),hydrogen(H_(2)),carbon dioxide(CO_(2)),and helium(He).At greater depth,the carbon isotope of methane becomes heavier,and the hydrogen isotope points to a lacustrine sedimentary environment.With increasing depth,the origins of N_(2)and CO_(2)change gradually from a mixture of organic and inorganic to inorganic.The origins of hydrogen gas are complex and include organic sources,water radiolysis,water-rock(Fe^(2+)-containing minerals)reactions,and mantle-derived.The shales of Denglouku and Shahezi Formations,as source rocks,provide the premise for generation and occurrence of organic gas.Furthermore,the deep faults and fluid activities in Basement Formation control the generation and migration of mantle-derived gas.The discovery of a high content of H_(2)in study area not only reveals the organic and inorganic association of natural-gas generation,but also provides a scientific basis for the exploration of deep hydrogen-rich gas. 展开更多
关键词 gas compositions Stable isotopes gas origins Hydrogen gas Songliao Basin
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Mold Filling and Prevention of Gas Entrapment in High-pressure Die-casting 被引量:1
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作者 Itsuo Ohnaka Akira Sugiyama +1 位作者 Takashi Ikeda Hideyuki Yasuda 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2008年第1期139-140,共2页
This paper presents some results of direct observation of mold filling in a specially designed die-casting by X-ray diffraction, including comparison with numerical simulation. Based on such work the authors discuss h... This paper presents some results of direct observation of mold filling in a specially designed die-casting by X-ray diffraction, including comparison with numerical simulation. Based on such work the authors discuss how to prevent gas entrapment and propose new methods. 展开更多
关键词 Direct observation Mold filling high-pressure die-casting Computer simulation gas entrapment
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Effects of ultrasound on the desulfurization performance of hot coal gas over Zn-Mn-Cu supported on semi-coke sorbent prepared by high-pressure impregnation method 被引量:4
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作者 Xiaoyang Zhang Xianrong Zheng +2 位作者 Peng Han Ze Liu Liping Chang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2015年第3期291-298,共8页
Zn-Mn-Cu/SC(U) sorbent was hydrothermally synthesized by ultrasound-assisted high-pressure impregnation method with semi-coke(SC)as support and the mixed solution of zinc nitrate,manganese nitrate and copper nitra... Zn-Mn-Cu/SC(U) sorbent was hydrothermally synthesized by ultrasound-assisted high-pressure impregnation method with semi-coke(SC)as support and the mixed solution of zinc nitrate,manganese nitrate and copper nitrate as active component precursors.The desulfurization performances of hot coal gas on the prepared sorbent at a mid-temperature of 500°C were tested in fixed-bed reactor.Morphology and pore structure of the prepared sorbent were also characterized by TEM,N2adsorption/desorption isotherms and XRD.For comparison,the sorbent of Zn-Mn-Cu/SC prepared by conventional high-pressure impregnation was also evaluated and characterized in order to study the effects of ultrasound treatment.Zn-Mn-Cu/SC(U) sorbent prepared by high-pressure impregnation under ultrasound-assisted condition showed a better desulfurization performance than Zn-Mn-Cu/SC.It could remove H2 S from 1000×10-6m3/m3 to 0.1×10-6m3/m3 at 500°C and maintained for 12.5 h with the sulfur capacity of 7.74%,in which both the breakthrough time and sulfur capacity were about 32% and 51% higher than those of Zn-Mn-Cu/SC sorbent.The introduction of ultrasound during high-pressure impregnation process greatly improved the morphology and pore structure of the sorbent.The ultrasonic treatment made particle size of active components smaller and made them more evenly disperse on semi-coke support,which provided more opportunities to contact with H2S in coal-based gases.However,there were no any difference in compositions and existing forms of active components on the Zn-Mn-Cu/SC and Zn-Mn-Cu/SC(U) sorbents. 展开更多
关键词 ultrasound-assistance high-pressure impregnation mid-temperature desulfurization Zn-Mn-Cu sorbent semi-coke support
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A new transition metal diphosphideα-MoP_(2) synthesized by a high-temperature and high-pressure technique
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作者 刘晓磊 于振海 +9 位作者 李建福 徐真真 周春银 董朝辉 张丽丽 王霞 余娜 邹志强 王晓丽 郭艳峰 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第1期563-567,共5页
Monoclinicα-MoP_(2),with the OsGe2-type structure(space group C2/m,Z=4)and lattice parameters a=8.7248(11)Å,b=3.2322(4)Å,c=7.4724(9)Å,andβ=119.263°,was synthesized under a pressure of 4~GPa at a ... Monoclinicα-MoP_(2),with the OsGe2-type structure(space group C2/m,Z=4)and lattice parameters a=8.7248(11)Å,b=3.2322(4)Å,c=7.4724(9)Å,andβ=119.263°,was synthesized under a pressure of 4~GPa at a temperature between 1100℃and 1200℃.The structure ofα-MoP_(2) and its relationship to other transition metal diphosphides are discussed.Surprisingly,the ambient pressure phase orthorhombicβ-MoP_(2)(space group Cmc21)is denser in structure thanα-MoP_(2).Room-temperature high-pressure x-ray diffraction studies exclude the possibility of phase transition fromβ-MoP_(2) to α-MoP_(2),suggesting thatα-MoP_(2) is a stable phase at ambient conditions;this is also supported by the total energy and phonon calculations. 展开更多
关键词 high-pressure synthesis monoclinic MoP_(2) crystal structure
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基于GAS算法的卵砾石粒径自动识别应用研究
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作者 蔡豫豪 高仕赵 +1 位作者 张丛林 董晓明 《泥沙研究》 CAS CSCD 北大核心 2024年第2期9-16,共8页
粒径和级配是表征床面组成的重要指标,基于GAS粒径自动识别技术可自动识别粗粒床面粒径并生成级配曲线,能够大幅提高现场采样和分析的效率。为了验证GAS的分割效果,采用GAS提供的默认参数进行分割,同时应用ImageJ软件手动分割进行验证... 粒径和级配是表征床面组成的重要指标,基于GAS粒径自动识别技术可自动识别粗粒床面粒径并生成级配曲线,能够大幅提高现场采样和分析的效率。为了验证GAS的分割效果,采用GAS提供的默认参数进行分割,同时应用ImageJ软件手动分割进行验证。结果表明:GAS级配曲线的相对误差为5.7%,相关系数为0.992。另外,采用单参数和多参数敏感性分析法来标准化参数调整方案,gre、can1和can2对GAS提取的级配曲线和特征粒径有显著影响,其中gre起主导作用,而can1和can2控制着砾石边界的检测完整性。 展开更多
关键词 粗粒床面 级配曲线 gas算法 数字筛分 图像处理
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High-pressure new phases of V–N compounds
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作者 时旭含 李志慧 +4 位作者 刘媛媛 王元元 刘冉 胡阔 姚震 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第5期560-565,共6页
The high-pressure diagram of V–N compounds is enriched by proposed seven new stable high-pressure phases.The P-1-VN_4with the armchair N-rich structure may be quenched to ambient conditions.The formed N–N covalent b... The high-pressure diagram of V–N compounds is enriched by proposed seven new stable high-pressure phases.The P-1-VN_4with the armchair N-rich structure may be quenched to ambient conditions.The formed N–N covalent bond plays an important role for the structural stability of N-chain.The charge transfer results in a V–N ionic bond interaction,which further improves the stability of N-chain structure.The P-1-VN_4,P4mnc-VN_8,and Immm-VN_(10)with the outstanding detonation properties have potential application in explosive field. 展开更多
关键词 high-pressure N-rich V–N compounds phase diagram STABILITY DFT calculation
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The discovery of TiO_(2)-Ⅱ,the α-PbO_(2)-structured high-pressure polymorph of rutile,in the Suizhou L6 chondrite
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作者 Xiande Xie Xiangping Gu Ming Chen 《Acta Geochimica》 EI CAS CSCD 2023年第1期1-8,共8页
We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact stru... We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact structures,and tektite.Our microscopic,Raman spectroscopic,electron microprobe and transmission electron microscopic investigations have revealed:(1) All observed TiO_(2)-Ⅱ grains are related with ilmenite and pyrophanite;(2) TiO_(2)-Ⅱ occurs as needle-and leaf-shaped inclusions in llmenite and patch-,tape-shaped body in pyrophanite;(3)The composition of TiO_(2)-Ⅱ is identical with that of its precursor rutile;(4) The Raman spectrum of TiO_(2)-Ⅱ is in good agreement with that of natural and synthesized α-PbO_(2)-type TiO_(2);(5) TiO_(2)-Ⅱ occurs mainly in the form of well-ordered nano-domains and small mis-orientation among the domains can be observed.(6) All electron diffraction reflections from TiO_(2)-Ⅱ can be indexed to α-PbO_(2)structure in space group Pbcn with lattice parameters of a=4.481 ?,b=5.578 A and c=4.921 A;(7) The exsolution inclusions of rutile from host ilmenite are mostly connected with an alternation process along the lamellar twinning plane of ilmenite induced by shockinduced high pressure and high temperature;(8) The P-T regime of 20-25 GPa and 1000 ℃ estimated for the Suizhou unmelted rock is suitable for phase transition of rutile into TiO_(2)-Ⅱ phase. 展开更多
关键词 RUTILE TiO_(2)-Ⅱ high-pressure polymorph Shock metamorphism Suizhou meteorite
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Repositioning fertilizer manufacturing subsidies for improving food security and reducing greenhouse gas emissions in China 被引量:1
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作者 Zongyi Wu Xiaolong Feng +1 位作者 Yumei Zhang Shenggen Fan 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2024年第2期430-443,共14页
China removed fertilizer manufacturing subsidies from 2015 to 2018 to bolster market-oriented reforms and foster environmentally sustainable practices.However,the impact of this policy reform on food security and the ... China removed fertilizer manufacturing subsidies from 2015 to 2018 to bolster market-oriented reforms and foster environmentally sustainable practices.However,the impact of this policy reform on food security and the environment remains inadequately evaluated.Moreover,although green and low-carbon technologies offer environmental advantages,their widespread adoption is hindered by prohibitively high costs.This study analyzes the impact of removing fertilizer manufacturing subsidies and explores the potential feasibility of redirecting fertilizer manufacturing subsidies to invest in the diffusion of these technologies.Utilizing the China Agricultural University Agri-food Systems model,we analyzed the potential for achieving mutually beneficial outcomes regarding food security and environmental sustainability.The findings indicate that removing fertilizer manufacturing subsidies has reduced greenhouse gas(GHG)emissions from agricultural activities by 3.88 million metric tons,with minimal impact on food production.Redirecting fertilizer manufacturing subsidies to invest in green and low-carbon technologies,including slow and controlled-release fertilizer,organic-inorganic compound fertilizers,and machine deep placement of fertilizer,emerges as a strategy to concurrently curtail GHG emissions,ensure food security,and secure robust economic returns.Finally,we propose a comprehensive set of government interventions,including subsidies,field guidance,and improved extension systems,to promote the widespread adoption of these technologies. 展开更多
关键词 food security fertilizer manufacturing subsidies agri-food systems greenhouse gas emissions
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Geochemical characteristics and exploration significance of ultra-deep Sinian oil and gas from Well Tashen 5,Tarim Basin,NW China 被引量:1
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作者 Zicheng Cao Anlai Ma +4 位作者 Qinqi Xu Quanyong Pan Kai Shang Fan Feng Yongli Liu 《Energy Geoscience》 EI 2024年第1期24-36,共13页
The Well Tashen 5(TS5),drilled and completed at a vertical depth of 9017 m in the Tabei Uplift of the Tarim Basin,NW China,is the deepest well in Asia.It has been producing both oil and gas from the Sinian at a depth ... The Well Tashen 5(TS5),drilled and completed at a vertical depth of 9017 m in the Tabei Uplift of the Tarim Basin,NW China,is the deepest well in Asia.It has been producing both oil and gas from the Sinian at a depth of 8780e8840 m,also the deepest in Asia in terms of oil discovery.In this paper,the geochemical characteristics of Sinian oil and gas from the well were investigated and compared with those of Cambrian oil and gas discovered in the same basin.The oil samples,with Pr/Ph ratio of 0.78 and a whole oil carbon isotopic value of31.6‰,have geochemical characteristics similar to those of Ordovician oils from the No.1 fault in the North Shuntuoguole area(also named Shunbei area)and the Middle Cambrian oil from wells Zhongshen 1(ZS1)and Zhongshen 5(ZS5)of Tazhong Uplift.The maturity of light hydrocarbons,diamondoids and aromatic fractions all suggest an approximate maturity of 1.5%e1.7%Ro for the samples.The(4-+3-)methyldiamantane concentration of the samples is 113.5 mg/g,indicating intense cracking with a cracking degree of about 80%,which is consistent with the high bottom hole temperature(179℃).The Sinian gas samples are dry with a dryness coefficient of 0.97.The gas is a mixture of kerogen-cracking gas and oil-cracking gas and has Ro values ranging between 1.5%and 1.7%,and methane carbon isotopic values of41.6‰.Based on the equivalent vitrinite reflectance(R_(eqv)=1.51%e1.61%)and the thermal evolution of source rocks from the Cambrian Yu'ertusi Formation of the same well,it is proposed that the Sinian oil and gas be mainly sourced from the Cambrian Yu'ertusi Formation during the Himalayan period but probably also be joined by hydrocarbon of higher maturity that migrated from other source rocks in deeper formations.The discovery of Sinian oil and gas from Well TS5 suggests that the ancient ultra-deep strata in the northern Tarim Basin have the potential for finding volatile oil or condensate reservoirs. 展开更多
关键词 Ultra-deep Sinian oil and gas Oil-cracking Well Tashen 5 Tarim Basin
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A developed dual-site Langmuir model to represent the high-pressure methane adsorption and thermodynamic parameters in shale
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作者 Ke Hu Qian Zhang +1 位作者 Yufei Liu Muhammad Abdurrahman Thaika 《International Journal of Coal Science & Technology》 EI CAS CSCD 2023年第5期21-37,共17页
Comprehending the mechanism of methane adsorption in shales is a crucial step towards optimizing the development of deep-buried shale gas. This is because the methane adsorbed in shale represents a significant proport... Comprehending the mechanism of methane adsorption in shales is a crucial step towards optimizing the development of deep-buried shale gas. This is because the methane adsorbed in shale represents a significant proportion of the subsurface shale gas resource. To properly characterize the methane adsorption on shale, which exhibits diverse mineral compositions and multi-scale pore sizes, it is crucial to capture the energy heterogeneity of the adsorption sites. In this paper, a dual-site Langmuir model is proposed, which accounts for the temperature and pressure dependence of the density of the adsorbed phase. The model is applied to the isothermals of methane adsorption on shale, at pressures of up to 30 MPa and temperatures ranging from 40 to 100 ℃. The results show that the proposed model can describe the adsorption behavior of methane on shale more accurately than conventional models, which assume a constant value for the density of adsorbed phase. Furthermore, the proposed model can be extrapolated to higher temperatures and pressures. Thermodynamic parameters were analyzed using correctly derived equations. The results indicate that the widely used, but incorrect, equation would underestimate the isosteric heat of adsorption. Neglecting the real gas behavior, volume of the adsorbed phase, and energy heterogeneity of the adsorption sites can lead to overestimation of the isosteric heat of adsorption. Furthermore, the isosteric heat evaluated from excess adsorption data can only be used to make a rough estimate of the real isosteric heat at very low pressure. 展开更多
关键词 Shale gas Adsorption-Dual-site Langmuir model Energy heterogeneity Isosteric heat
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Characteristics of carbon isotopic composition of alkane gas in large gas fields in China
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作者 DAI Jinxing NI Yunyan +4 位作者 GONG Deyu HUANG Shipeng LIU Quanyou HONG Feng ZHANG Yanling 《Petroleum Exploration and Development》 SCIE 2024年第2期251-261,共11页
Exploration and development of large gas fields is an important way for a country to rapidly develop its natural gas industry.From 1991 to 2020,China discovered 68 new large gas fields,boosting its annual gas output t... Exploration and development of large gas fields is an important way for a country to rapidly develop its natural gas industry.From 1991 to 2020,China discovered 68 new large gas fields,boosting its annual gas output to 1925×108m3in 2020,making it the fourth largest gas-producing country in the world.Based on 1696 molecular components and carbon isotopic composition data of alkane gas in 70 large gas fields in China,the characteristics of carbon isotopic composition of alkane gas in large gas fields in China were obtained.The lightest and average values ofδ^(13)C_(1),δ13C2,δ13C3andδ13C4become heavier with increasing carbon number,while the heaviest values ofδ^(13)C_(1),δ13C2,δ13C3andδ13C4become lighter with increasing carbon number.Theδ^(13)C_(1)values of large gas fields in China range from-71.2‰to-11.4‰(specifically,from-71.2‰to-56.4‰for bacterial gas,from-54.4‰to-21.6‰for oil-related gas,from-49.3‰to-18.9‰for coal-derived gas,and from-35.6‰to-11.4‰for abiogenic gas).Based on these data,theδ^(13)C_(1)chart of large gas fields in China was plotted.Moreover,theδ^(13)C_(1)values of natural gas in China range from-107.1‰to-8.9‰,specifically,from-1071%o to-55.1‰for bacterial gas,from-54.4‰to-21.6‰for oil-related gas,from-49.3‰to-13.3‰for coal-derived gas,and from-36.2‰to-8.9‰for abiogenic gas.Based on these data,theδ^(13)C_(1)chart of natural gas in China was plotted. 展开更多
关键词 China large gas field bacterial gas oil-related gas coal-derived gas abiogenic gas alkane gas carbon isotopic composition δ^(13)C_(1)chart
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低维GaS高响应度纸基光电探测器
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作者 辛巍 仲玮恒 +2 位作者 王晓颖 闫楚欣 刘为振 《物理实验》 2024年第4期7-11,24,共6页
随着石墨烯的发现,二维材料因其与众不同的理化性质,而在科研领域的关注度与日俱增.以石墨烯为起点的二维材料(例如MoS_(2),WS_(2),GaS等)因在器件中具有较好的光电性质和较高的迁移率,而在生产和生活中具有良好的应用前景.本文简要探... 随着石墨烯的发现,二维材料因其与众不同的理化性质,而在科研领域的关注度与日俱增.以石墨烯为起点的二维材料(例如MoS_(2),WS_(2),GaS等)因在器件中具有较好的光电性质和较高的迁移率,而在生产和生活中具有良好的应用前景.本文简要探讨了光电导效应的原理,采用铅笔勾勒的方法绘制出了石墨电极,并采用体材料液相超声后分散液滴涂的方法,制备了宏观尺度的GaS纸基光电探测器,该探测器具有可见光范围的光电响应,且具有较好的机械重复性.本文介绍的纸基光电探测器的制备方法对于高校基础物理和半导体物理课程的教学具有实际意义,有利于学生更好地理解光电导效应的原理.此外,纸基光电探测器不仅降低了制备成本,而且还有助于提高高校学生的科研实践能力. 展开更多
关键词 gas 光电导效应 纸基 光电探测器
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MXene Key Composites:A New Arena for Gas Sensors
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作者 Yitong Wang Yuhua Wang +2 位作者 Min Jian Qinting Jiang Xifei Li 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期350-391,共42页
With the development of science and technology,the scale of industrial production continues to grow,and the types and quantities of gas raw materials used in industrial production and produced during the production pr... With the development of science and technology,the scale of industrial production continues to grow,and the types and quantities of gas raw materials used in industrial production and produced during the production process are also constantly increasing.These gases include flammable and explosive gases,and even contain toxic gases.Therefore,it is very important and necessary for gas sensors to detect and monitor these gases quickly and accurately.In recent years,a new two-dimensional material called MXene has attracted widespread attention in various applications.Their abundant surface functional groups and sites,excellent current conductivity,tunable surface chemistry,and outstanding stability make them promising for gas sensor applications.Since the birth of MXene materials,researchers have utilized the efficient and convenient solution etching preparation,high flexibility,and easily functionalize MXene with other materials to pre-pare composites for gas sensing.This has opened a new chapter in high-performance gas sensing materials and provided a new approach for advanced sensor research.However,previous reviews on MXene-based composite materials in gas sensing only focused on the performance of gas sensing,without systematically explaining the gas sensing mechanisms generated by different gases,as well as summarizing and predicting the advantages and disadvantages of MXene-based composite materials.This article reviews the latest progress in the application of MXene-based composite materials in gas sensing.Firstly,a brief summary was given of the commonly used methods for preparing gas sens-ing device structures,followed by an introduction to the key attributes of MXene related to gas sensing performance.This article focuses on the performance of MXene-based composite materials used for gas sensing,such as MXene/graphene,MXene/Metal oxide,MXene/Transition metal sulfides(TMDs),MXene/Metal-organic framework(MOF),MXene/Polymer.It summarizes the advantages and disadvantages of MXene com-posite materials with different composites and discusses the possible gas sensing mechanisms of MXene-based composite materials for different gases.Finally,future directions and inroads of MXenes-based composites in gas sensing are presented and discussed. 展开更多
关键词 MXene Compound material gas sensor gas sensitive preparation gas sensitivity performance
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GAS6-AS1调节miR-370-3p/SPATA2轴对卵巢癌细胞增殖、迁移、侵袭、凋亡和EMT的影响
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作者 贾奕娟 王中显 +1 位作者 王冬花 龚世雄 《现代肿瘤医学》 CAS 2024年第3期424-431,共8页
目的:探讨长链非编码RNA GAS6反义RNA1(long non-coding RNA GAS6 antisense RNA1, lncRNA GAS6-AS1)调节miR-370-3p/精子发生相关蛋白2 (spermatogenesis-associated protein 2, SPATA2)轴对卵巢癌细胞增殖、迁移、侵袭、凋亡和上皮间... 目的:探讨长链非编码RNA GAS6反义RNA1(long non-coding RNA GAS6 antisense RNA1, lncRNA GAS6-AS1)调节miR-370-3p/精子发生相关蛋白2 (spermatogenesis-associated protein 2, SPATA2)轴对卵巢癌细胞增殖、迁移、侵袭、凋亡和上皮间质转化(epithelial mesenchymal transformation, EMT)的影响。方法:qRT-PCR、Western blot分别检测癌旁组织、卵巢癌组织、人正常卵巢上皮细胞IOSE80及卵巢癌细胞系HO-8910、SKOV3、A2780中GAS6-AS1、miR-370-3p及SPATA2蛋白表达。将SKOV3细胞分为:对照组(NC组)、 si-NC组、si-GAS6-AS1组、mimic NC组、miR-370-3p mimic组、si-GAS6-AS1+inhibitor NC组、si-GAS6-AS1+miR-370-3p inhibitor组,qRT-PCR检测细胞中GAS6-AS1、miR-370-3p表达;CCK-8法检测细胞增殖;流式细胞术检测细胞凋亡;划痕愈合实验检测细胞迁移;Transwell实验检测细胞侵袭;Western blot检测SPATA2、细胞周期素D1(CyclinD1)、Bcl-2相关X蛋白(Bcl-2-associated X,Bax)、E-钙黏蛋白(E-cadherin)、波形蛋白(Vimentin)、神经钙黏蛋白(N-cadherin)表达;双荧光素酶报告基因实验检测GAS6-AS1与miR-370-3p、 miR-370-3p与SPATA2的关系。结果:在卵巢癌组织和细胞中GAS6-AS1、SPATA2蛋白高表达,miR-370-3p低表达,且在SKOV3细胞中GAS6-AS1、SPATA2蛋白表达量最高,miR-370-3p表达水平最低,因此,选择SKOV3细胞为后续研究对象。与NC组、si-NC组比较,si-GAS6-AS1组GAS6-AS1、OD450值(24 h、48 h、72 h)、划痕愈合率、侵袭细胞数、SPATA2、CyclinD1、Vimentin、N-cadherin蛋白表达降低,miR-370-3p表达、细胞凋亡率、Bax、E-cadherin蛋白表达升高(P<0.05);与NC组、mimic NC组比较,miR-370-3p mimic组OD450值(24 h、48 h、72 h)、划痕愈合率、侵袭细胞数、SPATA2、CyclinD1、Vimentin、N-cadherin蛋白表达降低,miR-370-3p表达、细胞凋亡率、Bax、E-cadherin蛋白表达升高(P<0.05);miR-370-3p inhibitor减弱了沉默GAS6-AS1对SKOV3细胞增殖、迁移、侵袭及EMT的抑制及对细胞凋亡的促进作用。GAS6-AS1与miR-370-3p、miR-370-3p与SPATA2存在靶向调控关系。结论:沉默GAS6-AS1通过上调miR-370-3p来抑制SPATA2表达,从而抑制SKOV3细胞增殖、迁移、侵袭及EMT,并促进细胞凋亡。 展开更多
关键词 长链非编码RNA gas6反义RNA1 miR-370-3p 精子发生相关蛋白2 卵巢癌 上皮间质转化
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Experimental and numerical simulation study on the erosion behavior of the elbow of gathering pipeline in shale gas field
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作者 En-Bin Liu Shen Huang +3 位作者 Ding-Chao Tian Lai-Min Shi Shan-Bi Peng He Zheng 《Petroleum Science》 SCIE EI CAS CSCD 2024年第2期1257-1274,共18页
During the production period of shale gas, proppant particles and rock debris are produced together,which will seriously erode the elbows of gathering pipelines. In response to this problem, this paper takes the elbow... During the production period of shale gas, proppant particles and rock debris are produced together,which will seriously erode the elbows of gathering pipelines. In response to this problem, this paper takes the elbow of the gathering pipeline in the Changning Shale Gas Field as an example to test the erosion rate and material removal mechanism of the test piece at different angles of the elbow through experiments and compares the four erosion models with the experimental results. Through analysis, it is found that the best prediction model for quartz sand-carbon steel erosion is the Oka model. Based on the Oka model, FLUENT software was used to simulate and analyze the law of erosion of the elbow of the gas gathering pipeline under different gas flow velocities, gas gathering pressure, particle size, length of L1,and bending directions of the elbow. And a spiral pipeline structure is proposed to reduce the erosion rate of the elbow under the same working conditions. The results show that this structure can reduce erosion by 34%. 展开更多
关键词 Shale gas gas gathering pipeline ELBOW EROSION CFD
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Development,challenges and strategies of natural gas industry under carbon neutral target in China
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作者 ZOU Caineng LIN Minjie +10 位作者 MA Feng LIU Hanlin YANG Zhi ZHANG Guosheng YANG Yichao GUAN Chunxiao LIANG Yingbo WANG Ying XIONG Bo YU Hao YU Ping 《Petroleum Exploration and Development》 SCIE 2024年第2期476-497,共22页
In the mid-21st century,natural gas will enter its golden age,and the era of natural gas is arriving.This paper reviews the development stages of global natural gas industry and the enlightenment of American shale gas... In the mid-21st century,natural gas will enter its golden age,and the era of natural gas is arriving.This paper reviews the development stages of global natural gas industry and the enlightenment of American shale gas revolution,summarizes the development history and achievements of the natural gas industry in China,analyzes the status and challenges of natural gas in the green and low-carbon energy transition,and puts forward the natural gas industry development strategies under carbon neutral target in China.The natural gas industry in China has experienced three periods:start,growth,and leap forward.At present,China has become the fourth largest natural gas producer and third largest natural gas consumer in the world,and has made great achievements in natural gas exploration and development theory and technology,providing important support for the growth of production and reserves.China has set its goal of carbon neutrality to promote green and sustainable development,which brings opportunities and challenges for natural gas industry.Natural gas has significant low-carbon advantages,and gas-electric peak shaving boosts new energy development;the difficulty and cost of development are more prominent.For the national energy security and harmonious development between economy and ecology under the carbon neutral goal,based on the principle of"comprehensive planning,technological innovation,multi-energy complementarity,diversified integration,flexibility and efficiency,optimization and upgrading",the construction of the production-supplystorage-marketing system has to be improved so as to boost the development of the natural gas industry.First,it is necessary to strengthen efforts in the exploration and development of natural gas,making projects and arrangement in key exploration and development areas,meanwhile,it is urgent to make breakthroughs in key science theories and technologies,so as to increase reserve and production.Second,it should promote green and innovative development of the natural gas by developing new techniques,expanding new fields and integrating with new energy.Third,there is a demand to realize transformation and upgrading of the supply and demand structure of natural gas by strengthening the layout of pipeline gas,liquefied natural gas and the construction of underground gas storage,establishing reserve system for improving abilities of emergency response and adjustment,raising the proportion of natural gas in the primary energy consumption and contributing to the transformation of energy consumption structure,realizing low-carbon resources utilization and clean energy consumption. 展开更多
关键词 carbon neutrality natural gas shale gas tight gas coalbed methane new energy energy transition
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