Recent investigations reveal that the ultrahigh-pressure metamorphic (UHPM) rocks in the Donghai region of East China underwent ductile and transitional ductile-brittle structural events during their exhumation. The e...Recent investigations reveal that the ultrahigh-pressure metamorphic (UHPM) rocks in the Donghai region of East China underwent ductile and transitional ductile-brittle structural events during their exhumation. The earlier ductile deformation took place under the condition of amphibolite facies and the later transitional ductile-brittle deformation under the condition of greenschist facies. The hanging walls moved southeastward during both of these two events. The 40Ar/39Ar dating of muscovites from muscovite-plagioclase schists in the Haizhou phosphorous mine, which are structurally overlain by UHPM rocks, yields a plateau age of 218.0±2.9 Ma and isochron age of 219.8Ma, indicating that the earlier event of the ampibolite-facies deformation probably took place about 220 Ma ago. The 40Ar/39Ar dating of oriented amphiboles parallel to the movement direction of the hanging wall on a decollement plane yields a plateau age of 213.1±0.3 Ma and isochron age of 213.4±4.1 Ma, probably representing the age of the later event. The dating of pegmatitic biotites and K-feldspars near the decollement plane from the eastern Fangshan area yield plateau ages of 203.4±0.3 Ma, 203.6±0.4 Ma and 204.8±2.2 Ma, and isochron ages of 204.0±2.0 Ma, 200.6±3.1 Ma and 204.0±5.0 Ma, respectively, implying that the rocks in the studied area had not been cooled down to closing temperature of the dated biotites and K-feldspars until the beginning of the Jurassic (about 204 Ma). The integration of these data with previous chronological ages on the ultrahigh-pressure metamorphism lead to a new inference on the exhumation of the UHPM rocks. The UHPM rocks in the area were exhumed at the rate of 3-4 km/Ma from the mantle (about 80-100 km below the earth's surface at about 240 Ma) to the lower crust (at the depth of about 20-30km at 220 Ma), and at the rate of 1-2 km/Ma to the middle crust (at the depth of about 15 km at 213 Ma), and then at the rate of less than 1 km/Ma to the upper crust about 10 km deep at about 204 Ma.展开更多
Whole-rock Pb isotopic compositions of the high-pressure (HP) metamorphic rocks, consisting of two-mica albite gneisses and eclogites, and foliated granites from the HP metamorphic unit of the Tongbai-Dabie orogenic b...Whole-rock Pb isotopic compositions of the high-pressure (HP) metamorphic rocks, consisting of two-mica albite gneisses and eclogites, and foliated granites from the HP metamorphic unit of the Tongbai-Dabie orogenic belt are firstly reported in this paper. The results show that the HP metamorphic rocks in different parts of this orogenic belt have similar Pb isotopic compositions. The two- mica albite gneisses have 206 Pb/ 204 Pb=17.657-18.168, 207 Pb/ 204 Pb=15.318-15.573, 208 Pb/ 204 Pb=38.315-38.990, and the eclogites have 206 Pb/ 204 Pb=17.599-18.310, 207 Pb/ 204 Pb=15.465- 15.615 , 208 Pb/ 204 Pb=37.968-39.143. The HP metamorphic rocks are characterized by upper crustal Pb isotopic composition. Although the Pb isotopic composition of the HP metamorphic rocks partly overlaps that of the ultrahigh-pressure (UHP) metamorphic rocks, as a whole, the former is higher than the latter. The high radiogenic Pb isotopic composition for the HP metamorphic rocks confirms that the subducted Yangtze continental crust in the Tongbai-Dabie orogenic belt has the chemical structure of increasing radiogenic Pb isotopic composition from lower crust to upper crust. The foliated granites, intruded in the HP metamorphic rocks post the HP/UHP metamorphism, have 206 Pb/ 204 Pb=17.128-17.434, 207 Pb/ 204 Pb=15.313-15.422 and 208 Pb/ 204 Pb=37.631-38.122, which are obviously different from the Pb isotopic compositions of the HP metamorphic rocks but similar to those of the UHP metamorphic rocks and the foliated garnet-bearing granites in the UHP unit. This shows that the foliated granites from the HP and UHP units have common magma source. Combined with the foliated granites having the geochemical characteristics of A-type granites, it is suggested that the magma for the foliated granites in the UHP and HP unit would be derived from the partial melting of the retrometamorphosed UHP metamorphic rocks exhumed into middle to lower crust, and partial magmas were intruded into the HP unit.展开更多
Study practice has proved that the ultrahigh pressure metamorphic rocks iu Dabieshan must have exPerienced botk the retrograde metumorphism and partial melting under decompression and amphibolite-facies conditions dur...Study practice has proved that the ultrahigh pressure metamorphic rocks iu Dabieshan must have exPerienced botk the retrograde metumorphism and partial melting under decompression and amphibolite-facies conditions during their exhumation from mantel depth to lower-middle crust.The retrometamorphism and partial melting of the ultrahigh pressure rocks in association with thermal state changing in the middle-lower crust, under amphibolite-facies conditions, are important physical and chemical processes. It would result in a great detrease in the integrated yield strength, and the enhancement of the de formabilitY or the rocks, promoting the transition from contractional (collision) to extensional defoemational regime. The statement of tbe retrometamorphism and partial melting of the ultrahigh pressure rocks has proved the in-site model for the ultrahigh pressure rocks in Dabieshan. It not only clarifies the evolutiou from the UHP eclogite to the surrounding gneissic rock (so called UHP gueiss) and to the garnet-beariug roliated granites (non-UHP country rocks), but also provides scientific arguments for the establiskment of the dynamic model of the exhumation of UHP metamorphic rocks in Dabiesban. In general, Purely conductive heat transfer from the crust itself is probably insurficient to produce temperature conditions for partial melting, and additional heat sources must have been present during partial melting. We infer that the partial melting and extensional flow are probably driveu by delamination and magmatic underplating of thickeued lithospkeric mantle following the continental oblique collision.展开更多
A detailed tectonic analysis demonstrates that the present observed regional tectonic configuration of the ultrahigh-pressure metamorphic terrane in the Dabie massif was mainly formed by the extension processes of the...A detailed tectonic analysis demonstrates that the present observed regional tectonic configuration of the ultrahigh-pressure metamorphic terrane in the Dabie massif was mainly formed by the extension processes of the post-Indosinian continent-continent oblique collision between the Sino-Korean and Yangtze cratons and ultrahigh-pressure metamorphism (UHPM). The configuration is characterized by a regional tectonic pattern similar to metamorphic core complexes and by the development of multi-layered detachment zones. On the basis of the identification of compressional and extensional fabrics, it is indicated that the exhumation and uplift of ultrahigh-pressure (UHP) metamorphic rocks from the mantle depth to the surface can be divided into at least three different decompression retrogressive metamorphism and tectonic deformation stages, in which the subhorizontal crustal-scale extensional flow in the middle-lower crust under amphibolite facies conditions is an important geodynamic process in the exhumation of UHP metamorphic rocks. Moreover, the extensional flow is probably driven by delamination and magmatic underplating of thickened lithospheric mantle following the continental oblique collision.展开更多
A worldwide surge of research on ultrahigh-pressure (UHP) metamorphic rocks rose in 1984, when coesites were discovered independently in west Alps and Norway.Though eclogites in China have long been noticed since the ...A worldwide surge of research on ultrahigh-pressure (UHP) metamorphic rocks rose in 1984, when coesites were discovered independently in west Alps and Norway.Though eclogites in China have long been noticed since the 1960s, they were not considered as UHP rocks until coesite was reported from the Dabie Mountains by Xu in 1987.Since then, many international cooperative programs were launched jointly by Chinese and foreign geoscientists.An American group led by展开更多
New field observations and petrological data from Early Cretaceous metamorphic rocks in the Central Cordillera of the Colombian Andes allowed the recognition of thermally overprinted high-pressure rocks derived from o...New field observations and petrological data from Early Cretaceous metamorphic rocks in the Central Cordillera of the Colombian Andes allowed the recognition of thermally overprinted high-pressure rocks derived from oceanic crust protoliths.The obtained metamorphic path suggests that the rocks evolved from blueschist to eclogite facies towards upper amphibolite to high-pressure granulite facies transitional conditions.Eclogite facies conditions,better recorded in mafic protoliths,are revealed by relic lawsonite and phengite,bleb-to worm-like diopside-albite symplectites,as well as garnet core composition.Upper amphibolite to high pressure granulite facies overprinting is supported by coarse-grained brown-colored Ti-rich amphibole,augite,and oligoclase recrystallization,as well as the record of partial melting leucosomes.Phase equilibria and pressure-temperature(P-T)path modeling suggest initial high-pressure metamorphic conditions M1 yielding 18.2-24.5 kbar and 465-580℃,followed by upper amphibolite to high pressure granulite facies overprinting stage M2 yielding 6.5-14.2 kbar and 580-720℃.Retrograde conditions M3 obtained through chlorite thermometry yield temperatures ranging around 286-400℃at pressures below 6.5-11 kbar.The obtained clockwise P-T path,the garnet zonation pattern revealing a decrease in X_(grs)/X_(prp)related to Mg#increment from core to rim,the presence of partial melting veins,as well as regional constraints,document the modification of the thermal structure of the active subduction zone in Northern Andes during the Early Cretaceous.Such increment of the metamorphic gradient within the subduction interface is associated with slab roll-back geodynamics where hot mantle inflow was triggered.This scenario is also argued by the reported trench-ward magmatic arc migration and multiple extensional basin formation during this period.The presented example constitutes the first report of Cretaceous roll-back-related metamorphism in the Caribbean and Andean realms,representing an additional piece of evidence for a margin-scale extensional event that modified the northwestern border of South America during the Early Cretaceous.展开更多
Although tectonic models were presented for exhumation of ultrahigh-pressure (UHP) metamorphic rocks during the continental collision, there is increasing evidence for the decoupling between crustal slices at various ...Although tectonic models were presented for exhumation of ultrahigh-pressure (UHP) metamorphic rocks during the continental collision, there is increasing evidence for the decoupling between crustal slices at various depths within deeply subducted continental crust. This lends support to the multi-slice successive exhumation model of the UHP metamorphic rocks in the Dabie-Sulu orogen. The available evidence is summarized as follows: (1) the low-grade metamorphic slices, which have geotectonic affinity to the South China Block and part of them records the Triassic metamorphism, occur in the northern margin of the Dabie-Sulu UHP metamorphic zone, suggesting decoupling of the upper crust from the underlying basement during the initial stages of continental subduction; (2) the Dabie and Sulu HP to UHP metamorphic zones comprise several HP to UHP slices, which have an increased trend of metamorphic grade from south to north but a decreased trend of peak metamorphic ages correspondingly; and (3) the Chinese Continental Science Drilling (CCSD) project at Donghai in the Sulu orogen reveals that the UHP metamorphic zone is composed of several stacked slices, which display distinctive high and low radiogenic Pb from upper to lower parts in the profile, suggesting that these UHP crustal slices were derived from the subducted upper and middle crusts, respectively. Detachment surfaces within the deeply subducted crust may occur either along an ancient fault as a channel of fluid flow, which resulted in weakening of mechanic strength of the rocks adjacent to the fault due to fluid-rock interaction, or along the low-viscosity zones which resulted from variations of geotherms and lithospheric compositions at different depths. The multi-slice successive exhumation model is different from the traditional exhumation model of the UHP metamorphic rocks in that the latter assumes the detachment of the entire subducted continental crust from the underlying mantle lithosphere and its subsequent exhumation as a whole. This also reveals the difference between the continental subduction and oceanic subduction. In addition, several important proposals concerning the multi-slice successive exhumation model are made for further studies.展开更多
In this report, it is proven through stable iso-topic geochronological study that for the Jurassic sedimen-tary rocks in the Dushan area of Anhui Province, the source materials derived from high-pressure and ultrahigh...In this report, it is proven through stable iso-topic geochronological study that for the Jurassic sedimen-tary rocks in the Dushan area of Anhui Province, the source materials derived from high-pressure and ultrahigh-pressure metamorphic rocks are the products of subduction and ex-humation of the Yangtze plate under the North China plate during the Triassic period. The cobble of high-pressure or ultrahigh-pressure metamorphic rock in the Fenghuangtai Formation of Hefei Basin has Rb-Sr isotopic isochron age of phengite, apatite and whole rock, 232.1±2.1 Ma (MSWD = 0.59). Plateau ages of 40Ar/39Ar age spectra of detrital phengites in the Sanjianpu and Fenghuangtai formations are concordant, and they are 216.5±0.6 Ma and 217.4±1.3 Ma, respectively.展开更多
The most of high/ultrahigh-pressure(HP/UHP)terranes of the world are characterized by the occurrence of numerous pods,lenses or layered blocks of eclogite and amphibolites(e.g.O’Brien,1997;Elvevold and Gilotti,2000;Z...The most of high/ultrahigh-pressure(HP/UHP)terranes of the world are characterized by the occurrence of numerous pods,lenses or layered blocks of eclogite and amphibolites(e.g.O’Brien,1997;Elvevold and Gilotti,2000;Zhang et al.,2003;and references there in).Field and petrological features suggest that amphibolites should展开更多
Interpreting reservoir properties through log data and logging responses in complex strata is critical for efficient petroleum exploitation,particularly for metamorphic rocks.However,the unsatisfactory accuracy of suc...Interpreting reservoir properties through log data and logging responses in complex strata is critical for efficient petroleum exploitation,particularly for metamorphic rocks.However,the unsatisfactory accuracy of such interpretations in complex reservoirs has hindered their widespread application,resulting in severe inconvenience.In this study,we proposed a multi-mineral model based on the least-square method and an optimal principle to interpret the logging responses and petrophysical properties of complex hydrocarbon reservoirs.We began by selecting the main minerals based on a comprehensive analysis of log data,X-ray diffraction,petrographic thin sections and scanning electron microscopy(SEM)for three wells in the Bozhong 19-6 structural zone.In combination of the physical properties of these minerals with logging responses,we constructed the multi-mineral model,which can predict the log curves,petrophysical properties and mineral profile.The predicted and measured log data are evaluated using a weighted average error,which shows that the multi-mineral model has satisfactory prediction performance with errors below 11%in most intervals.Finally,we apply the model to a new well“x”in the Bozhong 19-6 structural zone,and the predicted logging responses match well with measured data with the weighted average error below 11.8%for most intervals.Moreover,the lithology is dominated by plagioclase,K-feldspar,and quartz as shown by the mineral profile,which correlates with the lithology of the Archean metamorphic rocks in this region.It is concluded that the multi-mineral model presented in this study provides reasonable methods for interpreting log data in complex metamorphic hydrocarbon reservoirs and could assist in efficient development in the future.展开更多
The Dashuigou tellurium deposit is the world’s only known independent tellurium deposit.By restoring metamorphic rocks’protolith,we seek to understand not only the development and evolution trajectory of the region ...The Dashuigou tellurium deposit is the world’s only known independent tellurium deposit.By restoring metamorphic rocks’protolith,we seek to understand not only the development and evolution trajectory of the region but also the origin of the relevant deposits.While there are many ways to restore metamorphic rocks’protolith,we take the host metamorphic rocks of Dashuigou tellurium deposit and leverage various petrochemical eigenvalues and related diagrams previously proposed to reveal the deposit’s host metamorphic rocks’protolith.The petrochemical eigenvalues include molecular number,Niggli’s value,REE parity ratio,CaO/Al_(2)O_(3)ratio,Fe^(3+) /(Fe^(3+) -+Fe^(2+) )ratio,chondrite-normalized REE value,logarithmic REE value,various REE eigenvalues including scandium,Eu/Sm ratio,total REE amount,light and heavy REEs,δEu,Eu anomaly,Sm/Nd ratio,and silicon isotope δ^(30) SiNBS-29‰,etc.The petrochemical plots include ACMs,100 mg-c-(al+alk),SiO_(2)-(Na_(2)O+K_(2)O),(al+fm)-(c+alk)versus Si,FeO+Fe_(2)O^(3+) TiO)-Al_(2)O_(3)-MgO,c-mg,Al_(2)O_(3)-(Na_(2)O+K_(2)O),chondrite-normalized REE model,La/Yb-REE,and Sm/Nd ratio,etc.On the basis of these comprehensive analyses,the following conclusions are drawn,starting from the many mantle-derived types of basalt developed in the study area of different geological ages,combined with the previously published research results on the deposit s fluid inclusions and sulfur and lead isotopes.The deposit is formed by mantle degassing in the form of a mantle plume in the late Yanshanian orogeny.The degassed fluids are rich in nano-sc ale substances including Fe,Te,S,As,Bi,Au,Se,H_(2),CO_(2),N_(2),H_(2)O,and CH_(4),which are enriched by nano-effect,and then rise to a certain part of the crust in the form of mantle plume along the lithospheric fault to form the deposit.The ultimate power for tellurium mineralization was from H_(2)flow with high energy,which was produced through radiation from the melted iron of the Earth’s outer core.The H,flow results in the Earth’s degassing,as well as the mantle and crust’s uplift.展开更多
Marble is a metamorphic rock, which is one of the 3 basic rock types (magmatic, sedimentary, metamorphic) forming the earth’s crust. The major characteristic sought after in a rock mass in the field for it to be expo...Marble is a metamorphic rock, which is one of the 3 basic rock types (magmatic, sedimentary, metamorphic) forming the earth’s crust. The major characteristic sought after in a rock mass in the field for it to be exportable and usable as marble is its suitability to be cut in blocks. In the process of producing marble slabs from marble blocks, the blocks are expected not to contain potentially problematic hard or weak zones and their geomechanical and chemical properties should conform to the relevant standards. Ignoring of the geological properties of the rock in the process of deciding for marble production at a marble site and determination of production location, direction and method is the most important parameter that would increase production loss. In order to reduce losses by determination of geological properties of marble, many academic studies have been conducted on the effects of water saturation, temperature, freezing and thawing on its mechanical and fracture properties. There are further studies on crack propagation in marble under stress. However, even those marble blocks that are obtained based on geological parameters may suffer serious cracks or fractures due to stresses caused by their weight and geometry. Therefore, cutting direction is of critical importance in order to minimize marble waste in the process of cutting a marble block which is brought to the inventory or processing site with cracks, cavities or fractures. Certain studies exist within such context, where the geometry of the discontinuity within a block is determined using non-destructive methods, such as ultrasonic testing, in order to determine the appropriate cutting direction. Such studies made use of ultrasonic waves to determine the physical and chemical structures of magmatic and sedimentary rocks by measuring the progress velocity of sonic waves in the rock. Said studies, however, mostly worked on sedimentary and magmatic rock specimens, focusing less on metamorphic rocks such as marble due to their anisotropic properties. Understanding the academic literature studies on marble would provide significant contribution to the reduction of production losses during the processing marble blocks in processing plants and the achievement of production efficiency levels that are within economic limits. Within such scope, this study has reviewed the past academic studies on marble, classified them under 6 categories, and comprehensively analyzed each category based on materials, testing setups, test specimens, test parameters and research techniques.展开更多
The Northern Qilian high-pressure metamorphic belt has experienced multipledeformation-metamorphism, which consists of at least four stages. In 550.8-526 Ma, eclogites wereformed. High temperature and pressure caused ...The Northern Qilian high-pressure metamorphic belt has experienced multipledeformation-metamorphism, which consists of at least four stages. In 550.8-526 Ma, eclogites wereformed. High temperature and pressure caused the escape of a large quantity of gas-liquid fluidsfrom rocks while silicate melt was generated. In the late stage, small amounts of CO_2 and H_2Oinfiltrating along fractures were introduced. In the formation of glaucophane schist (447-362 Ma),devolatilization reactions were dominated during the subduction-uplift stage of the paleoplate. Inthe uplift-exhumation stage (400-380 Ma) the increase of internal space of fractures in the rocksfavoured fluid infiltration and concentration. These fluids participated in hydration reactions inthe retro-metamorphism. The fluids participating in the mineral reactions have the compositions ofCaCl_2-NaCl-H_2O. In subsequent thrusting (<380 Ma), the metamorphic terrain was uplifted to theshallower crust and ductile-shearing deformation took place, which caused mainly dehydrationreactions of minerals. In a near-surface environment the metamorphic terrain experienced brittledeformation, forming many accompanying fractures. Immiscible CO_2 and low-salinity aqueous fluidsoccurred in these secondary microfractures and were trapped and sealed. The thermodynamic conditionsof different deformation-metamorphic stages of the metamorphic terrain were calculated and thecorresponding P-T-t path was deduced, showing that the metamorphic terrain has experienced aclockwise path indicated by T- and P-rising, and T- and P-falling processes. This reveals that thesubduction zone has undergone multiple tectono-dynamic processes, i.e. initial deep burial,subsequent quick uplift and near-surface tectonism.展开更多
We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact stru...We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact structures,and tektite.Our microscopic,Raman spectroscopic,electron microprobe and transmission electron microscopic investigations have revealed:(1) All observed TiO_(2)-Ⅱ grains are related with ilmenite and pyrophanite;(2) TiO_(2)-Ⅱ occurs as needle-and leaf-shaped inclusions in llmenite and patch-,tape-shaped body in pyrophanite;(3)The composition of TiO_(2)-Ⅱ is identical with that of its precursor rutile;(4) The Raman spectrum of TiO_(2)-Ⅱ is in good agreement with that of natural and synthesized α-PbO_(2)-type TiO_(2);(5) TiO_(2)-Ⅱ occurs mainly in the form of well-ordered nano-domains and small mis-orientation among the domains can be observed.(6) All electron diffraction reflections from TiO_(2)-Ⅱ can be indexed to α-PbO_(2)structure in space group Pbcn with lattice parameters of a=4.481 ?,b=5.578 A and c=4.921 A;(7) The exsolution inclusions of rutile from host ilmenite are mostly connected with an alternation process along the lamellar twinning plane of ilmenite induced by shockinduced high pressure and high temperature;(8) The P-T regime of 20-25 GPa and 1000 ℃ estimated for the Suizhou unmelted rock is suitable for phase transition of rutile into TiO_(2)-Ⅱ phase.展开更多
The Drillhole ZK703 with a depth of 558 m is located in the Donghai area of the southern Sulu ultrahigh-pressure (UHP) metamorphic belt, eastern China, and penetrates typical UHP eclogites and various non-mafic rocks,...The Drillhole ZK703 with a depth of 558 m is located in the Donghai area of the southern Sulu ultrahigh-pressure (UHP) metamorphic belt, eastern China, and penetrates typical UHP eclogites and various non-mafic rocks, including peridotite, gneiss, schist and quartzite. Their protoliths include ultramafic, mafic, intermediate, intermediate-acidic, acidic igneous rocks and sediments. These rocks are intimately interlayered, which are meters to millimeters thick with sharp and nontectonic contacts, suggesting in-situ metamorphism under UHP eclogite facies conditions. The following petrologic features indicate that the non-mafic rocks have experienced early-stage UHP metamorphism together with the eclogites: (1) phengite relics in gneisses and schists contain a high content of Si, up to 3.52 p.f.u. (per formula unit), while amphibolite-facies phengites have considerably low Si content (<3.26 p.f.u.); (2) jadeite relics are found in quartzite and jadeitite; (3) various types of symplectitic coronas and pseud展开更多
Sedimentary rocks cover-73% of the Earth's surface and metamorphic rocks account for approximately91% of the crust by volume. Understanding the average behavior and variability of heat production for these rock ty...Sedimentary rocks cover-73% of the Earth's surface and metamorphic rocks account for approximately91% of the crust by volume. Understanding the average behavior and variability of heat production for these rock types are vitally important for developing accurate models of lithospheric temperature. We analyze the heat production of ~204,000 whole rock geochemical data to quantify how heat production of these rocks varies with respect to chemistry and their evolution during metamorphism. The heat production of metaigneous and metasedimentary rocks are similar to their respective protoliths. Igneous and metaigneous samples increase in heat production with increasing SiO_2 and K_2 O, but decrease with increasing FeO, MgO and CaO. Sedimentary and metasedimentary rocks increase in heat production with increasing Al_2 O_3, FeO, TiO_2, and K_2 O but decrease with increasing CaO. For both igneous and sedimentary rocks, the heat production variations are largely correlated with processes that affect K_2 O concentration and covary with other major oxides as a consequence. Among sedimentary rocks,aluminous shales are the highest heat producing(2.9 μW^(-3)) whereas more common iron shales are lower heat producing(1.7 μW m^(-3)). Pure quartzites and carbonates are the lowest heat producing sedimentary rocks. Globally, there is little definitive evidence for a decrease in heat production with increasing metamorphic grade. However, there remains the need for high resolution studies of heat production variations within individual protoliths that vary in metamorphic grade. These results improve estimates of heat production and natural variability of rocks that will allow for more accurate temperature models of the lithosphere.展开更多
This paper puts forward using high-pressure water jet technology to control rock burst in roadway, and analyzes the theory of controlling rock burst in roadway by the weak structure zone model. The weak structure zone...This paper puts forward using high-pressure water jet technology to control rock burst in roadway, and analyzes the theory of controlling rock burst in roadway by the weak structure zone model. The weak structure zone is formed by using high-pressure water jet to cut the coal wall in a continuous and rotational way. In order to study the influence law of weak structure zone in surrounding rock, this paper numerically analyzed the influence law of weak structure zone, and the disturbance law of coal wall and floor under dynamic and static combined load. The results show that when the distance between high-pressure water jet drillings is 3 m and the diameter of drilling is 300 mm, continuous stress superposition zone can be formed. The weak structure zone can transfer and reduce the concentrated static load in surrounding rock, and then form distressed zone. The longer the high-pressure water jet drilling is, the larger the distressed zone is. The stress change and displacement change of non-distressed zone in coal wall and floor are significantly greater than that of distressed zone under dynamic and static combined load. And it shows that the distressed zone can effectively control rock burst in roadway under dynamic and static combined load. High-pressure water jet technology was applied in the haulage gate of 250203 working face in Yanbei Coal Mine, and had gained good effect. The study conclusions provide theoretical foundation and a new guidance for controlling rock burst in roadway.展开更多
Neoarchean metamorphic mafic rocks in the lower and the middle Wutai Complex mainly comprise metamorphic gabbros, amphibolites and chlorite schists. They can be subdivided into three groups according to chondrite norm...Neoarchean metamorphic mafic rocks in the lower and the middle Wutai Complex mainly comprise metamorphic gabbros, amphibolites and chlorite schists. They can be subdivided into three groups according to chondrite normalized REE patterns. Rocks in Group #1 are characterized by nearly flat REE patterns (Lan/Ybn=0.86-1.3), the lowest total REEs (29-52 ppm), and weak negative to positive Eu anomalies (Eun/Eun=0.84-1.02), nearly flat primitive mantle normalized patterns and strong negative Zr(Hf) anomalies. Their geochemical characteristics in REEs and trace elements are similar to those of ocean plateau tholeiite, which imply that this group of rocks can represent remnants of Archean oceanic crust derived from a mantle plume. Rocks in Group #2 are characterized by moderate total REEs (34-116 ppm), LREE-enriched (Lan/Ybn=1.76-4.34) chondrite normalized REE patterns with weak Eu anomalies (Eun/Eun=0.76-1.16), and negative Nb, Ta, Zr(Hf), Ti anomalies in the primitive mantle normalized spider diagram. The REE and trace element characteristics indicate that they represent arc magmas originating from a sub-arc mantle wedge metasomatized by slab-derived fluids. Rocks in Group #3 are characterized by the highest total REEs (61-192 ppm), the strongest LREEs enrichment (Lan/Ybn=7.12-16) with slightly negative Eu anomalies (Eun/Eun=0.81-0.95) in the chondrite normalized diagram. In the primitive mantle normalized diagram, these rocks are characterized by large negative anomalies in Nb, Ta, Ti, negative to no Zr anomalies. They represent arc magmas originating from a sub-arc mantle wedge enriched in slab-derived melts. The three groups of rocks imply that the formation of the Neoarchean Wutai Complex is related to mantle plumes and island-arc interaction.展开更多
The Xiaotongjiapuzi gold deposit occurs in a Palaeoproterozoic rift accretionary terrane in eastern Liaoning and is hosted by a carbonate formation of the Dashiqiao Formation, Liaohe Group. The metamorphic grade of th...The Xiaotongjiapuzi gold deposit occurs in a Palaeoproterozoic rift accretionary terrane in eastern Liaoning and is hosted by a carbonate formation of the Dashiqiao Formation, Liaohe Group. The metamorphic grade of the host rock is low amphibolite-high greenschist facies. Gold, which is mainly invisible, is distributed in pyrite and arsenopyrite. The grains of Au-bearing sulphide minerals are fine, ranging from 0.0 n to 1 mm. The wall-rock alterations are characterized by low-temperature silification, hydro-sericitization, sericitization and carbonatization. The homogenization temperatures of the fluid inclusions in quartz closely associated with gold mineralization range from 140 to 240°C. The metallogenic age represented by the Ar-Ar isotopic age of sericite is 167 Ma. Comparisons and studies show that the Xiaotongjiapuzi gold deposit can be classified as the submicron-sized disseminated deposit (analogous to the Carlin-type) hosted in metamorphic rocks.展开更多
Assessment of drillability of rocks is vital in the selection,operation,and performance evaluation of cutting tools used in various excavation machinery deployed in mining and tunneling.The commonly used rock drillabi...Assessment of drillability of rocks is vital in the selection,operation,and performance evaluation of cutting tools used in various excavation machinery deployed in mining and tunneling.The commonly used rock drillability prediction methods,namely,drilling rate index(DRI)and Cerchar hardness index(CHI)have limitations in predicting the penetration rate due to differential wear of the cutting tool in rocks with varied hardness and abrasivity.Since cutting tools get blunt differently in different rocks,the stress beneath the tip of the bit decreases until it reaches a threshold value beyond which the penetration rate becomes constant.In this research,a new composite penetration rate index(CPRI)is suggested based on the investigations on four metamorphic rocks viz.quartzite,gneiss,schist and phyllite with varied hardness-abrasivity values.The penetration-time behavior was classified into active,moderate,passive,and dormant phases based on the reduction in penetration rate at different stages of drilling.A comparison of predicted penetration rate values using DRI and CPRI with actual penetration rate values clearly establishes the supremacy of CPRI.Micro-structure and hardness-based index was also developed and correlated with CPRI.The new indices can help predict cutting tool penetration and its consumption more accurately.展开更多
文摘Recent investigations reveal that the ultrahigh-pressure metamorphic (UHPM) rocks in the Donghai region of East China underwent ductile and transitional ductile-brittle structural events during their exhumation. The earlier ductile deformation took place under the condition of amphibolite facies and the later transitional ductile-brittle deformation under the condition of greenschist facies. The hanging walls moved southeastward during both of these two events. The 40Ar/39Ar dating of muscovites from muscovite-plagioclase schists in the Haizhou phosphorous mine, which are structurally overlain by UHPM rocks, yields a plateau age of 218.0±2.9 Ma and isochron age of 219.8Ma, indicating that the earlier event of the ampibolite-facies deformation probably took place about 220 Ma ago. The 40Ar/39Ar dating of oriented amphiboles parallel to the movement direction of the hanging wall on a decollement plane yields a plateau age of 213.1±0.3 Ma and isochron age of 213.4±4.1 Ma, probably representing the age of the later event. The dating of pegmatitic biotites and K-feldspars near the decollement plane from the eastern Fangshan area yield plateau ages of 203.4±0.3 Ma, 203.6±0.4 Ma and 204.8±2.2 Ma, and isochron ages of 204.0±2.0 Ma, 200.6±3.1 Ma and 204.0±5.0 Ma, respectively, implying that the rocks in the studied area had not been cooled down to closing temperature of the dated biotites and K-feldspars until the beginning of the Jurassic (about 204 Ma). The integration of these data with previous chronological ages on the ultrahigh-pressure metamorphism lead to a new inference on the exhumation of the UHPM rocks. The UHPM rocks in the area were exhumed at the rate of 3-4 km/Ma from the mantle (about 80-100 km below the earth's surface at about 240 Ma) to the lower crust (at the depth of about 20-30km at 220 Ma), and at the rate of 1-2 km/Ma to the middle crust (at the depth of about 15 km at 213 Ma), and then at the rate of less than 1 km/Ma to the upper crust about 10 km deep at about 204 Ma.
文摘Whole-rock Pb isotopic compositions of the high-pressure (HP) metamorphic rocks, consisting of two-mica albite gneisses and eclogites, and foliated granites from the HP metamorphic unit of the Tongbai-Dabie orogenic belt are firstly reported in this paper. The results show that the HP metamorphic rocks in different parts of this orogenic belt have similar Pb isotopic compositions. The two- mica albite gneisses have 206 Pb/ 204 Pb=17.657-18.168, 207 Pb/ 204 Pb=15.318-15.573, 208 Pb/ 204 Pb=38.315-38.990, and the eclogites have 206 Pb/ 204 Pb=17.599-18.310, 207 Pb/ 204 Pb=15.465- 15.615 , 208 Pb/ 204 Pb=37.968-39.143. The HP metamorphic rocks are characterized by upper crustal Pb isotopic composition. Although the Pb isotopic composition of the HP metamorphic rocks partly overlaps that of the ultrahigh-pressure (UHP) metamorphic rocks, as a whole, the former is higher than the latter. The high radiogenic Pb isotopic composition for the HP metamorphic rocks confirms that the subducted Yangtze continental crust in the Tongbai-Dabie orogenic belt has the chemical structure of increasing radiogenic Pb isotopic composition from lower crust to upper crust. The foliated granites, intruded in the HP metamorphic rocks post the HP/UHP metamorphism, have 206 Pb/ 204 Pb=17.128-17.434, 207 Pb/ 204 Pb=15.313-15.422 and 208 Pb/ 204 Pb=37.631-38.122, which are obviously different from the Pb isotopic compositions of the HP metamorphic rocks but similar to those of the UHP metamorphic rocks and the foliated garnet-bearing granites in the UHP unit. This shows that the foliated granites from the HP and UHP units have common magma source. Combined with the foliated granites having the geochemical characteristics of A-type granites, it is suggested that the magma for the foliated granites in the UHP and HP unit would be derived from the partial melting of the retrometamorphosed UHP metamorphic rocks exhumed into middle to lower crust, and partial magmas were intruded into the HP unit.
文摘Study practice has proved that the ultrahigh pressure metamorphic rocks iu Dabieshan must have exPerienced botk the retrograde metumorphism and partial melting under decompression and amphibolite-facies conditions during their exhumation from mantel depth to lower-middle crust.The retrometamorphism and partial melting of the ultrahigh pressure rocks in association with thermal state changing in the middle-lower crust, under amphibolite-facies conditions, are important physical and chemical processes. It would result in a great detrease in the integrated yield strength, and the enhancement of the de formabilitY or the rocks, promoting the transition from contractional (collision) to extensional defoemational regime. The statement of tbe retrometamorphism and partial melting of the ultrahigh pressure rocks has proved the in-site model for the ultrahigh pressure rocks in Dabieshan. It not only clarifies the evolutiou from the UHP eclogite to the surrounding gneissic rock (so called UHP gueiss) and to the garnet-beariug roliated granites (non-UHP country rocks), but also provides scientific arguments for the establiskment of the dynamic model of the exhumation of UHP metamorphic rocks in Dabiesban. In general, Purely conductive heat transfer from the crust itself is probably insurficient to produce temperature conditions for partial melting, and additional heat sources must have been present during partial melting. We infer that the partial melting and extensional flow are probably driveu by delamination and magmatic underplating of thickeued lithospkeric mantle following the continental oblique collision.
文摘A detailed tectonic analysis demonstrates that the present observed regional tectonic configuration of the ultrahigh-pressure metamorphic terrane in the Dabie massif was mainly formed by the extension processes of the post-Indosinian continent-continent oblique collision between the Sino-Korean and Yangtze cratons and ultrahigh-pressure metamorphism (UHPM). The configuration is characterized by a regional tectonic pattern similar to metamorphic core complexes and by the development of multi-layered detachment zones. On the basis of the identification of compressional and extensional fabrics, it is indicated that the exhumation and uplift of ultrahigh-pressure (UHP) metamorphic rocks from the mantle depth to the surface can be divided into at least three different decompression retrogressive metamorphism and tectonic deformation stages, in which the subhorizontal crustal-scale extensional flow in the middle-lower crust under amphibolite facies conditions is an important geodynamic process in the exhumation of UHP metamorphic rocks. Moreover, the extensional flow is probably driven by delamination and magmatic underplating of thickened lithospheric mantle following the continental oblique collision.
基金Project supported by the National Natural Science Foundation of China.
文摘A worldwide surge of research on ultrahigh-pressure (UHP) metamorphic rocks rose in 1984, when coesites were discovered independently in west Alps and Norway.Though eclogites in China have long been noticed since the 1960s, they were not considered as UHP rocks until coesite was reported from the Dabie Mountains by Xu in 1987.Since then, many international cooperative programs were launched jointly by Chinese and foreign geoscientists.An American group led by
基金The National University of Colombia is acknowledged for its financial support。
文摘New field observations and petrological data from Early Cretaceous metamorphic rocks in the Central Cordillera of the Colombian Andes allowed the recognition of thermally overprinted high-pressure rocks derived from oceanic crust protoliths.The obtained metamorphic path suggests that the rocks evolved from blueschist to eclogite facies towards upper amphibolite to high-pressure granulite facies transitional conditions.Eclogite facies conditions,better recorded in mafic protoliths,are revealed by relic lawsonite and phengite,bleb-to worm-like diopside-albite symplectites,as well as garnet core composition.Upper amphibolite to high pressure granulite facies overprinting is supported by coarse-grained brown-colored Ti-rich amphibole,augite,and oligoclase recrystallization,as well as the record of partial melting leucosomes.Phase equilibria and pressure-temperature(P-T)path modeling suggest initial high-pressure metamorphic conditions M1 yielding 18.2-24.5 kbar and 465-580℃,followed by upper amphibolite to high pressure granulite facies overprinting stage M2 yielding 6.5-14.2 kbar and 580-720℃.Retrograde conditions M3 obtained through chlorite thermometry yield temperatures ranging around 286-400℃at pressures below 6.5-11 kbar.The obtained clockwise P-T path,the garnet zonation pattern revealing a decrease in X_(grs)/X_(prp)related to Mg#increment from core to rim,the presence of partial melting veins,as well as regional constraints,document the modification of the thermal structure of the active subduction zone in Northern Andes during the Early Cretaceous.Such increment of the metamorphic gradient within the subduction interface is associated with slab roll-back geodynamics where hot mantle inflow was triggered.This scenario is also argued by the reported trench-ward magmatic arc migration and multiple extensional basin formation during this period.The presented example constitutes the first report of Cretaceous roll-back-related metamorphism in the Caribbean and Andean realms,representing an additional piece of evidence for a margin-scale extensional event that modified the northwestern border of South America during the Early Cretaceous.
基金the Chinese Academy of Sciences (Grant No. kzcx2-yw-131)the National Natural Science Foundation of China (Grant Nos. 40572035, 40634023 and40773013).
文摘Although tectonic models were presented for exhumation of ultrahigh-pressure (UHP) metamorphic rocks during the continental collision, there is increasing evidence for the decoupling between crustal slices at various depths within deeply subducted continental crust. This lends support to the multi-slice successive exhumation model of the UHP metamorphic rocks in the Dabie-Sulu orogen. The available evidence is summarized as follows: (1) the low-grade metamorphic slices, which have geotectonic affinity to the South China Block and part of them records the Triassic metamorphism, occur in the northern margin of the Dabie-Sulu UHP metamorphic zone, suggesting decoupling of the upper crust from the underlying basement during the initial stages of continental subduction; (2) the Dabie and Sulu HP to UHP metamorphic zones comprise several HP to UHP slices, which have an increased trend of metamorphic grade from south to north but a decreased trend of peak metamorphic ages correspondingly; and (3) the Chinese Continental Science Drilling (CCSD) project at Donghai in the Sulu orogen reveals that the UHP metamorphic zone is composed of several stacked slices, which display distinctive high and low radiogenic Pb from upper to lower parts in the profile, suggesting that these UHP crustal slices were derived from the subducted upper and middle crusts, respectively. Detachment surfaces within the deeply subducted crust may occur either along an ancient fault as a channel of fluid flow, which resulted in weakening of mechanic strength of the rocks adjacent to the fault due to fluid-rock interaction, or along the low-viscosity zones which resulted from variations of geotherms and lithospheric compositions at different depths. The multi-slice successive exhumation model is different from the traditional exhumation model of the UHP metamorphic rocks in that the latter assumes the detachment of the entire subducted continental crust from the underlying mantle lithosphere and its subsequent exhumation as a whole. This also reveals the difference between the continental subduction and oceanic subduction. In addition, several important proposals concerning the multi-slice successive exhumation model are made for further studies.
基金supported by the State Key Basic Research Development Program of China(Grant No.G1999075507)
文摘In this report, it is proven through stable iso-topic geochronological study that for the Jurassic sedimen-tary rocks in the Dushan area of Anhui Province, the source materials derived from high-pressure and ultrahigh-pressure metamorphic rocks are the products of subduction and ex-humation of the Yangtze plate under the North China plate during the Triassic period. The cobble of high-pressure or ultrahigh-pressure metamorphic rock in the Fenghuangtai Formation of Hefei Basin has Rb-Sr isotopic isochron age of phengite, apatite and whole rock, 232.1±2.1 Ma (MSWD = 0.59). Plateau ages of 40Ar/39Ar age spectra of detrital phengites in the Sanjianpu and Fenghuangtai formations are concordant, and they are 216.5±0.6 Ma and 217.4±1.3 Ma, respectively.
文摘The most of high/ultrahigh-pressure(HP/UHP)terranes of the world are characterized by the occurrence of numerous pods,lenses or layered blocks of eclogite and amphibolites(e.g.O’Brien,1997;Elvevold and Gilotti,2000;Zhang et al.,2003;and references there in).Field and petrological features suggest that amphibolites should
基金funded by Science and Technology Major Project of China National Offshore Oil Corporation(CNOOC-KJ 135 ZDXM36 TJ 08TJ).
文摘Interpreting reservoir properties through log data and logging responses in complex strata is critical for efficient petroleum exploitation,particularly for metamorphic rocks.However,the unsatisfactory accuracy of such interpretations in complex reservoirs has hindered their widespread application,resulting in severe inconvenience.In this study,we proposed a multi-mineral model based on the least-square method and an optimal principle to interpret the logging responses and petrophysical properties of complex hydrocarbon reservoirs.We began by selecting the main minerals based on a comprehensive analysis of log data,X-ray diffraction,petrographic thin sections and scanning electron microscopy(SEM)for three wells in the Bozhong 19-6 structural zone.In combination of the physical properties of these minerals with logging responses,we constructed the multi-mineral model,which can predict the log curves,petrophysical properties and mineral profile.The predicted and measured log data are evaluated using a weighted average error,which shows that the multi-mineral model has satisfactory prediction performance with errors below 11%in most intervals.Finally,we apply the model to a new well“x”in the Bozhong 19-6 structural zone,and the predicted logging responses match well with measured data with the weighted average error below 11.8%for most intervals.Moreover,the lithology is dominated by plagioclase,K-feldspar,and quartz as shown by the mineral profile,which correlates with the lithology of the Archean metamorphic rocks in this region.It is concluded that the multi-mineral model presented in this study provides reasonable methods for interpreting log data in complex metamorphic hydrocarbon reservoirs and could assist in efficient development in the future.
基金supported by Orient Resources Ltd.College of Earth Sciences,Jilin University。
文摘The Dashuigou tellurium deposit is the world’s only known independent tellurium deposit.By restoring metamorphic rocks’protolith,we seek to understand not only the development and evolution trajectory of the region but also the origin of the relevant deposits.While there are many ways to restore metamorphic rocks’protolith,we take the host metamorphic rocks of Dashuigou tellurium deposit and leverage various petrochemical eigenvalues and related diagrams previously proposed to reveal the deposit’s host metamorphic rocks’protolith.The petrochemical eigenvalues include molecular number,Niggli’s value,REE parity ratio,CaO/Al_(2)O_(3)ratio,Fe^(3+) /(Fe^(3+) -+Fe^(2+) )ratio,chondrite-normalized REE value,logarithmic REE value,various REE eigenvalues including scandium,Eu/Sm ratio,total REE amount,light and heavy REEs,δEu,Eu anomaly,Sm/Nd ratio,and silicon isotope δ^(30) SiNBS-29‰,etc.The petrochemical plots include ACMs,100 mg-c-(al+alk),SiO_(2)-(Na_(2)O+K_(2)O),(al+fm)-(c+alk)versus Si,FeO+Fe_(2)O^(3+) TiO)-Al_(2)O_(3)-MgO,c-mg,Al_(2)O_(3)-(Na_(2)O+K_(2)O),chondrite-normalized REE model,La/Yb-REE,and Sm/Nd ratio,etc.On the basis of these comprehensive analyses,the following conclusions are drawn,starting from the many mantle-derived types of basalt developed in the study area of different geological ages,combined with the previously published research results on the deposit s fluid inclusions and sulfur and lead isotopes.The deposit is formed by mantle degassing in the form of a mantle plume in the late Yanshanian orogeny.The degassed fluids are rich in nano-sc ale substances including Fe,Te,S,As,Bi,Au,Se,H_(2),CO_(2),N_(2),H_(2)O,and CH_(4),which are enriched by nano-effect,and then rise to a certain part of the crust in the form of mantle plume along the lithospheric fault to form the deposit.The ultimate power for tellurium mineralization was from H_(2)flow with high energy,which was produced through radiation from the melted iron of the Earth’s outer core.The H,flow results in the Earth’s degassing,as well as the mantle and crust’s uplift.
文摘Marble is a metamorphic rock, which is one of the 3 basic rock types (magmatic, sedimentary, metamorphic) forming the earth’s crust. The major characteristic sought after in a rock mass in the field for it to be exportable and usable as marble is its suitability to be cut in blocks. In the process of producing marble slabs from marble blocks, the blocks are expected not to contain potentially problematic hard or weak zones and their geomechanical and chemical properties should conform to the relevant standards. Ignoring of the geological properties of the rock in the process of deciding for marble production at a marble site and determination of production location, direction and method is the most important parameter that would increase production loss. In order to reduce losses by determination of geological properties of marble, many academic studies have been conducted on the effects of water saturation, temperature, freezing and thawing on its mechanical and fracture properties. There are further studies on crack propagation in marble under stress. However, even those marble blocks that are obtained based on geological parameters may suffer serious cracks or fractures due to stresses caused by their weight and geometry. Therefore, cutting direction is of critical importance in order to minimize marble waste in the process of cutting a marble block which is brought to the inventory or processing site with cracks, cavities or fractures. Certain studies exist within such context, where the geometry of the discontinuity within a block is determined using non-destructive methods, such as ultrasonic testing, in order to determine the appropriate cutting direction. Such studies made use of ultrasonic waves to determine the physical and chemical structures of magmatic and sedimentary rocks by measuring the progress velocity of sonic waves in the rock. Said studies, however, mostly worked on sedimentary and magmatic rock specimens, focusing less on metamorphic rocks such as marble due to their anisotropic properties. Understanding the academic literature studies on marble would provide significant contribution to the reduction of production losses during the processing marble blocks in processing plants and the achievement of production efficiency levels that are within economic limits. Within such scope, this study has reviewed the past academic studies on marble, classified them under 6 categories, and comprehensively analyzed each category based on materials, testing setups, test specimens, test parameters and research techniques.
文摘The Northern Qilian high-pressure metamorphic belt has experienced multipledeformation-metamorphism, which consists of at least four stages. In 550.8-526 Ma, eclogites wereformed. High temperature and pressure caused the escape of a large quantity of gas-liquid fluidsfrom rocks while silicate melt was generated. In the late stage, small amounts of CO_2 and H_2Oinfiltrating along fractures were introduced. In the formation of glaucophane schist (447-362 Ma),devolatilization reactions were dominated during the subduction-uplift stage of the paleoplate. Inthe uplift-exhumation stage (400-380 Ma) the increase of internal space of fractures in the rocksfavoured fluid infiltration and concentration. These fluids participated in hydration reactions inthe retro-metamorphism. The fluids participating in the mineral reactions have the compositions ofCaCl_2-NaCl-H_2O. In subsequent thrusting (<380 Ma), the metamorphic terrain was uplifted to theshallower crust and ductile-shearing deformation took place, which caused mainly dehydrationreactions of minerals. In a near-surface environment the metamorphic terrain experienced brittledeformation, forming many accompanying fractures. Immiscible CO_2 and low-salinity aqueous fluidsoccurred in these secondary microfractures and were trapped and sealed. The thermodynamic conditionsof different deformation-metamorphic stages of the metamorphic terrain were calculated and thecorresponding P-T-t path was deduced, showing that the metamorphic terrain has experienced aclockwise path indicated by T- and P-rising, and T- and P-falling processes. This reveals that thesubduction zone has undergone multiple tectono-dynamic processes, i.e. initial deep burial,subsequent quick uplift and near-surface tectonism.
文摘We report the discovery of TiO_(2)-Ⅱ in the unmelted rock of the shocked Suizhou L6 chondrite.Natural TiO_(2)-Ⅱ was previously found in ultrahigh-pressure metamorphic and mantle-derived rocks,terrestrial impact structures,and tektite.Our microscopic,Raman spectroscopic,electron microprobe and transmission electron microscopic investigations have revealed:(1) All observed TiO_(2)-Ⅱ grains are related with ilmenite and pyrophanite;(2) TiO_(2)-Ⅱ occurs as needle-and leaf-shaped inclusions in llmenite and patch-,tape-shaped body in pyrophanite;(3)The composition of TiO_(2)-Ⅱ is identical with that of its precursor rutile;(4) The Raman spectrum of TiO_(2)-Ⅱ is in good agreement with that of natural and synthesized α-PbO_(2)-type TiO_(2);(5) TiO_(2)-Ⅱ occurs mainly in the form of well-ordered nano-domains and small mis-orientation among the domains can be observed.(6) All electron diffraction reflections from TiO_(2)-Ⅱ can be indexed to α-PbO_(2)structure in space group Pbcn with lattice parameters of a=4.481 ?,b=5.578 A and c=4.921 A;(7) The exsolution inclusions of rutile from host ilmenite are mostly connected with an alternation process along the lamellar twinning plane of ilmenite induced by shockinduced high pressure and high temperature;(8) The P-T regime of 20-25 GPa and 1000 ℃ estimated for the Suizhou unmelted rock is suitable for phase transition of rutile into TiO_(2)-Ⅱ phase.
基金supported by the Chinese National Key Scientific Program--the Chinese Continental Seientitle Drilling Projectthe National Natural Science Foundation of China(NSFC Grant 49772142)1:250000 Regional Geological Survey of the Lianyungang Sheet(I50C002004)of P.R.China and the Laboratory of Continental Dynamics of the Land and Resource Ministry of China
文摘The Drillhole ZK703 with a depth of 558 m is located in the Donghai area of the southern Sulu ultrahigh-pressure (UHP) metamorphic belt, eastern China, and penetrates typical UHP eclogites and various non-mafic rocks, including peridotite, gneiss, schist and quartzite. Their protoliths include ultramafic, mafic, intermediate, intermediate-acidic, acidic igneous rocks and sediments. These rocks are intimately interlayered, which are meters to millimeters thick with sharp and nontectonic contacts, suggesting in-situ metamorphism under UHP eclogite facies conditions. The following petrologic features indicate that the non-mafic rocks have experienced early-stage UHP metamorphism together with the eclogites: (1) phengite relics in gneisses and schists contain a high content of Si, up to 3.52 p.f.u. (per formula unit), while amphibolite-facies phengites have considerably low Si content (<3.26 p.f.u.); (2) jadeite relics are found in quartzite and jadeitite; (3) various types of symplectitic coronas and pseud
基金supported by Australian Government Research Training Program Scholarship
文摘Sedimentary rocks cover-73% of the Earth's surface and metamorphic rocks account for approximately91% of the crust by volume. Understanding the average behavior and variability of heat production for these rock types are vitally important for developing accurate models of lithospheric temperature. We analyze the heat production of ~204,000 whole rock geochemical data to quantify how heat production of these rocks varies with respect to chemistry and their evolution during metamorphism. The heat production of metaigneous and metasedimentary rocks are similar to their respective protoliths. Igneous and metaigneous samples increase in heat production with increasing SiO_2 and K_2 O, but decrease with increasing FeO, MgO and CaO. Sedimentary and metasedimentary rocks increase in heat production with increasing Al_2 O_3, FeO, TiO_2, and K_2 O but decrease with increasing CaO. For both igneous and sedimentary rocks, the heat production variations are largely correlated with processes that affect K_2 O concentration and covary with other major oxides as a consequence. Among sedimentary rocks,aluminous shales are the highest heat producing(2.9 μW^(-3)) whereas more common iron shales are lower heat producing(1.7 μW m^(-3)). Pure quartzites and carbonates are the lowest heat producing sedimentary rocks. Globally, there is little definitive evidence for a decrease in heat production with increasing metamorphic grade. However, there remains the need for high resolution studies of heat production variations within individual protoliths that vary in metamorphic grade. These results improve estimates of heat production and natural variability of rocks that will allow for more accurate temperature models of the lithosphere.
基金supported by the National Natural Science Foundation of China (Nos. 51574243, 51404269)the Fundamental Research Funds for the Central Universities of China (No. 2014XT01)+1 种基金Guizhou Science and Technology Foundation of China (No. 20152072)the Priority Academic Program Development of Jiangsu Higher Education Institutions, China (No. SZBF2011-6B35)
文摘This paper puts forward using high-pressure water jet technology to control rock burst in roadway, and analyzes the theory of controlling rock burst in roadway by the weak structure zone model. The weak structure zone is formed by using high-pressure water jet to cut the coal wall in a continuous and rotational way. In order to study the influence law of weak structure zone in surrounding rock, this paper numerically analyzed the influence law of weak structure zone, and the disturbance law of coal wall and floor under dynamic and static combined load. The results show that when the distance between high-pressure water jet drillings is 3 m and the diameter of drilling is 300 mm, continuous stress superposition zone can be formed. The weak structure zone can transfer and reduce the concentrated static load in surrounding rock, and then form distressed zone. The longer the high-pressure water jet drilling is, the larger the distressed zone is. The stress change and displacement change of non-distressed zone in coal wall and floor are significantly greater than that of distressed zone under dynamic and static combined load. And it shows that the distressed zone can effectively control rock burst in roadway under dynamic and static combined load. High-pressure water jet technology was applied in the haulage gate of 250203 working face in Yanbei Coal Mine, and had gained good effect. The study conclusions provide theoretical foundation and a new guidance for controlling rock burst in roadway.
基金The National Natural Science Foundation of. China (Grant No.40420120135 and 40472096) are thankefl for the fthancial support.
文摘Neoarchean metamorphic mafic rocks in the lower and the middle Wutai Complex mainly comprise metamorphic gabbros, amphibolites and chlorite schists. They can be subdivided into three groups according to chondrite normalized REE patterns. Rocks in Group #1 are characterized by nearly flat REE patterns (Lan/Ybn=0.86-1.3), the lowest total REEs (29-52 ppm), and weak negative to positive Eu anomalies (Eun/Eun=0.84-1.02), nearly flat primitive mantle normalized patterns and strong negative Zr(Hf) anomalies. Their geochemical characteristics in REEs and trace elements are similar to those of ocean plateau tholeiite, which imply that this group of rocks can represent remnants of Archean oceanic crust derived from a mantle plume. Rocks in Group #2 are characterized by moderate total REEs (34-116 ppm), LREE-enriched (Lan/Ybn=1.76-4.34) chondrite normalized REE patterns with weak Eu anomalies (Eun/Eun=0.76-1.16), and negative Nb, Ta, Zr(Hf), Ti anomalies in the primitive mantle normalized spider diagram. The REE and trace element characteristics indicate that they represent arc magmas originating from a sub-arc mantle wedge metasomatized by slab-derived fluids. Rocks in Group #3 are characterized by the highest total REEs (61-192 ppm), the strongest LREEs enrichment (Lan/Ybn=7.12-16) with slightly negative Eu anomalies (Eun/Eun=0.81-0.95) in the chondrite normalized diagram. In the primitive mantle normalized diagram, these rocks are characterized by large negative anomalies in Nb, Ta, Ti, negative to no Zr anomalies. They represent arc magmas originating from a sub-arc mantle wedge enriched in slab-derived melts. The three groups of rocks imply that the formation of the Neoarchean Wutai Complex is related to mantle plumes and island-arc interaction.
文摘The Xiaotongjiapuzi gold deposit occurs in a Palaeoproterozoic rift accretionary terrane in eastern Liaoning and is hosted by a carbonate formation of the Dashiqiao Formation, Liaohe Group. The metamorphic grade of the host rock is low amphibolite-high greenschist facies. Gold, which is mainly invisible, is distributed in pyrite and arsenopyrite. The grains of Au-bearing sulphide minerals are fine, ranging from 0.0 n to 1 mm. The wall-rock alterations are characterized by low-temperature silification, hydro-sericitization, sericitization and carbonatization. The homogenization temperatures of the fluid inclusions in quartz closely associated with gold mineralization range from 140 to 240°C. The metallogenic age represented by the Ar-Ar isotopic age of sericite is 167 Ma. Comparisons and studies show that the Xiaotongjiapuzi gold deposit can be classified as the submicron-sized disseminated deposit (analogous to the Carlin-type) hosted in metamorphic rocks.
基金Authors thank the CPRI Project(NPP/2016/HY/1/13042016)for partially supporting the study.Support from NHPC Ltd.and NTPC Ltd.is also thankfully acknowledged.
文摘Assessment of drillability of rocks is vital in the selection,operation,and performance evaluation of cutting tools used in various excavation machinery deployed in mining and tunneling.The commonly used rock drillability prediction methods,namely,drilling rate index(DRI)and Cerchar hardness index(CHI)have limitations in predicting the penetration rate due to differential wear of the cutting tool in rocks with varied hardness and abrasivity.Since cutting tools get blunt differently in different rocks,the stress beneath the tip of the bit decreases until it reaches a threshold value beyond which the penetration rate becomes constant.In this research,a new composite penetration rate index(CPRI)is suggested based on the investigations on four metamorphic rocks viz.quartzite,gneiss,schist and phyllite with varied hardness-abrasivity values.The penetration-time behavior was classified into active,moderate,passive,and dormant phases based on the reduction in penetration rate at different stages of drilling.A comparison of predicted penetration rate values using DRI and CPRI with actual penetration rate values clearly establishes the supremacy of CPRI.Micro-structure and hardness-based index was also developed and correlated with CPRI.The new indices can help predict cutting tool penetration and its consumption more accurately.