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A discussion about the limitations of the Eurocode’s high-speed load model for railway bridges
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作者 Gonçalo Ferreira Pedro Montenegro +2 位作者 JoséRui Pinto António Abel Henriques Rui Calçada 《Railway Engineering Science》 EI 2024年第2期211-228,共18页
High-speed railway bridges are subjected to normative limitations concerning maximum permissible deck accelerations.For the design of these structures,the European norm EN 1991-2 introduces the high-speed load model(H... High-speed railway bridges are subjected to normative limitations concerning maximum permissible deck accelerations.For the design of these structures,the European norm EN 1991-2 introduces the high-speed load model(HSLM)—a set of point loads intended to include the effects of existing high-speed trains.Yet,the evolution of current trains and the recent development of new load models motivate a discussion regarding the limits of validity of the HSLM.For this study,a large number of randomly generated load models of articulated,conventional,and regular trains are tested and compared with the envelope of HSLM effects.For each type of train,two sets of 100,000 load models are considered:one abiding by the limits of the EN 1991-2 and another considering wider limits.This comparison is achieved using both a bridge-independent metric(train signatures)and dynamic analyses on a case study bridge(the Canelas bridge of the Portuguese Railway Network).For the latter,a methodology to decrease the computational cost of moving loads analysis is introduced.Results show that some theoretical load models constructed within the stipulated limits of the norm can lead to effects not covered by the HSLM.This is especially noted in conventional trains,where there is a relation with larger distances between centres of adjacent vehicle bogies. 展开更多
关键词 high-speed load model Dynamic analysis high-speed railways Train signature Railway bridges Deck acceleration
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Stability analysis of loose accumulation slopes under rainfall:case study of a high‑speed railway in Southwest China
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作者 Xin Wang Qian Su +2 位作者 Zongyu Zhang Feihu Huang Chenfang He 《Railway Engineering Science》 EI 2024年第1期95-106,共12页
The high and steep slopes along a high-speed railway in the mountainous area of Southwest China are mostly composed of loose accumulations of debris with large internal pores and poor stability,which can easily induce... The high and steep slopes along a high-speed railway in the mountainous area of Southwest China are mostly composed of loose accumulations of debris with large internal pores and poor stability,which can easily induce adverse geological disasters under rainfall conditions.To ensure the smooth construction of the high-speed railway and the subsequent safe operation,it is necessary to master the stability evolution process of the loose accumulation slope under rainfall.This article simulates rainfall using the finite element analysis software’s hydromechanical coupling module.The slope stability under various rainfall situations is calculated and analysed based on the strength reduction method.To validate the simulation results,a field monitoring system is established to study the deformation characteristics of the slope under rainfall.The results show that rainfall duration is the key factor affecting slope stability.Given a constant amount of rainfall,the stability of the slope decreases with increasing duration of rainfall.Moreover,when the amount and duration of rainfall are constant,continuous rainfall has a greater impact on slope stability than intermittent rainfall.The setting of the field retaining structures has a significant role in improving slope stability.The field monitoring data show that the slope is in the initial deformation stage and has good stability,which verifies the rationality of the numerical simulation method.The research results can provide some references for understanding the influence of rainfall on the stability of loose accumulation slopes along high-speed railways and establishing a monitoring system. 展开更多
关键词 high-speed railway Loose accumulation slope Slope stability analysis Rainfall effect Strength reduction
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Investigation on influencing factors of wheel polygonization of a plateau high-speed EMU train
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作者 Wei Li Xiaoxuan Yang +2 位作者 Peng Wang Zefeng Wen Jian Han 《Railway Sciences》 2024年第5期593-608,共16页
Purpose–This study aims to investigate the cause of high-order wheel polygonization in a plateau high-speed electric multiple unit(EMU)train.Design/methodology/approach–A series of field tests were conducted to meas... Purpose–This study aims to investigate the cause of high-order wheel polygonization in a plateau high-speed electric multiple unit(EMU)train.Design/methodology/approach–A series of field tests were conducted to measure the vibration accelerations of the axle box and bogie when the wheels of the EMU train passed through tracks with normal rail roughness after re-profiling.Additionally,the dynamic characteristics of the track,wheelset and bogie were also measured.These measurements provided insights into the mechanisms that lead to wheel polygonization.Findings–The results of the field tests indicate that wheel polygonal wear in theEMUtrain primarily exhibits 14–16 and 25–27 harmonic orders.The passing frequencies of wheel polygonization were approximately 283–323 Hz and 505–545 Hz,which closely match the dominated frequencies of axle box and bogie vibrations.These findings suggest that the fixed-frequency vibrations originate from the natural modes of the wheelset and bogie,which can be excited by wheel/rail irregularities.Originality/value–The study provides novel insights into the mechanisms of high-order wheel polygonization in plateau high-speed EMU trains.Futher,the results indicate that operating the EMU train on mixed lines at variable speeds could potentially mitigate high-order polygonal wear,providing practical value for improving the safety,performance and maintenance efficiency of high-speed EMU trains. 展开更多
关键词 Wheel polygonization high-speed EMU train Modal analysis Field tests
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High-speed railway and safety: Insights from a bibliometric approach
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作者 Apostolos Anagnostopoulos 《High-Speed Railway》 2024年第3期187-196,共10页
High-Speed Rail(HSR)systems represent a significant advancement in modern transportation.They offer rapid,efficient,and environmentally friendly alternatives to traditional rail,air travel and road transportation.Even... High-Speed Rail(HSR)systems represent a significant advancement in modern transportation.They offer rapid,efficient,and environmentally friendly alternatives to traditional rail,air travel and road transportation.Even if highspeed trains appeared approximately in the middle of the previous century,several aspects concerning safety remain.This study aims to comprehensively review the scientific literature related to the safety issues of high-speed railways.A bibliometric analysis was carried out utilizing 2358 publications from the last two decades(2004-2023)to understand better the existing research on HSR and safety.Future trends and thematic areas of research are identified and analyzed.Chinese researchers and universities have led the total number of current publications related to the context of HSR safety.While most of the publications come from Chinese institutions,a significant international collaboration can be identified.The main areas of research on HSR and safety can be classified into four main clusters based on the keywords co-occurrence analysis and are related to risk management,structural dynamics and resilience in railway systems,geotechnical engineering and tunnelling and maintenance technologies.Researchers and policymakers can use the results of this study to better understand the dynamics of scientific research in the field of highspeed railways and safety and make decisions about future directions and funding priorities. 展开更多
关键词 high-speed rail SAFETY Literature review Bibliometric analysis VOSViewer
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Study on the Influence of Lanzhou-Urumqi High-Speed Railway on Regional Accessibility and Economic Development
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作者 Lili Ma Xiaolong Han Miao Gong 《Proceedings of Business and Economic Studies》 2024年第2期22-31,共10页
The Lanzhou-Urumqi high-speed railway is an important part of the railway network connecting Gansu,Qinghai,and Xinjiang,and it is of far-reaching significance in facilitating China’s western development.An accessibil... The Lanzhou-Urumqi high-speed railway is an important part of the railway network connecting Gansu,Qinghai,and Xinjiang,and it is of far-reaching significance in facilitating China’s western development.An accessibility model and a double difference model were built to analyze the impact of the Lanzhou-Urumqi high-speed railway on regional accessibility and economic development of the areas along the line before(2012-2014)and after(2017-2019)its opening.The results show that the regional accessibility remains unchanged before and after the operation of this railway line.However,there is a spatial difference in improvement,that of central cities being better.The opening of the high-speed railway is conducive to driving the overall economic development of the region and promoting the comprehensive and coordinated development of regional economies. 展开更多
关键词 Lanzhou-Urumqi high-speed railway Regional economy Double difference model Accessibility model Empirical analysis
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Dynamic Stability Analysis of Cages in High-Speed Oil-Lubricated Angular Contact Ball Bearings 被引量:12
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作者 刘秀海 邓四二 滕弘飞 《Transactions of Tianjin University》 EI CAS 2011年第1期20-27,共8页
To investigate the cage stability of high-speed oil-lubricated angular contact ball bearings, a dynamic model of cages is developed on the basis of Gupta’s and Meeks’ work. The model can simulate the cage motion und... To investigate the cage stability of high-speed oil-lubricated angular contact ball bearings, a dynamic model of cages is developed on the basis of Gupta’s and Meeks’ work. The model can simulate the cage motion under oil lubrication with all six degrees of freedom. Particularly, the model introduces oil-film damping and hysteresis damping, and deals with the collision contact as imperfect elastic contact. In addition, the effects of inner ring rotational speed, the ratio of pocket clearance to guiding clearance and applied load on the cage stability are investigated by simulating the cage motion with the model. The results can provide a theoretical basis for the design of ball bearing parameters. 展开更多
关键词 dynamic analysis high-speed angular contact ball bearing CAGE STABILITY SIMULATION
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Parametric analysis on buffeting performance of a long-span high-speed railway suspension bridge 被引量:5
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作者 ZHAO Kai-yong WANG Hao +2 位作者 TAO Tian-you GAO Hui WU Tong 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第8期2574-2588,共15页
The buffeting performance of kilometer-level high-speed railway suspension bridges has a great impact on the smooth operation of high-speed trains.To investigate the buffeting performance of the structure significantl... The buffeting performance of kilometer-level high-speed railway suspension bridges has a great impact on the smooth operation of high-speed trains.To investigate the buffeting performance of the structure significantly different from traditional suspension bridges,the first long-span high-speed railway suspension bridge,Wufengshan Yangtze River Bridge(WYRB),is taken as a numerical example to demonstrate the effects of structural parameters and wind field parameters on the buffeting responses.Based on the design information,the spatial finite element model(FEM)of WYRB is established before testing its accuracy.The fluctuating wind fields are simulated via both classical and stochastic wave based spectral representation method(SRM).Finite element method is further taken to analyze the parametric sensitivity on wind induced buffeting responses in time domain.The results show that the vertical displacement is more sensitive to the changing dead load than the lateral and torsional ones.The larger stiffness of the main girder and the lower sag-to-span ratio are both helpful to reduce the buffeting responses.Wind spectrum and coherence function are key influencing factors to the responses so setting proper wind field parameters are essential in the wind-resistant design stage.The analytical results can provide references for wind resistance analysis and selection of structural and fluctuating wind field parameters for similar long-span high-speed railway suspension bridges. 展开更多
关键词 high-speed railway suspension bridge buffeting performance numerical analysis parametric analysis wind field simulation
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AN ANALYSIS METHOD FOR HIGH-SPEED CIRCUIT SYSTEMS 被引量:2
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作者 Dou Lei Wang Zhiquan 《Journal of Electronics(China)》 2006年第3期467-470,共4页
A new method for analyzing high-speed circuit systems is presented. The method adds transmission line end currents to the circuit variables of the classical modified nodal approach. Then the matrix equation describing... A new method for analyzing high-speed circuit systems is presented. The method adds transmission line end currents to the circuit variables of the classical modified nodal approach. Then the matrix equation describing high-speed circuit system can be formulated directly and analyzed conveniently for its normative form. A time-domain analysis method for transmission lines is also introduced. The two methods are combined together to efficiently analyze high-speed circuit systems having general transmission lines. Numerical experiment is presented and the results are compared with that calculated by Hspice. 展开更多
关键词 Transmission lines high-speed circuit system MacCormack method Circuit analysis
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Network analysis and spatial agglomeration of China’s high-speed rail: A dual network approach 被引量:1
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作者 Wei Wang Wen-Bo Du +2 位作者 Wei-Han Li Lu(Carol)Tong Jiao-E Wang 《Chinese Physics B》 SCIE EI CAS CSCD 2021年第1期612-622,共11页
China has the largest high-speed railway(HSR) system in the world, and it has gradually reshaped the urban network.The HSR system can be represented as different types of networks in terms of the nodes and various rel... China has the largest high-speed railway(HSR) system in the world, and it has gradually reshaped the urban network.The HSR system can be represented as different types of networks in terms of the nodes and various relationships(i.e.,linkages) between them. In this paper, we first introduce a general dual network model, including a physical network(PN)and a logical network(LN) to provide a comparative analysis for China’s high-speed rail network via complex network theory. The PN represents a layout of stations and rail tracks, and forms the basis for operating all trains. The LN is a network composed of the origin and destination stations of each high-speed train and the train flows between them. China’s high-speed railway(CHSR) has different topological structures and link strengths for PN in comparison with the LN. In the study, the community detection is used to analyze China’s high-speed rail networks and several communities are found to be similar to the layout of planned urban agglomerations in China. Furthermore, the hierarchies of urban agglomerations are different from each other according to the strength of inter-regional interaction and intra-regional interaction, which are respectively related to location and spatial development strategies. Moreover, a case study of the Yangtze River Delta shows that the hub stations have different resource divisions and are major contributors to the gap between train departure and arrival flows. 展开更多
关键词 China’s high-speed rail dual network network analysis urban agglomeration
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Analysis of droplet transfer of pulsed MIG welding based on electrical signal and high-speed photography 被引量:1
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作者 姚屏 薛家祥 +1 位作者 黄文超 张瑞 《China Welding》 EI CAS 2009年第1期67-72,共6页
In order to study how welding parameters affect welding quality and droplet transfer, a synchronous acquisition and analysis system is established to acquire and analyze electrical signal and instantaneous images of d... In order to study how welding parameters affect welding quality and droplet transfer, a synchronous acquisition and analysis system is established to acquire and analyze electrical signal and instantaneous images of droplet transfer simultaneously, which is based on a self-developed soft-switching inverter. On the one hand, welding current and voltage signals are acquired and analyzed by a self-developed dynamic wavelet analyzer. On the other hand, images are filtered and optimized after they are captured by high-speed camera. The results show that instantaneous waveforms and statistical data of electrical signal contribute to make an overall assessment of welding quality, and that optimized high-speed images allow a visual and clear observation of droplet transfer process. The analysis of both waveforms and images leads to a further research on droplet transfer mechanism and provides a basis for precise control of droplet transfer. 展开更多
关键词 pulsed MIG welding droplet transfer high-speed photography image processing wavelet analysis
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Structural analysis and design of frost resistance function for subgrade of high-speed railway ballasted track in cold regions 被引量:1
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作者 Qiang Luo WenQiang Lv +1 位作者 QingZhi Ye RuiGuo Zhang 《Research in Cold and Arid Regions》 CSCD 2015年第5期594-604,共11页
According to the technical characteristics of short fixed wheelbase of a high-speed carriage, a subgrade-track integrated space mechanical response analysis model is proposed for trains under the action ofbiaxial load... According to the technical characteristics of short fixed wheelbase of a high-speed carriage, a subgrade-track integrated space mechanical response analysis model is proposed for trains under the action ofbiaxial load after the comparison of the stress distribution characteristics of the ballast track subgrade bed structures for high-speed railway under the action of uniaxial load and biaxial load. The loading threshold value (high-cycle long-term dynamic strength) under the circum- stance where the cumulative deformation of subgrade structure gradually develops and finally reaches the convergent state, and its relationship with the foundation coefficient K30 were deduced, based on the characteristics of cumulative defor- mation evolution obtained from the unit structure filling model test under the action of cyclic loading. In view of structure stability and frost resistance requirements of the railway subgrade in cold regions, technical conditions to maintain good service performance of subgrade structure of high-speed railway ballasted track are discussed and analyzed. Study results show that the additive effect manifests itself obviously for railway train bogies under the action of biaxial load than uni- axial load, which has a significant dynamic effect on the subgrade bed bottom and a slight effect on the surface layer. Thus, the adoption of a biaxial load model in the design of a high-speed railway subgrade accurately reflects the vehicle load. Pursuant to the structure design principle, the design method of the subgrade structure of high-speed railway ballasted track is proposed to meet the technical requirements such as structural strength, bearing stiffness and high-cyclic and long-term stability. Technical indicators are obtained for the variation of thickness of the surface layer of reinforced sub- grade bed in the double-layer subgrade mode along with the change of K30 at the subgrade bed bottom. The double-layer structure mode of "closure on the upper layer and drainage on the lower layer" was proposed in order to meet the water- proofing and drainage requirements of the upper layer of the subgrade bed in cold regions. A dense-framework graded gravel filler with weak water permeability at a coefficient of 10 4 cm/s is used on the upper layer and the void-framework graded gravel filler at the water permeability coefficient of 10 2 cm/s is adopted on the lower layer. 展开更多
关键词 high-speed railway in cold regions subgrade structure biaxial load mode structural analysis design of frostresistance function
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Evaluation and optimization analysis of high-speed rail network structure in Northeast China under the background of northeast revitalization 被引量:1
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作者 XU Shaojie WANG Fuyuan WANG Kaiyong 《Regional Sustainability》 2021年第4期349-362,共14页
The construction of high-speed rail(HSR)network has promoted the social-economic ties of cities,accelerated the compression of time and space,and changed the pattern of regional development.In this paper,with the adop... The construction of high-speed rail(HSR)network has promoted the social-economic ties of cities,accelerated the compression of time and space,and changed the pattern of regional development.In this paper,with the adoption of the operation frequency data of HSR from 12306 website,and based on the HSR connection strength model and social network analysis model,as well as according to the HSR connection strength,HSR network density,centrality,agglomeration subgroup,and other indicators,we analyzed the characteristics of HSR network structure in Northeast China.Results show that the number of HSR cities in Northeast China is small,cities in HSR network generally exhibit weak connectivity,and the existence of HSR network marginalizes cities such as Ulanhot,Baicheng,and Songyuan,which significantly reduce the overall network connectivity of Northeast China.The overall centrality of HSR network in Northeast China is characterized by“one axis,four edges”;specifically,the one axis is located in Harbin-Dalian transportation line and the four edges are located on both sides of the main axis of Harbin-Dalian transportation line.Eight agglomeration subgroups(four double city subgroups and four multi city subgroups)have formed in Northeast China.The core status of Shenyang in HSR network is improved significantly,and“one axis and two wings”HSR network in Liaoning Province is improved significantly.With the gradual expansion of Chaoyang-Fuxin,Dandong-Benxi,and Jilin-Yanji branch networks,the“point axis”HSR network mode in Northeast China has gradually developed and matured.In the future,it is recommended to rely on eight agglomerating subgroups to encrypt HSR network structure,create secondary node central cities,and gradually build a new pattern of opening up in Northeast China. 展开更多
关键词 Social network analysis high-speed rail network structure Operation frequency Intercity connection intensity Network density analysis Northeast China
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Simulation Analysis Module of High-speed Rail Bearings Based on Secondary Development in ADAMS 被引量:4
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《Computer Aided Drafting,Design and Manufacturing》 2013年第3期46-50,共5页
This paper develops a strong secondary development based on ADAMS feature which creates high-speed rail bearings for simulation analysis module. This thesis is in the case of non-circular pattern instructions of how t... This paper develops a strong secondary development based on ADAMS feature which creates high-speed rail bearings for simulation analysis module. This thesis is in the case of non-circular pattern instructions of how to achieve rapid roller modeling, with analysis of functions and parameters required for the design of the simulation module of the high-speed rail bearing, as well as the design of dialog boxes, the environment and file structure. The specific modules is based on the secondary development language provided by ADAMS ! View. Through the menus, dialog boxes which input parameters, it can achieve high iron bearing automatic modeling, dynamic analysis and post-processing to simplify the analysis of high-speed rail bearing operations, as well as improving the high-speed rail bearing development efficiency. 展开更多
关键词 ADAMS secondary development high-speed rail bearing simulation analysis
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Sensitivity analysis of distributed parameter elements in high-speed circuit networks
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作者 Lei DOU Zhiquan WANG 《控制理论与应用(英文版)》 EI 2007年第1期53-56,共4页
This paper presents an analysis method, based on MacCormack's technique, for the evaluation of the time domain sensitivity of distributed parameter elements in high-speed circuit networks. Sensitivities can be calcul... This paper presents an analysis method, based on MacCormack's technique, for the evaluation of the time domain sensitivity of distributed parameter elements in high-speed circuit networks. Sensitivities can be calculated from electrical and physical parameters of the distributed parameter elements. The proposed method is a direct numerical method of time-space discretization and does not require complicated mathematical deductive process. Therefore, it is very convenient to program this method. It can be applied to sensitivity analysis of general transmission lines in linear or nonlinear circuit networks. The proposed method is second-order-accurate. Numerical experiment is presented to demonstrate its accuracy and efficiency. 展开更多
关键词 Sensitivity analysis Distributed parameter Multiconductor transmission fines high-speed circuit networks MacCormack method
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Parametric analysis of wheel wear in high-speed vehicles
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作者 Na Wu Jing Zeng 《Journal of Modern Transportation》 2014年第2期76-83,共8页
In order to reduce the wheel profile wear of highspeed trains and extend the service life of wheels, a dynamic model for a high-speed vehicle was set up, in which the wheelset was regarded as flexible body, and the ac... In order to reduce the wheel profile wear of highspeed trains and extend the service life of wheels, a dynamic model for a high-speed vehicle was set up, in which the wheelset was regarded as flexible body, and the actual measured track irregularities and line conditions were considered. The wear depth of the wheel profile was calculated by the well-known Archard wear law. Through this model, the influence of the wheel profile, primary suspension stiffness, track gage, and rail cant on the wear of wheel profile were studied through multiple iterafive calculations. Numerical simulation results show that the type XP55 wheel profile has the smallest cumulative wear depth, and the type LM wheel profile has the largest wear depth. To reduce the wear of the wheel profile, the equivalent conicity of the wheel should not be too large or too small. On the other hand, a small primary vertical stiffness, a track gage around 1,435-1,438 mm, and a rail cant around 1:35-1:40 are beneficial for dynamic performance improvement and wheel wear alleviation. 展开更多
关键词 Parametric analysis Wheel profile wear Flexible wheelset high-speed railway Vehicle dynamicmodel Finite element method
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The price analysis of Chinese high-speed economic growth
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作者 ZHOU Yu-feng 《Chinese Business Review》 2008年第9期32-34,共3页
Accelerating economic development in various countries today is the common demands. In the past 20 years, China created an economic development miracle, but also highlighted the depletion of resources, the deteriorati... Accelerating economic development in various countries today is the common demands. In the past 20 years, China created an economic development miracle, but also highlighted the depletion of resources, the deterioration of ecological, unfair distribution, the income gap and other social issues. The article analyses the causes of the price and the countermeasures. 展开更多
关键词 Chinese economy high-speed Growth the price analysis
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Multi-objective optimization of the cathode catalyst layer micro-composition of polymer electrolyte membrane fuel cells using a multi-scale,two-phase fuel cell model and data-driven surrogates 被引量:1
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作者 Neil Vaz Jaeyoo Choi +3 位作者 Yohan Cha Jihoon Kong Yooseong Park Hyunchul Ju 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第6期28-41,I0003,共15页
Polymer electrolyte membrane fuel cells(PEMFCs)are considered a promising alternative to internal combustion engines in the automotive sector.Their commercialization is mainly hindered due to the cost and effectivenes... Polymer electrolyte membrane fuel cells(PEMFCs)are considered a promising alternative to internal combustion engines in the automotive sector.Their commercialization is mainly hindered due to the cost and effectiveness of using platinum(Pt)in them.The cathode catalyst layer(CL)is considered a core component in PEMFCs,and its composition often considerably affects the cell performance(V_(cell))also PEMFC fabrication and production(C_(stack))costs.In this study,a data-driven multi-objective optimization analysis is conducted to effectively evaluate the effects of various cathode CL compositions on Vcelland Cstack.Four essential cathode CL parameters,i.e.,platinum loading(L_(Pt)),weight ratio of ionomer to carbon(wt_(I/C)),weight ratio of Pt to carbon(wt_(Pt/c)),and porosity of cathode CL(ε_(cCL)),are considered as the design variables.The simulation results of a three-dimensional,multi-scale,two-phase comprehensive PEMFC model are used to train and test two famous surrogates:multi-layer perceptron(MLP)and response surface analysis(RSA).Their accuracies are verified using root mean square error and adjusted R^(2).MLP which outperforms RSA in terms of prediction capability is then linked to a multi-objective non-dominated sorting genetic algorithmⅡ.Compared to a typical PEMFC stack,the results of the optimal study show that the single-cell voltage,Vcellis improved by 28 m V for the same stack price and the stack cost evaluated through the U.S department of energy cost model is reduced by$5.86/k W for the same stack performance. 展开更多
关键词 Polymer electrolyte membrane fuel cell Surrogate modeling Multi-layer perceptron(MLP) Response surface analysis(RSA) Non-dominated sorting genetic algorithmⅡ(NSGAⅡ)
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Artificial Hybrid Solid Electrolyte-Mediated Ca Metal for Ultradurable Room Temperature 5 V Calcium Batteries
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作者 Huawei Song Chengxin Wang 《Energy & Environmental Materials》 SCIE EI CAS CSCD 2023年第2期142-151,共10页
The anodic stability and reversibility of Ca metal electrodeposition/dissolution have always been hampered by surface passivation and anion corrosion,especially in F-based carbonate ester electrolytes at high device v... The anodic stability and reversibility of Ca metal electrodeposition/dissolution have always been hampered by surface passivation and anion corrosion,especially in F-based carbonate ester electrolytes at high device voltages.To avoid direct Ca metal/electrolyte reactions,an artificial hybrid solid electrolyte layer(AHSEL),which is characteristic of sodium/calcium carbonate and calcium hydride nitride nanocrystals of size<10 nm encapsulated by amorphous C,N species,is constructed on calcium with good ion conductivity(≈0.01 mS cm^(-1))and uniform coating of thickness≈20μm.After cycling in the KPF_(6) electrolyte,AHSEL is transformed into Na/K/Ca hybrid solid electrolyte interphases(SEIs),which is a compact layer composed of monodisperse nanocrystals(mostly Ca_(2)NH)and small amorphous zones,thus greatly suppressing the fluoridation of the Ca deposit.Consequently,the plating/stripping performance of AHSEL-modified Ca(AHSEL-Ca)is markedly improved compared with that of pristine Ca,lasting for>1400 h at a polarization shift of<0.4 mV/h.The AHSEL-Ca anode also endows Ca batteries with superior anodic stability with a ceiling voltage of up to 5.0 V,a high discharge voltage(>3.3 V),a large capacity of≈80 mAh g^(-1)at 200 mA g^(-1),and an ultralong lifespan≈5000 cycles. 展开更多
关键词 artificial solid electrolyte calcium metal batteries depth analysis electrolyte interphases high voltage
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Feasibility of Scaling up the Cost-Competitive and Clean Electrolytic Hydrogen Supply in China
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作者 Guangsheng Pan Wei Gu +4 位作者 Zhongfan Gu Jin Lin Suyang Zhou Zhi Wu Shuai Lu 《Engineering》 SCIE EI CAS CSCD 2024年第8期154-165,共12页
Scaling up clean hydrogen supply in the near future is critical to achieving China’s hydrogen development target.This study established an electrolytic hydrogen development mechanism considering the generation mix an... Scaling up clean hydrogen supply in the near future is critical to achieving China’s hydrogen development target.This study established an electrolytic hydrogen development mechanism considering the generation mix and operation optimization of power systems with access to hydrogen.Based on the incremental cost principle,we quantified the provincial and national clean hydrogen production cost performance levels in 2030.The results indicated that this mechanism could effectively reduce the production cost of clean hydrogen in most provinces,with a national average value of less than 2 USD·kg^(-1) at the 40-megaton hydrogen supply scale.Provincial cooperation via power transmission lines could further reduce the production cost to 1.72 USD·kg^(-1).However,performance is affected by the potential distribution of hydrogen demand.From the supply side,competitiveness of the mechanism is limited to clean hydrogen production,while from the demand side,it could help electrolytic hydrogen fulfil a more significant role.This study could provide a solution for the ambitious development of renewables and the hydrogen economy in China. 展开更多
关键词 Low-carbon energy system electrolytic hydrogen RENEWABLES Cost optimization and analysis
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Differential Electrolytic Potentiometry a Detector in Flow Injection Analysis for Cyanide Determination
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作者 Safwan Fraihat Abdullah Abulkibash 《材料科学与工程(中英文A版)》 2011年第2X期248-252,共5页
关键词 流动注射分析 氰化物测定 电位 电解 检测器 差分 试剂浓度 定量测定
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