The microstructure of the thin-walled tubes with high-strength aluminum alloy determines their final forming quality and performance. This type of tube can be manufactured by multi-pass hot power backward spinning pro...The microstructure of the thin-walled tubes with high-strength aluminum alloy determines their final forming quality and performance. This type of tube can be manufactured by multi-pass hot power backward spinning process as it can eliminate casting defects, refine microstructure and improve the plasticity of the tube. To analyze the microstructure distribution characteristics of the tube during the spinning process, a 3D coupled thermo-mechanical FE model coupled with the microstructure evolution model of the process was established under the ABAQUS environment. The microstructure evolution characteristics and laws of the tube for the whole spinning process were analyzed. The results show that the dynamic recrystallization is mainly produced in the spinning deformation zone and root area of the tube. In the first pass, the dynamic recrystallization phenomenon is not obvious in the tube. With the pass increasing, the trend of dynamic recrystallization volume percentage gradually increases and extends from the outer surface of the tube to the inner surface. The fine-grained area shows the states of concentration, dispersion, and re-concentration as the pass number increases. .展开更多
This study aims to explore a method suitable for welding 7A52 high-strength aluminum alloy plates with continuously varying thicknesses and the causes of microscopic defects in welds in order to improve welding qualit...This study aims to explore a method suitable for welding 7A52 high-strength aluminum alloy plates with continuously varying thicknesses and the causes of microscopic defects in welds in order to improve welding quality.Comparative tests were conducted to analyze weld defects and deformation when welding the aluminum alloy plates with varying thicknesses at constant laser power.The laser power required for melting welds at varying-thickness positions was estimated.Weld defects and deformation when welding aluminum alloy plates with varying thicknesses at con-tinuous variable laser power were detected.The causes of microscopic weld defects during constant-power welding were analyzed.The welding defects and deformation and the welding quality were improved by welding aluminum alloy plates at continuous variable power.展开更多
The process of friction-stir welding 2A12CZ alloy has been studied. And strength and elongation tests have been performed, which demonstrated that the opportunity existed to manipulate friction-stir welding parameters...The process of friction-stir welding 2A12CZ alloy has been studied. And strength and elongation tests have been performed, which demonstrated that the opportunity existed to manipulate friction-stir welding parameters in order to improve a range of material properties. The results showed that the joint strength and elongation arrived at their maximums (331 MPa and 4%) at 37.5 mm/min and 300 rpm. As welding parameters changing, joint tensile strength and elongation had similar development. Hardness measurement indicated that the weld was softened. However, there was considerable difference in softening degree for different joint zone. The weld top had lower hardness and wider softening zone than other zone of the weld. And softening zone at advancing side was wider than that at retreating side.展开更多
The two-phase zone continuous casting(TZCC)technique was used to continuously cast high-strength aluminum alloy hollow billets,and a verified 3D model of TZCC was used to simulate the flow and temperature fields at ca...The two-phase zone continuous casting(TZCC)technique was used to continuously cast high-strength aluminum alloy hollow billets,and a verified 3D model of TZCC was used to simulate the flow and temperature fields at casting speeds of 2-6 mm·min^(-1).Hollow billets under the same conditions were prepared,and their macro/microstructures were analyzed by an optical microscope and a scanning electron microscope.During the TZCC process,a circular fluid flow appears in front of the mushy zone,and the induction heated stepped mold and convective heat transfer result in a curved solidification front with depressed region near the inner wall and a vertical temperature gradient.The deflection of the solidification front decreases and the average cooling rate in the mushy zone increases with increasing casting speed.Experimental results for a 2D12 alloy show that hot tearing periodically appears in the hollow billet accompanied by macrosegregation near the inner wall at casting speeds of 2 and 4 mm·min^(-1),while macroscopic defects of hot tearing and macrosegregation weaken and the average size of columnar crystals in the hollow billets decreases with further increasing casting speed.2D12 aluminum alloy hollow billets with no macroscopic defects,the finest columnar crystals,and excellent mechanical properties were prepared by TZCC at a casting speed of 6 mm·min^(-1),which is beneficial for the further plastic forming process.展开更多
Friction stir welding (FSW) has been widely used in many industries, with which high-strength aluminum alloys can be well joined. However, the corrosion resistance of FSW high-strength Al alloy joints is relatively ...Friction stir welding (FSW) has been widely used in many industries, with which high-strength aluminum alloys can be well joined. However, the corrosion resistance of FSW high-strength Al alloy joints is relatively poor, which limits their industrial applications. The joints shall be protected against corrosion. In this review, therefore, the current status and development of corrosion protection for FSW high-strength Al alloy joints are presented. Particular emphasis has been given to different protection methods : lowering heat input, post-weld heat treatment, surface modification and spray coatings. Finally, opportunities are identified for further research and development in corrosion protection of FSW high-strength Al alloy joints.展开更多
A Ni–P alloy gradient coating consisting of multiple electroless Ni–P layers with various phosphorus contents was prepared on the aviation aluminum alloy. Several characterization and electrochemical techniques were...A Ni–P alloy gradient coating consisting of multiple electroless Ni–P layers with various phosphorus contents was prepared on the aviation aluminum alloy. Several characterization and electrochemical techniques were used to characterize the different Ni–P coatings’ morphologies, phase structures, elemental compositions, and corrosion protection. The gradient coating showed good adhesion and high corrosion and wear resistance, enabling the application of aluminum alloy in harsh environments. The results showed that the double zinc immersion was vital in obtaining excellent adhesion (81.2 N). The optimal coating was not peeled and shredded even after bending tests with angles higher than 90°and was not corroded visually after 500 h of neutral salt spray test at 35℃. The high corrosion resistance was attributed to the misaligning of these micro defects in the three different nickel alloy layers and the amorphous structure of the high P content in the outer layer. These findings guide the exploration of functional gradient coatings that meet the high application requirement of aluminum alloy parts in complicated and harsh aviation environments.展开更多
Lightweight aluminum(Al)alloys have been widely used in frontier fields like aerospace and automotive industries,which attracts great interest in additive manufacturing(AM)to process high-value Al parts.As a mainstrea...Lightweight aluminum(Al)alloys have been widely used in frontier fields like aerospace and automotive industries,which attracts great interest in additive manufacturing(AM)to process high-value Al parts.As a mainstream AM technique,laser-directed energy deposition(LDED)shows good scalability to meet the requirements for large-format component manufacturing and repair.However,LDED Al alloys are highly challenging due to their inherent poor printability(e.g.low laser absorption,high oxidation sensitivity and cracking tendency).To further promote the development of LDED high-performance Al alloys,this review offers a deep understanding of the challenges and strategies to improve printability in LDED Al alloys.The porosity,cracking,distortion,inclusions,element evaporation and resultant inferior mechanical properties(worse than laser powder bed fusion)are the key challenges in LDED Al alloys.Processing parameter optimizations,in-situ alloy design,reinforcing particle addition and field assistance are the efficient approaches to improving the printability and performance of LDED Al alloys.The underlying correlations between processes,alloy innovation,characteristic microstructures,and achievable performances in LDED Al alloys are discussed.The benchmark mechanical properties and primary strengthening mechanism of LDED Al alloys are summarized.This review aims to provide a critical and in-depth evaluation of current progress in LDED Al alloys.Future opportunities and perspectives in LDED high-performance Al alloys are also outlined.展开更多
The evolution of microstructure during hot deformation is key to achieving good mechanical properties in aluminum alloys.We have developed a cellular automaton(CA) based model to simulate the microstructural evolution...The evolution of microstructure during hot deformation is key to achieving good mechanical properties in aluminum alloys.We have developed a cellular automaton(CA) based model to simulate the microstructural evolution in 7075 aluminum alloy during hot deformation.Isothermal compression tests were conducted to obtain material parameters for 7075 aluminum alloy,leading to the establishment of models for dislocation density,nucleation of recrystallized grains,and grain growth.Integrating these aspects with grain topological deformation,our CA model effectively predicts flow stress,dynamic recrystallization(DRX) volume fraction,and average grain size under diverse deformation conditions.A systematic comparison was made between electron back scattered diffraction(EBSD) maps and CA model simulated under different deformation temperatures(573 to 723 K),strain rates(0.001 to 1 s^(-1)),and strain amounts(30% to 70%).These analyses indicate that large strain,high temperature,and low strain rate facilitate dynamic recrystallization and grain refinement.The results from the CA model show good accuracy and predictive capability,with experimental error within 10%.展开更多
The AA5052 aluminum alloy is widely used in automobile and aerospace manufacturing,and with the development of light-weight alloys,it is required that these materials exhibit better mechanical properties.Previous stud...The AA5052 aluminum alloy is widely used in automobile and aerospace manufacturing,and with the development of light-weight alloys,it is required that these materials exhibit better mechanical properties.Previous studies have demonstrated that the addition of Sc to aluminum alloys can improve both the microstructure and properties of the alloys.In this study,the effect of Sc on the Fe-rich phase and properties of the AA5052 aluminum alloy was studied by adding 0%,0.05%,0.2%,and 0.3%Sc.The results show that with the increase of Sc,the coarse needle-like Fe-rich phase gradually transforms into Chinese-script and then nearly spherical particles,reduce the size of Fe-rich phase,and refine the grain with increase of high angle grain boundaries(HAGBs).These microstructure changes enhance the strength of the AA5052 alloy through Sc addition.The ductility of the alloy is obviously improved because the addition of a lower amount of Sc changes the morphology of Fe-rich phase from needle-like into a Chinese-script,and it is subsequently reduced as a result of significant increase in HAGBs with increasing Sc content.展开更多
In order to overcome the problems of many pores,large deformation and unstable weld quality of traditional laser welded aluminumcopper alloy joints,a red-blue dual-beam laser source and a swinging laser were introduce...In order to overcome the problems of many pores,large deformation and unstable weld quality of traditional laser welded aluminumcopper alloy joints,a red-blue dual-beam laser source and a swinging laser were introduced for welding.T2 copper and 6063 aluminum thin plates were lap welded by coaxial dual-beam laser welding.The morphology of weld cross section was compared to explore the influence of process parameters on the formation of lap joints.The microstructure characteristics of the weld zone were observed and compared by optical microscope.The results show that the addition of laser beam swing can eliminate the internal pores of the weld.With the increase of the swing width,the weld depth decreases,and the weld width increases first and then decreases.The influence of welding speed on the weld cross section morphology is similar to that of swing width.With the increase of welding speed,the weld width increases first and then decreases,while the weld depth decreases all the time.This is because that the red laser is used as the main heat source to melt the base metals,with the increase of red laser power,the weld depth increases.As an auxiliary laser source,blue laser reduces the total energy consumption,consequently,the effective heat input increases and the spatter is restrained effectively.As a result,the increase of red laser power has an enhancement effect on the weld width and weld depth.When the swing width is 1.2 mm,the red laser power is 550 W,the blue laser power is 500 W,and the welding speed is 35 mm/s,the weld forming is the best.The lap joint of T2 copper and 6063 aluminum alloy thin plate can be connected stably with the hybrid of blue laser.The effect rules of laser beam swing on the weld formation were obtained,which improved the quality of the joints.展开更多
2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed...2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed of 2000 r/min and welding speed of 30 mm/min,joint with smooth surface,small reduction in thickness and little inner defects was obtained.The weld nugget zone was approx-imately circular,which was a unique morphology for SSFSW.The heat-affected zone(HAZ)and thermo-mechanically affected zone(TMAZ)were both quite narrow due to the lower heat input and slight mechanical action of the stationary shoulder.The fraction of high angle grain boundaries(HAGBs)exhibited a“W”shape along horizontal direction(from advancing side to retreating side),and the minim-um value located at HAZ.The average ultimate tensile strength and elongation of the joint were 325 MPa and 4.5%,respectively,with the joint efficiency of 68.3%.The joint was ductile fractured and the fracture surface contained two types of dimples morphology in different re-gions of the joint.Microhardness distribution in the joint exhibited a“W”shape,and the difference along the thickness direction was negli-gible.The joint had strong stress corrosion cracking susceptibility,and the slow stain rate tensile strength was 139 MPa.Microcrack and Al2O3 particulates were observed at the fracture surface.展开更多
This research considered the effect of non-natural aging on the microstructural characteristics and mechanical properties of as-cast aluminum 6063 alloys. The samples were developed through a sand casting process and ...This research considered the effect of non-natural aging on the microstructural characteristics and mechanical properties of as-cast aluminum 6063 alloys. The samples were developed through a sand casting process and machined into tensile and impact test samples before carrying out solution heat treatment at 550?C (0.83 T<sub>m</sub>) on two parts of the samples while retaining one part as the control. The two parts were further divided into sets denoted A and B and were aged at 180?C (0.27 T<sub>m</sub>) and 160?C (0.24 T<sub>m</sub>), respectively, for 12 hours. The results showed that sample A has the optimal yield strength and ultimate tensile strength of 192 and 206 MPa, respectively. Likewise, the sample gave the highest impact strength value of about 9.63 J/mm<sup>2</sup>. The observed results were supported by the optical micrograph, which revealed that the sample has evenly dispersed precipitates in its microstructure. This is deemed responsible for the observed increase in strength of the sample.展开更多
With the intensification of market competition in the aluminum alloy strip processing industry,it is dif-ficult to control the mass production of the same specifications,which is bound to affect the hot rolling produc...With the intensification of market competition in the aluminum alloy strip processing industry,it is dif-ficult to control the mass production of the same specifications,which is bound to affect the hot rolling production.This paper studied the effect of the hot rolling order of aluminum alloy on the surface quality of strip,such as roll printing,color difference,anodic oxidation,etc.,reasonable discharge sequence and corresponding optimization measures were formulated.展开更多
The corrosion evolution of 2024-T351 and 7075-T651 aluminum alloys in the thin electrolyte layer(TEL)and wet-dry alternating cycle(WDAC)environment is studied in this work.The results show that in the TEL environment,...The corrosion evolution of 2024-T351 and 7075-T651 aluminum alloys in the thin electrolyte layer(TEL)and wet-dry alternating cycle(WDAC)environment is studied in this work.The results show that in the TEL environment,the competitive effect between H+that accelerates corrosion reactions and deposition of aluminum sulfate that impedes corrosion attacks exists during the corrosion exposure.The difference is that with increasing HSO_(3)^(-),subsurface intergranular corrosion on 2024-T351 is promoted to form exfoliation corrosion eventually and the degree of exfoliation corrosion begins to decrease because the blocking effect of aluminum sulfate exceeds the expediting effect of H+.For 7075-T651,the corrosion area and the corrosion diameter decrease gradually,which is attributed to the HSO_(3)^(-)-enhanced deposition of corrosion products and their blocking effect.In the WDAC environment,the corrosion processes of 2024-T351 and 7075-T651 are the acidic dissolution of the matrix during the soaking phase.When the HSO_(3)^(-)concentration is high enough(0.1 M),the inhibiting effect of aluminum sulfate becomes the dominant factor.展开更多
Aluminum alloy tubes were prepared by tube spinning.The intergranular and electrochemical corrosion tests were used to investigate the intergranular corrosion behavior of the 5A06 aluminum alloy blank sample and the s...Aluminum alloy tubes were prepared by tube spinning.The intergranular and electrochemical corrosion tests were used to investigate the intergranular corrosion behavior of the 5A06 aluminum alloy blank sample and the spinning sample.Results showed that the intergranular corrosion resistance of the spinning sample was higher than that of the blank sample.In addition,the electrochemical corrosion resistance of the spinning sample was higher than that of the blank sample.The EDS maps indicated a uniform element distribution pattern of aluminum and magnesium.Moreover,the phase composition and lattice constant of the samples were obtained by XRD analysis.The differences in microstructure between the aluminum alloy subjected to the spinning process and the untreated aluminum alloy were determined by EBSD.The differences were mainly attributed to the complex interactions among grain size,dislocations and grain boundaries.展开更多
The surface composite modification of the 7050 aluminum alloy friction stir-welded joints was performed by shot peening(SP)/multiple rotation rolling(MRR)and MRR/SP,and the fatigue performance of the nugget zone(NZ)wa...The surface composite modification of the 7050 aluminum alloy friction stir-welded joints was performed by shot peening(SP)/multiple rotation rolling(MRR)and MRR/SP,and the fatigue performance of the nugget zone(NZ)was investigated.The results demonstrated that the fatigue life of SP/MRR samples is longer than that of MRR/SP.On the plane 150μm below the surface.The grains with high angle grain boundary account for 71.5%and 34.3%for MRR/SP and SP/MRR samples,respectively.The crack propagation path of the MRR/SP is transgranular and intergranular,and it is intergranular for the MRR/SP.Multitudinous fatigue striations and some voids appeared at the fracture during the stable crack propagation stage.However,fatigue striations for SP/MRR are with smaller spacing,fewer holes,and smaller size under SP/MRR compared with fatigue fracture of MRR/SP.The differences in fatigue properties and fracture characteristics of the NZ are related to the microstructure after the two combined surface modifications.展开更多
High reactivity and ease of ignition are the major obstacles for the application of Mg alloys in aerospace.Thus,the ignition mechanisms of Mg alloys should be investigated systematically,which can guide the ignition-p...High reactivity and ease of ignition are the major obstacles for the application of Mg alloys in aerospace.Thus,the ignition mechanisms of Mg alloys should be investigated systematically,which can guide the ignition-proof alloy design.This article concludes the factors influencing the ignition resistance of Mg alloys from oxide film and substrate microstructure,and also the mechanisms of alloying elements improving the ignition resistance.The low strength is another reason restricting the development of Mg alloys.Therefore,at the last section,Mg alloys with the combination of high strength and good ignition-proof performance are summarized,including Mg-Al-Ca based alloys,SEN(Mg-Al-Zn-Ca-Y)alloys as well as Mg-Y and Mg-Gd based alloys.Besides,the shortages and the future focus of theses alloys are also reviewed.The aim of this article is to promote the understanding of oxidation and ignition mechanisms of Mg alloys and to provide reference for the development of Mg alloys with high strength and excellent ignition-proof performance at the same time.展开更多
Artificial ageing above 165℃directly after quenching induces the formation of^50 nm wide precipitatefree zone(PFZ)and^100 nm wide precipitate-sparse zone(PSZ)consisting of coarse precipitates with a gradient in size ...Artificial ageing above 165℃directly after quenching induces the formation of^50 nm wide precipitatefree zone(PFZ)and^100 nm wide precipitate-sparse zone(PSZ)consisting of coarse precipitates with a gradient in size and density toward the grain center in a commercial Al-Zn-Mg-Cu alloy.With the grain size decreasing,the fraction of PFZ and PSZ in a grain becomes larger and could even occupy the entire volume of the grain.This undesirable microstructure near the grain boundary is mitigated substantially by natural pre-ageing,leading to an exceptional enhancement of the age hardening potential at elevated temperatures.Natural ageing could fundamentally alter the precipitation near grain boundary,and is a promising method to optimize the precipitation hardening in high strength aluminum alloys with unconventionally small grains.展开更多
The effect of Ti and Ce microalloying on the mechanical properties of Al-9Si-3.5Cu-0.2Zr-0.1Sr cast aluminum alloy was investigated,and it was hoped that the cast aluminum alloy with excellent comprehensive properties...The effect of Ti and Ce microalloying on the mechanical properties of Al-9Si-3.5Cu-0.2Zr-0.1Sr cast aluminum alloy was investigated,and it was hoped that the cast aluminum alloy with excellent comprehensive properties could be obtained.On the basis of Zr-Sr microalloyed cast aluminum alloy(Al-9Si-3.5Cu-0.2Zr-0.1Sr),the effects of 0.2Zr-0.1Sr-0.16Ti ternary microalloying and 0.2Zr-0.1Sr-0.16Ti-0.1Ce quaternary microalloying on the microstructure and properties of the alloy were investigated.The experimental results show that compared with Zr-Sr microalloying,Zr-Sr-Ti microalloying and Zr-Sr-Ti-Ce microalloying can effectively refine the microstructure,improve the modification effect of Si phase,and promote the improvement of Al_(2)Cu phase,thus improving the properties.The higher the degree of microalloying,the hardness is gradually increasing,but the electrical conductivity is gradually decreasing.Zr-Sr-Ti microalloying can increase the tensile strength of the alloy to 400.07 MPa and the elongation to 9.5%.Zr-Sr-Ti-Ce microalloying do not continue to improve the properties of the alloy,and the tensile strength and elongation after fracture decrease to a certain extent due to the addition of Ce.Therefore,the best comprehensive properties can be obtained by ZrSr-Ti microalloying(Al-9Si-3.5Cu-0.2Zr-0.1Sr-0.16Ti).展开更多
The influence of thermal-cold cycling treatment on mechanical properties and microstructure of 6061 aluminum alloy was investigated by means of tensile test, optical microscopy(OM), X-ray diffraction(XRD) and transmis...The influence of thermal-cold cycling treatment on mechanical properties and microstructure of 6061 aluminum alloy was investigated by means of tensile test, optical microscopy(OM), X-ray diffraction(XRD) and transmission electron microscopy(TEM). The cryogenic treatment mechanism of the alloys was discussed. The results show that thermal-cold cycling treatment is beneficial since it produces a large number of dislocations and accelerates the ageing process of the alloy and yields the finer dispersed β" precipitates in the matrix. This variation of microstructural changes leads to more favorable mechanical properties than the other investigated states, while grain boundary precipitation is coarse and distributed discontinuously along grain boundaries, with a lower precipitation free zone(PEZ) on the both sides of precipitated phase. As a result, the tensile strength, elongation and conductivity of 6061 aluminum alloy after thermal-cold cycling treatment are 373.37 MPa, 17.2% and 28.2 MS/m, respectively. Compared with conventional T6 temper, the mechanical properties are improved significantly.展开更多
文摘The microstructure of the thin-walled tubes with high-strength aluminum alloy determines their final forming quality and performance. This type of tube can be manufactured by multi-pass hot power backward spinning process as it can eliminate casting defects, refine microstructure and improve the plasticity of the tube. To analyze the microstructure distribution characteristics of the tube during the spinning process, a 3D coupled thermo-mechanical FE model coupled with the microstructure evolution model of the process was established under the ABAQUS environment. The microstructure evolution characteristics and laws of the tube for the whole spinning process were analyzed. The results show that the dynamic recrystallization is mainly produced in the spinning deformation zone and root area of the tube. In the first pass, the dynamic recrystallization phenomenon is not obvious in the tube. With the pass increasing, the trend of dynamic recrystallization volume percentage gradually increases and extends from the outer surface of the tube to the inner surface. The fine-grained area shows the states of concentration, dispersion, and re-concentration as the pass number increases. .
基金supported by the Guangxi College Youth Project Foundation(No.2023KY0913)Technology Project of Guizhou Province,Guizhou Science and Technology Cooper-ation Support Project Foundation[2020](No.2Y055)。
文摘This study aims to explore a method suitable for welding 7A52 high-strength aluminum alloy plates with continuously varying thicknesses and the causes of microscopic defects in welds in order to improve welding quality.Comparative tests were conducted to analyze weld defects and deformation when welding the aluminum alloy plates with varying thicknesses at constant laser power.The laser power required for melting welds at varying-thickness positions was estimated.Weld defects and deformation when welding aluminum alloy plates with varying thicknesses at con-tinuous variable laser power were detected.The causes of microscopic weld defects during constant-power welding were analyzed.The welding defects and deformation and the welding quality were improved by welding aluminum alloy plates at continuous variable power.
文摘The process of friction-stir welding 2A12CZ alloy has been studied. And strength and elongation tests have been performed, which demonstrated that the opportunity existed to manipulate friction-stir welding parameters in order to improve a range of material properties. The results showed that the joint strength and elongation arrived at their maximums (331 MPa and 4%) at 37.5 mm/min and 300 rpm. As welding parameters changing, joint tensile strength and elongation had similar development. Hardness measurement indicated that the weld was softened. However, there was considerable difference in softening degree for different joint zone. The weld top had lower hardness and wider softening zone than other zone of the weld. And softening zone at advancing side was wider than that at retreating side.
基金the National Natural Science Foundation of China(No.U1703131,No.51674027,No.51974027 and No.52004028)Guangdong Basic and Applied Basic Research Foundation(2019A1515111126)the Fundamental Research Funds for the Central Universities(FRF-TP-18-005C1 and FRF-TP-18-041A1).
文摘The two-phase zone continuous casting(TZCC)technique was used to continuously cast high-strength aluminum alloy hollow billets,and a verified 3D model of TZCC was used to simulate the flow and temperature fields at casting speeds of 2-6 mm·min^(-1).Hollow billets under the same conditions were prepared,and their macro/microstructures were analyzed by an optical microscope and a scanning electron microscope.During the TZCC process,a circular fluid flow appears in front of the mushy zone,and the induction heated stepped mold and convective heat transfer result in a curved solidification front with depressed region near the inner wall and a vertical temperature gradient.The deflection of the solidification front decreases and the average cooling rate in the mushy zone increases with increasing casting speed.Experimental results for a 2D12 alloy show that hot tearing periodically appears in the hollow billet accompanied by macrosegregation near the inner wall at casting speeds of 2 and 4 mm·min^(-1),while macroscopic defects of hot tearing and macrosegregation weaken and the average size of columnar crystals in the hollow billets decreases with further increasing casting speed.2D12 aluminum alloy hollow billets with no macroscopic defects,the finest columnar crystals,and excellent mechanical properties were prepared by TZCC at a casting speed of 6 mm·min^(-1),which is beneficial for the further plastic forming process.
文摘Friction stir welding (FSW) has been widely used in many industries, with which high-strength aluminum alloys can be well joined. However, the corrosion resistance of FSW high-strength Al alloy joints is relatively poor, which limits their industrial applications. The joints shall be protected against corrosion. In this review, therefore, the current status and development of corrosion protection for FSW high-strength Al alloy joints are presented. Particular emphasis has been given to different protection methods : lowering heat input, post-weld heat treatment, surface modification and spray coatings. Finally, opportunities are identified for further research and development in corrosion protection of FSW high-strength Al alloy joints.
基金financially supported by the National Natural Science Foundation of China (No.52271073)。
文摘A Ni–P alloy gradient coating consisting of multiple electroless Ni–P layers with various phosphorus contents was prepared on the aviation aluminum alloy. Several characterization and electrochemical techniques were used to characterize the different Ni–P coatings’ morphologies, phase structures, elemental compositions, and corrosion protection. The gradient coating showed good adhesion and high corrosion and wear resistance, enabling the application of aluminum alloy in harsh environments. The results showed that the double zinc immersion was vital in obtaining excellent adhesion (81.2 N). The optimal coating was not peeled and shredded even after bending tests with angles higher than 90°and was not corroded visually after 500 h of neutral salt spray test at 35℃. The high corrosion resistance was attributed to the misaligning of these micro defects in the three different nickel alloy layers and the amorphous structure of the high P content in the outer layer. These findings guide the exploration of functional gradient coatings that meet the high application requirement of aluminum alloy parts in complicated and harsh aviation environments.
基金supported by the 2022 MTC Young Individual Research Grants(Grant No.M22K3c0097)the Singapore Research,Innovation and Enterprise(RIE)2025 PlanSingapore Aerospace Programme Cycle 16(Grant No.M2215a0073)。
文摘Lightweight aluminum(Al)alloys have been widely used in frontier fields like aerospace and automotive industries,which attracts great interest in additive manufacturing(AM)to process high-value Al parts.As a mainstream AM technique,laser-directed energy deposition(LDED)shows good scalability to meet the requirements for large-format component manufacturing and repair.However,LDED Al alloys are highly challenging due to their inherent poor printability(e.g.low laser absorption,high oxidation sensitivity and cracking tendency).To further promote the development of LDED high-performance Al alloys,this review offers a deep understanding of the challenges and strategies to improve printability in LDED Al alloys.The porosity,cracking,distortion,inclusions,element evaporation and resultant inferior mechanical properties(worse than laser powder bed fusion)are the key challenges in LDED Al alloys.Processing parameter optimizations,in-situ alloy design,reinforcing particle addition and field assistance are the efficient approaches to improving the printability and performance of LDED Al alloys.The underlying correlations between processes,alloy innovation,characteristic microstructures,and achievable performances in LDED Al alloys are discussed.The benchmark mechanical properties and primary strengthening mechanism of LDED Al alloys are summarized.This review aims to provide a critical and in-depth evaluation of current progress in LDED Al alloys.Future opportunities and perspectives in LDED high-performance Al alloys are also outlined.
基金Funded by the Central Government Guides Local Funds for Science and Technology Development(No.YDZJSX20231A045)the Fundamental Research Program of Shanxi Province(Nos.202103021223288 and 202103021224282)。
文摘The evolution of microstructure during hot deformation is key to achieving good mechanical properties in aluminum alloys.We have developed a cellular automaton(CA) based model to simulate the microstructural evolution in 7075 aluminum alloy during hot deformation.Isothermal compression tests were conducted to obtain material parameters for 7075 aluminum alloy,leading to the establishment of models for dislocation density,nucleation of recrystallized grains,and grain growth.Integrating these aspects with grain topological deformation,our CA model effectively predicts flow stress,dynamic recrystallization(DRX) volume fraction,and average grain size under diverse deformation conditions.A systematic comparison was made between electron back scattered diffraction(EBSD) maps and CA model simulated under different deformation temperatures(573 to 723 K),strain rates(0.001 to 1 s^(-1)),and strain amounts(30% to 70%).These analyses indicate that large strain,high temperature,and low strain rate facilitate dynamic recrystallization and grain refinement.The results from the CA model show good accuracy and predictive capability,with experimental error within 10%.
基金supported by the Key Research&Development Program of Yunnan Province(Grant numbers 202103AA080017,202203AE140011).
文摘The AA5052 aluminum alloy is widely used in automobile and aerospace manufacturing,and with the development of light-weight alloys,it is required that these materials exhibit better mechanical properties.Previous studies have demonstrated that the addition of Sc to aluminum alloys can improve both the microstructure and properties of the alloys.In this study,the effect of Sc on the Fe-rich phase and properties of the AA5052 aluminum alloy was studied by adding 0%,0.05%,0.2%,and 0.3%Sc.The results show that with the increase of Sc,the coarse needle-like Fe-rich phase gradually transforms into Chinese-script and then nearly spherical particles,reduce the size of Fe-rich phase,and refine the grain with increase of high angle grain boundaries(HAGBs).These microstructure changes enhance the strength of the AA5052 alloy through Sc addition.The ductility of the alloy is obviously improved because the addition of a lower amount of Sc changes the morphology of Fe-rich phase from needle-like into a Chinese-script,and it is subsequently reduced as a result of significant increase in HAGBs with increasing Sc content.
基金supported by Guangdong Science and Technology Plan Project(Grant No.20170902,No.20180902)Yangjiang Science and Technology Plan Project(Grant No.SDZX2020063)+1 种基金Shenzhen Key Projects of Innovation and Entrepreneurship Plan Technology(JSGG20210420091802007)Yunfu 2023 Science and Technology Plan Project(S2023020201).
文摘In order to overcome the problems of many pores,large deformation and unstable weld quality of traditional laser welded aluminumcopper alloy joints,a red-blue dual-beam laser source and a swinging laser were introduced for welding.T2 copper and 6063 aluminum thin plates were lap welded by coaxial dual-beam laser welding.The morphology of weld cross section was compared to explore the influence of process parameters on the formation of lap joints.The microstructure characteristics of the weld zone were observed and compared by optical microscope.The results show that the addition of laser beam swing can eliminate the internal pores of the weld.With the increase of the swing width,the weld depth decreases,and the weld width increases first and then decreases.The influence of welding speed on the weld cross section morphology is similar to that of swing width.With the increase of welding speed,the weld width increases first and then decreases,while the weld depth decreases all the time.This is because that the red laser is used as the main heat source to melt the base metals,with the increase of red laser power,the weld depth increases.As an auxiliary laser source,blue laser reduces the total energy consumption,consequently,the effective heat input increases and the spatter is restrained effectively.As a result,the increase of red laser power has an enhancement effect on the weld width and weld depth.When the swing width is 1.2 mm,the red laser power is 550 W,the blue laser power is 500 W,and the welding speed is 35 mm/s,the weld forming is the best.The lap joint of T2 copper and 6063 aluminum alloy thin plate can be connected stably with the hybrid of blue laser.The effect rules of laser beam swing on the weld formation were obtained,which improved the quality of the joints.
基金supported by the Research and Development Project of“Jianbing”in Zhejiang Province(2024C01085)Natural Science and Foundation of Ningbo(2022J052).
文摘2A14-T62 butt joint was successfully welded by stationary shoulder friction stir welding(SSFSW)method.The results showed that using a pin with small shoulder could broaden the process window,and under a rotation speed of 2000 r/min and welding speed of 30 mm/min,joint with smooth surface,small reduction in thickness and little inner defects was obtained.The weld nugget zone was approx-imately circular,which was a unique morphology for SSFSW.The heat-affected zone(HAZ)and thermo-mechanically affected zone(TMAZ)were both quite narrow due to the lower heat input and slight mechanical action of the stationary shoulder.The fraction of high angle grain boundaries(HAGBs)exhibited a“W”shape along horizontal direction(from advancing side to retreating side),and the minim-um value located at HAZ.The average ultimate tensile strength and elongation of the joint were 325 MPa and 4.5%,respectively,with the joint efficiency of 68.3%.The joint was ductile fractured and the fracture surface contained two types of dimples morphology in different re-gions of the joint.Microhardness distribution in the joint exhibited a“W”shape,and the difference along the thickness direction was negli-gible.The joint had strong stress corrosion cracking susceptibility,and the slow stain rate tensile strength was 139 MPa.Microcrack and Al2O3 particulates were observed at the fracture surface.
文摘This research considered the effect of non-natural aging on the microstructural characteristics and mechanical properties of as-cast aluminum 6063 alloys. The samples were developed through a sand casting process and machined into tensile and impact test samples before carrying out solution heat treatment at 550?C (0.83 T<sub>m</sub>) on two parts of the samples while retaining one part as the control. The two parts were further divided into sets denoted A and B and were aged at 180?C (0.27 T<sub>m</sub>) and 160?C (0.24 T<sub>m</sub>), respectively, for 12 hours. The results showed that sample A has the optimal yield strength and ultimate tensile strength of 192 and 206 MPa, respectively. Likewise, the sample gave the highest impact strength value of about 9.63 J/mm<sup>2</sup>. The observed results were supported by the optical micrograph, which revealed that the sample has evenly dispersed precipitates in its microstructure. This is deemed responsible for the observed increase in strength of the sample.
文摘With the intensification of market competition in the aluminum alloy strip processing industry,it is dif-ficult to control the mass production of the same specifications,which is bound to affect the hot rolling production.This paper studied the effect of the hot rolling order of aluminum alloy on the surface quality of strip,such as roll printing,color difference,anodic oxidation,etc.,reasonable discharge sequence and corresponding optimization measures were formulated.
基金The authors wish to acknowledge the financial support of the Natural Science Foundation of China(No.51931008)the Ministry of Industry and Information Technology Project(No.MJ-2017-J-99),and the Shandong Provincial Key R&D plan(No.2019GHY112050).
文摘The corrosion evolution of 2024-T351 and 7075-T651 aluminum alloys in the thin electrolyte layer(TEL)and wet-dry alternating cycle(WDAC)environment is studied in this work.The results show that in the TEL environment,the competitive effect between H+that accelerates corrosion reactions and deposition of aluminum sulfate that impedes corrosion attacks exists during the corrosion exposure.The difference is that with increasing HSO_(3)^(-),subsurface intergranular corrosion on 2024-T351 is promoted to form exfoliation corrosion eventually and the degree of exfoliation corrosion begins to decrease because the blocking effect of aluminum sulfate exceeds the expediting effect of H+.For 7075-T651,the corrosion area and the corrosion diameter decrease gradually,which is attributed to the HSO_(3)^(-)-enhanced deposition of corrosion products and their blocking effect.In the WDAC environment,the corrosion processes of 2024-T351 and 7075-T651 are the acidic dissolution of the matrix during the soaking phase.When the HSO_(3)^(-)concentration is high enough(0.1 M),the inhibiting effect of aluminum sulfate becomes the dominant factor.
基金Funded by the National Natural Science Foundation of China(No.51802189)the Shanghai Lingang Innovation Program(No.SH-LG-GK-2020-28)。
文摘Aluminum alloy tubes were prepared by tube spinning.The intergranular and electrochemical corrosion tests were used to investigate the intergranular corrosion behavior of the 5A06 aluminum alloy blank sample and the spinning sample.Results showed that the intergranular corrosion resistance of the spinning sample was higher than that of the blank sample.In addition,the electrochemical corrosion resistance of the spinning sample was higher than that of the blank sample.The EDS maps indicated a uniform element distribution pattern of aluminum and magnesium.Moreover,the phase composition and lattice constant of the samples were obtained by XRD analysis.The differences in microstructure between the aluminum alloy subjected to the spinning process and the untreated aluminum alloy were determined by EBSD.The differences were mainly attributed to the complex interactions among grain size,dislocations and grain boundaries.
基金supported by the National Natural Science Foundation of China(Grants 51865028)the Gansu Provincial Science and Technology Planning Project(Grant No.20YF8GA056).
文摘The surface composite modification of the 7050 aluminum alloy friction stir-welded joints was performed by shot peening(SP)/multiple rotation rolling(MRR)and MRR/SP,and the fatigue performance of the nugget zone(NZ)was investigated.The results demonstrated that the fatigue life of SP/MRR samples is longer than that of MRR/SP.On the plane 150μm below the surface.The grains with high angle grain boundary account for 71.5%and 34.3%for MRR/SP and SP/MRR samples,respectively.The crack propagation path of the MRR/SP is transgranular and intergranular,and it is intergranular for the MRR/SP.Multitudinous fatigue striations and some voids appeared at the fracture during the stable crack propagation stage.However,fatigue striations for SP/MRR are with smaller spacing,fewer holes,and smaller size under SP/MRR compared with fatigue fracture of MRR/SP.The differences in fatigue properties and fracture characteristics of the NZ are related to the microstructure after the two combined surface modifications.
基金the financial supports from the National Key Research and Development Plan(Grant No.2021YFB3701100)the National Natural Science Foundation of China(Grant No.U2241231,No.52071206)。
文摘High reactivity and ease of ignition are the major obstacles for the application of Mg alloys in aerospace.Thus,the ignition mechanisms of Mg alloys should be investigated systematically,which can guide the ignition-proof alloy design.This article concludes the factors influencing the ignition resistance of Mg alloys from oxide film and substrate microstructure,and also the mechanisms of alloying elements improving the ignition resistance.The low strength is another reason restricting the development of Mg alloys.Therefore,at the last section,Mg alloys with the combination of high strength and good ignition-proof performance are summarized,including Mg-Al-Ca based alloys,SEN(Mg-Al-Zn-Ca-Y)alloys as well as Mg-Y and Mg-Gd based alloys.Besides,the shortages and the future focus of theses alloys are also reviewed.The aim of this article is to promote the understanding of oxidation and ignition mechanisms of Mg alloys and to provide reference for the development of Mg alloys with high strength and excellent ignition-proof performance at the same time.
基金the National Natural Science Foundation of China(Nos.51601060,51675538 and 11872380)the Natural Science Foundation of Hunan Province(No.2018JJ3655)+3 种基金the National Key R&D Program of China(No.2017YFB0306300)the Innovation-driven Plan in Central South University(No.2015CX002)the Science and Technology Plan in Hunan Province(No.2016RS2015)the Fundamental Research Funds for the Central Universities of Central South University(No.2018zzts154)。
文摘Artificial ageing above 165℃directly after quenching induces the formation of^50 nm wide precipitatefree zone(PFZ)and^100 nm wide precipitate-sparse zone(PSZ)consisting of coarse precipitates with a gradient in size and density toward the grain center in a commercial Al-Zn-Mg-Cu alloy.With the grain size decreasing,the fraction of PFZ and PSZ in a grain becomes larger and could even occupy the entire volume of the grain.This undesirable microstructure near the grain boundary is mitigated substantially by natural pre-ageing,leading to an exceptional enhancement of the age hardening potential at elevated temperatures.Natural ageing could fundamentally alter the precipitation near grain boundary,and is a promising method to optimize the precipitation hardening in high strength aluminum alloys with unconventionally small grains.
基金Funded by the Key Projects of Equipment Pre-research Foundation of the Ministry of Equipment Development of the Central Military Commission of China(No.6140922010201)the Key R&D Plan of Zhenjiang in 2018(No.GY2018021)。
文摘The effect of Ti and Ce microalloying on the mechanical properties of Al-9Si-3.5Cu-0.2Zr-0.1Sr cast aluminum alloy was investigated,and it was hoped that the cast aluminum alloy with excellent comprehensive properties could be obtained.On the basis of Zr-Sr microalloyed cast aluminum alloy(Al-9Si-3.5Cu-0.2Zr-0.1Sr),the effects of 0.2Zr-0.1Sr-0.16Ti ternary microalloying and 0.2Zr-0.1Sr-0.16Ti-0.1Ce quaternary microalloying on the microstructure and properties of the alloy were investigated.The experimental results show that compared with Zr-Sr microalloying,Zr-Sr-Ti microalloying and Zr-Sr-Ti-Ce microalloying can effectively refine the microstructure,improve the modification effect of Si phase,and promote the improvement of Al_(2)Cu phase,thus improving the properties.The higher the degree of microalloying,the hardness is gradually increasing,but the electrical conductivity is gradually decreasing.Zr-Sr-Ti microalloying can increase the tensile strength of the alloy to 400.07 MPa and the elongation to 9.5%.Zr-Sr-Ti-Ce microalloying do not continue to improve the properties of the alloy,and the tensile strength and elongation after fracture decrease to a certain extent due to the addition of Ce.Therefore,the best comprehensive properties can be obtained by ZrSr-Ti microalloying(Al-9Si-3.5Cu-0.2Zr-0.1Sr-0.16Ti).
基金Key Scientific and Technological Project of Henan Province (No.222102230021)Key Scientific Research Projects of Universities in Henan Province (No.21B430003)The Training Program for Young Backbone Teachers in Henan Higher Education Institutions (No.2019GGJS266)。
文摘The influence of thermal-cold cycling treatment on mechanical properties and microstructure of 6061 aluminum alloy was investigated by means of tensile test, optical microscopy(OM), X-ray diffraction(XRD) and transmission electron microscopy(TEM). The cryogenic treatment mechanism of the alloys was discussed. The results show that thermal-cold cycling treatment is beneficial since it produces a large number of dislocations and accelerates the ageing process of the alloy and yields the finer dispersed β" precipitates in the matrix. This variation of microstructural changes leads to more favorable mechanical properties than the other investigated states, while grain boundary precipitation is coarse and distributed discontinuously along grain boundaries, with a lower precipitation free zone(PEZ) on the both sides of precipitated phase. As a result, the tensile strength, elongation and conductivity of 6061 aluminum alloy after thermal-cold cycling treatment are 373.37 MPa, 17.2% and 28.2 MS/m, respectively. Compared with conventional T6 temper, the mechanical properties are improved significantly.