Synergistic effect of Zr and Mo on precipitation and high-temperature properties of Al-Si-Cu-Mg alloys

This study focuses on finding a solution to the sharp decline in mechanical properties of Al-Si-Cu-Mg alloys due to rapid coarsening of traditional intermediate phases at high temperature.A new type of modified al oy,to be used in automobile engines at high temperatures,was prepared by adding Zr and Mo into Al-Si-Cu-Mg alloy.The synergistic effects of Zr and Mo on the microstructure evolution and high-temperature mechanical properties were studied.Results show that the addition of Zr and Mo generates a series of intermetallic phases dispersed in the alloy.They can improve the strength of the alloy by hindering dislocation movement and crack propagation.In addition,some nano-strengthened phases show coherent interfaces with the matrix and improve grain refinement.The addition of Mo greatly improves the heat resistance of the alloy.The extremely low diffusivity of Mo enables it to improve the thermal stability of the intermetallic phases,inhibit precipitation during aging,reduce the size of the precipitates,and improve the heat resistance of the alloy.

High-temperature compressive properties of TiC–TiB_2/Cu composites prepared by self-propagating high-temperature synthesis

TiC-TiB2/Cu composites were prepared by self-propagating high-temperature synthesis with pseudo hot isostatic pressing using Ti, B4C, and Cu powders. The compressive deformation of the composites at high tem- perature was investigated. It is found that the maximum compressive strength decreases with the increase of tem- perature and Cu content. The deformation of the composites includes the steps of elastic, stable theology, and inaction. The maximum strain is in the range of 5 %-10 %. Before fracture, TiC-TiB2/40Cu becomes drum-shaped at 1123 K; however, TiC-TiB2/20Cu only has a brittle frac- ture along the axial direction of 45~. The results show that the compressive strength of TiC-TiB2/Cu decreases from 823 to 1223 K. However, the maximum compressive strength of TiC-TiB2/20Cu reaches 1850 MPa at 823 K, which predicts that this series of composites could be applied to high-temperature compressive materials.

Effect of ball milling time on the microstructure and compressive properties of the Fe–Mn–Al porous steel

In the present work,Fe–Mn–Al–C powder mixtures were manufactured by elemental powders with different ball milling time,and the porous high-Mn and high-Al steel was fabricated by powder sintering.The results indicated that the powder size significantly decreased,and the morphology of the Fe powder tended to be increasingly flat as the milling time increased.However,the prolonged milling duration had limited impact on the phase transition of the powder mixture.The main phases of all the samples sintered at 640℃ were α-Fe,α-Mn and Al,and a small amount of Fe2Al5 and Al8Mn5.When the sintering temperature increased to 1200℃,the phase composition was mainly comprised of γ-Fe and α-Fe.The weight loss fraction of the sintered sample decreased with milling time,i.e.,8.3wt% after 20 h milling compared to15.3wt% for 10 h.The Mn depletion region(MDR) for the 10,15,and 20 h milled samples was about 780,600,and 370 μm,respectively.The total porosity of samples sintered at 640℃ decreased from ~46.6vol% for the 10 h milled powder to ~44.2vol% for 20 h milled powder.After sintering at 1200℃,the total porosity of sintered samples prepared by 10 and 20 h milled powder was ~58.3vol% and ~51.3vol%,respectively.The compressive strength and ductility of the 1200℃ sintered porous steel increased as the milling time increased.

The Research for Surface Properties of Steel Slag Powder and High-Temperature Rheological Properties of Asphalt Mortar

In order to evaluate the feasibility of steel slag powder as filler,the coating properties of steel slag and limestone aggregate were compared by water boiling test,the micro morphology difierences between steel slag powder and mineral powder(limestone powder)were compared by scanning electron microscope(SEM),and the high-temperature rheological properties of asphalt mortar with difierent ratio of filler quality to asphalt quality(F/A)and difierent substitution rates of mineral powder(S/F)were studied by dynamic shear rheological test.The results show that the surface microstructure of steel slag powder is more abundant than that of mineral powder,and the adhesion of steel slag to asphalt is better than that of limestone.At the same temperature,the lower the ratio of S/F is,the greater the rutting factor and complex modulus will be.In addition,the complex modulus and rutting factor of the asphalt mortar increase with the increase of F/A,and the filler type and F/A have a negligible efiect on the phase angle.

Experimental Investigation on Compressive Properties of Fiber Recycled Aggregate Concrete

This paper presents an experimental study to explore the compressive properties of fiber recycled aggregate concrete.A total of 75 specimens with the replacement rate of recycled coarse aggregate and fiber type were conducted under a uniaxial compressive test.The failure modes,stress-strain whole curves,peak stress,peak strain,and energy dissipation capacity were systematically observed and revealed.Test results indicate that steel fiber has the best modification effect on energy dissipation capacity and the toughness index of recycled concrete,corresponding to the enhancement of 81.75% and 22.90% on average.The addition of polyvinyl alcohol fiber can effectively improve the compressive strength and energy dissipation capacity of recycled aggregate concrete by 28.49% and 29.43% on average,respectively.The compressive strength and energy dissipation capacity of recycled aggregate concrete is increased by an average of 16.5% and 24.4% by incorporating carbon fiber.The energy dissipation capacity of recycled aggregate concrete is increased by an average of 13.5% with the incorporation of polypropylene fiber.However,the addition of carbon fiber results in a slight reduction of toughness by 16.97%,and the effect of polyvinyl alcohol fiber on the energy dissipation capacity is limited.Besides,with the increase in replacement rate,the compressive strength and the energy dissipation capacity of recycled coarse aggregate concrete with fiber decreased,and toughness first decreased and then increased.Finally,based on the analysis of test data,a segment-based stress-strain model of fiber recycled aggregate concrete was proposed,which shows good agreement with the test results.

Effect of extrusion process on microstructure and mechanical properties of Ni_3Al-B-Cr alloy during self-propagation high-temperature synthesis

The well-densified Ni3Al-0.5B-5Cr alloy was fabricated by self-propagation high-temperature synthesis and extrusion technique. Microstructure examination shows that the synthesized alloy has fine microstructure and contains Ni3Al, Al2O3, Ni3B and Cr3Ni2 phases. Moreover, the self-propagation high-temperature synthesis and extrusion lead to great deformation and recrystallization in the alloy, which helps to refine the microstructure and weaken the misorientation. In addition, the subsequent extrusion procedure redistributes the Al2O3 particles and eliminates the γ-Ni phase. Compared with the alloy synthesized without extrusion, the Ni3Al-0.5B-5Cr alloy fabricated by self-propagation high-temperature synthesis and extrusion has better room temperature mechanical properties, which should be ascribed to the microstructure evolution.

Influence of hydrogen content on room temperature compressive properties of Ti-6Al-4V alloy at high strain rate

Electromagnetic forming tests were done at room temperature to reveal the influence of hydrogen content on the compressive properties of Ti-6Al-4V alloy at high strain rate. Microstructure was observed to reveal the mechanism of hydrogen-enhanced compressive properties. The experimental results indicate that hydrogen has favorable effects on the compressive properties of Ti-6Al-4V alloy at high strain rate. Compression of Ti-6Al-4V alloy first increases up to a maximum and then decreases with the increase of hydrogen content at the same discharge energy under EMF tests. The compression increases by 47.0% when 0.2% (mass fraction) hydrogen is introduced into Ti-6Al-4V alloy. The optimal hydrogen content for cold formation of Ti–6Al–4V alloy under EMF was determined. The reasons for the hydrogen-induced compressive properties were discussed.

Effects of Sn element on microstructure and properties of Zn-Cu-Bi-Sn high-temperature solder

The microstructures and properties of the Zn-Cu-Bi-Sn(ZCBS) high-temperature solders with various Sn contents were studied using differential scanning calorimetry(DSC),scanning electron microscopy(SEM) and X-ray diffraction(XRD).The results indicate that the increase of Sn content can both decrease the melting temperature and melting range of ZCBS solders and it can also effectively improve the wettability on Cu substrate.The shear strength of solder joints reaches a maximum value with the Sn addition of 5%(mass fraction),which is attributed to the formation of refined β-Sn and primary ε-CuZn_5 phases in η-Zn matrix.However,when the content of Sn exceeds 5%,the shear strength decreases due to the formation of coarse β-Sn phase,which is net-shaped presented at the grain boundary.

Effect of hot isostatic pressure on the microstructure and tensile properties of γ'-strengthened superalloy fabricated through induction-assisted directed energy deposition

The microstructure characteristics and strengthening mechanism of Inconel738LC(IN-738LC) alloy prepared by using induction-assisted directed energy deposition(IDED) were elucidated through the investigation of samples subjected to IDED under 1050℃ preheating with and without hot isostatic pressing(HIP,1190℃,105 MPa,and 3 h).Results show that the as-deposited sample mainly consisted of epitaxial columnar crystals and inhomogeneously distributed γ’ phases in interdendritic and dendritic core regions.After HIP,grain morphology changed negligibly,whereas the size of the γ’ phase became increasingly even.After further heat treatment(HT,1070℃,2 h + 845℃,24 h),the γ’ phase in the as-deposited and HIPed samples presented a bimodal size distribution,whereas that in the as-deposited sample showed a size that remained uneven.The comparison of tensile properties revealed that the tensile strength and uniform elongation of the HIP + HTed sample increased by 5% and 46%,respectively,due to the synergistic deformation of bimodal γ’phases,especially large cubic γ’ phases.Finally,the relationship between phase transformations and plastic deformations in the IDEDed sample was discussed on the basis of generalized stability theory in terms of the trade-off between thermodynamics and kinetics.

Effect of Weft Binding Structure on Compression Properties of Three-Dimensional Woven Spacer Fabrics and Composites

With the wide use of three-dimensional woven spacer composites(3DWSCs),the market expects greater mechanical properties from this material.By changing the weft fastening method of the traditional I-shape pile yarns,we designed three-dimensional woven spacer fabrics(3DWSFs)and 3DWSCs with the weft V-shape to improve the compression performance of traditional 3DWSFs.The effects of weft binding structures,V-pile densities,and V-shaped angle were investigated in this paper.It is found that the compression resistance of 3DWSFs with the weft V-shape is improved compared to that with the weft I-shape,the fabric height recovery rate is as high as 95.7%,and the average elastic recovery rate is 59.39%.When the interlayer pile yarn density is the same,the weft V-shaped and weft I-shaped 3DWSCs have similar flatwise pressure and edgewise pressure performance.The compression properties of the composite improve as the density of the V-pile yarns increases.The flatwise compression load decreases as the V-shaped angle decreases.When the V-shaped angle is 28°and 42°,the latitudinal V-shaped 3DWSCs perform exceptionally well in terms of anti-compression cushioning.The V-shaped weft binding method offers a novel approach to structural design of 3DWSCs.

Experimental Study on Mechanical Properties of Self-Compacting Recycled Concrete

The application of self-compacting recycled concrete can solve the problem of environmental pollution caused by construction waste but its mechanical properties have not been unified and need further study.The strength of recycled concrete is unstable,and its performance still needs further study.The combination of fixed sand and stone volume method and free water cement ratio method is used to determine the mix ratio of self-compacting recycled concrete.24 sets of slump expansion tests and 24 sets of cube axial compression tests were carried out to study the effect of recycled aggregate replacement rate on the flow performance and axial compressive strength of self-compacting recycled concrete,and the performance conversion formula of self-compacting recycled concrete was given.The results show that with the increase of the regenerated coarse aggregate substitution rate,the fluidity and filling property of the self-compacting regenerated concrete mix decreased.The failure of self-compacting recycled concrete is mainly due to the failure of strength between old mortar and new mixture.As the substitution rate increases from 0 to 100%,the axial compressive strength decreases by 15.2%.

Compressive properties and energy absorption characteristics of open-cell nickel foams

Open-cell nickel foams with different relative densities and pre-stretching degrees were subjected to room temperature quasi-static compressive tests to explore their compressive properties. The compressive properties of the nickel foams including yield strength, elastic modulus, energy absorption density and energy absorption efficiency were calculated accurately. The results show that the compressive properties of yield strength, elastic modulus and energy absorption density increase with the increase of relative density of nickel foams. The compressive properties are sensitive to the pre-stretching degree, and the values of yield strength, elastic modulus and energy absorption density decrease with the increase of pre-stretching degree. However, the energy absorption efficiency at the densification strain state exhibits the independence of relative density and pre-stretching degree. The value of energy absorption efficiency reaches its peak when the strain is at the end of the collapse plateau region.

Magnetic properties of La-Zn substituted Sr-hexaferrites by self-propagation high-temperature synthesis

The La-Zn substituted SrM-type ferrites with the composition of Sr1-xLaxFe12-xZnxO19 （x=0-0.4） were prepared by self-propagating high-temperature synthesis （SHS）. The single SrM phase was detected by XRD in the as-received samples by controlling the Fe contents in the reagents. The substitution of La^3＋and Zn^2＋ obviously increased the magnetic properties of the as-prepared samples. The maximum improvements of Br, Hcb and （BH）m were 14.4%, 15.3% and 30.7%, respectively compared with that of the samples without La-Zn substitution. Microstructure observation by SEM showed that the SHS method benefited forming the better particle features and achieving the higher Hcj in comparison with the traditional firing method.

Microstructure and high-temperature mechanical properties of laser beam welded TC4/TA15 dissimilar titanium alloy joints

The microstructure evolution and high-temperature mechanical properties of laser beam welded TC4/TA15 dissimilar titanium alloy joints under different welding parameters were studied.The results show that the weld fusion zone of TC4/TA15 dissimilar welded joints consists of coarsenedβcolumnar crystals that contain mainly acicularα’martensite.The heat affected zone is composed of the initialαphase and the transformedβstructure,and the width of heat affected zone on the TA15 side is narrower than that on the TC4 side.With increasing temperature,the yield strength and ultimate tensile strength of the TC4/TA15 dissimilar welded joints decrease and the highest plastic deformation is obtained at 800°C.The tensile strength of the dissimilar joints with different welding parameters and base material satisfies the following relation(from high to low):TA15 base material>dissimilar joints>TC4 base material.The microhardness of a cross-section of the TC4/TA15 dissimilar joints reaches a maximum at the centre of the weld and is reduced globally after heat treatment,but the microhardness distribution is not changed.An elevated temperature tensile fracture of the dissimilar joints is located on the side of the TC4 base material.Necking occurs during the tensile tests and the fracture characteristics are typical when ductility is present in the material.

High-temperature mechanical properties of aluminium alloys reinforced with titanium diboride (TiB_2) particles

The physical and mechanical properties of metal matrix composites were improved by the addition of reinforcements. The mechanical properties of particulate-reinforced metal-matrix composites based on aluminium alloys （6061 and 7015） at high temperatures were studied. Titanium diboride （TiB2） particles were used as the reinforcement. All the composites were produced by hot extrusion. The tensile properties and fracture characteristics of these materials were investigated at room temperature and at high temperatures to determine their ultimate strength and strain to failure. The fracture surface was analysed by scanning electron microscopy. TiB2 particles provide high stability of the alumin- ium alloys （6061 and 7015） in the fabrication process. An improvement in the mechanical behaviour was achieved by adding TiB2 particles as reinforcement in both the aluminium alloys. Adding TiB2 particles reduces the ductility of the aluminium alloys but does not change the microscopic mode of failure, and the fracture surface exhibits a ductile appearance with dimples formed by coalescence.

Enhanced thermal stability and mechanical properties of high-temperature resistant Al-Cu alloy with Zr and Mn micro-alloying

The high temperature(HT)thermal stability and mechanical properties of Al-5%Cu(AC)and Al-5%Cu-0.2%Mn-0.2 Zr%(ACMZ)alloys from 573 to 673 K were systematically studied.The results displayed that micro-alloying additions of Zr and Mn elements have presented a significant role in stabilizing the main strengthening metastableθ′precipitates at a temperature as high as 573 K.Simultaneously,the HT tensile test demonstrated that ACMZ alloy retained their strength of(88.6±8.8)MPa,which was much higher than that of AC alloy((32.5±0.8)MPa)after the thermal exposure at 573 K for 200 h.Finally,the underlying mechanisms of strength and ductility enhancement mechanism of the ACMZ alloy at HT were discussed in detail.

Effects of porosity and pore size on the compressive properties of closed-cell Mg alloy foam

In our current work,AZ31 magnesium alloy foams with closed-cell were successfully fabricated by melt foaming method using Ca and CaCO3 as thickening and blowing agent,respectively.The influences of porosity and pore size on the quasi-static compressive properties of the foams were systematically investigated.The results showed that the yield strength,energy absorption capacity and ideality energy absorption efficiency were decreased with the increase in porosity.However,specimens with porosities of 60%,65%and 70%possessed similar total energy absorption capacity and ideality energy absorption efficiency.Meanwhile,experimental results showed that mean plateau strength of the foams was increased first and then decreased with increase in mean pore size.In addition,energy absorption capacities were almost the same in the initial stage,while the differences were obvious in the middle stage.From the engineering point of view,the specimens with mean pore size of 1.5 mm possess good combination of mean plateau strength and energy absorption characteristics under the present conditions.

Microstructure and high-temperature mechanical properties of near net shaped Ti−45Al−7Nb−0.3W alloy by hot isostatic pressing process

Near net shaped Ti−45Al−7Nb−0.3W alloy(at.%)parts were manufactured by hot isostatic pressing(HIP).The microstructure and high-temperature mechanical properties of the alloy were investigated by X-ray diffractometry(XRD),scanning electron microscopy(SEM)and transmission electron microscopy(TEM).The results show that at a temperature of 700℃,the peak yield stress(YS)and ultimate tensile stress(UTS)of alloy are 534 and 575 MPa,respectively,and the alloy shows satisfactory comprehensive mechanical properties at 850℃.The alloy exhibits superplastic characteristics at 1000℃ with an initial strain rate of 5×10^−5 s^−1.When the tensile temperature is below 750℃,the deformation mechanisms are dislocation movements and mechanical twinning.Increasing the tensile temperature above 800℃,grain boundary sliding and grain rotation occur more frequently due to the accumulation of dislocations at grain boundary.

Effects of foaming parameters on microstructure and compressive properties of aluminum foams produced by powder metallurgy method

Semi open-cell aluminum foams having channels between individual cells were produced using low cost CaCO3foamingagent and applying the powder compact melting process.To this end,the aluminum and CaCO3powder mixtures were coldcompacted into dense cylindrical precursors for foaming at specific temperatures under air atmosphere.The effects of severalparameters including precursor compaction pressure,foaming agent content as well as temperature and time of the foaming processon the cell microstructure,linear expansion,relative density and compressive properties were investigated.A uniform distribution ofcells with sizes less than100μm,which form semi open-cell structures with relative densities in the range of55.4%-84.4%,wasobtained.The elevation of compaction pressure between127-318MPa and blowing agent up to15%(mass fraction)led to anincrease in the linear expansion,compressive strength and densification strain.By varying the foaming temperature from800to1000°C,all of the investigated parameters increased except compressive strength and relative density.The results indicated theoptimal foaming temperature and time as900°C and10-25min,respectively.

Effect of Porosity and Cell Size on the Dynamic Compressive Properties of Aluminum Alloy Foams

The dynamic mechanical properties of open-cell aluminum alloy foams with different relative densities and cell sizes have been investigated by compressive tests. The strain rates varied from 700 s-1 to 2600 s-1. The experimental results showed that the dynamic compressive stress-strain curves exhibited a typical three-stage behavior: elastic, plateau and densification. The dynamic compressive strength of foams is affected not only by the relative density but also by the strain rate and cell size. Aluminum alloy foams with higher relative density or smaller cell size are more sensitive to the strain rate than foams with lower relative density or larger cell size.