期刊文献+
共找到2篇文章
< 1 >
每页显示 20 50 100
煤基固废复合改性剂高温重构钢渣的性能及机理研究
1
作者 王长龙 李鑫 +9 位作者 陈敬亮 张岳文 张苏花 荊牮霖 马锦涛 平浩岩 齐洋 郑永超 翟玉新 刘枫 《科学技术与工程》 北大核心 2023年第28期12215-12224,共10页
为了促进钢渣(steel slag,SS)和煤基固废的综合利用,研究了煤基固废复合改性剂(CMCSR)(煤气化渣-硅钙渣-煤田区域水库底泥)对高温重构钢渣(SHTM)的胶凝性能和体积稳定性的影响,采用X射线衍射(X-ray diffraction,XRD)、扫描电镜(scanning... 为了促进钢渣(steel slag,SS)和煤基固废的综合利用,研究了煤基固废复合改性剂(CMCSR)(煤气化渣-硅钙渣-煤田区域水库底泥)对高温重构钢渣(SHTM)的胶凝性能和体积稳定性的影响,采用X射线衍射(X-ray diffraction,XRD)、扫描电镜(scanning electron microscope,SEM)、能谱仪(energy dispersive spectrometer,EDS)等测试方法,对重构钢渣的物相组成、微观结构及高温重构机理进行分析。结果表明:CMCSR可以提高钢渣的胶凝性能,显著降低了钢渣中游离氧化钙(f-CaO)含量。当重构温度为1250℃,CMCSR掺量为25%时,重构钢渣28 d活性指数比原钢渣可提高16.1%,重构钢渣中f-CaO的含量由4.04%降至1.90%,满足《用于水泥和混凝土中的钢渣粉》(GB/T 20491—2017)中f-CaO含量≤3%的要求。CMCSR掺量由15%增加至35%,重构钢渣中形成透辉石(CMS2)、钙铝黄长石(C_(2)AS)、C_(3)A等硅铝基矿物。高温重构过程促使RO相(CaO-FeO-MnO-MgO固溶体)中的FeO转变为镁铁尖晶石(MgFe_(2)O_(4))和磁铁矿(Fe_(3)O_(4))。重构温度为1250℃,掺25%CMCSR的重构钢渣形成结晶良好、粒径可达10μm以上椭圆形的C_(2)S颗粒。掺入煤基固废复合改性剂的高温改性钢渣,其体积稳定性、胶凝活性和易磨性得到了有效改善,从而为钢渣的低能耗细磨加工进行制品开发,或在水泥和混凝土中的直接应用提供了可能,实现了煤基固废与冶金固废的协同利用。 展开更多
关键词 钢渣(SS) 复合改性剂 高温重构(htm) 胶凝性能 体积稳定性
下载PDF
Surface Microstructure and High Temperature Oxidation Resistance of Thermal Sprayed NiCoCrAlY Bond-Coat Modified by Cathode Plasma Electrolysis 被引量:3
2
作者 Shunjie Deng Peng Wang +1 位作者 Yedong He Jin Zhang 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2017年第9期1055-1060,共6页
The surface properties of the air-plasma sprayed bond-coat have been modified by cathode plasma electrolysis(CPE). After modification, a re-melted layer without obvious pores and oxide stringers is formed,the gain s... The surface properties of the air-plasma sprayed bond-coat have been modified by cathode plasma electrolysis(CPE). After modification, a re-melted layer without obvious pores and oxide stringers is formed,the gain size of re-melted layer is approximately 80–120 nm. It is shown, from cyclic oxidation at 1100℃,that a thin oxide scale mainly composed of α-Al;O;has been formed on the modified bond-coat and the oxidation resistance of the modified bond-coat has been significantly improved. Such beneficial result can be attributed to following effects: during CPE process, the plasma discharges with high temperature take place on the bond-coat surface. With plasma discharge treatment, the surface is melted and quickly re-solidified, the grain size decreases, and the pores and oxide stringers disappear. During cyclic oxidation, owing to the above modification of surface properties, the critical content of Al for selective oxidation is significantly decreased. Therefore, a continuous Al;O;scale is formed. 展开更多
关键词 Cathode plasma electrolysis NiCoCrAlY bond-coat Surface modification Microstructure high-temperature oxidation
原文传递
上一页 1 下一页 到第
使用帮助 返回顶部