高温硫化(HTV)硅橡胶凭其强憎水性、憎水迁移性和恢复性等优越性能,成为合成绝缘子外绝缘的首选材料。然而,与无机材料相比,高温硫化硅橡胶更易受环境影响而老化,因此通过氙灯辐照对高温硫化硅橡胶进行紫外加速老化试验。采用静态接触...高温硫化(HTV)硅橡胶凭其强憎水性、憎水迁移性和恢复性等优越性能,成为合成绝缘子外绝缘的首选材料。然而,与无机材料相比,高温硫化硅橡胶更易受环境影响而老化,因此通过氙灯辐照对高温硫化硅橡胶进行紫外加速老化试验。采用静态接触角法测量和评价硅橡胶材料的憎水性,同时进行了硬度以及扫描电子显微镜(SEM)测试,另外采用image-pro plus 6.0软件对SEM图片进行测试分析。试验结果表明:短时氙灯辐照对高温硫化硅橡胶表面憎水性影响不大,材料硬度有变大趋势,材料表面凹凸不平,粗糙度变大,并有填充物外露的趋势。随着辐照时间增加,欲析出颗粒数目逐渐增多,颗粒大小逐渐变大,总面积增加。展开更多
为了研究交流电晕对室温硫化(room temperature vulcanization,RTV)和高温硫化(high temperature vul-canization,HTV)硅橡胶憎水性丧失和恢复的影响,基于硅橡胶电晕测试系统在相同的温度、湿度和场强下对同样厚度的RTV和HTV硅橡胶进行...为了研究交流电晕对室温硫化(room temperature vulcanization,RTV)和高温硫化(high temperature vul-canization,HTV)硅橡胶憎水性丧失和恢复的影响,基于硅橡胶电晕测试系统在相同的温度、湿度和场强下对同样厚度的RTV和HTV硅橡胶进行了电晕,测量了不同电压和电晕持续时间情况下RTV和HTV硅橡胶在电晕和恢复时的静态接触角随时间的变化情况。研究发现:同样的电压和加压时间情况下,RTV硅橡胶电晕后憎水性丧失速度慢于HTV硅橡胶,憎水性恢复到初始值所需时间明显短于HTV硅橡胶。随电晕时间的增加硅橡胶憎水性恢复到初始值所需时间存在增加的趋势。随电晕电压的增加硅橡胶憎水性下降速度加快,憎水性恢复到初值所需时间存在增加的趋势;随电晕时间、电压的增加晕圈逐渐增大。电晕的开始阶段憎水性快速下降,随时间增加速度逐渐下降,后来憎水性逐渐趋于稳定;恢复的开始阶段憎水性恢复速度快,随时间增加速度逐渐下降,后来憎水性逐渐趋于稳定。对电晕后硅橡胶表面进行了扫描电镜(scanning electron microscope,SEM)分析,发现RTV硅橡胶表面破坏情况比HTV硅橡胶严重。展开更多
Slow positron beam was applied to study the depth profile structure of the virgin and the aged high-temperature vulcanized silicone rubber(HTV). Scanning electron microscope(SEM) images show that the surface of virgin...Slow positron beam was applied to study the depth profile structure of the virgin and the aged high-temperature vulcanized silicone rubber(HTV). Scanning electron microscope(SEM) images show that the surface of virgin sample is smooth, while the outdoor aged samples are all rough. According to the S(E) curves obtained by slow positron beam, in a depth of more than 1 μm, the S parameter of the sample aged at low-potential side keeps the same value with the virgin one;while the S values of the highpotential side aged sample remain rather low in a depth of about 5 μm. Thermo gravimetric analysis(TGA) results show that the sample in high potential side contains more inorganic constituents than that of other samples. The results are attributed to the strong electric field induced corona aging at high potential side of the composite insulator.展开更多
文摘高温硫化(HTV)硅橡胶凭其强憎水性、憎水迁移性和恢复性等优越性能,成为合成绝缘子外绝缘的首选材料。然而,与无机材料相比,高温硫化硅橡胶更易受环境影响而老化,因此通过氙灯辐照对高温硫化硅橡胶进行紫外加速老化试验。采用静态接触角法测量和评价硅橡胶材料的憎水性,同时进行了硬度以及扫描电子显微镜(SEM)测试,另外采用image-pro plus 6.0软件对SEM图片进行测试分析。试验结果表明:短时氙灯辐照对高温硫化硅橡胶表面憎水性影响不大,材料硬度有变大趋势,材料表面凹凸不平,粗糙度变大,并有填充物外露的趋势。随着辐照时间增加,欲析出颗粒数目逐渐增多,颗粒大小逐渐变大,总面积增加。
文摘为了研究交流电晕对室温硫化(room temperature vulcanization,RTV)和高温硫化(high temperature vul-canization,HTV)硅橡胶憎水性丧失和恢复的影响,基于硅橡胶电晕测试系统在相同的温度、湿度和场强下对同样厚度的RTV和HTV硅橡胶进行了电晕,测量了不同电压和电晕持续时间情况下RTV和HTV硅橡胶在电晕和恢复时的静态接触角随时间的变化情况。研究发现:同样的电压和加压时间情况下,RTV硅橡胶电晕后憎水性丧失速度慢于HTV硅橡胶,憎水性恢复到初始值所需时间明显短于HTV硅橡胶。随电晕时间的增加硅橡胶憎水性恢复到初始值所需时间存在增加的趋势。随电晕电压的增加硅橡胶憎水性下降速度加快,憎水性恢复到初值所需时间存在增加的趋势;随电晕时间、电压的增加晕圈逐渐增大。电晕的开始阶段憎水性快速下降,随时间增加速度逐渐下降,后来憎水性逐渐趋于稳定;恢复的开始阶段憎水性恢复速度快,随时间增加速度逐渐下降,后来憎水性逐渐趋于稳定。对电晕后硅橡胶表面进行了扫描电镜(scanning electron microscope,SEM)分析,发现RTV硅橡胶表面破坏情况比HTV硅橡胶严重。
基金Funded by the National Natural Science Foundation of China(No.21174108)the Science and Technology Project of China Southern Power Grid Co,Ltd(No.GDKJQQ20161197)
文摘Slow positron beam was applied to study the depth profile structure of the virgin and the aged high-temperature vulcanized silicone rubber(HTV). Scanning electron microscope(SEM) images show that the surface of virgin sample is smooth, while the outdoor aged samples are all rough. According to the S(E) curves obtained by slow positron beam, in a depth of more than 1 μm, the S parameter of the sample aged at low-potential side keeps the same value with the virgin one;while the S values of the highpotential side aged sample remain rather low in a depth of about 5 μm. Thermo gravimetric analysis(TGA) results show that the sample in high potential side contains more inorganic constituents than that of other samples. The results are attributed to the strong electric field induced corona aging at high potential side of the composite insulator.
