Autogenous Shrinkage of High Strength Lightweight Aggregate Concrete

The characteristic of autogenous shrinkage（AS） and its effect on high strength lightweight aggregate concrete（HSLAC） were studied.The experimental results show that the main shrinkage of high strength concrete is AS and the amount of cement can affect the AS of HSLAC remarkably,At the early stage the AS of HSLAC is lower than that of high strength normal concrete,but it has a large growth at the later stage.The AS of high strength normal concrete becomes stable at 90d age,but HSLAC still has a high AS growth .It is found that adjusting the volume rate of lightweight aggregate,mixing with a proper dosage of fly ash and raising the water saturation degree of lightweight aggregate can markedly reduce the AS rate of HSLAC.

Bond Behavior between BFRP Bars and Hybrid Fiber Recycled Aggregate Concrete after High Temperature

The aim of this study is to improve the bond performance of basalt fiber reinforced polymer(BFRP)bars and recycled aggregate concrete(RAC)after being exposed to high temperatures.The bond behavior(failure modes,bond strength,bond stress-slip curves)between BFRP bars and hybrid fiber recycled aggregate concrete(HFRAC)after being exposed to temperatures ranging from 20℃up to 500℃was studied by using pull-out tests.The effect of high temperatures on mechanical properties of concrete(compressive strength,splitting tensile strength)and tensile strength of BFRP bars was also investigated.The bond strength decreased as the temperature increased and the drop of bond strength between RAC and BFRP bar was larger than that between HFRAC and BFRP bar.As the temperature rises,the key factor affecting the bond strength was gradually transformed from concrete strength to BFRP bar strength.The relationship between bond stress and slip in the dimensionless bond stress-slip ascending section was established,which was in good agreement with the experimental results.

Influences of Seasonal Freezing and Thawing on Soil Water-stable Aggregates in Orchard in High Cold Region,Northeast China

Soil aggregate stability,as an important indicator of soil functions,may be affected by seasonal freezing and thawing(SFT)and land use in high cold and wet regions.Therefore,comprehensive understanding the effects of SFT on aggregate stability in orchards during winter and spring is crucial to develop appropriate management strategies that can effectively alleviate the degradation of soil quality to ensure sustainable development of orchard ecosystems.To determine the mechanism of degradation in orchard soil quality,the effects of SFT on the stability of water-stable aggregates were examined in apple-pear orchards(Pyrus ussuriensis var.ovoidea)of four different ages(11,25,40,and 63 yr)on 0 to 5%slopes before freezing and after thawing from October 2015 to June 2016 in Longjing City,Yanbian Prefecture,Northeast China,involving a comparison of planted versus adjacent uncultivated lands(control).Soil samples were collected to investigate water-stable aggregate stability in three incremental soil layers(0–20,20–40 and 40–60 cm).In the same samples,iron oxide,organic matter,and clay contents of the soil were also determined.Results showed that the destructive influences of SFT on water-stable aggregates were more pronounced with the increased orchards ages,and SFT exerted severe effects on water-stable aggregates of older orchards(40 and 63 yr)than juvenile orchards.Undergoing SFT,the soil instability index and the percentage of aggregate destruction increased by mean 0.15 mm and 1.86%,the degree of aggregation decreased by mean 1.32%,and the erosion resistance weakened,which consequently led to aggregate stability decreased.In addition,soil free,amorphous,and crystalline iron oxide as well as soil organic matter and clay contents are all important factors affecting the stability of water-stable aggregates,and their changes in their contents were consistent with those in the stability of water-stable aggregates.The results of this study suggest that long-term planting fruit trees can exacerbate the damaging effects of SFT on aggregate stability and further soil erosion increases and nutrient losses in an orchard,which hider sustainable use of soil and the productivity orchards.

Brittleness Generation Mechanism and Failure Model of High Strength Lightweight Aggregate Concrete

The brittleness generation mechanism of high strength lightweight aggregate con-crete(HSLWAC) was presented, and it was indicated that lightweight aggregate was the vulnerable spot, initiating brittleness. Based on the analysis of the brittleness failure by the load-deflection curve, the brittleness presented by HSLWAC was more prominent compared with ordinary lightweight aggregate concrete of the same strength grade. The model of brittleness failure was also established.

Experimental Study on Compressive Strength of Recycled Aggregate Concrete under High Temperatur

This research aims to study the effect of elevated temperature on the compressive strength evolution of concrete made with recycled aggregate.Demolished building concrete samples were collected from four different sites in Saudi Arabia,namely from Tabuk,Madina,Yanbu,and Riyadh.These concretes were crushed and recycled into aggregates to be used to make new concrete samples.These samples were tested for axial compressive strength at ages 3,7,14,and 28 days at ambient temperature.Samples of the same concrete mixes were subjected to the elevated temperature of 300°C and tested for compressive strength again.The experimental result reveals that the recycled aggregate concrete samples have good quality at ambient and elevated temperatures and are considered fairly close to the concrete made with natural aggregate.However,recycled aggregate concrete at high temperatures showed higher strength degradation than natural aggregate concrete,but with differences that do not exceed 5%to 10%.The concrete samples made from recycled coarse aggregates also reached the design strength.It can be considered acceptable,considering the high variation in the concrete’s thermal response found in the literature.

Relation between Modulus of Elasticity and Compressive Strength of Ultrahigh-Strength Mortar with Mixed Silicon Carbide as Fine Aggregate

Ultrahigh-strength mortar mixed surface-oxidized silicon carbide as a fine aggregate was prepared by means of press-casting followed by curing in an autoclave. The relation between modulus of elssticity up to 111 GPa and compressive strength up to 360 MPa of mortar mixed silicon carbide was discussed and it was revealed that the contributions of the aggregate hardness and of the interfacial strength between the aggregate and the cement paste on the elasticity of mortar were imporant.

Different Curing Systems on Mechanical Properties of Ultra-High Performance Concrete with Coarse Aggregate

High durability and high tensile strength makes ultra-high performance concrete( UHPC) an ideal material for bridges,while its early shrinkage in the construction of cast-in-situ mass concrete leads structure crack-easily,which restricts the application of UHPC in deck system. Whether reasonable amount of coarse aggregate can influence the strength of UHPC and improve the shrinkage performance or reduce the cost is still in doubt. Besides,in order to improve its constructability and workability, whether autoclaved curing system of UHPC can be changed remains to be further researched. In response to these circumstances, a systematic experimental study on the strength of UHPC mixed with coarse aggregate in different ratios has been presented in this paper. The three curing systems,namely standard curing,180-200 ℃/1. 1 MPa autoclaved curing,and hot water curing were tested to reveal the relationship between UHPC's properties and curing systems,and the UHPC ' s microstructure was also preliminarily studied by scanning electron microscope( SEM). The experimental research can draw the following conclusions. Under the condition of the same mix ratio, autoclaved curing guarantees the highest compressive strength,followed by hot water curing and standard curing. The compressive strength of concrete increases with the temperature in the range of 25 to 90 ℃ hot water curing,and high temperature in precuring period can speed up the strength development of UHPC,but the sequence of precuring period does not obviously affect the results. In 90 ℃ hot water and autoclaved curing,the strength is over 150 MPa,and it has little relation with gravel ratio. While the value increases first and then decreases in a lower temperature curing with the increasing of gravel amount,even only about 80 MPa at room temperature. The strength increases moderately along with the increase of the curing age by standard curing,especially in the initial stage.

A Study on the Impact of Chemical Structure on the Evolution of Aggregate Structure in Fiber-shaped High Density Polyethylene Vitrimer

Vitrimers have emerged as a prominent research area in the field of polymer materials.Most of the studies have focused on synthesizing polymers with versatile dynamic crosslinking structures,while the impact of chemical structure on aggregate structure of vitrimers,particularly during polymer processing,remains insufficiently investigated.The present study employed commercial maleic anhydride-grafted-high density polyethylene(M-g-HDPE)as the matrix and hexanediol as the crosslinker to facilely obtain fiber-shaped HDPE vitrimers through a reaction extrusion and post-drawing process.Through chemical structure characterization,morphology observation,thermal and mechanical properties investigation,as well as aggregate structure analysis,this work revealed the influence of dynamic bonds on the formation of aggregate structures during fiber-shaped vitrimers processing.A small amount of dynamic bonds in HDPE restricts the motion of PE chain during melt-extruding and post-drawing,resulting in a lower orientation of the PE chains.However,lamellar growth and fibril formation during post-drawing at high temperature are enhanced to some extent due to the competition between dynamic bond and chain relaxation.The uneven morphology of fibershaped HDPE vitrimers can be attributed to the stronger elastic effect brought by dynamic bonding,which plays a more dominant role in determining the mechanical properties of fiber-shaped vitrimers compared to aggregate structure.Abstract Vitrimers have emerged as a prominent research area in the field of polymer materials.Most of the studies have focused on synthesizing polymers with versatile dynamic crosslinking structures,while the impact of chemical structure on aggregate structure of vitrimers,particularly during polymer processing,remains insufficiently investigated.The present study employed commercial maleic anhydride-grafted-high density polyethylene(M-g-HDPE)as the matrix and hexanediol as the crosslinker to facilely obtain fiber-shaped HDPE vitrimers through a reaction extrusion and post-drawing process.Through chemical structure characterization,morphology observation,thermal and mechanical properties investigation,as well as aggregate structure analysis,this work revealed the influence of dynamic bonds on the formation of aggregate structures during fiber-shaped vitrimers processing.A small amount of dynamic bonds in HDPE restricts the motion of PE chain during melt-extruding and post-drawing,resulting in a lower orientation of the PE chains.However,lamellar growth and fibril formation during post-drawing at high temperature are enhanced to some extent due to the competition between dynamic bond and chain relaxation.The uneven morphology of fibershaped HDPE vitrimers can be attributed to the stronger elastic effect brought by dynamic bonding,which plays a more dominant role in determining the mechanical properties of fiber-shaped vitrimers compared to aggregate structure.

Shear behavior of coarse aggregates for dam construction under varied stress paths

Coarse aggregates are the major infrastructure materials of concrete-faced rock-fill dams and are consolidated to bear upper and lateral loads. With the increase of dam height, high confining pressure and complex stress states complicate the shear behavfor of coarse aggregates, and thus impede the high dam＇s proper construction, operation and maintenance. An experimental program was conducted to study the shear behavior of dam coarse aggregates using a large-scale triaxial shear apparatus. Through triaxial shear tests, the strain-stress behaviors of aggregates were observed under constant confining pressures： 300 kPa, 600 kPa 900 kPa and 1200 kPa. Shear strengths and aggregate breakage characteristics associated with high pressure shear processes are discussed. Stress path tests were conducted to observe and analyze coarse aggregate response under complex stress states. In triaxial shear tests, it was found that peak deviator stresses increase along with confining pressures, whereas the peak principal stress ratios decrease as confining pressures increase With increasing confining pressures, the dilation decreases and the contraction eventually prevails. Initial strength parameters （Poisson＇s ratio and tangent modulus） show a nonlinear relationship with confining pressures when the pressures are relatively low. Shear strength parameters decrease with increasing confining pressures. The failure envelope lines are convex curves, with clear curvature under low confining pressures. Under moderate confining pressures, dilation is offset by particle breakage. Under high confining pressures, dilation disappears.

Effect of Pre-wetted Light-weight Aggregate on Internal RelativeHumidity and Autogenous Shrinkage of Concrete

This research indicates that the gradient of internal relative humidity （IRH） decreases rapidly within 7-day curing age in HPC. The amount of water imported by pre-wetted light-weight aggregate can regulate IRH of concrete. By importing a proper amount of water, the process of the decline of IRH can be delayed and the autogenous shrinkage can be reduced. The relationship among the amount of water imported by pre- wetted lightweight aggregate, IRH and AS was established. The result provides a new method of reducing early AS and enhancing early cracking resistance of HPC.

Fine particle aggregating and flotation behavior induced by high intensity conditioning of a CO_2 saturation slurry

The influence on fine particle aggregation and flotation behavior induced by high intensity conditioning(HIC) from saturated of the slurry with CO2 saturation was investigated.Bubble size measurements were conducted.The effect of dissolved gas,xanthate addition and agitation speed on fine sphalerite particle aggregation-and flotation-behavior were studied.The results show that during HIC in air or CO2 saturated water xanthate acts as a frother.The dissolved gas content in the pulp and HIC play a synergistic role in promoting fine particle aggregation and hence flotation;a significantly enhanced aggregation of fine sphalerite particles in a CO2 saturated slurry by HIC is observed.The aggregate size increased when the agitation speed was increased from 700 r/min to 1500 r/min.Increasing the HIC speed to 1500 r/min caused a positive impact on flotation kinetics.Further increasing the speed to 2000 r/min resulted in an adverse effect on flotation kinetics.

Observation of fine particle aggregating behavior induced by high intensity conditioning using high speed CCD

The aggregating behavior between bubbles and particles induced by high intensity conditioning (HIC) was studied using high speed CCD technique. Bubble size measurement was conducted, and the attachment behavior between bubbles and particles in HIC cell and flotation cell were observed. The results show that in HIC cell, high intensity conditioning creates an advantage environment for the formation of small size bubble due to hydrodynamic cavitations, and these fine bubbles have high probability of bubble-particle collision, which will enhance fine particle flotation. The bubble-particle attachment experiments indicate that in high intensity conditioning cell, a lot of fine bubbles are produced in situ on the surface of fine particles, and most of fine particles are aggregated under the bridging action of fine bubbles. The observation of bubble-particle interaction in flotation cell illustrates that aggregates created by HIC can be loaded more easily by big air bubble in flotation cell than those created by normal conditioning.

Inhibitory effects and mechanisms of high molecular-weight phlorotannins from Sargassum thunbergii on ADP-induced platelet aggregation

We evaluated the effects of high molecular-weight phlorotannins from Sargassum thunbergii(STP) on ADP-induced platelet aggregation and arachidonic acid(AA) metabolism in New Zealand white rabbits and Wistar rats.The inhibition of STP on platelet aggregation was investigated using a turbidimetric method,and the levels of the terminal products of AA metabolism were measured using the corresponding kits for maleic dialdehyde(MDA),thromboxane B2(TXB2) and 6-keto-prostaglandin F1α(6-keto-PGF1α) by colorimetry and radioimmunoassay,as appropriate.We found that STP could inhibit ADP-induced platelet aggregation,and the inhibitory ratio was 91.50% at the STP concentration of 4.0 mg/mL.Furthermore,STP markedly affected AA metabolism by decreasing the synthesis of MDA(P<0.01) and increasing the synthesis of 6-keto-PGF1α,thus changing the plasma TXB2/6-keto-PGF1α balance when the platelets were activated(P<0.01).Therefore,STP altered AA metabolism and these findings partly revealed the molecular mechanism by which STP inhibits ADP-induced platelet aggregation.

不同纤维对高强轻骨料混凝土力学性能影响及微观机理研究

为改善高强轻骨料混凝土的力学性能和弯曲韧性,研究了玄武岩纤维、细聚乙烯醇纤维、仿钢纤维、聚丙烯纤维和粗聚乙烯醇纤维的掺入对高强轻骨料混凝土抗压强度、劈裂抗拉强度和抗弯强度的影响规律。通过4点弯曲试验获取荷载-挠度曲线,基于韧性指标对比分析了5种纤维对高强轻骨料混凝土弯曲韧性的影响。通过扫描电子显微镜观察纤维破坏前后的表面微观形貌,阐释了不同纤维的增强增韧机理。研究结果表明:掺入纤维对高强轻骨料混凝土的力学性能均有提升,主要提升高强轻骨料混凝土的抗拉性能和弯曲韧性。粗聚乙烯醇纤维提升劈裂抗拉强度和抗弯强度程度最大,分别提高了83%和220%,使高强轻骨料混凝土破坏由脆性转为高延性。纤维对高强轻骨料混凝土抗拉性能和韧性的提升与纤维表面损伤程度成正比。

基于骨料运移的高浓度充填管道磨损机制

高浓度充填管道磨损威胁矿山安全,但磨损机制尚不明析。采用CFD-DEM模拟高浓度充填管道磨蚀、骨料运移、骨料与管壁接触,结合理论分析和现场实测揭示管道磨损机制。结果表明:料浆承载力充足时,固液两相在管内呈柱塞流,骨料向管道中心运移,管壁处形成减磨滑移层,管道四周磨损较均匀;反之,骨料在管底呈滑动床,管底磨损最严重。滑动床对管壁的作用力是柱塞流时的2.46~2.76倍,管底磨损是柱塞流时的1.48倍。骨料在管壁附近的运动轨迹类似波形线,以小角度接触管壁并滑滚,对管壁的切向力是法向力的27.44~30.84倍,管壁磨损受骨料切向刮擦主导。非稳态输送、粗糙管壁和过高浓度会劣化滑移层的减磨效果。根据模拟结果提出六条磨损防控措施,可供相关矿山借鉴。

粗集料对超高强混凝土徐变的影响

徐变是混凝土固有的时变特性,对混凝土结构和构件的受力及长期服役性能有着重大影响。以粗集料为切入点,研究粗集料的掺量、粗集料最大粒径以及粗集料与基体性质协调性等因素对超高强混凝土的力学性能和徐变性能的影响。结果表明:掺粗集料的超高强混凝土徐变明显小于不掺粗集料的混凝土,掺粗集料可有效降低超高强混凝土的徐变,但减小粗集料的最大粒径对徐变无明显抑制效果。此外,超高强混凝土并非强度越高徐变越小,其徐变的大小主要受超高强混凝土强度与弹性模量的协同发展程度的影响。通过修正FIB MC2010模型,建立了适用于超高强混凝土的徐变预测模型。

基于高速摄像技术的气液两相流型分析实验设计

针对流体力学教学中难以观察流体动态运动过程的问题,通过调整课程结构,将高速摄像技术与传统的气液两相流实验平台相结合,使流体力学抽象概念得到具象化呈现。实验结果表明,借助该可视化实验教学平台,能够研究气泡的运移特征,研究旋流场内气泡的破碎和聚并行为,分析不同工况条件下的气泡形态,得出旋流场内气液两相流型。对培养学生分析和解决问题能力,提升实验教学效果有很好的促进作用。

基于声发射技术的高强全珊瑚钢筋混凝土板破坏特性研究

为了探究全珊瑚钢筋混凝土板破坏特性,设计了3种不同配筋率(0.85%、1.13%和1.41%)的高强全珊瑚钢筋混凝土板构件.结合声发射技术,开展了全珊瑚混凝土板构件四点弯曲加载试验,揭示了配筋率对高强全珊瑚钢筋混凝土板力学性能的影响.基于声发射参数速率过程理论,建立了损伤定量评估模型,并进一步提出了可用于工程实践的损伤评估准则.结果表明:随配筋率增大,高强全珊瑚混凝土板构件起裂荷载、起裂时间与峰值荷载均增大,但中心挠度降低了11.29%;单位时间声发射参数变化均存在2个峰值区,可作为板构件的起裂评判和破坏预兆;根据声发射参数累计值变化可将高强全珊瑚混凝土板构件破坏过程划分为轻度(<0.35)、中度(0.35~0.66)、高度(0.66~0.84)和重度(>0.84)损伤4个程度.所建立模型适用于不同配筋率的全珊瑚混凝土板构件损伤评估.

淀粉及其改性产品对东鞍山细粒赤铁矿聚团——磁选的影响

针对东鞍山强磁选抛尾存在粒度小于20μm的微细粒铁矿物流失的问题,研究了不同种类淀粉及其改性产品对微细粒赤铁矿的选择性聚团效果,通过团聚—磁选试验确定了适宜的团聚药剂和用量,借助偏光显微镜和红外光谱等手段检测了药剂与赤铁矿和石英作用前后的形貌特征,最后通过研究高分子药剂的作用机理,论述了药剂的选择性和团聚效果。结果表明:在药剂用量为200 g/t时,交联玉米淀粉的选矿指标优于其他几种药剂,团聚药剂的加入能实现微细粒赤铁矿的选择性聚团,使铁精矿回收率提高2.13~3.94个百分点,选矿效率提高2.77~3.46个百分点,但由于赤铁矿被团聚后呈不规则絮状,在较大的聚团中会夹杂少量石英,导致磁选精矿铁品位略微降低。

碳纤维轻骨料混凝土高温后动态压缩性能研究

目前针对碳纤维轻骨料混凝土在高温作用后的力学性能研究匮乏,考虑到火灾伴随的冲击和爆炸荷载对结构的破坏,采用直径74 mm的分离式霍普金森压杆(SHPB)装置,对轻骨料混凝土(LWAC)进行了动态压缩试验,研究了温度和碳纤维含量对LWAC动态压缩性能的影响,并通过SEM扫描电镜揭示了高温对LWAC微观结构的影响。结果表明:碳纤维掺量的增加提高了LWAC的静态抗压强度,而高温对其静态抗压强度具有劣化作用,纤维的掺入能够在一定程度上阻止高温强度劣化。LWAC的应力-应变曲线随着温度的升高趋于扁平,动态抗压强度降低而峰值应变和极限应变增大,动态抗压强度、峰值应变和极限应变随着碳纤维掺量的增加均出现先增大后减小的趋势。不同温度作用和碳纤维掺量下LWAC试样的DIF随应变率的增加呈线性增加,普通LWAC试件比碳纤维LWAC试样的速率敏感性更高。高温最初改善了LWAC的内部微观结构,但随着温度持续升高,试样内部微观结构严重劣化。