Spatial-temporal distribution and geochemistry of highly evolved Mesozoic granites in Great Xing’an Range,NE China:Discriminant criteria and geological significance

Highly evolved granite is an important sign of the mature continent crust and closely associated with deposits of rare metals.In this work,the authors undertake systematically zircon U-Pb ages and whole rock elemental data for highly evolved granitic intrusions from the Great Xing’an Range(GXR),NE China,to elucidate their discriminant criteria,spatial-temporal distribution,differentiation and geodynamic mecha-nism.Geochemical data of these highly evolved granites suggest that high w(SiO_(2))(>70%)and differentiation index(DI>88)could be quantified indicators,while strong Eu depletion,high TE_(1,3),lowΣREE and low Zr/Hf,Nb/Ta,K/Rb could only be qualitative indicators.Zircon U-Pb ages suggest that the highly evolved gran-ites in the GXR were mainly formed in Late Mesozoic,which can be divided into two major stages:Late Ju-rassic-early Early Cretaceous(162-136 Ma,peak at 138 Ma),and late Early Cretaceous(136-106 Ma,peak at 126 Ma).The highly evolved granites are mainly distributed in the central-southern GXR,and display a weakly trend of getting younger from northwest to southeast,meanwhile indicating the metallogenic potential of rare metals within the central GXR.The spatial-temporal distribution,combined with regional geological data,indicates the highly evolved Mesozoic granites in the GXR were emplaced in an extensional environ-ment,of which the Late Jurassic-early Early Cretaceous extension was related to the closure of the Mongol-Okhotsk Ocean and roll-back of the Paleo-Pacific Plate,while the late Early Cretaceous extension was mainly related to the roll-back of the Paleo-Pacific Plate.

Study on the Relationship among Forest Fire,Temperature and Precipitation and Its Spatial-temporal Variability in China

[Objective] The aim was to discuss the relationship between forest fire and meterological elements （precipitation and temprature） in each region of China.[Method] Firstly,the average precipitation and temperature in forest area of each province in fire season were obtained based on meterological data,forest distribution data,seasonal and monthly data of forest fire in China.Secondly,the relationship among forest fire area,precipitation and temperature was discussed through temporal and correlation analysis.[Result] The changes of precipitation and temperature with time could reflect the annual variation of fire area well.Forest fire area went up with the decrease of precipitation and increase of temprature,and visa versa.Meanwhile,there existed diffirences in the relationship in various regions over time.Correlation analyses revealed that there was positive correlation between forest fire area and temperature,especailly Northwest China （R=0.367,P〈0.01）,Southwest China （R=0.327,P〈0.05）,South China （R=0.33,P〈0.05）,East China （R=0.516,P〈0.01） and Xinjiang （R=0.447,P〈0.05） with obviously positive correlation.At the same time,the correlation between forest fire area and precipitation was significantly positive in Northwest China （R=0.482,P〈0.01）,while it was significantly negaive in South China （R=-0.323,P=0.03）,but there was no significant correlation in other regions.[Conclusion] Relationships between forest fire and meteorological elements （precipitation and temprature） revealed in the study would be useful for fire provention and early warning in China.

Spatial-temporal Variation of Extreme Precipitation Events in Northwest China During 1961-2010

Using the daily precipitation data of 118 meteorological stations in Northwest China from January 1, 1961 to December 31,2010, we analyzed extreme precipitation events from prime precipitation data by applying R-language Climate Index （RClimDex）. The spatial-temporal change characteristics in the past 50 years have been examined using the method of trend analysis, Mann-Kendall and the spatial analysis module of Arcgis9.2. The results show that the spatial distribution of the indices for extreme precipitation in Northwest China is greatly influenced by geographic location, atmospheric circulation and topography, and the spatial difference of extreme precipitation events is very evident, while the indices reduce from the southeast to the northwest except Consecutive Dry Days （CDD）. In Xinjiang region, high values appear in Tianshan Mountains and decrease towards the south and north respectively. In the past 50 years, the temporal variation tendency of the indices for extreme precipitation in Northwest China has a great spatial distinction. It shows that the variation tendency is opposite between the east （decrease） and the west （increase）, and CDD has a decreasing tendency while other indices increase. For each region, it is found that the indices for extreme precipitation in Xinjiang and Qinghai Province shows an increasing trend, and it is remarkable in Tianshan Mountains, the north of Xinjiang and the northeast of Qinghai Province. The temporal variation tendency of the indices for extreme precipitation in Ningxia, Shaanxi and Gansu has a large spatial distinction. The stations which have an increasing tend are mainly found in the north of Ningxia, south of Shaanxi and Hexi Corridor of Gansu. However, the south of Ningxia, north of Shaanxi and Longnan of Gansu Province mainly present a decreasing trend. The temporal variation tendency of the indices for extreme precipitation in Inner Mongolia is not obvious. Overall, the east part of Northwest China has a dry tendency, while the west part has an opposite trend.

Spatial-Temporal Variations in January Precipitation over the Period of 1950-2000 in Pakistan and Possible Links with Global Teleconnections: Geographical Perspective

Empirical Orthogonal Function (EOF) was performed to investigate spatial variation in January precipitation over Pakistan using ground observed mean monthly precipitation data from 1950-2000 with a combination of gridded reanalysis data of sea level pressure (SLP) and 500 hPa geopotential height. The leading EOF mode captures 37.51% of the total variance and the spatial-temporal variability of January precipitation was consistent in the study area. The temporal changes explicate non-periodic interannual variability and some tacit interdecadal variation. The anomalous condition is more prominent along the western bordering mountains and northern high mountainous region than any other region of Pakistan. Based on results the study reveals spatial-temporal variation in January precipitation and possible links with global teleconnections located both in the proximity as well as in the remote areas from the study locus.

Relationships between Western Pacific Subtropical High and Seasonal Precipitation in Eastern China

The monthly observed average precipitation data of 160 meteorological stations in China from 1960 to 2007,had been reorganized by the China Meteorological Administration.By employing that precipitation data,NCEP/NCAR reanalysis data and the index of intensity of western Pacific subtropical high,the seasonal variations of subtropical high and precipitation in eastern China during the past decades are discussed.The relationships between them also are discussed by correlation and composite analyses.The results show that the intensity of subtropical high,which has significantly strengthened in the recent 50 years,especially in spring,autumn and winter,has notable impact on the simultaneous rainfall in the eastern region of China for all seasons,especially in winter.

Initial Analysis on the Effect of High-low Altitude Jet Stream on Heavy Precipitation in Guangxi

By using the routine observation data,a heavy precipitation process which happened in Guangxi on May 27,2006 was analyzed.The results that this heavy precipitation occurred in the common coordination weather system which included the high-altitude trough,the shear line and the ground cold front.The ascent branch of subtropical longitude circle circulation and the polar front jet stream longitude circle circulation had the important role for the formation of rainstorm area.The coupling effect of southerly jet,low-altitude westerly jet and high-altitude westerly jet in the boundary layer was the important reason of rainstorm occurrence.

Synergistic Contribution of Precipitation Anomalies over Northwestern India and the South China Sea to High Temperature over the Yangtze River Valley

This study explores the characteristics of high temperature anomalies over eastern China and associated influencing factors using observations and model outputs.Results show that more long-duration（over 8 days） high temperature events occur over the middle and lower reaches of the Yangtze River Valley（YRV） than over the surrounding regions,and control most of the interannual variation of summer mean temperature in situ.The synergistic effect of summer precipitation over the South China Sea（SCS） region（18°–27°N,115°–124°E） and the northwestern India and Arabian Sea（IAS） region（18°–27°N,60°–80°E） contributes more significantly to the variation of summer YRV temperature,relative to the respective SCS or IAS precipitation anomaly.More precipitation（enhanced condensational heating） over the SCS region strengthens the western Pacific subtropical high（WPSH） and simultaneously weakens the westerly trough over the east coast of Asia,and accordingly results in associated high temperature anomalies over the YRV region through stimulating an East Asia–Pacific（EAP） pattern.More precipitation over the IAS region further adjusts the variations of the WPSH and westerly trough,and eventually reinforces high temperature anomalies over the YRV region.Furthermore,the condensational heating related to more IAS precipitation can adjust upper-tropospheric easterly anomalies over the YRV region by exciting a circumglobal teleconnection,inducing cold horizontal temperature advection and related anomalous descent,which is also conducive to the YRV high temperature anomalies.The reproduction of the above association in the model results indicates that the above results can be explained both statistically and dynamically.

PRECIPITATION BEHAVIOR OF M_(2)N IN A HIGH-NITROGEN AUSTENITIC STAINLESS STEEL DURING ISOTHERMAL AGING

The precipitation behavior of M2N and the microstructural evolution in a Cr-Mn austenitic stainless steel with a high nitrogen content of 0.43mass% during isothermal aging has been investigated using optical microscopy （ OM）, scanning electron microscopy （SEM）, and transmission electron microscopy （TEM）. The aging treatments have led to the decomposition of nitrogen supersaturated austenitic matrix through discontinuous cellular precipitation. The precipitated cells comprise alternate lamellae of M2N precipitate and austenitic matrix. This kind of precipitate morphology is similar to that of pearlite. However, owing to the non-eutectoidic mechanism of the reaction, the growth characteristic of the cellular precipitates is different from that of pearlite in Fe-C binary alloys. M2N precipitate in the cell possesses a hexagonal crystal structure with the parameters a = 0.4752nm and c = 0.4429nm, and the orientation relationship between the M2V precipitates and austenite determined from the SADP is [01^-10]M2N//[101]γ, [2^-1^-10]M2N//[010]γ.

Complex Precipitation Mechanism of Ti-Nb-V Microalloyed Bainitic Base High Strength Steel

The addition of high Ti（>0.1%） in microalloyed bainitic high strength steel was designed, and the precipitation morphology of steels with different Ti, Nb, and V contents was studied by utilizing transmission electron microscopy（TEM）. Based on the classical nucleation-crystal growth theory and the Johnson-Mehl-Avrami equation, the precipitation thermodynamic and kinetic model of second phase particles in austenite was established in the form of（Nbx,Vy,Tiz）C, and the complex precipitation mechanism of second phase particles was emphatically studied. The experimental results show that the complex precipitation particles could be divided into two categories: the coarser particles with about 100 nm grain size and the independent complex precipitation particles in the form of（Nb,V,Ti）C with 35-50 nm grain size. The latter has a better precipitation strengthening effect, and the calculated PTT curve shows a typical "C" shape. When the deformed storage energy is 3 820 J?mol-1, the fastest precipitation temperature of calculated PTT curve is 925 °C, and the calculated result is essentially consistent with experimental values. The increase of Ti content increased the nose point temperature and expanded the range of fastest precipitation temperature.

Precipitation under Subtropical High Conditions:Evidence and Implications

The impact of the subtropical high (STH) on precipitation was investigated on a daily timescale using matched NCEP and the Global Precipitation Climatology Project (GPCP) datasets.Comparison of the conditional probability (intensity) of precipitation under STH condi-tions with that under non-STH conditions suggests that the presence of the STH conditions has a limited impact on local precipitation.In the West Pacific Subtropical High (WPSH) and the North Atlantic Subtropical High (NASH),precipitation was only 30% lower under STH conditions than under non-STH conditions.The STH conditions had somewhat more impact on precipitation intensity,but it was still 50% less than the intensity under non-STH conditions (mean of roughly 5 mm d 1).Pre-cipitation under STH conditions was found to be highly correlated with vertical motion.Active updrafts occurring even under STH conditions are essential for frequent oc-currences and moderate intensities of precipitation.

Precipitation behavior of Ti in high strength steels

Precipitation behavior of Ti in high strength steels was investigated by means of the equilibrium solid solubility theory. The contributions of Ti content to yield strength were calculated. The calculated results were verified by the hot rolling experiment for C–Mn steel and C–Mn–Ti micro alloyed steel, respectively. The research results show that the precipitates are mainly Ti N at the higher temperature. With the decreasing temperature, the proportion of Ti C in precipitates increases gradually. When the temperature drops to 800 °C, Ti C will become predominant for the precipitation of Ti. When Ti content is less than 0.014%(mass fraction), Ti has little influence on the yield strength. When Ti content is in the range of 0.014%–0.03%(mass fraction), the yield strength of Ti micro alloyed steel is greatly increased, which leads to instability of the mechanical properties of the steel. Therefore, the design of Ti content in high strength steels should avoid this Ti content range. When Ti content is higher than 0.03%, the yield strength increases stably. In this experiment, when added Ti content was controlled in the range of 0.03%–0.05%, the contribution to the yield strength of Ti micro alloyed steel can reach about 92.44 MPa.

THE TIMING OF SOUTH-ASIAN HIGH ESTABLISHMENT AND ITS RELATION TO TROPICAL ASIAN SUMMER MONSOON AND PRECIPITATION OVER EAST-CENTRAL CHINA IN SUMMER

The timing of the South Asian High(SAH) establishment over the Indochina Peninsula(IP) from April to May and its relations to the setup of the subsequent tropical Asian summer monsoon and precipitation over eastern-central China in summer are investigated by using NCEP/NCAR daily reanalysis data,outgoing longwave radiation(OLR)data and the daily precipitation data from 753 weather stations in China.It is found that the transitions of the zonal wind vertical shear and convection establishment over tropical Asia are earlier(later) in the years of early(late) establishment of SAH.In the lower troposphere,anti-cyclonic(cyclonic) anomaly circulation dominates the equatorial Indian Ocean.Correspondingly,the tropical Asian summer monsoon establishes earlier(later).Furthermore,the atmospheric circulation and the water vapor transport in the years of advanced SAH establishment are significantly different from the delayed years in Asia in summer.Out-of-phase distribution of precipitation in eastern-central China will appear with a weak(strong) SAH and western Pacific subtropical high,strong(weak) ascending motion in the area south of Yangtze River but weak(strong) ascending motion in the area north of it,and cyclonic(anti-cyclonic) water vapor flux anomaly circulation from the eastern-central China to western Pacific.Accordingly,the timing of the SAH establishment at the upper levels of IP is indicative of the subsequent onset of the tropical Asian summer monsoon and the flood-drought pattern over eastern-central China in summer.

Effects of pre-precipitation of Cr_2N on microstructures and properties of high nitrogen stainless steel

Aging precipitation and solid solution heat treatment were carried out on three steels which have chromium content of 18%, manganese content of 12%, 15%, 18%, and nitrogen content of 0.43%, 0.53%, 0.67%, respectively. The mechanisms of precipitation and solid solution of high nitrogen anstenitic stainless steel were studied using the scanning electron microscopy, transmission electron microscopy, electron probe micro analysis and mechanical testing. The results show that, Cr2N is the primary precipitate in the tested stainless steels instead of Cr23C6. Cr2N nucleates at austenitic grain boundaries and grows towards inner grains with a lameUar morphology. By means of pre-precipitation of Cr2N at 800 ~C, the microstructure of the steels at solid solution state can be refined, thus improving the strength and plasticity. After the proposed treatment, the tensile strength, the proof strength and the elongation of the tested steel reach 881 MPa, 542 MPa and 54%, respectively.

Effect of the precipitation state on high temperature tensile and creep behaviors of Mg-15Gd alloy

Due to the effective precipitation strengthening effect of the β phase, Mg-Gd alloys exhibit excellent room temperature mechanical behaviors. However, when served at high temperatures, the metastable β phase will transform to other phases, resulting in severe performance degradation. In this study, we investigated the effect of precipitation state achieved by different heat treatments on high temperature tensile and creep behaviors of the Mg-15Gd alloy by comparing the properties of the as-cast, solid-solutioned(T4) and peak-aged(T6) alloys. The results showed that the tensile mechanical properties of the T6 alloy were always highest from room temperature to 300 ℃, in spite of an abnormal strength increase with temperature existed in the T4 alloy. For tensile creep properties, the T6 alloy exhibited the lowest steady creep rate below 235 ℃ while the T4 alloy possessed the best properties above 260 ℃. Microstructure characterization revealed that the transition was caused by the stress-promoted precipitation of β phase in the T4 alloy and rapid phase transformation in the T6 alloy at high temperatures. At 260 ℃, the calculated stress exponent n was 3.1 and 2.8 for the T4 and T6 alloys, respectively, suggesting the creep deformation mechanism was dislocation slip, which was further confirmed by the microstructure after creeping. Our findings can provide new insights into the heat treatment process of Mg-Gd alloys served at high temperatures.

Projection of Future Precipitation Change over China with a High-Resolution Global Atmospheric Model

Projections of future precipitation change over China are studied based on the output of a global AGCM, ECHAM5, with a high resolution of T319 （equivalent to 40 km）. Evaluation of the model’s performance in simulating present-day precipitation shows encouraging results. The spatial distributions of both mean and extreme precipitation, especially the locations of main precipitation centers, are reproduced reasonably. The simulated annual cycle of precipitation is close to the observed. The performance of the model over eastern China is generally better than that over western China. A weakness of the model is the overestimation of precipitation over northern and western China. Analyses on the potential change in precipitation projected under the A1B scenario show that both annual mean precipitation intensity and extreme precipitation would increase significantly over southeastern China. The percentage increase in extreme precipitation is larger than that of mean precipitation. Meanwhile, decreases in mean and extreme precipitation are evident over the southern Tibetan Plateau. For precipitation days, extreme precipitation days are projected to increase over all of China. Both consecutive dry days over northern China and consecutive wet days over southern China would decrease.

A Study on Precipitation Products with High Resolution in Anhui Province Based on Thin Plate Smoothing Spline

In order to achieve refined precipitation grid data with high accuracy and high spatial resolution,hourly precipitation grid dataset with 1 km spatial resolution in Anhui Province from May to September (in the rainy season) in 2016 and from August 2017 to July 2018 was established based on thin plate smoothing spline (TPS),which meets the needs of climate change research and meteorological disaster risk assessment.The interpolation errors were then analyzed.The grid precipitation product obtained based on thin plate smoothing spline,CLDAS-FAST and CLDAS-FRT were evaluated.The results show that the interpolated values of hourly precipitation by thin plate smoothing spline are close to the observed values in the rainy season of 2016.The errors are generally below 0.9 mm/h.However,the errors of precipitation in the mountainous areas of eastern Huaibei and western Anhui are above 1.2 mm/h.On monthly scale,the errors in June and July are the largest,and the proportion of absolute values of the errors ≥2 mm/h is up to 2.0% in June and 2.2% in July.The errors in September are the smallest,and the proportion of absolute values of the errors ≥2 mm/h is only 0.6%.The root mean square (RMSE) is only 0.37 mm/h,and the correlation coefficient (COR) is 0.93.The interpolation accuracy of CLDAS-FRT is the highest,with the smallest RMSE (0.65 mm/h) and mean error ( ME =0.01 mm/h),and the largest COR (0.81).The accuracy of the precipitation product obtained by thin plate smoothing spline interpolation is close to that of CLDAS-FAST.Its RMSE is up to 0.80 mm/h,and its ME is only -0.01 mm/h.Its COR is 0.73,but its bias (BIAS) is up to 1.06 mm/h.

Influence of chemical composition and cold deformation on aging precipitation behavior of high nitrogen austenitic stainless steels

The influence of chemical composition and cold deformation on aging precipitation behavior of 18Cr-16Mn-2Mo-I.IN （HNS-A）, 18Cr-16Mn-I.3N （HNS-B）, 18Cr-18Mn-2Mo-0.96N （HNS-C） and 18Cr-18Mn-2Mo-0.77N （I-INS-D） high nitrogen austenitic stainless steels was investigated. The results show that the ＂nose＂ temperatures and incubation periods of the initial time-temperature-precipitation （TTP） curves of aged HNSs are found to be 850 ℃, 60 s; 850 ℃, 45 s; 850 ℃, 60 s and 900 ℃, 90 s, respectively. Based on the analysis of SAD patterns, the coarse cellular Cr2N precipitate which presents a lamellar structure has a hexagonal structure of a=0.478 nm and c=0.444 nm. The Z phase corresponding to a composition of Fe36Cr^2Mo10, is determined to be a body-centered cubic structure ofa=0.892 nm. The precipitating sensitivity presents no more difference with the nitrogen content increasing from 0.77% to 0.96%, but exhibits so obviously that the cellular precipitates nearly overspread the whole field. The addition of Mo element can restrain the TTP curves moving left and down, which means decreasing the sensitivity of aging precipitation. With increasing the cold deformation, the sensitivity of precipitation increases obviously.

In-situ Observation of Dark Phase Precipitation during Heating and Soaking Process of a High Nickel Steel

In-situ observation of microstructural evolution during heating and soaking process was carded out for a high nickel steel using HTCLSM. Dark phases were observed when soaking at 900℃. Results showed that the number of the dark phases culminated in about 50 s during soaking at 900℃. With the increase of soaking time the area proportion of the dark phases increased and reached the maximum value in about 3 min, When temperature rose from 900 ℃, the dark phases remained steady initially, but started to dissolve into the matrix at about 1 060 ℃ and completely disappeared at 1 132℃. When the specimen soaked at 900 ℃ was cooled down to room temperature （RT）, the dark phases kept stable. Energy spectrum analysis results showed that the dark phases contained much more Cr and Mn elements than the matrix and,were also rich in V. Tensile test results showed that the dark phase strengthened the steel with the maximum tensile strength obtained after soaking at 900 ℃ for 3 minutes.

Aging precipitation and recrystallization in high-nitrogen austenitic stainless steel

The interaction between precipitation and recrystallization in cold deformed Fe-18Cr-12Mn-0.48N high-nitrogen austenitic stainless steel was investigated by means of hardness test, optical microscopy (OM) and transmission electron microscopy (TEM). The results show that the recrystallization of the steel begins at about 750℃ . When aging at 750℃ , the precipitation occurs prior to recrystallization. Large numbers of the second phases nucleate in dislocation, grain boundary and subgrain boundary. Precipitation of the second-phase particles hinders the formation of recrystallization nucleus.

High-Throughput Screening of Nanoparticle-Stabilizing Ligands:Application to Preparing Antimicrobial Curcumin Nanoparticles by Antisolvent Precipitation

Water-dispersible curcumin nanoparticles were prepared by bottom-up antisolvent precipitation approach. A new high-throughput screening technique was developed for selecting appropriate ligands stabilizing the nanoparticles in aqueous medium and improving their performance. The initial set of twenty-eight potential stabilizing ligands was evaluated based on their capacity to improve curcumin dispersibility in aqueous medium. The performance of four promising ligands(amino acid proline, polyphenol tannic acid, polycation Polyquaternium 10, and neutral polymer polyvinylpyrrolidone) was tested in ultrasound-aided antisolvent precipitation trials. Using the selected stabilizing ligands diminished the average particle size from ca. 1,200 to 170–230 nm, reduced their dispersity, improved stability, and allowed reaching curcumin concentration of up to 1.4 m M in aqueous medium. Storage stability of the aqueous nanodispersions varied from 2 days to 2 weeks, depending on stabilizing ligand. Studying the effects of ionic strength and pH on size and f-potential of the particles suggested that electrostatic forces and hydrophobic interactions could be the major factors affecting their stability. The ligand-protected nanoparticles showed minimal inhibitory concentration of 400 or500 μM toward Escherichia coli. We suggest that the presented screening approach may be useful for preparing nanoparticles of various poorly water-soluble bioactive materials.