Introduction: Total hip arthroplasty of complex morphology is a challenge for the orthopaedic surgeon. Careful analysis of the hip’s anatomy helps to unravel the difficulties and anticipate the procedures to be perfo...Introduction: Total hip arthroplasty of complex morphology is a challenge for the orthopaedic surgeon. Careful analysis of the hip’s anatomy helps to unravel the difficulties and anticipate the procedures to be performed and the implants to be planned. The aim was to identify the types of hip that make first-line THR difficult, specify the technical procedures to be used on these sites, and assess the functional results of the series. Material and Methods: This was a retrospective study that concerned patients operated on for total hip arthroplasty between January 2015 and December 2022 at the medical center “La Grâce” in Bobo-Dioulasso, Burkina Faso. Patients with coxarthrosis (on hip dysplasia, acetabular protrusio, acetabular malunion or neurological hip) and those with ankylosis of the hip, osteonecrosis secondary to neglected dislocation of the hip or hemoglobinopathy were included. Results: A total of 31 total hip replacements were performed in 30 patients. The mean age of patients at the surgery time was 36.2 years with extremes of 17 and 61 years. The male-to-female sex ratio was 1. The main indications for THA were the dysplasic hip osteoarthritis (11 cases) and the neglected hip dislocations (7 cases). In situ femoral neck osteotomy before hip dislocation was performed in seven cases. The acetabulum reconstruction techniques varied from the structural iliac bone graft (n = 3) and cancellous bone graft (n = 4) to the Kerboull plate (n = 1). After 45 months of mean follow-up, all hips were evaluated. The mean PMA score increased from 7.1 [4 - 8] before the surgery to 13.2 [13 - 17]. Conclusion: The large spectrum of challenges in complex hip management requires effective preoperative planning. Preoperative planning minimizes complications and ensures a better outcome.展开更多
以某采用吸附法模拟移动床技术新建的单系列1.5 Mt a对二甲苯芳烃联合装置(其公用工程依托企业原有设施)为举例装置,针对全厂事故停电时,原有火炬系统的接收能力仅有500 t h,不能满足需求的问题,分别对装置中二甲苯塔、抽出液塔、重整...以某采用吸附法模拟移动床技术新建的单系列1.5 Mt a对二甲苯芳烃联合装置(其公用工程依托企业原有设施)为举例装置,针对全厂事故停电时,原有火炬系统的接收能力仅有500 t h,不能满足需求的问题,分别对装置中二甲苯塔、抽出液塔、重整油分馏塔实施高完整性保护系统(HIPS)措施,并对抽余液塔采用夹点设计优化,从而大幅度降低装置的火炬排放量。结果表明,应用HIPS和夹点技术后,装置火炬排放量从常规时的3790 t h降低到438 t h,满足了项目全厂事故停电时的火炬排放要求。展开更多
以过氧化二异丙苯 (DCP)为引发剂 ,甲基丙烯酸缩水甘油酯 (GMA)为活性单体 ,高抗冲苯乙烯(HIPS)通过熔融接枝制得了功能化的高抗冲聚苯乙烯接枝物 (HIPS g GMA)。用红外光谱和电子能谱对其结构进行了表征。HIPS g GMA的红外谱图 ,证明GM...以过氧化二异丙苯 (DCP)为引发剂 ,甲基丙烯酸缩水甘油酯 (GMA)为活性单体 ,高抗冲苯乙烯(HIPS)通过熔融接枝制得了功能化的高抗冲聚苯乙烯接枝物 (HIPS g GMA)。用红外光谱和电子能谱对其结构进行了表征。HIPS g GMA的红外谱图 ,证明GMA已经接枝到HIPS上。电子能谱分析也提供了相似的结论。研究了单体浓度和DCP用量对产物接枝率的影响 ,并用化学滴定方法测定了接枝物的接枝率。用DSC、SEM、WAXD、DMA等研究了PBT/HIPS和PBT/HIPS g GMA的结晶、形态结构、动态力学性能及力学性能随组成的变化。SEM及DMA分析表明增容后体系的相容性得到改善 ,力学性能有较大提高。展开更多
The compatibitily and morphology of HIPS/PC and HIPS g GMA/PC blends were studied.The compatibility and morphology of HIPS/PC blends were characterized by DSC and SEM,respectively.The result of DSC shows that T g of P...The compatibitily and morphology of HIPS/PC and HIPS g GMA/PC blends were studied.The compatibility and morphology of HIPS/PC blends were characterized by DSC and SEM,respectively.The result of DSC shows that T g of PS doesn’t change with the blend composition,and T g of PC decreases with the increase in weight fraction of HIPS,which indicates that the PC/HIPS blend is a partially miscible system.Results of SEM indicate that the decrease in T g of PC results from PS interpenetrating into the phase of PC,and no change in T g of PS results from PC not interpenetrating into the phase of PS.The copolymer of HIPS g GMA was prepared by reactive grafting method.The IR spectrum shows that GMA is grafted on the chain of HIPS.The compatibility and morphology of HIPS g GMA(35)/PC(65) were studied by DSC and SEM.PC(65)/HIPS g GMA(35) blend exhibits reduced size of disperse phase,enhanced interface adhesion and lower T g of PC phase as compared with the PC(65)/HIPS(35) blend.It implies that HIPS g GMA is an effective compatibilizer of the HIPS/PC blend.展开更多
采用热重法进行了含阻燃添加剂的高抗冲聚苯乙烯塑料（flamere tarded high impact polystyrene，Br-Sb-HIPS）在不同升温速率下的热解实验，建立了包含3个连续反应的阻燃HIPS热解动力学模型。通过Flyrm-Wall-Ozawa法得到阻燃HIPS热解...采用热重法进行了含阻燃添加剂的高抗冲聚苯乙烯塑料（flamere tarded high impact polystyrene，Br-Sb-HIPS）在不同升温速率下的热解实验，建立了包含3个连续反应的阻燃HIPS热解动力学模型。通过Flyrm-Wall-Ozawa法得到阻燃HIPS热解过程的活化能为103~307kJ·mol-1，利用多元非线性无约束最优化方法求得模型参数。研究表明，Br-Sb-HIPS3个反应的活化能和指前因子分别为191．632、213．263、238．331kJ·mol-1和II．641、12．772、11．666min-1。动力学模型能够很好地预测阻燃HIPS热解过程。展开更多
文摘Introduction: Total hip arthroplasty of complex morphology is a challenge for the orthopaedic surgeon. Careful analysis of the hip’s anatomy helps to unravel the difficulties and anticipate the procedures to be performed and the implants to be planned. The aim was to identify the types of hip that make first-line THR difficult, specify the technical procedures to be used on these sites, and assess the functional results of the series. Material and Methods: This was a retrospective study that concerned patients operated on for total hip arthroplasty between January 2015 and December 2022 at the medical center “La Grâce” in Bobo-Dioulasso, Burkina Faso. Patients with coxarthrosis (on hip dysplasia, acetabular protrusio, acetabular malunion or neurological hip) and those with ankylosis of the hip, osteonecrosis secondary to neglected dislocation of the hip or hemoglobinopathy were included. Results: A total of 31 total hip replacements were performed in 30 patients. The mean age of patients at the surgery time was 36.2 years with extremes of 17 and 61 years. The male-to-female sex ratio was 1. The main indications for THA were the dysplasic hip osteoarthritis (11 cases) and the neglected hip dislocations (7 cases). In situ femoral neck osteotomy before hip dislocation was performed in seven cases. The acetabulum reconstruction techniques varied from the structural iliac bone graft (n = 3) and cancellous bone graft (n = 4) to the Kerboull plate (n = 1). After 45 months of mean follow-up, all hips were evaluated. The mean PMA score increased from 7.1 [4 - 8] before the surgery to 13.2 [13 - 17]. Conclusion: The large spectrum of challenges in complex hip management requires effective preoperative planning. Preoperative planning minimizes complications and ensures a better outcome.
文摘以某采用吸附法模拟移动床技术新建的单系列1.5 Mt a对二甲苯芳烃联合装置(其公用工程依托企业原有设施)为举例装置,针对全厂事故停电时,原有火炬系统的接收能力仅有500 t h,不能满足需求的问题,分别对装置中二甲苯塔、抽出液塔、重整油分馏塔实施高完整性保护系统(HIPS)措施,并对抽余液塔采用夹点设计优化,从而大幅度降低装置的火炬排放量。结果表明,应用HIPS和夹点技术后,装置火炬排放量从常规时的3790 t h降低到438 t h,满足了项目全厂事故停电时的火炬排放要求。
文摘以过氧化二异丙苯 (DCP)为引发剂 ,甲基丙烯酸缩水甘油酯 (GMA)为活性单体 ,高抗冲苯乙烯(HIPS)通过熔融接枝制得了功能化的高抗冲聚苯乙烯接枝物 (HIPS g GMA)。用红外光谱和电子能谱对其结构进行了表征。HIPS g GMA的红外谱图 ,证明GMA已经接枝到HIPS上。电子能谱分析也提供了相似的结论。研究了单体浓度和DCP用量对产物接枝率的影响 ,并用化学滴定方法测定了接枝物的接枝率。用DSC、SEM、WAXD、DMA等研究了PBT/HIPS和PBT/HIPS g GMA的结晶、形态结构、动态力学性能及力学性能随组成的变化。SEM及DMA分析表明增容后体系的相容性得到改善 ,力学性能有较大提高。
文摘The compatibitily and morphology of HIPS/PC and HIPS g GMA/PC blends were studied.The compatibility and morphology of HIPS/PC blends were characterized by DSC and SEM,respectively.The result of DSC shows that T g of PS doesn’t change with the blend composition,and T g of PC decreases with the increase in weight fraction of HIPS,which indicates that the PC/HIPS blend is a partially miscible system.Results of SEM indicate that the decrease in T g of PC results from PS interpenetrating into the phase of PC,and no change in T g of PS results from PC not interpenetrating into the phase of PS.The copolymer of HIPS g GMA was prepared by reactive grafting method.The IR spectrum shows that GMA is grafted on the chain of HIPS.The compatibility and morphology of HIPS g GMA(35)/PC(65) were studied by DSC and SEM.PC(65)/HIPS g GMA(35) blend exhibits reduced size of disperse phase,enhanced interface adhesion and lower T g of PC phase as compared with the PC(65)/HIPS(35) blend.It implies that HIPS g GMA is an effective compatibilizer of the HIPS/PC blend.
文摘采用热重法进行了含阻燃添加剂的高抗冲聚苯乙烯塑料（flamere tarded high impact polystyrene，Br-Sb-HIPS）在不同升温速率下的热解实验，建立了包含3个连续反应的阻燃HIPS热解动力学模型。通过Flyrm-Wall-Ozawa法得到阻燃HIPS热解过程的活化能为103~307kJ·mol-1，利用多元非线性无约束最优化方法求得模型参数。研究表明，Br-Sb-HIPS3个反应的活化能和指前因子分别为191．632、213．263、238．331kJ·mol-1和II．641、12．772、11．666min-1。动力学模型能够很好地预测阻燃HIPS热解过程。
