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Study on a new nano-dispersing agent and its effect for increasing suspension ability of alcohol-based coatings 被引量:1
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作者 S.P.Li X.C.Du +2 位作者 H.Z.Song L.Li J.Y.Zhou 《China Foundry》 SCIE CAS 2004年第S1期54-57,共4页
A study for further improving the suspension rate of alcohol-based coatings using a new nano-dispersing agent has been presented in this paper. The results of experiments show that the new nano-dispersing agent should... A study for further improving the suspension rate of alcohol-based coatings using a new nano-dispersing agent has been presented in this paper. The results of experiments show that the new nano-dispersing agent should be used in combination with organic auxiliary agent which significantly increases the suspension effect of alcohol-based coatings. By the methods, the suspension rates of 99%, 98%, 96% and 94% can be achieved at 2h, 2h, 48h and 72h, respectively. These alcohol-based coatings have characters of higher strength, lower gas evolution, better brush ability and no blister after ignition. 展开更多
关键词 alcohol-based coating nano-dispersing agent SUSPENSION ABILITY organic auxiliary agent
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A distributed algorithm for signal coordination of multiple agents with embedded platoon dispersion model
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作者 别一鸣 王殿海 +1 位作者 马东方 朱自博 《Journal of Southeast University(English Edition)》 EI CAS 2011年第3期311-315,共5页
In order to reduce average arterial vehicle delay, a novel distributed and coordinated traffic control algorithm is developed using the multiple agent system and the reinforce learning (RL). The RL is used to minimi... In order to reduce average arterial vehicle delay, a novel distributed and coordinated traffic control algorithm is developed using the multiple agent system and the reinforce learning (RL). The RL is used to minimize average delay of arterial vehicles by training the interaction ability between agents and exterior environments. The Robertson platoon dispersion model is embedded in the RL algorithm to precisely predict platoon movements on arteries and then the reward function is developed based on the dispersion model and delay equations cited by HCM2000. The performance of the algorithm is evaluated in a Matlab environment and comparisons between the algorithm and the conventional coordination algorithm are conducted in three different traffic load scenarios. Results show that the proposed algorithm outperforms the conventional algorithm in all the scenarios. Moreover, with the increase in saturation degree, the performance is improved more significantly. The results verify the feasibility and efficiency of the established algorithm. 展开更多
关键词 multiple agents signal coordination reinforce learning platoon dispersion model
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Dispersion of graphene in silane coupling agent aqueous solutions 被引量:4
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作者 Guo Liping Wang Hong +1 位作者 Chen Bo Qian Wenxun 《Journal of Southeast University(English Edition)》 EI CAS 2020年第1期67-72,共6页
In order to reduce the agglomeration of nanographene and improve its dispersibility,six silane coupling agents were used to modify the surface of the nanographene particles.Visual inspection,Fourier-transform infrared... In order to reduce the agglomeration of nanographene and improve its dispersibility,six silane coupling agents were used to modify the surface of the nanographene particles.Visual inspection,Fourier-transform infrared spectroscopy,transmission electron microscopy,Raman spectroscopy,and X-ray diffraction were employed to evaluate the dispersion properties of the resulting graphene in an aqueous solution of silane coupling agents.Results show that all six types of silane coupling agents are efficient in promoting the dispersion of graphene in aqueous solutions,and no obvious sedimentation of the graphene dispersion solution is observed after a stationary storage period of 30 d.Taking 3-aminopropyltriethoxysilane(KH-550)as an example,after the graphene is dispersed in the KH-550 aqueous solution,the carboxyl group on the surface of the graphene reacts with the KH-550 amino group to form an amide bond,and KH-550 is successfully grafted onto the graphene surface.Polar functional groups ionize in water,creating an electrostatic repulsion effect,or hydrophilic functional groups form hydrogen bonds with water molecules,which is believed to improve the dispersion stability of graphene.The dispersed graphene is curled and contains many folds.Each fold has about three or four layers,with an interlayer spacing of about 0.65 nm.The dispersed graphene also has a complete lattice and a reduced number of defects.Nanographene disperses well in silane coupling agent aqueous solutions and can,therefore,be used to prepare cement-based composites. 展开更多
关键词 GRAPHENE silane coupling agent surface modification dispersIBILITY
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Beneficial effects of high-pressure homogenization on the dispersion stability of aqueous hydrolysate from Mytilus edulis 被引量:3
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作者 Fengjiao Mao Maolin Tu +3 位作者 Fengjiao Fan Chao Wu Cuiping Yu Ming Du 《Food Science and Human Wellness》 SCIE 2020年第4期394-401,共8页
Owing to the formation of aggregation and gelation during storage,certain proteins and peptides exhibit limited applications in aqueous protein food products.The purpose of this study was to investigate the influence ... Owing to the formation of aggregation and gelation during storage,certain proteins and peptides exhibit limited applications in aqueous protein food products.The purpose of this study was to investigate the influence of homogenization and xanthan gum addition on the dispersion stability of Mytilus edulis hydrolysate(PHM).High-pressure homogenization(HPH)at 360 and 40 bar in the first and second values,respectively,and adding xanthan gum at a concentration of 1 mg/mL showed significantly improvement on the stability of the PHM solution.PHM-xanthan gum solutions(PHMX)showed the highest polypeptide precipitation rate and turbidity retention rate compared with those of PHM.Moreover,the centrifugal precipitation rate of PHMX without HPH was higher than that of homogeneous PHMX.After HPH treatment at 400 bar,the percentage of smaller particles in PHM and PHMX was increased,the aqueous system became more uniform,and the fluorescence intensity reached its maximum.HPH pretreatment improved the polypeptide dispersion stability and turbidity retention rate of PHM and PHMX and reduced the fluorescence intensity.The interactions of xanthan gum and polypeptide render the network microstructure more uniform under the conditions of homogenization,thus improving the dispersion stability of PHMX solutions.Therefore,under the premise of adding xanthan gum,HPH can better enhance the dispersion stability of the polypeptide in PHM. 展开更多
关键词 Mytilus edulis POLYPEPTIDE Xanthan gum homogenized mixed system dispersion stability
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Preparation of aqueous dispersion of epoxy curing agent with specially synthesized phase inversion emulsifier 被引量:4
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作者 周继亮 涂伟萍 胡剑青 《化工学报》 EI CAS CSCD 北大核心 2005年第10期2029-2032,共4页
关键词 相反转乳化剂 水基环氧固化剂分散体 制备方法 理化性能
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EFFECTS OF AMIODARONE AND SOME CLASS ⅠAGENTS ON QT DISPERSION
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作者 周礼明 赵佩琪 +1 位作者 朱文敏 徐济民 《Medical Bulletin of Shanghai Jiaotong University》 CAS 1999年第2期87-89,94,共4页
Objective To investigate the elfects of some class Ⅰ antiarrhythmic agents on QT dispersion and compared with those of amiodarone. Methods Group I was composed of 30 cases, they were all treated with class Ⅰ agents.... Objective To investigate the elfects of some class Ⅰ antiarrhythmic agents on QT dispersion and compared with those of amiodarone. Methods Group I was composed of 30 cases, they were all treated with class Ⅰ agents. The drugs used include: mexiletine (8 cases), moricizine (9), propafenone (12) and apridine (1). GrouP Ⅱ was composed of other 30 patients, and were all treated with amiodarone. The ddlerences of QT intervals between ECG leads (QTd and QTcd) were measured belore and aler medication. Results Before medication, the QTmax and QTcmax in group Ⅱ were signilicantly longer than those of group Ⅰ, resulting in greater QTd and QTcd in grouP Ⅱ (QTd:66± 14ms vs 31± 16ms, P<0.01; QTcd:71±36ms vs 44± 18ms, P<0.01). Alter medication, QTmax and QTcmax of group Ⅰ were prolonged, leading to the lengthening of QTd (from 31±16ms to 45±17ms, P<0.01) and QTcd (from 44± 18 ms to 58± 21ms, P<0.05), indicating the increase of inhomogeneity of myocardial repolarization after the treatment of class Ⅰ agents. Alter amiodarone treatment, QTmin and QTmax in grouP Ⅱ were both prolonged, with a greater amplitude of QTmin prolongation, resulting in decreased QTd and QTcd in group Ⅱ (QTd /rom 66± 14ms to 36±22ms, P<0.01, QTcd from 71±36ms to 45±27ms, P<0.01). The signifcant dofference of QTd and QTcd between two groups disappeared aler medication. Conclusion The results of the present study may relect the opposite effects of amiodarone and these class Ⅰ agents on myocardial repolarization. 展开更多
关键词 QT INTERVAL QT dispersion ARRHYTHMIA ANTIARRHYTHMIC agentS AMIODARONE
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Effects of Dispersive Agent and Alumina Micropowder on Workability of Al_2O_3-MgO Castables for Steel Ladles
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作者 WANG Qingheng LI Yuanbing +4 位作者 WEI Hao XU Nana LI Shujing LUO Han XIANG Ruofei 《China's Refractories》 CAS 2018年第3期38-43,共6页
This work aims at enhancing the workability of Al2 O3-Mg O castables. Al2 O3-Mg O castables were prepared using tabular alumina particles( 5-3,3-1,≤1 mm),tabular alumina fines( ≤0. 088 mm),fused magnesia( ≤1 m... This work aims at enhancing the workability of Al2 O3-Mg O castables. Al2 O3-Mg O castables were prepared using tabular alumina particles( 5-3,3-1,≤1 mm),tabular alumina fines( ≤0. 088 mm),fused magnesia( ≤1 mm),reactive alumina micropowder( PFR40,PBR,and CL) and calcined alumina micropowder( AC34 B5 and CT) as the main starting materials,calcium aluminate cement( Secar71) as the binder,and polycarboxylic acid water reducer WS,FS,and AD as the dispersive agent,respectively. Effects of three dispersive agents addition( 0. 4 mass% WS,0. 2 mass% FS and 1 mass% AD),two kinds of reactive alumina micropowder addition( PFR40 and PBR),composite alumina micropowder addition( PFR40-AC34 B5 and CL-CT,the mass ratio from 9/0 to 3/6)on the flow value,apparent porosity,bulk density,cold crushing strength and cold modulus of rupture of Al2 O3-MgO castables were investigated. The results show that:( 1) with PBR or PFR40,the castables with0. 4 mass% WS own better performance than those with0. 2 mass% FS or 1 mass% AD;( 2) compared with the castables with CL-CT composite powder, the castables with PFR40-AC34 B5 composite powder have slightly higher flow value; with the decreasing ratio of PFR40 and AC34 B5,or the decreasing ratio of CL andCT,the castables have declined flow value and the dried castable specimens have decreased density but the mildly changed strength; in consideration of the high price of reactive alumina,a proper compositing ratio shall be selected. 展开更多
关键词 dispersive agent PFR40 PBR AC34B5 flow value
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THE SIZE EFFECT ON THE DISPERSION OF A PARTICLE IN A HOMOGENEOUS ISOTROPIC TURBULENCE
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作者 谢定国 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI 1990年第6期587-594,共8页
The mechanism of the response motion of a suspended particle to turbulent motion of its surrounding fluid is different according to si:e of turbulent eddies. The particle is dragged by the viscous force of large eddie... The mechanism of the response motion of a suspended particle to turbulent motion of its surrounding fluid is different according to si:e of turbulent eddies. The particle is dragged by the viscous force of large eddies, and meanwhile driven randomly by small eddies. Based on this understanding, the dispersion of a particle with finite size in a homogeneous isotropic turbulence is calculated in this study. Results show that there are two competing effects: when enhanced by the inertia of a particle, the long-term particle diffusivity is reduced by the finite size of the particle. 展开更多
关键词 THE SIZE EFFECT ON THE dispersION OF A PARTICLE IN A homogenEOUS ISOTROPIC TURBULENCE THAN
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酸酐固化剂复配对环氧树脂复合材料性能分散度的影响
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作者 赵玉顺 白金辉 +3 位作者 罗子民 闫程 王琨 杨威 《高压电器》 CAS CSCD 北大核心 2024年第8期221-229,共9页
酸酐固化剂因具有耐热性好、固化收缩小、绝缘性能好等优点,被广泛应用于电力装备用环氧树脂复合材料浇注体系。电力系统正在向高电压、大容量方向发展,对电力装备性能提出了更高要求。为获得高性能环氧复合绝缘材料,文中研究了5种常用... 酸酐固化剂因具有耐热性好、固化收缩小、绝缘性能好等优点,被广泛应用于电力装备用环氧树脂复合材料浇注体系。电力系统正在向高电压、大容量方向发展,对电力装备性能提出了更高要求。为获得高性能环氧复合绝缘材料,文中研究了5种常用酸酐固化剂对环氧复合材料性能的影响,发现苯酐存在固化物性能优异,但有固化工艺性差、固化物性能分散度大的问题。进一步,制备了苯酐/六氢苯酐复配固化剂,并研究了复配固化剂对环氧复合材料机械性能和电气性能的影响。实验结果表明,当苯酐/六氢苯酐复配摩尔比例为1∶3时,复配固化剂的熔点最低、固化工艺性较好,固化产物的拉伸、弯曲和击穿强度最大值虽略有降低,但平均值提升显著,分散度显著减小,且耐电弧性能提高了49%。 展开更多
关键词 酸酐固化剂 电力装备 复配固化剂 分散度
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涂料助剂对PDMS改性环氧树脂/Al复合涂层性能的影响
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作者 张伟钢 李娇 吕丹丹 《材料导报》 EI CAS CSCD 北大核心 2024年第10期278-282,共5页
为进一步降低超疏水低红外发射率复合涂层的发射率并提高涂层的附着力,采用分散剂和硅烷偶联剂KH560来改善聚二甲基硅氧烷(PDMS)改性环氧树脂/Al复合涂层的填料分散状态及界面结构。系统研究了分散剂添加量(质量分数)及KH560添加量(质... 为进一步降低超疏水低红外发射率复合涂层的发射率并提高涂层的附着力,采用分散剂和硅烷偶联剂KH560来改善聚二甲基硅氧烷(PDMS)改性环氧树脂/Al复合涂层的填料分散状态及界面结构。系统研究了分散剂添加量(质量分数)及KH560添加量(质量分数)对涂层微结构、光学性能、疏水性能及附着力的影响规律。结果表明:聚羧酸盐阴离子型分散剂可通过静电斥力和降低填料颗粒的表面能来改善涂层中片状Al粉和纳米SiO_(2)的分散状态,从而在一定程度上降低涂层的红外发射率,同时可使涂层具备较低的光泽度和良好的超疏水性能。KH560可利用其分子结构两端的甲氧基和环氧基在涂层中发挥桥连作用。通过KH560的桥连作用,涂层中的树脂基体和填料间可形成良好的化学键结合,从而使涂层表面结构更加致密,孔隙减少,进而可使涂层的发射率有所降低。同时,KH560改性可使涂层中的树脂基体与金属基板间形成化学键结合,从而可明显提高涂层的附着力。当涂层中分散剂和KH560的添加量分别为5%和3%时,涂层具有最佳的发射率(0.619)、光泽度(2.9)及附着力(1级)。同时,涂层具备良好的超疏水性能(水接触角为154°,滚动角为6°)。 展开更多
关键词 复合涂层 低红外发射率 超疏水 分散剂 硅烷偶联剂
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新型分散型抗垢剂在S Zorb装置的工业应用
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作者 郑从武 庞建龙 +3 位作者 杨华栋 付鑫 何欧鹏 程文武 《当代化工研究》 CAS 2024年第1期68-70,共3页
中国石化广州分公司S Zorb装置为有效抑制原料侧换热器E-7101A-G因高温结垢而导致的换热器传热效率下降、换热器总压差上涨过快等影响装置长周期运行问题,决定使用浙江杭化科技股份有限公司生产的新型分散型抗垢剂HK-17DC。工业应用结... 中国石化广州分公司S Zorb装置为有效抑制原料侧换热器E-7101A-G因高温结垢而导致的换热器传热效率下降、换热器总压差上涨过快等影响装置长周期运行问题,决定使用浙江杭化科技股份有限公司生产的新型分散型抗垢剂HK-17DC。工业应用结果表明,HK-17DC在线除垢及阻垢作用良好,且使用HK-17DC对装置运行和产品质量无不良影响。 展开更多
关键词 S Zorb装置 催化汽油 换热器结垢 分散型抗垢剂 在线除垢
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塔河稠油高黏特性及其侵入钻井液治理探索
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作者 刘湘华 范胜 +4 位作者 张淑霞 李双贵 于洋 沐宝泉 刘贺 《钻井液与完井液》 CAS 北大核心 2024年第2期198-204,共7页
为了解决塔河高黏稠油侵害钻井液的问题,研究对比了塔河稠油与典型劣质重油的关键性质及塔河稠油沥青质-甲苯溶液黏度随浓度的变化规律,发现塔河稠油的高黏特性主要原因是沥青质含量高与芳香度高,以此为基础,设计2种实验方案。一是针对... 为了解决塔河高黏稠油侵害钻井液的问题,研究对比了塔河稠油与典型劣质重油的关键性质及塔河稠油沥青质-甲苯溶液黏度随浓度的变化规律,发现塔河稠油的高黏特性主要原因是沥青质含量高与芳香度高,以此为基础,设计2种实验方案。一是针对钻井初期稠油侵入量少的情况,通过在钻井液中添加适宜的分散剂和芳香馏分的复配体系,将稠油进行分散,结果为5#钻井液体系效果最好,TH121155X井稠油在无固钻井液中的分散度超过99%。二是针对稠油侵入量大的情况,对稠油进行包裹,使稠油失去黏附性,降低稠油在钻具上黏附,确保地面振动筛能够顺利筛分。研究数据表明,BGJ-2-4复配的包裹剂对塔河TH12471H井稠油具有良好的包裹效果,罐黏附率仅为0.3%。 展开更多
关键词 稠油 钻井液 分散剂 包裹剂
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有机磷酸盐聚丙烯成核剂细微化制备及分散技术研究进展
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作者 郭照琰 赖金梅 +2 位作者 戚桂村 茹越 张晓红 《石油化工》 CAS CSCD 北大核心 2024年第4期594-600,共7页
有机磷酸盐类成核剂可改善聚丙烯(PP)的刚性和热性能,且具有热稳定性好、无毒、不易溶出等优势,应用范围广泛。但有机磷酸盐类成核剂与PP树脂的相容性有限,通常不易配混,需开发能够降低成核剂粒径、载体复配的细微化制备及分散技术,以... 有机磷酸盐类成核剂可改善聚丙烯(PP)的刚性和热性能,且具有热稳定性好、无毒、不易溶出等优势,应用范围广泛。但有机磷酸盐类成核剂与PP树脂的相容性有限,通常不易配混,需开发能够降低成核剂粒径、载体复配的细微化制备及分散技术,以提高有机磷酸盐类成核剂在聚丙烯中的分散效果。随着聚烯烃市场竞争愈加激烈,开发低成本的成核剂细微化制备工艺及复配技术,改善成核剂在聚丙烯中的分散性,将更有利于提升国产成核剂以及高性能聚烯烃的市场竞争力。 展开更多
关键词 有机磷酸盐成核剂 聚丙烯 细微化制备 载体分散
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水下不分散混凝土抗分散剂优化设计与凝结时间调控
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作者 刘祥胜 纪厚祥 +3 位作者 郑圣飚 詹炳根 余其俊 李占甫 《合肥工业大学学报(自然科学版)》 CAS 北大核心 2024年第10期1427-1433,共7页
水下不分散混凝土(non-dispersible underwater concrete,NDC)为涉水工程的施工提供抗冲刷能力,为实现水下不分散混凝土性能的提升,文章探讨抗分散剂的优化设计和凝结时间的调控,选取聚丙烯酰胺(polyacrylamide,PAM)和羟丙基甲基纤维素(... 水下不分散混凝土(non-dispersible underwater concrete,NDC)为涉水工程的施工提供抗冲刷能力,为实现水下不分散混凝土性能的提升,文章探讨抗分散剂的优化设计和凝结时间的调控,选取聚丙烯酰胺(polyacrylamide,PAM)和羟丙基甲基纤维素(hydroxypropyl methyl cellulose,HPMC)作为抗分散剂主剂,聚羧酸减水剂、有机硅和聚醚类消泡剂作为辅剂,从抗分散性和流动性的角度对水下不分散混凝土抗分散剂的组成进行优化设计,同时选取碳酸锂和硫酸铝作为调凝剂,对水下不分散混凝土的凝剂时间进行调控。研究结果表明:采用HPMC作为主剂、聚羧酸减水剂和聚醚类消泡剂作为辅剂制备抗分散剂,可以使得水下不分散混凝土具有较好的抗分散性和流动性;其中,含水泥质量分数0.45%的HPMC和1%聚羧酸减水剂的新拌水泥砂浆(水胶质量比为0.5,胶砂质量比为2)表现出优异的抗分散性和良好的流动性,其pH值为9,扩展度为150 mm;在该体系中,硫酸铝的调凝效果较好且经济效益更高,但使用时用量应少于2%。对抗分散剂的优化设计和凝结时间的调控为水下不分散混凝土的相关实验研究提供了重要参考。 展开更多
关键词 水下不分散混凝土(NDC) 抗分散剂 减水剂 凝结时间
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PHMG-KH560@TiO_(2)抗菌剂的制备及在涂料中的应用
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作者 宋佳 徐晶璐 +3 位作者 王继虎 温绍国 丁胜男 郭正钰 《电镀与涂饰》 CAS 北大核心 2024年第9期108-116,共9页
[目的]细菌的滋生和繁殖会使涂膜霉变,降低对基材的保护作用。为了提高涂膜的抗菌性能,通常在涂料中添加抗菌剂。[方法]以γ-缩水甘油醚氧丙基三甲氧基硅烷(KH560)为偶联剂,对纳米二氧化钛(TiO_(2))进行表面改性,接着与聚六亚甲基盐酸胍... [目的]细菌的滋生和繁殖会使涂膜霉变,降低对基材的保护作用。为了提高涂膜的抗菌性能,通常在涂料中添加抗菌剂。[方法]以γ-缩水甘油醚氧丙基三甲氧基硅烷(KH560)为偶联剂,对纳米二氧化钛(TiO_(2))进行表面改性,接着与聚六亚甲基盐酸胍(PHMG)接枝反应,制备了有机-无机复合抗菌剂PHMG-KH560@TiO_(2),并将其加入水性丙烯酸涂料中。[结果]傅里叶变换红外光谱(FT-IR)、X射线光电子能谱(XPS)和透射电镜(TEM)对改性前后纳米TiO_(2)结构和形貌的表征结果证实成功对TiO_(2)进行了改性。Zeta电位和贮存稳定性测试表明,改性后TiO_(2)的分散稳定性得到了提升。通过平板涂布计数法对TiO_(2)、PHMG-KH560@TiO_(2)及其水性丙烯酸树脂涂膜的抗菌性能进行测试时发现,改性后纳米TiO_(2)的抑菌率是改性前的2倍以上;与含有TiO_(2)的涂膜相比,添加PHMG-KH560@TiO_(2)的涂膜的抑菌率提高了20多倍。[结论]抗菌剂PHMG-KH560@TiO_(2)在水性涂料应用中表现良好。 展开更多
关键词 纳米二氧化钛 硅烷偶联剂 聚六亚甲基盐酸胍 抗菌剂 水性丙烯酸涂料 分散性
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多Agent模式在制造系统信息化中的应用 被引量:7
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作者 阎树田 何芹 《兰州理工大学学报》 CAS 北大核心 2004年第2期44-47,共4页
针对分散网络化制造的特点,将多Agent系统引入到分散网络化制造环境中.介绍了Agent和多Agent的概念,并研究在网络化制造环境中Agent和多Agent系统的结构特点及表现形式.讨论了多Agent系统的通讯交互机制和协作协商机制.最后,提出了分散... 针对分散网络化制造的特点,将多Agent系统引入到分散网络化制造环境中.介绍了Agent和多Agent的概念,并研究在网络化制造环境中Agent和多Agent系统的结构特点及表现形式.讨论了多Agent系统的通讯交互机制和协作协商机制.最后,提出了分散网络化制造环境中多Agent系统研究应该集中注意的几个关键性问题,并对分散化环境中多Agent系统的研究作了展望. 展开更多
关键词 agent模式 网络化制造 agent通信机制 agent结构
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分散网络化制造环境下基于移动Agent和Web的生产监控研究 被引量:2
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作者 王纯贤 王治森 +1 位作者 褚学宁 高锷 《制造业自动化》 2002年第2期36-40,共5页
针对分散网络化制造的特点,把移动Agent和Web技术应用到分散网络化制造环境下的生产监控中,提出了基于移动Agent和Web的生产监控系统框架,利用Concordia移动Agent系统开发了原型系统,证明该系统框架能够有效地降低网络流量,改善网络性能... 针对分散网络化制造的特点,把移动Agent和Web技术应用到分散网络化制造环境下的生产监控中,提出了基于移动Agent和Web的生产监控系统框架,利用Concordia移动Agent系统开发了原型系统,证明该系统框架能够有效地降低网络流量,改善网络性能,提高监控效率。 展开更多
关键词 生产监控 移动agent WEB 分散网络化制造
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纳米石榴石固体电解质粉体在聚合物电解质中的均匀分散 被引量:1
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作者 吕寒梅 陈昕 +2 位作者 孙麒富 赵宁 郭向欣 《物理化学学报》 SCIE CAS CSCD 北大核心 2024年第3期46-47,共2页
固态锂电池(SSLBs)因采用金属锂负极和固体电解质,具有提高能量密度和安全性的潜质。固体电解质作为固态锂电池的关键材料,对电池性能有重要影响。其中,聚合物-石榴石型复合固态电解质因结合了聚合物电解质的易加工性以及石榴石电解质... 固态锂电池(SSLBs)因采用金属锂负极和固体电解质,具有提高能量密度和安全性的潜质。固体电解质作为固态锂电池的关键材料,对电池性能有重要影响。其中,聚合物-石榴石型复合固态电解质因结合了聚合物电解质的易加工性以及石榴石电解质的热稳定性和高离子电导率的优点,在固态电池规模化制造中具有良好的应用前景。然而,由于纳米固体电解质粉体的表面能高、与有机物的界面兼容性差,导致纳米锂镧锆氧颗粒在聚合物基体中容易发生团聚,进而导致复合电解质的离子电导率降低。本工作引入硅烷偶联剂3-缩水甘油氧基丙基三甲氧基硅烷(GPTMS)对Li_(6.4)La_(3)Zr_(1.4)Ta_(0.6)O_(12)(LLZTO)的表面进行改性,旨在改善LLZTO颗粒在溶剂和聚合物基体中的分散性。LLZTO纳米颗粒表面的羟基与GPTMS分子反应形成共价键,在颗粒表面形成一层厚度约5 nm的GPTMS修饰层。GPTMS中具有亲脂性的环氧基团,使改性后的LLZTO纳米颗粒(LLZTO@GPTMS)在有机溶剂中均匀分散。粒度分布实验表明,LLZTO纳米颗粒的分散性与溶剂的极性呈正相关。采用均匀分散的LLZTO悬浮液,制备的PEO:LLZTO复合电解质的室温离子电导率可以达到2.31×10^(-4)S·cm^(-1)。使用优化后的PEO:LLZTO@GPTMS电解质组装的锂对称电池以及以LiFePO_(4)(LFP)为正极、金属锂为负极的SSLBs均表现出更长的循环寿命。此外,GPTMS的修饰有助于LLZTO纳米颗粒在聚乙烯(Polyethylene,PE)隔膜上的均匀涂覆。采用LLZTO@GPTMS涂覆PE隔膜的LFP|Li电池比采用未修饰LLZTO涂覆PE隔膜的电池展现出更优异的循环稳定性。结果表明,GPTMS能够有效提高LLZTO纳米颗粒在有机溶剂和聚合物基质中的分散性,对其他有机-无机复合材料体系具有指导意义。 展开更多
关键词 固态锂电池 石榴石型电解质 复合固体电解质 硅烷偶联剂 纳米粉体分散
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阳离子自交联苯丙聚合物及其改性ASA乳液的制备与性能研究
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作者 张勇 李小瑞 《中国造纸》 CAS 北大核心 2024年第5期124-129,170,共7页
本研究选用甲基丙烯酰氧乙基三甲基氯化铵(DMC)、丙烯酰胺(AM)、苯乙烯(St)、丙烯酸丁酯(BA)、N-羟甲基丙烯酰胺(NMA)为共聚单体,经水溶液共聚方式制得阳离子自交联苯丙聚合物,并对其乳化ASA的实验条件进行了探究。结果表明,功能型单体... 本研究选用甲基丙烯酰氧乙基三甲基氯化铵(DMC)、丙烯酰胺(AM)、苯乙烯(St)、丙烯酸丁酯(BA)、N-羟甲基丙烯酰胺(NMA)为共聚单体,经水溶液共聚方式制得阳离子自交联苯丙聚合物,并对其乳化ASA的实验条件进行了探究。结果表明,功能型单体的最佳用量为(相对于共聚单体)DMC 9.5%、NMA 2%,ASA与阳离子自交联苯丙聚合物最佳质量比为4.5∶1,改性后的ASA乳液具有优良的分散性和稳定性;用阳离子淀粉、矾土为双元助留剂,在浆料pH值为6.5,改性ASA乳液用量(相对于阔叶木浆)为0.15%,抄造的纸张施胶度达92 s;与原纸相比,施胶纸张耐折度、撕裂指数、抗张指数、环压指数分别提高41.2%、38.3%、45.6%、58.7%;碳酸钙填料为15%~20%,具有良好的施胶效果,适用于中性施胶。 展开更多
关键词 阳离子自交联苯丙聚合物 改性ASA施胶剂 分散性 稳定性 中性施胶
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Effect of Sodium Tripolyphosphate and Silica Fume on Hydration of High Alumina Cement
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作者 WANG Jingran YANG Zongyuan +3 位作者 ZHANG Shuai ZHANG Jinhua HAN Bingqiang KE Changming 《Journal of Wuhan University of Technology(Materials Science)》 SCIE EI CAS CSCD 2024年第5期1246-1252,共7页
It was found that silica fume can reduce the maximum hydration heat release rate of cement by microcalorimetry,inhibit CAH_(10),promote the generation of C_(3)AH_(6)and strätlingite C_(2)ASH_(8),or promote the co... It was found that silica fume can reduce the maximum hydration heat release rate of cement by microcalorimetry,inhibit CAH_(10),promote the generation of C_(3)AH_(6)and strätlingite C_(2)ASH_(8),or promote the conversion of CAH_(10)to C_(3)AH_(6).Sodium tripolyphosphate can retard the early hydration of cement,have a slight effect on 1 d hydration products of cement and inhibit the generation hydration products.Sodium tripolyphosphate and silica fume can promote the early hydration of cement,advance the formation of C_(2)ASH_(8)or the conversion from CAH_(10)to C_(3)AH_(6)at 1 d. 展开更多
关键词 high aluminum cement silica fume dispersing agent HYDRATION
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