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海泥孔隙率对海底微生物燃料电池电化学性能影响及有机质扩散分析
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作者 李洋 刘志 +5 位作者 宰学荣 黄翔 陈岩 曹亚俐 张怀静 付玉彬 《上海交通大学学报》 EI CAS CSCD 北大核心 2024年第10期1567-1574,I0003,共9页
海底沉积物微生物燃料电池(MSMFC)在长期运行过程中,海泥孔隙率影响阳极表面水平方向有机质扩散,进而影响阳极电化学性能和电池功率输出.通过人工调节孔隙率在实验室模拟并研究孔隙率对MSMFC的影响,建立孔隙率与MSMFC产电量和水平扩散... 海底沉积物微生物燃料电池(MSMFC)在长期运行过程中,海泥孔隙率影响阳极表面水平方向有机质扩散,进而影响阳极电化学性能和电池功率输出.通过人工调节孔隙率在实验室模拟并研究孔隙率对MSMFC的影响,建立孔隙率与MSMFC产电量和水平扩散系数之间定量关系式.结果表明:随着孔隙率升高,阳极动力学活性先降低后升高,最高动力学活性是最低动力学活性的3.85倍;电池最大输出功率密度在孔隙率为45.2%时,达到最大值206.8 mW/m 2.随着孔隙率的增大,有机质水平扩散系数升高,并与MSMFC产电量存在线性关系.当孔隙率为45.2%时,扩散系数为0.48 m 2/s,MSMFC产电量达到804.04 J.该研究结果将为MSMFC在不同海域布放选址、阳极结构设计及电池长期产电运行提供技术支撑. 展开更多
关键词 海泥孔隙率 海底微生物燃料电池 电化学特性 电池功率 稳态扩散 有机质水平扩散系数
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太湖典型草、藻型湖区紫外辐射的衰减及影响因素分析 被引量:14
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作者 张运林 秦伯强 +2 位作者 马荣华 朱广伟 陈伟民 《生态学报》 CAS CSCD 北大核心 2005年第9期2354-2361,共8页
2004年4月通过野外原位观测和实验室测定相结合的方法对东太湖和梅梁湾典型草、藻型湖区紫外辐射光谱衰减及影响因素进行了研究.结果表明,320 nm(UV-B)、380 nm(UV-A)的衰减系数在6.33~19.59 m-1、3.41~13.64 m-1间变化,对应的1%表面... 2004年4月通过野外原位观测和实验室测定相结合的方法对东太湖和梅梁湾典型草、藻型湖区紫外辐射光谱衰减及影响因素进行了研究.结果表明,320 nm(UV-B)、380 nm(UV-A)的衰减系数在6.33~19.59 m-1、3.41~13.64 m-1间变化,对应的1%表面光强穿透深度分别为0.24~0.73 m、0.35~1.35 m,到达湖面的99%UV-B辐射在0.5 m左右表层水就衰减完毕,东太湖和梅梁湾紫外辐射衰减系数存在明显的湖区差异;溶解性有机碳(DOC)的浓度在6.60~17.17 mg/L间变化,其均值为(9.99±2.48)mg/L;375 nm波长处CDOM吸收系数为1.78~6.25 m-1,均值为(3.70±1.10)m-1;在短波部分CDOM吸收与DOC浓度存在显著性相关,相关性大致随波长降低而增加,320 nm处的线性关系式:ad320=0.885DOC+2.182;紫外辐射衰减主要受制于水体中的CDOM浓度,衰减系数与DOC浓度、CDOM吸收系数存在显著性相关,340 nm处的关系式分别为:Kd340=0.82+1.05DOC、Kd340=1.98+1.49ad340.在太湖紫外辐射衰减还要受悬浮物和叶绿素a浓度的影响,衰减系数与DOC、叶绿素a和悬浮物浓度多元回归的结果明显要高于单独与DOC浓度或CDOM吸收系数的回归结果. 展开更多
关键词 紫外辐射 衰减系数 有色可溶性有机物(CDOM) 溶解性有机碳(DOC) 太湖
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Seasonal and spatial distributions of euphotic zone and longterm variations in water transparency in a clear oligotrophic Lake Fuxian, China 被引量:19
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作者 Qichao Zhou Yunlin Zhang +4 位作者 Kaidi Li Licheng Huang Fengle Yang Yuanyang Zhou Junjun Chang 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2018年第10期185-197,共13页
To assess the seasonal and spatial variations and long-term trends in water optical properties in Lake Fuxian, investigations based on field work in four seasons and a long-term analysis of data from 1980 to 2014 were... To assess the seasonal and spatial variations and long-term trends in water optical properties in Lake Fuxian, investigations based on field work in four seasons and a long-term analysis of data from 1980 to 2014 were conducted. The results show that there was no significant variation in the euphotic depth(Z(eu)) across the four seasons, and no significant correlations between Z(eu) and potential influencing factors in seasons other than summer, suggesting that the water itself may be a major factor regulating the Z(eu)in general. Nevertheless, significant differences in Z(eu) between the north region(NR) and the south region(SR) were observed in all seasonal tests except spring. This finding relates to a higher abundance of chromophoric dissolved organic matter(CDOM) in the NR due to runoff, especially in the rainy seasons(summer and autumn).CDOM and its terrigenous component had an important impact on Z(eu)in summer, with the highest precipitation, and impacts from suspended solids and non-algal particles were also found in the NR in summer. The Secchi disk depth in the lake decreased clearly over the years,with significantly negative correlations with the increasing permanganate index and air temperature, implying that organic contaminants(CDOM and/or phytoplankton) are important regulators of water transparency. We estimate that the combined effects of climate warming and changes in land use and land cover are also indirect regulating factors. These findings should be considered in the protection of Lake Fuxian, owing to the importance of light penetration in aquatic ecosystems. 展开更多
关键词 Photosynthetic active radiation Diffuse attenuation coefficient Euphotic depth Secchi disk depth Chromophoric dissolved organic matter Yunnan-Guizhou Plateau
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