The bonding mechanism between straw and concrete was analyzed through testing the compressive strength and flexural strength of hollow block, with different straw amount and different dosage and types of admixtures. T...The bonding mechanism between straw and concrete was analyzed through testing the compressive strength and flexural strength of hollow block, with different straw amount and different dosage and types of admixtures. The test results show that the mechanical properties of hollow blocks reduced after adding straws, and the more straws was added, the more hollow block density decreased. But adding A12（SO4）3 and CaC12 could improve the dense degree between rice straw and concrete. And when the proportion of straw mixing amount was 10%, the flexural strength of the early strength agent （2% A12（SO4）3, CaC12） added hollow block reached as maximal as 3.1 MPa, while the compressive strength was 9.1 MPa, consisting with the strength grade of common concrete hollow block MU7.5.展开更多
A self-regulated anti-diabetic drug release device mimicking pancreatic cells is highly desirable for the therapy of diabetes. Herein, a glucose-mediated dual-responsive drug delivery system, which combines pH-and H_(...A self-regulated anti-diabetic drug release device mimicking pancreatic cells is highly desirable for the therapy of diabetes. Herein, a glucose-mediated dual-responsive drug delivery system, which combines pH-and H_(2)O_(2)-responsive block copolymer grafted hollow mesoporous silica nanoparticles(HMSNs)with microneedle(MN) array patch, has been developed to achieve self-regulated administration.The poly[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl acrylate]-b-poly[2-(dimethylamino)ethyl methacrylate](PPBEM-b-PDM) polymer serves as gate keeper to prevent drug release from the cavity of HMSNs at normoglycemic level. In contrast, the drug release rate is significantly enhanced upon H_(2)O_(2)and pH stimuli due to the chemical change of H_(2)O_(2)sensitive PPBEM block and acid responsive PDM block. Therefore, incorporation of anti-diabetic drug and glucose oxidase(GOx, which can oxidize glucose to gluconic acid and in-situ produce H_(2)O_(2)) into stimulus polymer coated HMSNs results in a glucose-mediated MN device after depositing the drug-loaded nanoparticles into MN array patch. Both in vitro and in vivo results show this MN device presents a glucose mediated self-regulated drug release characteristic, which possesses a rapid drug release at hyperglycemic level but retarded drug release at normoglycemic level. The result indicates that the fabricated smart drug delivery system is a good candidate for the therapy of diabetes.展开更多
In this paper,some effort is provided to optimize the geometry of a concrete hollow brick(used in the construction of building roofs)in order to increase the related thermal resistance,thereby reducing energy consumpt...In this paper,some effort is provided to optimize the geometry of a concrete hollow brick(used in the construction of building roofs)in order to increase the related thermal resistance,thereby reducing energy consumption.The analysis is conducted for three different configurations of the hollow concrete bricks.Coupling of conduction,natural convection and thermal radiation phenomena is considered.Moreover,the flows are assumed to be laminar and two-dimensional for the whole range of parameters examined.The conservation equations are solved by a finite difference method based on the control volumes approach and the SIMPLE algorithm for velocity-pressure coupling.The results show that the aspect ratio affects neither the nature of the fluid flow nor the number of convective cells.However,the extension of the circulation cells increases with this parameter.Moreover,the cavities with a large aspect ratio lead to significant reductions in the heat transfer through the hollow block,these reductions reaching approximately 14%.展开更多
This work presents the results of a set of steady-state numerical simulations about heat transfer in hollow blocks in the presence of coupled natural convection,conduction and radiation.Blocks with two air cells deep ...This work presents the results of a set of steady-state numerical simulations about heat transfer in hollow blocks in the presence of coupled natural convection,conduction and radiation.Blocks with two air cells deep in the vertical direction and three identical cavities in the horizontal direction are considered(typically used for building ceilings).Moreover,their outside horizontal surface is subjected to an incident solar flux and outdoor environment temperature while the inside surface is exposed to typical indoor environment conditions.The flows are considered laminar and two-dimensional over the whole range of parameters examined.The conservation equations are solved by means of a finite difference method based on the control volumes approach,relying on the SIMPLE algorithm for what concerns the coupling of pressure and velocity.The effects of the number of cells in the horizontal direction and the thermal conductivity on the heat transfer through the alveolar structure have been investigated.The results show that the number of holes has a significant impact on the value of the overall heat flux through the considered structure.展开更多
Agricultural wastes and sawdust combined with cement matrix in the manufacture of building elements has been practiced with success in developed countries. In this study, sawdust from wood species (Pinus caribaea and ...Agricultural wastes and sawdust combined with cement matrix in the manufacture of building elements has been practiced with success in developed countries. In this study, sawdust from wood species (Pinus caribaea and Eucalyptus grandis) and an agricultural waste—rice husk (Oriza sativa) were combined with Portland cement type V (high initial strength), modified by polymer styrene-butadiene (SBR) addition. Hollow blocks produced with Eucalyptus grandis and rice husk residues showed better compressive strength;however, those produced with residues derived from Pinus caribaea presented non-satisfactory results, due to the particle size that was used.展开更多
During both hot and cold seasons,masonry walls play an important role in the thermal performance between the interior and the exterior of occupied spaces.It is thus essential to analyze the thermal behavior at the hol...During both hot and cold seasons,masonry walls play an important role in the thermal performance between the interior and the exterior of occupied spaces.It is thus essential to analyze the thermal behavior at the hollow block’s level in order to better understand the temperature and heat flux distribution in its structure and potentially limit as much as possible the heat transfer through the block.In this scope,this paper offers an experimental and numerical in-depth analysis of heat transfer phenomena inside a hollow block using a dedicated experimental setup including a well-insulated reference box and several thermocouples and fluxmeters distributed at the boundaries and inside the hollow block.The block was then numerically 3D modelled and simulated using COMSOL Multiphysics under the same conditions,properties,and dimensions as the experimentally tested block.The comparison between the numerical and experimental results provides very satisfactory results with relative difference of less than 4%for the computed thermal resistance.展开更多
Poly（vinylidene fluoride） （PVDF） has become one of the most popular materials for membrane preparation via nonsolvent induced phase separation （NIPS） process. In this study, an amphiphilic block copolymer, Pluro...Poly（vinylidene fluoride） （PVDF） has become one of the most popular materials for membrane preparation via nonsolvent induced phase separation （NIPS） process. In this study, an amphiphilic block copolymer, Pluronic F127, has been used as both a pore-former and a surface-modifier in the fabrication of PVDF hollow fibermembranes to enhance the membrane permeability and hydrophilicity. The effects of 2nd additive and coagulant temperature on the formation of PVDF/Pluronic F 127 membranes have also been investigated. The as-spun hollow fibers were characterized in terms of cross-sectional morphology, pure water permeation （PWP）, relative molecular mass cut-off （MWCO）, membrane chemistry, and hydrolphilicity. It was obsered that the addition of Pluronic F 127 significantly increased the PWP of as-spun fibers, while the membrane contact angle was reduced. However, the size of macrovoids in the membranes was undesirably large. The addition of a 2nd additive, including lithium chloride （LiC1） and water, or an increase in coagulant temperature was found to effectively suppress the macrovoid for- mation in the Pluronic-containing membranes. In addition, the use of LiC1 as a 2nd additive also further enhanced the PWP and hydrophilicity of the membranes, while the surface pore size became smaller. PVDF hollow fiber with a PWP as high as 2330 L·m-2·h-1·MPa-1, a MWCO of 53000 and＇a contact angle of 71 o was successfully fabricated with 3% （by mass） of Pluronic F127 and 3% （by mass） of LiC1 at a coagulant temperature of 25 ℃, which shows better performance as compared with most of PVDF hollow fiber membranes made by NIPS method.展开更多
基金Funded by The National Key Technology R&D Program of China for the 12th Five-Year Plan(No.2012BAJ20B03)
文摘The bonding mechanism between straw and concrete was analyzed through testing the compressive strength and flexural strength of hollow block, with different straw amount and different dosage and types of admixtures. The test results show that the mechanical properties of hollow blocks reduced after adding straws, and the more straws was added, the more hollow block density decreased. But adding A12（SO4）3 and CaC12 could improve the dense degree between rice straw and concrete. And when the proportion of straw mixing amount was 10%, the flexural strength of the early strength agent （2% A12（SO4）3, CaC12） added hollow block reached as maximal as 3.1 MPa, while the compressive strength was 9.1 MPa, consisting with the strength grade of common concrete hollow block MU7.5.
基金financially supported by the Zhejiang Provincial Natural Science Foundation of China (LY20E030005)Natural Science Foundation of Zhejiang Education Department (Y201942793)the Opening Project of Jiangxi Province Key Laboratory of Polymer Micro/Nano Manufacturing and Devices (PMND201905)。
文摘A self-regulated anti-diabetic drug release device mimicking pancreatic cells is highly desirable for the therapy of diabetes. Herein, a glucose-mediated dual-responsive drug delivery system, which combines pH-and H_(2)O_(2)-responsive block copolymer grafted hollow mesoporous silica nanoparticles(HMSNs)with microneedle(MN) array patch, has been developed to achieve self-regulated administration.The poly[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl acrylate]-b-poly[2-(dimethylamino)ethyl methacrylate](PPBEM-b-PDM) polymer serves as gate keeper to prevent drug release from the cavity of HMSNs at normoglycemic level. In contrast, the drug release rate is significantly enhanced upon H_(2)O_(2)and pH stimuli due to the chemical change of H_(2)O_(2)sensitive PPBEM block and acid responsive PDM block. Therefore, incorporation of anti-diabetic drug and glucose oxidase(GOx, which can oxidize glucose to gluconic acid and in-situ produce H_(2)O_(2)) into stimulus polymer coated HMSNs results in a glucose-mediated MN device after depositing the drug-loaded nanoparticles into MN array patch. Both in vitro and in vivo results show this MN device presents a glucose mediated self-regulated drug release characteristic, which possesses a rapid drug release at hyperglycemic level but retarded drug release at normoglycemic level. The result indicates that the fabricated smart drug delivery system is a good candidate for the therapy of diabetes.
文摘In this paper,some effort is provided to optimize the geometry of a concrete hollow brick(used in the construction of building roofs)in order to increase the related thermal resistance,thereby reducing energy consumption.The analysis is conducted for three different configurations of the hollow concrete bricks.Coupling of conduction,natural convection and thermal radiation phenomena is considered.Moreover,the flows are assumed to be laminar and two-dimensional for the whole range of parameters examined.The conservation equations are solved by a finite difference method based on the control volumes approach and the SIMPLE algorithm for velocity-pressure coupling.The results show that the aspect ratio affects neither the nature of the fluid flow nor the number of convective cells.However,the extension of the circulation cells increases with this parameter.Moreover,the cavities with a large aspect ratio lead to significant reductions in the heat transfer through the hollow block,these reductions reaching approximately 14%.
文摘This work presents the results of a set of steady-state numerical simulations about heat transfer in hollow blocks in the presence of coupled natural convection,conduction and radiation.Blocks with two air cells deep in the vertical direction and three identical cavities in the horizontal direction are considered(typically used for building ceilings).Moreover,their outside horizontal surface is subjected to an incident solar flux and outdoor environment temperature while the inside surface is exposed to typical indoor environment conditions.The flows are considered laminar and two-dimensional over the whole range of parameters examined.The conservation equations are solved by means of a finite difference method based on the control volumes approach,relying on the SIMPLE algorithm for what concerns the coupling of pressure and velocity.The effects of the number of cells in the horizontal direction and the thermal conductivity on the heat transfer through the alveolar structure have been investigated.The results show that the number of holes has a significant impact on the value of the overall heat flux through the considered structure.
文摘Agricultural wastes and sawdust combined with cement matrix in the manufacture of building elements has been practiced with success in developed countries. In this study, sawdust from wood species (Pinus caribaea and Eucalyptus grandis) and an agricultural waste—rice husk (Oriza sativa) were combined with Portland cement type V (high initial strength), modified by polymer styrene-butadiene (SBR) addition. Hollow blocks produced with Eucalyptus grandis and rice husk residues showed better compressive strength;however, those produced with residues derived from Pinus caribaea presented non-satisfactory results, due to the particle size that was used.
文摘During both hot and cold seasons,masonry walls play an important role in the thermal performance between the interior and the exterior of occupied spaces.It is thus essential to analyze the thermal behavior at the hollow block’s level in order to better understand the temperature and heat flux distribution in its structure and potentially limit as much as possible the heat transfer through the block.In this scope,this paper offers an experimental and numerical in-depth analysis of heat transfer phenomena inside a hollow block using a dedicated experimental setup including a well-insulated reference box and several thermocouples and fluxmeters distributed at the boundaries and inside the hollow block.The block was then numerically 3D modelled and simulated using COMSOL Multiphysics under the same conditions,properties,and dimensions as the experimentally tested block.The comparison between the numerical and experimental results provides very satisfactory results with relative difference of less than 4%for the computed thermal resistance.
文摘Poly（vinylidene fluoride） （PVDF） has become one of the most popular materials for membrane preparation via nonsolvent induced phase separation （NIPS） process. In this study, an amphiphilic block copolymer, Pluronic F127, has been used as both a pore-former and a surface-modifier in the fabrication of PVDF hollow fibermembranes to enhance the membrane permeability and hydrophilicity. The effects of 2nd additive and coagulant temperature on the formation of PVDF/Pluronic F 127 membranes have also been investigated. The as-spun hollow fibers were characterized in terms of cross-sectional morphology, pure water permeation （PWP）, relative molecular mass cut-off （MWCO）, membrane chemistry, and hydrolphilicity. It was obsered that the addition of Pluronic F 127 significantly increased the PWP of as-spun fibers, while the membrane contact angle was reduced. However, the size of macrovoids in the membranes was undesirably large. The addition of a 2nd additive, including lithium chloride （LiC1） and water, or an increase in coagulant temperature was found to effectively suppress the macrovoid for- mation in the Pluronic-containing membranes. In addition, the use of LiC1 as a 2nd additive also further enhanced the PWP and hydrophilicity of the membranes, while the surface pore size became smaller. PVDF hollow fiber with a PWP as high as 2330 L·m-2·h-1·MPa-1, a MWCO of 53000 and＇a contact angle of 71 o was successfully fabricated with 3% （by mass） of Pluronic F127 and 3% （by mass） of LiC1 at a coagulant temperature of 25 ℃, which shows better performance as compared with most of PVDF hollow fiber membranes made by NIPS method.
