Petrochemical eigenvalues and diagrams for the identification of metamorphic rocks'protolith,taking the host rocks of Dashuigou tellurium deposit in China as an example

The Dashuigou tellurium deposit is the world’s only known independent tellurium deposit.By restoring metamorphic rocks’protolith,we seek to understand not only the development and evolution trajectory of the region but also the origin of the relevant deposits.While there are many ways to restore metamorphic rocks’protolith,we take the host metamorphic rocks of Dashuigou tellurium deposit and leverage various petrochemical eigenvalues and related diagrams previously proposed to reveal the deposit’s host metamorphic rocks’protolith.The petrochemical eigenvalues include molecular number,Niggli’s value,REE parity ratio,CaO/Al_(2)O_(3)ratio,Fe^(3+) /(Fe^(3+) -+Fe^(2+) )ratio,chondrite-normalized REE value,logarithmic REE value,various REE eigenvalues including scandium,Eu/Sm ratio,total REE amount,light and heavy REEs,δEu,Eu anomaly,Sm/Nd ratio,and silicon isotope δ^(30) SiNBS-29‰,etc.The petrochemical plots include ACMs,100 mg-c-(al+alk),SiO_(2)-(Na_(2)O+K_(2)O),(al+fm)-(c+alk)versus Si,FeO+Fe_(2)O^(3+) TiO)-Al_(2)O_(3)-MgO,c-mg,Al_(2)O_(3)-(Na_(2)O+K_(2)O),chondrite-normalized REE model,La/Yb-REE,and Sm/Nd ratio,etc.On the basis of these comprehensive analyses,the following conclusions are drawn,starting from the many mantle-derived types of basalt developed in the study area of different geological ages,combined with the previously published research results on the deposit s fluid inclusions and sulfur and lead isotopes.The deposit is formed by mantle degassing in the form of a mantle plume in the late Yanshanian orogeny.The degassed fluids are rich in nano-sc ale substances including Fe,Te,S,As,Bi,Au,Se,H_(2),CO_(2),N_(2),H_(2)O,and CH_(4),which are enriched by nano-effect,and then rise to a certain part of the crust in the form of mantle plume along the lithospheric fault to form the deposit.The ultimate power for tellurium mineralization was from H_(2)flow with high energy,which was produced through radiation from the melted iron of the Earth’s outer core.The H,flow results in the Earth’s degassing,as well as the mantle and crust’s uplift.

Zircon U-Pb Geochronology and Geochemical Characteristics of the Volcanic Host Rocks from the Tongyu VHMS Copper Deposit in the Western North Qinling Orogen and Their Geological Significance

Precise in situ zircon U-Pb dating and Lu-Hf isotopic measurement using an LA-ICP-MS system, whole-rock major and trace element geochemistry and Sr-Nd isotope geochemistry were conducted on the volcanic host rocks of the Tongyu copper deposit on the basis of further understanding of its geological characteristics. Three zircon samples from the volcanic host rocks yielded 206Pb/238 U weighted average ages ranging from 436±4 Ma to 440±5 Ma, which are statistically indistinguishable and coeval with the ca. 440 Ma northward subduction event of the Paleo-Qinling oceanic slab. The volcanic host rocks were products of magmatic differentiation that evolved from basalt to andesite to dacite to rhyolite, forming an integrated tholeiitic island arc volcanic rock suite. The primitive mantle-normalized trace element patterns for most samples show characteristics of island arc volcanic rocks, such as relative enrichment of LILE（e.g. Th, U, Pb and La） and depletion of HFSE（e.g. Nb, Ta, Ti, Zr and Hf）. Discrimination diagrams of Ta/Yb vs Th/Yb, Ta vs Th, Yb vs Th/Ta, Ta/Hf vs Th/Hf, Hf/3 vs Th vs Nb/16, La vs La/Nb and Nb vs Nb/Th all suggest that both the volcanic host rocks from the Tongyu copper deposit and the volcanic rocks from the regional Xieyuguan Group were formed in an island arc environment related to subduction of an oceanic slab. Values of ISr（0.703457 to 0.708218） and εNd（t）（-2 to 5.8） indicate that the source materials of volcanic rocks from the Tongyu copper deposit and the Xieyuguan Group originated from the metasomatised mantle wedge with possible crustal material assimilation. Most of the volcanic rock samples show good agreement with the values of typical island arc volcanic rocks in the ISr-εNd（t） diagram. The involvement of crustal-derived material in the magma of the volcanic rocks from the Tongyu copper deposit was also reflected in the zircon εHf（t） values, which range from-3.08 to 10.7, and the existence of inherited ancient xenocrystic zircon cores（2616±39 Ma and 1297±22 Ma）. The mineralization of the Tongyu copper deposit shows syn-volcanic characteristics such as layered orebodies interbedded with the volcanic rock strata, thus, the zircon U-Pb age of the volcanic host rocks can approximately represent the mineralization age of the Tongyu copper deposit. Both the Meigou pluton and the volcanic host rocks were formed during the ca. 440 Ma northward subduction of the Paleo-Qinling Ocean when high oxygen fugacity aqueous hydrothermal fluid released by dehydration of the slab and the overlying sediments fluxed into the mantle wedge, triggered partial melting of the mantle wedge, and activated and extracted Cu and other ore-forming elements. The magma and ore-bearing fluid upwelled and erupted, and consequently formed the island arc volcanic rock suite and the Tongyu VHMS-type copper deposit.

Constraints of REE and trace elements of high-pressure-veins and host rocks in western Tianshan on origin of deep fluids in paleosubduction zones

The western Tianshan high-pressure(HP) metamorphic belt represents the paleosubduction mélange of paleozoic south Tianshan ocean between the Yili-central Tianshan and Tarim plates. High-pressure veins are extensively developed in this HP belt. Compared with normal mid-ocean ridge basalt(N-MORB), the high-pressure veins and host rocks are enriched in light rare earth elements(LREE) and incompatible elements. But high-pressure veins show a larger variation than host rocks in total REE abundance. On the trace element spidergram, all the samples are enriched in incompatible elements and show strong positive Pb anomaly relative to N-MORB. The array tendency lines of plots of the HP rocks have apparent slopes on diagram of m(Sr) vs m(Sr)/m(Zr), m(Li) vs m(Li)/m(Y) and (m(Ce)) vs m(Ce)/m(Pb), which indicates that the enrichment in LREE and incompatible elements relative to N-MORB of the HP-metamorphic rocks from western Tianshan is not attributed to magma evolution process of the protolith. High field strength elements, such as Nb, Ta, Ti, Zr and Hf, do not show negative anomaly relative to N-MORB, which is dissimilar to that of island arc basalts. Therefore, the enrichment in LREE and incompatible elements of the HP rocks is not attributed to the enrichment of the source of the protolith. The mass ratios of Rb to Ba, Ce to Pb, Nb to U and Ta to U of high-pressure veins and host rocks are intermediate of mid-ocean ridge basalt or oceanic island basalt and continental crust. The fluids in western Tianshan paleosubduction zones are mixtures of two sources, dehydration or devolatilization of host rocks and of subducted sediments.

Origin of the deep fluids in the paleosubduction zones in western Tianshan:Evidence from Pb-and Sr-isotope compositions of high-pressure veins and host rocks

Fluids in the deep subduction zones play an important role in crust-mantle ex-change related to the subduction process. Identification of fluids origin, internal or external, can help us to evaluate the contribution of crust materials to mantle during this process. High-pressure veins, which developed in the western Tianshan HP-metamorphic belt extensively, are the direct products of the fluids in subduction zones. In western Tianshan, high-pressure veins and host rocks have overall Pb- and Sr-isotope compositions. At t = 340 Ma, the high-pressure metamorphic time, the ratios of 206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb and 87Sr/86Sr of high pressure veins are 17.122―18.431, 15.477―15.611, 37.432―38.689 and 0.70529―0.70705, and are 17.605―17.834, 15.508―15.564, 37.080―38.145 and 0.70522―0.70685 for host rocks. However, high-pressure veins show a much larger variation in Pb-isotope composi-tions than host rocks. Plots of samples are distributed roughly along a line parallel to and far away from the Northern Hemisphere reference line (NHRL) on the plot of 206Pb/204Pb vs 207Pb/204Pb. On the plot of 206Pb/204Pb vs 208Pb/204Pb, plots of data are distributed nearby mid-ocean-ridge basalts (MORB) area or along a line parallel to and not far away from NHRL, which shows that the data plots are farther away from MORB and ocean island basalts (OIB) areas on the plot of 206Pb/204Pb vs 207Pb/204Pb than on the plot of 206Pb/204Pb vs 208Pb/204Pb. The compositions of Pb- and Sr-isotopes of these high-pressure metamorphic rocks are between that of enriched mantle 1(EMI) and of sediments or upper crust. A notable characteristic can be seen from plots of Pb-isotope ratio vs Pb-isotope ratio and 206Pb/204Pb vs 87Sr/86Sr that array of plots shows an evident tendency of mixture of two end members. Ratios of Rb/Ba, Ce/Pb, Nb/U and Ta/U of high-pressure veins and host rocks are between that of OIB or MORB and that of conti-nental crust, which indicates that continental crust materials probably have been incorporated into the rocks. The fluids in the paleosubduction zones in western Tianshan are mixtures of two sources, one originating from the devolatilzation of the host rocks with protolithes similar to ocean basalts from enriched mantle 1 (EMI), the other from the dehydration of subducted sediments.

Metallogeny of the Lannigou Sedimentary Rock-hosted Disseminated Gold Deposit in Southwestern Guizhou Province,China

The Lannigou deposit is a large-sized sedimentary rock-hosted disseminated gold （SRHDG） deposit located in the Youjiang Basin. It is hosted by the Middle Triassic turbidite. Wall rock alterations, including silicification, pyritization, arsenopyritization, carbonatization and argillization, commonly occur along fractures. PGE study demonstrates that either Permian basalts or Triassic ultrabasic intrnsives are unlikely to be the main source of gold mineralization. Coupled with the lack of other nmgmatic activity in the vicinity of the mining area, an amagmatic origin is proposed. Organic matter compositions and GC-MS analysis of the ores and host rocks show that the organics in the ores and the host rocks have a common source; the organic matter in the ores was mainly indigenous. The positive correlation between S2 and Au contents, along with the common occurrence of organic inclusions, suggest involvement of organic matter in the ore-forming process in terms of promoting Au leaching from the source rocks, making colloidal Au migration possible, as well as hydrocarbon reduction of sulphate. Geological and geochemical characteristics of the Lannigou deposit suggest that it was formed through circulation of meteoric water and probably less importantly organic bearing formation water driven by high geothermal gradient caused by late Yanshanian extension, which leached Au from the source bed, and then migrated as Au-bisnlfides and colloidal Au, culminating in deposition by reduction-adsorption and surface complexation of gold onto the growth surface of arsenlan pyrite.

Leaching experiment research on host rocks of Qiaogashan gold deposit in Shanshan County, Xinjiang, China

1 Geological setting of the deposit THE Qiaogashan gold deposit is located at contact zone of middle Tianshan terrance and south Tianshanback-arc basin, and near the latter side. The orebodies are controlled by middle Tianshan brittle-ductileshear zone. The main ore types are auriferous quartz veins and fractured and alterated rocks. The southpart of the deposit is hosted in striking sheared Devonian rocks, while the north part in a diorite body,which was deformed by a nape shear zone. 2 Geology and geochemistry of host rocks The host rocks of south part of the deposit are Devonian detrital stone of terrigenous origin, interlayering volcanic detrial stone of back-arc basin facies, which locally suffered intensive ductile-brittle shearing. The rock type is composed mainly of gray-green siltstone, poststone, metasiltstone, etc., and a se-

中非新元古代造山带钴超常富集研究进展与展望

钴被誉为“低碳能源金属”,是我国乃至全球急缺的关键金属矿产。中非新元古代铜钴矿带内的沉积岩容矿型铜钴矿床每年为全球提供了60%以上的钴金属产量,是研究钴超常富集的最佳区域。前人对该矿带的研究主要聚焦于铜的成矿作用,然而该矿带内的铜矿床并非都伴生钴,目前对伴生钴的来源-富集过程及其与沉积、成岩、造山作用的成因联系仍缺乏系统研究。本文综述了中非铜钴矿带内沉积岩容矿型铜钴矿床主要研究进展及存在问题,认为超大陆裂解过程改变了中非铜钴矿带的沉积盆地环境,使得钴在沉积地层中发生初始预富集,此外古气候条件,包括增氧事件和冰川事件,也可能对该矿带内的大规模钴的聚集产生了积极作用。新元古代造山作用重新活化沉积地层呈分散分布的钴元素,导致钴的进一步富集。因此,中非铜钴矿带中的钴超常富集是大气-地球-水圈-生物圈之间长期相互作用而形成的成矿效应。在矿床尺度,深入理解沉积岩容矿型铜钴矿床的形成过程,有助于在中非铜钴矿带,甚至在全球其他有利沉积盆地内,勘探更多的钴资源。

造山型金矿容矿建造分类、成矿模式及找矿勘查

造山型金矿床指造山过程中形成的后生脉状金矿床,受构造、建造双重控制,是全球最重要的金矿勘查类型。按容矿岩石建造的不同,造山型金矿可分为绿岩带型(包括绿片岩型、BIF型和花岗-片麻岩型3个亚类型)、浊积岩型、碳酸盐岩型和浅成侵入岩型,构成了造山型金矿床完整的成矿谱系。不同类型之间具有紧密的时空和成因联系,可互为找矿标志。绿岩组合和浊积岩系具有高的金丰度,既是容矿岩系,也是重要的矿源层,多类型造山作用驱动大规模区域性流体活动,造就了造山型金矿省/巨型成矿带,岩浆流体叠加和“热机效应”是形成超大型金矿床的重要因素。构建了多源区域性流体+岩浆流体叠加的地壳连续成矿模型和造山型金矿区域成矿模式,强调了多旋回造山作用对造山型金矿的成矿意义。“富金矿源层+剪切变形带+浅成侵入岩”组合是大型金矿系统的勘查选区标志,靶区优选的目标是获取找矿潜力大的优质矿权;矿权区勘查的优先目标是发现可规模化露天开采的矿床(体),通过化探异常评价和浅钻追索次生富集带,可快速发现主矿体;矿区深部找矿(深度>300 m)潜力巨大,主攻目标是资源量大、品位高的热液通道相的厚板状或筒状矿体。

烃源岩作为铀源岩的可能性:研究现状与展望

烃源岩与砂岩型铀矿通常同盆共生,除了提供矿化剂之外,烃源岩能否成为铀源岩对砂岩型铀矿的勘探范围向盆地纵深部位拓展具有重要意义。研究针对烃源岩能否成为铀源岩所涉及的三个关键问题,即“铀从烃源岩中迁出的比例、如何随地层流体运移、在何种条件下沉淀和聚集”,梳理了国内外相关研究进展,指出了有必要加强研究的薄弱环节。结果表明:热模拟实验证实烃源岩中的铀能够迁出,迁出的铀很可能以U(IV)/U(VI)混合的形式随含烃地层水和石油运移,温度、压力的降低以及pH、Eh变化会导致铀溶解度的下降和铀运移载体的分解而发生铀沉淀,沉淀物也可能重新被含氧的地层水溶解。问题与建议包括:(1)铀从烃源岩中迁出的比例存在不确定性,迁出的机制以及地质规律尚不清楚,需要开展进一步的生烃排铀模拟实验及排铀动力学表征研究;(2)铀在低温、含烃、还原性热液中的赋存状态是研究其迁移机制的基础,目前对与铀结合的优势配体的类型、产物热力学性质、铀在含烃地下水与石油中的分布比例所知甚少,有必要开展基于热模拟实验的原位测试研究;(3)携铀流体向浅部运移的过程中温度、压力、pH、Eh、有机无机组分的变化控制铀的迁移/沉淀,不同组合条件下铀赋存形式的转化规律、主控因素尚不清楚,有待开展多因素、多变量的烃铀运移模拟实验进行揭示。

广东省广宁县丰木地区金矿地质特征及找矿标志

丰木地区金矿床位于粤西广宁县北部,黄泥坑金矿床的南西部。区内多期次岩浆活动,断裂构造发育,具有良好的构造蚀变岩型金多金属矿床的成矿条件。本文对丰木地区金矿区的地质特征进行研究,判断其为剪切带控制的中低温热液金矿床,并总结了找矿标志,为下一步勘查提供依据。

黔西南两类容矿围岩金矿对比及对深部找矿勘查的指示

黔西南是中国著名的卡林型金矿集区,已查明金资源量约750 t,特别是近年来在该地区新发现了玄武岩容矿金矿,以架底大型金矿床、大麦地中型金矿床为典型代表,取得了新的找矿突破和认识,至此,该地区原生金矿容矿围岩主要有玄武岩和沉积岩两类。通过对黔西南玄武岩容矿金矿与沉积岩容矿金矿进行对比分析研究,认为:(1)卡林型金矿的定义可能存在一定局限性,需进一步拓展,黔西南玄武岩容矿金矿与沉积岩容矿金矿典型特征相似,可能形成于同一区域成矿事件,是同一区域岩浆热液成矿作用形成的卡林型金矿,在深部勘查与研究工作中应系统考虑;(2)构造(背斜、穹隆、断裂、SBT)+有利岩石组合(厚度大于100 m的碳酸盐岩与上覆厚度大于50 m的碎屑岩或玄武岩/凝灰岩)+Au-As-Sb-Hg-Tl组合异常+围岩蚀变(硅化、黄铁矿化、毒砂化),可能指示深部存在卡林型金矿;(3)玄武质岩石也是卡林型金矿很好的赋矿围岩,卡林型金矿容矿岩石、容矿地层具有多样性,几乎区内所有岩石和地层均可以成为卡林型金矿的容矿岩石和容矿地层,但具体到某一个特定的矿床时,往往有特定的就位地层和特殊的容矿围岩。

Geology and Geochemistry of Reworking Gold Deposits in Intrusive Rocks of China-I.Features of the Intrusive Rocks

Most gold deposits in intrusive rocks were formed as a result of reworking processes.The intrusive rocks containing gold deposits and consisting of ultramafic-mafic, intermediate-acid and alkaline rocks of the Archean, Proterozoic, Caledonian, Hercynian and Yenshanian periods occur in cratons, activated zones of cratons and fold belts. Among them, ultramafic-mafic rocks, diorite, alkaline rocks, and anorthosite are products of remelting in the mantle or mantle-crust or mantle with crustal contamination. However, auriferous intermediate-acid rocks are products of metasomatic-remelting in auriferous volcanic rocks or auriferous volcano-sedimentary rocks in the deep crust.

东昆仑五龙沟金成矿系统:基本特征、成矿控制与勘查标志

五龙沟金矿田位于东昆仑造山带东段,金成矿与三叠纪岩浆作用、脆性和/或韧性变形显示密切时空联系。但是,金容矿地质体类型与控矿构造特征尚不清,金成矿受哪些关键要素控矿尚不明确。本文通过广泛深入的文献资料调研与详细的野外调查,详细阐明了五龙沟地区金矿床地质特征与成矿地质环境,系统梳理、总结与对比了不同地段金矿床的矿化类型、容矿地质体与控矿构造。研究表明,五龙沟金矿田发育微细脉型、蚀变岩型、石英脉型等3种矿化类型,容矿地质体主要以元古界—奥陶系变质岩系与侵入岩类为主。早期韧性剪切作用导致矿源层中金的活化与预富集,金矿化主要受控于晚期北西向脆性变形及相关断裂破碎带。大规模金成矿与古特提斯洋关闭及伴随的同/后碰撞构造过程有关。北西向构造—蚀变带、侵入岩类与古老变质基底是五龙沟金矿田的重要勘查标志。

胶西北大尹格庄金矿床与夏甸金矿床差异性研究

大尹格庄金矿床和夏甸金矿床均分布于招平断裂中段,但二者在赋矿围岩岩性与化学成分、矿石特征、蚀变岩与蚀变矿物特征等方面存在显著差异。与夏甸金矿床相比,大尹格庄金矿床的招平断裂主裂面断层泥颜色浅,厚度小;玲珑型花岗岩含SiO_(2)、K_(2)O相对较低,含Al_(2)O_(3)、CaO、MgO、TFe_(2)O_(3)相对较高,且少见变质岩残留体;红化蚀变规模和强度较高;金矿化主要产于蚀变的玲珑型花岗岩围岩中,属典型蚀变岩型金矿床,矿石银含量较高,且常见菱铁矿。与大尹格庄金矿床相比,夏甸金矿床的招平断裂主裂面断层泥颜色黑,厚度大;矿体上盘变质岩中见有大理岩夹层;玲珑型花岗岩中常见变质岩残留体;暗灰色矿石中保留有变片麻状构造和变条带状构造,空间和成因上与变质岩关系密切,常见磁黄铁矿化;蚀变岩中见含钨金红石及白钨矿化,局部还见有石英脉型金矿化;黄铁绢英岩中SiO_(2)、Al_(2)O_(3)含量较低,K_(2)O、Na_(2)O、CaO、MgO含量较高,红化蚀变花岗岩中K_(2)O含量低于新鲜玲珑型花岗岩。赋矿围岩岩性差异及对成矿的制约是导致大尹格庄金矿床与夏甸金矿床差异性的关键。根据电化学成矿机制,夏甸金矿床成矿元素主要来自矿体上盘变质岩围岩,而大尹格庄金矿床成矿元素主要有2种来源,即胶东群变质岩和玲珑型花岗岩。

黔东北地区金亮萤石矿床稀土元素地球化学特征与成矿物质来源

黔东北-渝东南一带分布有大量的萤石矿床(点),这些矿床(点)主要分布在北东向区域性断裂两盘的奥陶系下统桐梓组和红花园组灰岩中NW、NNW向张性断裂内,矿体呈脉状或透镜状产出,深部至奥陶系下统桐梓组逐渐尖灭,关于该区萤石矿成因及物质来源长期存在较大争议。金亮萤石矿床是黔东北沿河地区代表性小型萤石矿床,本文对该矿床中萤石开展稀土元素地球化学研究。结果表明,萤石ΣREE为67.4×10^(-6)~90.55×10^(-6),LREE/HREE值为43.98~78.78,δEu值为77.07~94.71,δCe值为0.39~0.42。矿床萤石稀土分布模式呈明显右倾曲线,为轻稀土相对富集型,以Eu正异常和Ce负异常明显为特征。结合矿床地质特征,认为该萤石矿床为热液成因的产物,萤石为同源同期热液流体在氧化环境成矿。萤石成矿作用与沉积岩关系密切,其中成矿物质Ca主要来源于下奥陶统红花园组灰岩,可能部分来源于深部碳酸盐岩,而成矿物质F主要来源于深部上震旦统陡山沱组至下寒武统明心寺组高氟地层。

阿拉善右旗特拜金矿赋矿变沉积岩地球化学特征、源区属性及构造意义

本次对阿拉善右旗特拜金矿赋矿变沉积岩进行地球化学分析,主要岩性为云母石英片岩、变质粉砂岩、变质岩屑石英砂岩等;主量元素SiO_(2)平均含量62.39%,Al_(2)O_(3)平均含量15.40%,Fe_(2)O_(3)平均含量6.57%,MgO平均含量3.84%,CaO平均含量2.31%,K_(2)O平均含量2.65%,Na_(2)O平均含量2.09%。ΣREE配分模式曲线一致,LREE/HREE=5.75~8.34,平均为7.18,(La/Yb)_(N)=5.39~8.38,平均6.83,Eu负异常明显,轻稀土元素相对重稀土元素明显富集;微量元素中相对稳定元素比值如La/Sc、Th/Sc、Cr/Zr显示出物源来自上地壳长英质;Rb-K_(2)O图解、Ni-TiO_(2)图解和La/Yb-ΣREE图解表明其母岩主要来源于花岗岩,结合古水流特征以及碎屑锆石年龄证据等推测物源可能来自北大山地区花岗岩。结合特拜赋矿变沉积岩岩石组合特征、构造特征和地球化学特征,认为其源岩形成于大陆岛弧构造环境。

内蒙古红水泉铅锌银矿床成因研究:矿物学和地球化学证据

红水泉铅锌银矿床产于大兴安岭西北段的碳酸盐岩建造,矿床成因鲜有研究。本文以矿床硫化物的矿物学及地球化学特征为切入点,探讨了矿床成因及成矿物质来源。矿物学研究表明,闪锌矿存在2个世代,其微量元素FeS温度计指示主成矿阶段早期为中温范围,Zn/Cd值为160~215;方铅矿表现为富Ag、Sb贫Bi的特点;黄铁矿的Co/Ni>1,Fe/(S+As)均值为0.871。3种硫化物元素标型特征指示出中低温、中浅成、岩浆热液与沉积作用叠加的成因特点。黄铁矿、闪锌矿和方铅矿的硫同位素δ^(34)S为-6.13‰~0.25‰,均值-2.8‰,暗示硫主要是通过岩浆活动带来的深源硫,其次是赋矿碳酸盐岩建造的地层硫,整体表现为岩浆硫与地层硫混合的特点。3种硫化物铅均值为^(206)Pb/^(204)Pb=18.46~18.55,^(207)Pb/^(204)Pb=15.59~15.65,^(208)Pb/^(204)Pb=38.08~38.51,与闪长岩铅同位素组成相似,在构造判别图解中二者呈线性相关,位于造山带与上地壳演化区间。综合来看,认为红水泉铅锌银矿床为中低温热液充填脉状铅锌银矿床。

龙门山造山带北段黄泥坪金矿床蚀变矿化特征与SWIR勘查应用研究

黄泥坪金矿床位于扬子地块西北缘,是龙门山造山带北段新发现的一个重要的中型金矿床,研究程度较低,蚀变矿化分布特征和矿床成因仍不清楚,需要新的勘查方法和思路开展下一步找矿工作。基于详细的矿床地质和短波红外光谱(SWIR)研究,发现黄泥坪金矿床的围岩蚀变主要有黄铁矿化、毒砂化、白云母化、硅化和碳酸盐化,白云母通常呈细小鳞片状分布于毒砂和黄铁矿的周围,金主要以不可见金的形式存在于毒砂和黄铁矿中。汉树沟、山关石、柳树坪和石罐子4个矿段应属同一成矿系统,其中汉树沟和山关石矿段的蚀变矿化期次可分为早期变质成矿期和晚期热液脉成矿期,变质成矿期包括石英多金属硫化物阶段和浸染状毒砂-黄铁矿阶段,热液脉成矿期包括石英-方解石粗脉阶段和毒砂-黄铁矿-方解石细脉阶段。变质成矿期发生了第一次金矿化,热液脉成矿期发生了第二次金矿化。SWIR勘查应用研究发现,矿体上盘千枚岩和下盘变质砂岩中发育较多Al–OH吸收峰位值较大的变质成因多硅白云母,而矿化部位则主要发育Al–OH吸收峰位值较小的热液白云母,Pos2200≤2202.5nm可作为热液白云母族矿物与变质成岩白云母族矿物或者二者混合相(指变质成岩白云母族矿物占主导,含有部分热液白云母族矿物)的大致界线。同时Pos2200≤2202.5 nm,且IC值为1.0~1.5可作为黄泥坪矿床新的勘查指标。本研究可以为认识龙门山北段浅变质沉积岩容矿的金矿床成矿规律和找矿勘查提供新的科学依据。

西藏自治区察隅县若瓦沙底铅锌矿地质特征浅析

西藏自治区察隅县若瓦沙底铅锌矿产于侏罗纪花岗斑岩与中二叠统雄恩错组白云质灰岩的接触部位,赋矿岩石主要为外接触带矽卡岩,次为强蚀变花岗斑岩,脉状产出,其展布方向明显受断裂构造及侵入岩体控制,矿床成因类型属矽卡岩型。侵入岩体与围岩的接触带、矽卡岩分布区、构造破碎带与成矿有关的蚀变及矿化等是本区主要的找矿标志。通过对若瓦沙底铅锌矿矿床地质特征和找矿标志进行分析,认为成矿条件较好,矿产资源潜力巨大,为该地区进一步开展地质找矿工作提供了新的找矿思路。

辽宁排山楼金矿围岩的岩石学特征(英文)

Standard laboratory procedures and remote sensing techniques were employed in the characterization of gold bearing rocks of the Paishanlou area. Results indicate that, the rocks were formed in an alteration complex of medium temperature and pressure. The area was under intense polymetamorphism (ductile shearing, and hydrothermal metamorphism), which occurred along the deformation zone stretching from Jinzhou to Fuxin. The area bears some propylitic, phyllic (or sericitic) and argillic alteration styles. Gold minerals are contained in fine grained pyrite in silicified zones, and associated with metamorphosed Precambrian rocks. The host rock is composed of gneiss, mylonite and trondhjemite granite, and has a distinctive gold lead geochemical affinity.