In this paper, we demonstrate that controlled dopantoncentration is an essential issue for charge carriers transporting in red Phosphorescent Organic Light-Emitting Device （PHOLED）. Carriers transport via dopant mol...In this paper, we demonstrate that controlled dopantoncentration is an essential issue for charge carriers transporting in red Phosphorescent Organic Light-Emitting Device （PHOLED）. Carriers transport via dopant molecules in the emitting layer with a single host, however, via both dopant and host molecules when their energy levels are well aligned. Conditions for reduced driving-voltage and enhanced efficiency of red PHOLED are obtained by employing a mixed host structure. A pure red PHOLED with color coordinates of （0.67, 0.33） has been realized by using only 4 wt% dopant, The device achieves 100 cd/cm2 at 2.9 V, with correspond- ing power efficiency of 9.3im/W and external quantum efficiency of 14.3%.展开更多
A series of novel hyperbranched polymers （HBPs） consisting ofa 2,7-subsituted 9-（heptadecan-9-yl）-9H-carbazole unit （A2＋A2＇） and a tetra-substituted green thermally activated delayed fluorescence （TADF） dye ...A series of novel hyperbranched polymers （HBPs） consisting ofa 2,7-subsituted 9-（heptadecan-9-yl）-9H-carbazole unit （A2＋A2＇） and a tetra-substituted green thermally activated delayed fluorescence （TADF） dye of 2,3,5,6-tetra（9H- carbazol-9-yl）-4-pyridinecarbonitrile （4CzCNPy, B4） have been synthesized via Suzuki cross-coupling reaction following an ＂Az＋A2＇＋B4＂ method. The polymers are named according to the polymerization ratio of 4CzCNPy monomer （5 mol%, 10 mol% and 15 mol% for HBPs of P2-P4 respectively, and 0 mol% for the control linear polymer P1）. Their thermal, optoelectronic and electrochemical properties have been characterized by a combination of techniques. All the polymers exhibit high thermal stability with the decomposition temperatures （Ta） above 400 ℃ and glass transition temperatures （Tg） up to 98℃. Unfortunately, the incorporation of TADF moiety into these HBP materials induced non-TADF characteristics. However, when the HBPs functionalized as the host for our previously developed 4CzCNPy TADF dopant in solution processed devices, maximum external quantum efficiency of 5.7% and current efficiency of 17.9 cd/A have been achieved in P3-based device, which is significantly higher than those of 1.5% and 4.2 cd/A for the linear polymer P1.展开更多
基金the National Hi-Tech Research and Development Program of China，the Ministry of Science and Technology of China，the National Natural Science Foundation of China，the Research Fund for the Doctoral Program of Higher Education，the Scientific and Technological Developing Scheme of Jilin Province
文摘In this paper, we demonstrate that controlled dopantoncentration is an essential issue for charge carriers transporting in red Phosphorescent Organic Light-Emitting Device （PHOLED）. Carriers transport via dopant molecules in the emitting layer with a single host, however, via both dopant and host molecules when their energy levels are well aligned. Conditions for reduced driving-voltage and enhanced efficiency of red PHOLED are obtained by employing a mixed host structure. A pure red PHOLED with color coordinates of （0.67, 0.33） has been realized by using only 4 wt% dopant, The device achieves 100 cd/cm2 at 2.9 V, with correspond- ing power efficiency of 9.3im/W and external quantum efficiency of 14.3%.
基金financially supported by the National Natural Science Foundation of China(No.21304047)Natural Science Foundation of Jiangsu Province(No.BK2016042)Research Fund for the Doctoral Program of Higher Education(No.20133221120015)
文摘A series of novel hyperbranched polymers （HBPs） consisting ofa 2,7-subsituted 9-（heptadecan-9-yl）-9H-carbazole unit （A2＋A2＇） and a tetra-substituted green thermally activated delayed fluorescence （TADF） dye of 2,3,5,6-tetra（9H- carbazol-9-yl）-4-pyridinecarbonitrile （4CzCNPy, B4） have been synthesized via Suzuki cross-coupling reaction following an ＂Az＋A2＇＋B4＂ method. The polymers are named according to the polymerization ratio of 4CzCNPy monomer （5 mol%, 10 mol% and 15 mol% for HBPs of P2-P4 respectively, and 0 mol% for the control linear polymer P1）. Their thermal, optoelectronic and electrochemical properties have been characterized by a combination of techniques. All the polymers exhibit high thermal stability with the decomposition temperatures （Ta） above 400 ℃ and glass transition temperatures （Tg） up to 98℃. Unfortunately, the incorporation of TADF moiety into these HBP materials induced non-TADF characteristics. However, when the HBPs functionalized as the host for our previously developed 4CzCNPy TADF dopant in solution processed devices, maximum external quantum efficiency of 5.7% and current efficiency of 17.9 cd/A have been achieved in P3-based device, which is significantly higher than those of 1.5% and 4.2 cd/A for the linear polymer P1.
