Materials data deep-excavation is very important in materials genome exploration.In order to carry out materials data deep-excavation in hot die steels and obtain the relationships among alloying elements,heat treatme...Materials data deep-excavation is very important in materials genome exploration.In order to carry out materials data deep-excavation in hot die steels and obtain the relationships among alloying elements,heat treatment parameters and materials properties,a 11×12×12×4 back-propagation(BP)artificial neural network(ANN)was set up.Alloying element contents,quenching and tempering temperatures were selected as input;hardness,tensile and yield strength were set as output parameters.The ANN shows a high fitting precision.The effects of alloying elements and heat treatment parameters on the properties of hot die steel were studied using this model.The results indicate that high temperature hardness increases with increasing alloying element content of C,Si,Mo,W,Ni,V and Cr to a maximum value and decreases with further increase in alloying element content.The ANN also predicts that the high temperature hardness will decrease with increasing quenching temperature,and possess an optimal value with increasing tempering temperature.This model provides a new tool for novel hot die steel design.展开更多
The effects of RE modification on structure and the properties of a new cast hot work die (CHD) steel were investigated. The grains of the CHD steel are refined by RE modification. With the increase of RE addition, b...The effects of RE modification on structure and the properties of a new cast hot work die (CHD) steel were investigated. The grains of the CHD steel are refined by RE modification. With the increase of RE addition, both grain size and inclusion amount are reduced. Appropriate amount of RE results in decrease in inclusion amount and formation of spheroidal inclusions uniformly-distributed in steel, so that the morphology and distribution of inclusions are improved. RE composite modification favors the formation of bainite, austenite and fine lath martensite with dense dislocation. When the residual RE content reaches 0.02%, no obvious changes in strength and hardness are found, while fracture toughness and threshold of fatigue crack growth are increased. The impact toughness, elongation and reduction of cross sectional area are increased by a factor of two, and thermal fatigue resistance is also improved.展开更多
Taking the hot working die steel (HWDS) 4Cr3Mo2NbVNi as an example, the phase electron structures (PES) and the biphase interface electron structures (BIES) of Mo2C and V4 C3 , which are two kinds of important c...Taking the hot working die steel (HWDS) 4Cr3Mo2NbVNi as an example, the phase electron structures (PES) and the biphase interface electron structures (BIES) of Mo2C and V4 C3 , which are two kinds of important carbides precipitated during tempering in steel were calculated, on the basis of the empirical electron theory of solids and molecules and the improved TFD theory. The influence of Mo2 C and V4 C3 on the mechanical properties of HWDS has been analyzed at electron structure level, and the fundamental reason that the characteristic of the PES and the BIES of carbides decides the behavior of them has been revealed.展开更多
The effect of main alloying elements on thermal wear of cast hot-forging die steels was studied. The wear mechanism was discussed. The results show that alloying elements have significant influences on the thermal wea...The effect of main alloying elements on thermal wear of cast hot-forging die steels was studied. The wear mechanism was discussed. The results show that alloying elements have significant influences on the thermal wear of cast hot-forging die steels. The wear rates decrease with an increase in chromium content from 3% to 4% and molybdenum content from 2% to 3%, respectively. With further increase of chromium and molybdenum contents, chromium slightly reduces the wear resistance and molybdenum severely deteriorates the wear resistance with high wear rate. Lower vanadium/carbon ratio (1.5-2.5) leads to a lower wear resistance with higher wear rate. With an increase in vanadium/carbon ratio, the wear resistance of the cast steel substantially increases. When vanadium/carbon ratio is 3, the wear rate reaches the lowest value. The predominant mechanism of thermal wear of cast hot-forging die steels are oxidation wear and fatigue delamination. The Fe2O3 and Fe3O4 or lumps of brittle wear debris are formed on the wear surface.展开更多
This paper studies a compound treatment. i. e. liquid S , N,C co-diffusing with rare earth (RE) and then oxidization , for hot-working die steels , and the effect of RE on thermal fatigue behavior of the diffused laye...This paper studies a compound treatment. i. e. liquid S , N,C co-diffusing with rare earth (RE) and then oxidization , for hot-working die steels , and the effect of RE on thermal fatigue behavior of the diffused layer. XRD and SEM energy spectrum prove that trace RE element actually penetrates into the surface layer of steels. The result shows that RE can reduce the gradient of change of hardness in diffused layer, improve the morphology and distribution of compounds , and reduce the degree of surface alligator crack for thermal fatigue. The behavior of thermal fatigue of hot-working die steels is raised by 70% or so after the application of RE. The effect of RE is analysed according to the theory.展开更多
The characteristics and microstructural changes of cyclic softening in hot-working die steels 5CrNiMo and 5Cr2NiMoVSi were studied under strain controlled low-cycle fatigue.The re- sults show that the cyclic softening...The characteristics and microstructural changes of cyclic softening in hot-working die steels 5CrNiMo and 5Cr2NiMoVSi were studied under strain controlled low-cycle fatigue.The re- sults show that the cyclic softening is featured in both steels hardened in different conditions under the strain controlled amplitude range of Δε_t/2=0.6-1.8×10^(-2).The softening effect mainly occurs in some initial cycles and the stress amplitude varies slightly in the sequential cycles,i.e.the softening effect is minified.No obvious stress saturation phenomenon was ob- served during the whole cyclic deformation.The TEM analysis shows that the cyclic softening is related to heterogenity of plastic deformation.The softening of the tested steels is caused by the formation of the dislocation cell structure with low density and low internal stress,and by the fragmentation and redissolution of fine carbides into matrix.展开更多
The tempering stability of three Fe–Cr–Mo–W–V hot forging die steels(DM, H21, and H13) was investigated through hardness measurements and transmission electron microscopy(TEM) observations. Both dilatometer tests ...The tempering stability of three Fe–Cr–Mo–W–V hot forging die steels(DM, H21, and H13) was investigated through hardness measurements and transmission electron microscopy(TEM) observations. Both dilatometer tests and TEM observations revealed that DM steel has a higher tempering stability than H21 and H13 steels because of its substantial amount of M_2C(M represents metallic element) carbide precipitations. The activation energies of the M_2C carbide precipitation processes in DM, H21, and H13 steels are 236.4, 212.0, and 228.9 kJ/mol, respectively. Furthermore, the results indicated that vanadium atoms both increase the activation energy and affect the evolution of M_2C carbides, resulting in gradual dissolution rather than over-aging during tempering.展开更多
Thermal wear of cast hot-forging die steel modified by rare earths(RE) was studied and compared with commercially used die steels. The function of RE and the mechanism of thermal wear of cast steel modified by RE we...Thermal wear of cast hot-forging die steel modified by rare earths(RE) was studied and compared with commercially used die steels. The function of RE and the mechanism of thermal wear of cast steel modified by RE were discussed. The results showed that with increasing content of RE, the wear rate of cast steel reduced at first and then increased. By adding 0.05% (mass fraction) RE, the cast hot-forging die steel with optimum thermal wear resistance was obtained, which was better than that of H13 and 3Cr2WSV. The large amount of coarse inclusions, (RE)2O2S, resulted from excessive RE, which obviously deteriorated thermal wear resistance. The mechanism of thermal wear of the modified cast die steel is oxidation wear and oxide fatigue delamination. The wear debris are lumps of Fe2O3 and Fe3O4.展开更多
ERH end-quenching method was used to determine the hardenability of four kinds hot-forging die steels with deep-hardening and hence the order of their hardenability was given.The tempering hardness of the steels was m...ERH end-quenching method was used to determine the hardenability of four kinds hot-forging die steels with deep-hardening and hence the order of their hardenability was given.The tempering hardness of the steels was measured and the tempering resistance was studied.It was approved that ERH method is effective for the determination of hardenability of deep-hardening steel and the beginning of hardness drop in the ERH specimen is caused by bainite occurring.展开更多
The understanding of oxidation behaviors on H13 steel was helpful to improve the service life and performance of hot work moulds and dies. Thermal-Calc Software was performed to calculate the oxidation phases on H13 s...The understanding of oxidation behaviors on H13 steel was helpful to improve the service life and performance of hot work moulds and dies. Thermal-Calc Software was performed to calculate the oxidation phases on H13 steel along with different partial oxygen pressures in the interesting temperature range of 500-700 ℃. In this range H13 steel samples were treated respectively in different atmosphere including flowing water vapor (0.2 MPa), normal pressure air (0.1 MPa) and low pressure air (0. 001 MPa). The different oxidation films were detected with optical microscopy and X-ray diffraction. The microstructures and phase constitutions of the films formed in low pressure air were similar to those of the films formed in water vapor, and obviously different to those of the films formed in normal pressure air. The oxidation mechanisms of H13 steel in different atmosphere were also discussed.展开更多
基于热锻条件,使用销-盘摩擦设备对6061热锻铝合金和H13钢基自润滑模具材料进行了高温对磨实验,通过电子探针和能谱仪分析了不同工况下工件和模具的磨损机理。结果表明,随着载荷的增加,工件和模具之间的摩擦因数与磨损率先降低后升高;...基于热锻条件,使用销-盘摩擦设备对6061热锻铝合金和H13钢基自润滑模具材料进行了高温对磨实验,通过电子探针和能谱仪分析了不同工况下工件和模具的磨损机理。结果表明,随着载荷的增加,工件和模具之间的摩擦因数与磨损率先降低后升高;随着转速的增加,工件和模具之间的摩擦因数增大,磨损率呈倍数增加;当载荷为12 N、转速为100 r·min^(-1)时,工件和模具之间的摩擦因数最小,其值为0.416,磨损率仅为24.591 mm 3·N^(-1)·m^(-1);随着转速和载荷的增加,工件和模具之间的粘着磨损加重并且逐渐出现磨粒磨损和氧化磨损。展开更多
文摘Materials data deep-excavation is very important in materials genome exploration.In order to carry out materials data deep-excavation in hot die steels and obtain the relationships among alloying elements,heat treatment parameters and materials properties,a 11×12×12×4 back-propagation(BP)artificial neural network(ANN)was set up.Alloying element contents,quenching and tempering temperatures were selected as input;hardness,tensile and yield strength were set as output parameters.The ANN shows a high fitting precision.The effects of alloying elements and heat treatment parameters on the properties of hot die steel were studied using this model.The results indicate that high temperature hardness increases with increasing alloying element content of C,Si,Mo,W,Ni,V and Cr to a maximum value and decreases with further increase in alloying element content.The ANN also predicts that the high temperature hardness will decrease with increasing quenching temperature,and possess an optimal value with increasing tempering temperature.This model provides a new tool for novel hot die steel design.
文摘The effects of RE modification on structure and the properties of a new cast hot work die (CHD) steel were investigated. The grains of the CHD steel are refined by RE modification. With the increase of RE addition, both grain size and inclusion amount are reduced. Appropriate amount of RE results in decrease in inclusion amount and formation of spheroidal inclusions uniformly-distributed in steel, so that the morphology and distribution of inclusions are improved. RE composite modification favors the formation of bainite, austenite and fine lath martensite with dense dislocation. When the residual RE content reaches 0.02%, no obvious changes in strength and hardness are found, while fracture toughness and threshold of fatigue crack growth are increased. The impact toughness, elongation and reduction of cross sectional area are increased by a factor of two, and thermal fatigue resistance is also improved.
基金ItemSponsored by National Natural Science Foundation of China (50271030) Provincial Natural Science Foundation ofLiaoning Province of China (972072)
文摘Taking the hot working die steel (HWDS) 4Cr3Mo2NbVNi as an example, the phase electron structures (PES) and the biphase interface electron structures (BIES) of Mo2C and V4 C3 , which are two kinds of important carbides precipitated during tempering in steel were calculated, on the basis of the empirical electron theory of solids and molecules and the improved TFD theory. The influence of Mo2 C and V4 C3 on the mechanical properties of HWDS has been analyzed at electron structure level, and the fundamental reason that the characteristic of the PES and the BIES of carbides decides the behavior of them has been revealed.
基金Item Sponsored by Early-Term Key Technology of Industrialization and Whole Set Equipment From Plan Committee of China(1999317) ,863 Project of China (2002AA331180) ,and Project of Key Lab of Universities in Jiangsu Province of China(Kjsmcx04004)
文摘The effect of main alloying elements on thermal wear of cast hot-forging die steels was studied. The wear mechanism was discussed. The results show that alloying elements have significant influences on the thermal wear of cast hot-forging die steels. The wear rates decrease with an increase in chromium content from 3% to 4% and molybdenum content from 2% to 3%, respectively. With further increase of chromium and molybdenum contents, chromium slightly reduces the wear resistance and molybdenum severely deteriorates the wear resistance with high wear rate. Lower vanadium/carbon ratio (1.5-2.5) leads to a lower wear resistance with higher wear rate. With an increase in vanadium/carbon ratio, the wear resistance of the cast steel substantially increases. When vanadium/carbon ratio is 3, the wear rate reaches the lowest value. The predominant mechanism of thermal wear of cast hot-forging die steels are oxidation wear and fatigue delamination. The Fe2O3 and Fe3O4 or lumps of brittle wear debris are formed on the wear surface.
文摘This paper studies a compound treatment. i. e. liquid S , N,C co-diffusing with rare earth (RE) and then oxidization , for hot-working die steels , and the effect of RE on thermal fatigue behavior of the diffused layer. XRD and SEM energy spectrum prove that trace RE element actually penetrates into the surface layer of steels. The result shows that RE can reduce the gradient of change of hardness in diffused layer, improve the morphology and distribution of compounds , and reduce the degree of surface alligator crack for thermal fatigue. The behavior of thermal fatigue of hot-working die steels is raised by 70% or so after the application of RE. The effect of RE is analysed according to the theory.
文摘The characteristics and microstructural changes of cyclic softening in hot-working die steels 5CrNiMo and 5Cr2NiMoVSi were studied under strain controlled low-cycle fatigue.The re- sults show that the cyclic softening is featured in both steels hardened in different conditions under the strain controlled amplitude range of Δε_t/2=0.6-1.8×10^(-2).The softening effect mainly occurs in some initial cycles and the stress amplitude varies slightly in the sequential cycles,i.e.the softening effect is minified.No obvious stress saturation phenomenon was ob- served during the whole cyclic deformation.The TEM analysis shows that the cyclic softening is related to heterogenity of plastic deformation.The softening of the tested steels is caused by the formation of the dislocation cell structure with low density and low internal stress,and by the fragmentation and redissolution of fine carbides into matrix.
基金financially supported by the National Key Technologies R & D Program of China (Nos.2016YFB0300400 and 2016YFB0300402)
文摘The tempering stability of three Fe–Cr–Mo–W–V hot forging die steels(DM, H21, and H13) was investigated through hardness measurements and transmission electron microscopy(TEM) observations. Both dilatometer tests and TEM observations revealed that DM steel has a higher tempering stability than H21 and H13 steels because of its substantial amount of M_2C(M represents metallic element) carbide precipitations. The activation energies of the M_2C carbide precipitation processes in DM, H21, and H13 steels are 236.4, 212.0, and 228.9 kJ/mol, respectively. Furthermore, the results indicated that vanadium atoms both increase the activation energy and affect the evolution of M_2C carbides, resulting in gradual dissolution rather than over-aging during tempering.
基金Project supported by the Itemof Early-TermKey Technology of Industrialization ,Plan Committee of China (1999317) 863project of China (2002AA331180)
文摘Thermal wear of cast hot-forging die steel modified by rare earths(RE) was studied and compared with commercially used die steels. The function of RE and the mechanism of thermal wear of cast steel modified by RE were discussed. The results showed that with increasing content of RE, the wear rate of cast steel reduced at first and then increased. By adding 0.05% (mass fraction) RE, the cast hot-forging die steel with optimum thermal wear resistance was obtained, which was better than that of H13 and 3Cr2WSV. The large amount of coarse inclusions, (RE)2O2S, resulted from excessive RE, which obviously deteriorated thermal wear resistance. The mechanism of thermal wear of the modified cast die steel is oxidation wear and oxide fatigue delamination. The wear debris are lumps of Fe2O3 and Fe3O4.
基金Project sponsored by Research Fund for Doctoral Program of Higher Education(9514509)
文摘ERH end-quenching method was used to determine the hardenability of four kinds hot-forging die steels with deep-hardening and hence the order of their hardenability was given.The tempering hardness of the steels was measured and the tempering resistance was studied.It was approved that ERH method is effective for the determination of hardenability of deep-hardening steel and the beginning of hardness drop in the ERH specimen is caused by bainite occurring.
基金ItemSponsored by Science and Technology Development Fund of Shanghai Municipality (015211010)ASSABTooling Technology (Shanghai) Co Ltd
文摘The understanding of oxidation behaviors on H13 steel was helpful to improve the service life and performance of hot work moulds and dies. Thermal-Calc Software was performed to calculate the oxidation phases on H13 steel along with different partial oxygen pressures in the interesting temperature range of 500-700 ℃. In this range H13 steel samples were treated respectively in different atmosphere including flowing water vapor (0.2 MPa), normal pressure air (0.1 MPa) and low pressure air (0. 001 MPa). The different oxidation films were detected with optical microscopy and X-ray diffraction. The microstructures and phase constitutions of the films formed in low pressure air were similar to those of the films formed in water vapor, and obviously different to those of the films formed in normal pressure air. The oxidation mechanisms of H13 steel in different atmosphere were also discussed.
文摘基于热锻条件,使用销-盘摩擦设备对6061热锻铝合金和H13钢基自润滑模具材料进行了高温对磨实验,通过电子探针和能谱仪分析了不同工况下工件和模具的磨损机理。结果表明,随着载荷的增加,工件和模具之间的摩擦因数与磨损率先降低后升高;随着转速的增加,工件和模具之间的摩擦因数增大,磨损率呈倍数增加;当载荷为12 N、转速为100 r·min^(-1)时,工件和模具之间的摩擦因数最小,其值为0.416,磨损率仅为24.591 mm 3·N^(-1)·m^(-1);随着转速和载荷的增加,工件和模具之间的粘着磨损加重并且逐渐出现磨粒磨损和氧化磨损。