The one-ladle technology requires an efficient ironmaking and steelmaking interface. The scheduling of the hot metal ladle in the steel plant determines the overall operational efficiency of the interface. Considering...The one-ladle technology requires an efficient ironmaking and steelmaking interface. The scheduling of the hot metal ladle in the steel plant determines the overall operational efficiency of the interface. Considering the strong uncertainties of real-world production environments, this work studies the dynamic scheduling problem of hot metal ladles and develops a data-driven three-layer approach to solve this problem. A dynamic scheduling optimization model of the hot metal ladle operation with a minimum average turnover time as the optimization objective is also constructed. Furthermore, the intelligent perception of industrial scenes and autonomous identification of disturbances, adaptive configuration of dynamic scheduling strategies, and real-time adjustment of schedules can be realized. The upper layer generates a demand-oriented prescheduling scheme for hot metal ladles. The middle layer adaptively adjusts this scheme to obtain an executable schedule according to the actual supply–demand relationship. In the lower layer, three types of dynamic scheduling strategies are designed according to the characteristics of the dynamic disturbance in the model:real-time flexible fine-tuning, local machine adjustment, and global rescheduling. Case test using 24 h production data on a certain day during the system operation of a steel plant shows that the method and system can effectively reduce the fluctuation and operation time of the hot metal ladle and improve the stability of the ironmaking and steelmaking interface production rhythm. The data-driven dynamic scheduling strategy is feasible and effective, and the proposed method can improve the operation efficiency of hot metal ladles.展开更多
<span style="font-family:Verdana;">A straightforward kinetic model for the hot metal desulphurization process is presented. The model contains some of the most important parameters and variables that g...<span style="font-family:Verdana;">A straightforward kinetic model for the hot metal desulphurization process is presented. The model contains some of the most important parameters and variables that govern the process. The inputs, outputs and parameters of a desulphurization program employed at industry are discussed. The model is able to cope with different injection policies of desulphurizers such as mono-</span><span style="font-family:""> </span><span style="font-family:Verdana;">injection, co-injection or multi-injection. When compared to the rotary impeller method, results of this model shows that the weight of lime consumed in the lance injection method is lesser than that consumed in the rotary impeller method for the same conditions of the hot metal charge.</span>展开更多
The time series data of silicon content in hot metal were identified to have the chaotic feature because of the positive maximum Lyapunov exponent, and then the time scales to predict future were estimated. Finally a ...The time series data of silicon content in hot metal were identified to have the chaotic feature because of the positive maximum Lyapunov exponent, and then the time scales to predict future were estimated. Finally a chaotic local-region model was constructed to predict silicon content in hot metal with good performance due to high hitting rate.展开更多
Some key operation variables influencing hot metal silicon content were selected, and time lag of each of them was obtained. A standardized fuzzy system model was developed to approach the random nonlinear dynamic sys...Some key operation variables influencing hot metal silicon content were selected, and time lag of each of them was obtained. A standardized fuzzy system model was developed to approach the random nonlinear dynamic system of the change of silicon content, forecast the change of silicon content and calculate silicon content. The prediction of hot metal silicon content is very successful with the data collected online from BF No.1 at Laiwu Iron and Steel Group Co.展开更多
To resolve the difficulty in slag formation during steelmaking with low silicon hot metal and to increase productivity, a new 5-hole lance was developed by increasing oxygen flow from 50 000 m3/h to 60 000 m3/h. Synth...To resolve the difficulty in slag formation during steelmaking with low silicon hot metal and to increase productivity, a new 5-hole lance was developed by increasing oxygen flow from 50 000 m3/h to 60 000 m3/h. Synthetic slag was added to adjust the slag composition. The problems such as difficulty in dephosphorization and slag adhesion to oxygen lance and hood were settled. Steel production and metal yield were increased and the nozzle life was prolonged through these techniques.展开更多
The vacuum treatment for simultaneous desulphurization and dephosphorization of hot metal and molten steel with pre-melted CaO-based slag was carried out. For pre-treatment of hot metal, both desulphurization and deph...The vacuum treatment for simultaneous desulphurization and dephosphorization of hot metal and molten steel with pre-melted CaO-based slag was carried out. For pre-treatment of hot metal, both desulphurization and dephosphorization are improved with the increase of CaO in slag, but deteriorated with the increase of CaF2 in slag. The average desulphurization and dephosphorization rate is 68.83 % and 78.46 %, respectively. For molten steel, the substitution of BaO for CaO in slag has minor effect on simultaneous desulphurization and dephosphorization. The desulphurization and dephosphorization rate is higher than 90 % and 50 % respectively with the lowest final sulfur and phosphorus mass percent being 0.001 2 % and 0.010 %, respectively. The overall effect of simultaneous desulphurization and dephosphorization of molten steel is better than that of hot metal.展开更多
The spheroidiser is a necessary additive to manufacture ductile iron. Sometimes with the same hot metal, spheroidisers and treated technology, reactions differ greatly from each other. The reaction may be quite normal...The spheroidiser is a necessary additive to manufacture ductile iron. Sometimes with the same hot metal, spheroidisers and treated technology, reactions differ greatly from each other. The reaction may be quite normal in one case, but very intensive for another one. The effects of kinetic factors such as size, surface area and morphology of spheroidiser on the reaction of spheoidization are studied.展开更多
There are some problems in steelmaking with hot metal containing low silicon content such as difficulty in slag formation, less slag for dephosphorization and slag adhesion on oxygen lance and hood. To overcome these ...There are some problems in steelmaking with hot metal containing low silicon content such as difficulty in slag formation, less slag for dephosphorization and slag adhesion on oxygen lance and hood. To overcome these problems, experiments were conducted and some improvements were obtained, such as adding appropriate flux, increasing the lance position slightly during steelmaking and using effective multi-outlet nozzle. Moreover, to keep normal heating rate, the ore and scrap charge should be reduced due to less chemical heat input in steelmaking.展开更多
The paper describes the recent developing situation and the latest research achievements of refractory for hot metal pretreatment. The relationship among desiliconization, dephosphorization and desulphurization techni...The paper describes the recent developing situation and the latest research achievements of refractory for hot metal pretreatment. The relationship among desiliconization, dephosphorization and desulphurization techniques and the main corrosion reactions by various treating agents is analyzed. Some improving measures for several problems in practice are put forward while we anticipate the future developing direction of refractory for hot metal pretreatment.展开更多
Hot metal transfer ladles were historically lined with high alumina refractories because of compatibility of high alumina refractories with the highly acidic slag,which is transferred from the iron making plant along ...Hot metal transfer ladles were historically lined with high alumina refractories because of compatibility of high alumina refractories with the highly acidic slag,which is transferred from the iron making plant along with hot metal.With the introduction of higher capacity ladles,technological advancement in the process and increased productivity,calls for a higher campaign life of hot metal ladles,which could not be performed by ordinary high alumina refractories.Resin bonded Al2O3-SiC-C(hereinafter ASC)bricks gradually developed which at present taking place replacing the conventional refractories.Considerable work has been carried out in developing the ASC refractory to reach the present state.However,for higher capacity ladles still there is a lot of scope for improvement.The present paper deals with the newly developed ASC bricks,which was used in 165 ton capacity hot metal ladles in one European plant and has given a substantial increase in performance.But,the customer was not fully satisfied since the brick was reported to produce smokes during preheating of the ladle.In the subsequent supply the smoke generation problem was taken care by adjusting the binders and additives and eco-friendly bricks were re-engineered and supplied to the same plant,which also performed splendidly and created all time record in their plant history.展开更多
In recent years,many Ni-containing materials manufactured from laterite have played a significant role in supporting the rapid development of the stainless steel industry in China. Currently,pyrometallurgy is the main...In recent years,many Ni-containing materials manufactured from laterite have played a significant role in supporting the rapid development of the stainless steel industry in China. Currently,pyrometallurgy is the main process for laterite smelting,where blast furnaces are employed to make Ni-containing hot metal. With the aim of giving some references for making good use of laterite,technical and economic analysis was conducted in this paper,based on the discussion of the key technologies of Ni-containing hot metal production with laterite ( 50. 4% Fe) in blast furnaces.展开更多
The desulfurization of hot metal by the mono-injection of lime powder and the co-injection of lime, calcium carbide and magnesium powders is mathematically modeled. The mono-injection model is derived from the continu...The desulfurization of hot metal by the mono-injection of lime powder and the co-injection of lime, calcium carbide and magnesium powders is mathematically modeled. The mono-injection model is derived from the continuity equation and is validated using experimental results and data previously reported in the literature. The co-injection model and the rate constant of the injected mixture are determined from the molar fractions and rate constants of the individual powders. The effect of the lime content of the mixture on the desulfurization dynamics is studied and discussed.展开更多
To maintain the safety of an open-type hot-metal car and to reduce wheel-rail wear during transportation, simulation models of the main components of such car were built using Pro/E software and then tested. In partic...To maintain the safety of an open-type hot-metal car and to reduce wheel-rail wear during transportation, simulation models of the main components of such car were built using Pro/E software and then tested. In particular, the Pro/E models were imported into ADAMS/Rail for assembly and then used to construct a complete hot-metal car dynamic model. Locomotive wheel-rail attack angle, wheel-rail lateral force, and wear index were used as evaluation parameters during the simulation to analyze the effects of bogie parameter, rail parameter, and speed of the hot-metal car on wheel-rail wear. An improvement scheme for reducing wheel-rail wear was proposed based on the result of the dynamic simulation, wherein wheel-rail wear and curving performance were analyzed and compared. The simulation provided an important reference for evaluating and improving the dynamic performance of the hot-metal car. The applied effect showed that the improvement scheme is effective.展开更多
The system of hot metal quality monitoring was established based on big data and machine learning using the real-time production data of a steel enterprise in China.A working method that combines big data technology w...The system of hot metal quality monitoring was established based on big data and machine learning using the real-time production data of a steel enterprise in China.A working method that combines big data technology with process theory was proposed for the characteristics of blast furnace production data.After the data have been comprehensively processed,the independent variables that affect the target parameters are selected by using the method of multivariate feature selection.The use of this method not only ensures the interpretability of the input variables,but also improves the accuracy of the machine learning process and is more easily accepted by enterprises.For timely guidance on production,specific evaluation rules are established for the key quality that affects the quality of hot metal on the basis of completed predictions work and uses computer technology to build a quality monitoring system for hot metal.The online results show that the hot metal quality monitoring system established by relying on big data and machine learning operates stably on site,and has good guiding significance for production.展开更多
The reaction of CO_2 gas with hot metal was investigated based on the thermodynamic analysis and experimental results.It shows that both silicon and carbon in hot metal can be oxidized by CO_2 gas in the temperature r...The reaction of CO_2 gas with hot metal was investigated based on the thermodynamic analysis and experimental results.It shows that both silicon and carbon in hot metal can be oxidized by CO_2 gas in the temperature range of 1 300-1 500 ℃.When using graphite crucible,temperature has little influence on final mass percent of carbon w[C]because of the carburization effect.Decarburization degree rises significantly with increasing gas injection rate and w[C]can be reduced to 3.2% at most when using MgO crucible.Lower temperature or higher gas injection rate is propitious to promote desilication reaction,but only 5%-10% of desilication ratio could be obtained in 20 min.The final mass percent of silicon w[Si]when using MgO crucible is lower than that when using graphite crucible.Experimental results also demonstrate that CO_2 injection has no effect on the concentration of manganese,sulfur and phosphorus in hot metal.In view of the weak oxidation ability and temperature drop of hot metal,CO_2 gas is suggested to be used as carrier gas in desilication process rather than oxidizing agent.展开更多
A kinetic model on hot metal desulfurization with mechanical stirring was established using FactSage Macro Processing.The sulfur diffusion in the molten steel and reactions at the interface between the molten steel an...A kinetic model on hot metal desulfurization with mechanical stirring was established using FactSage Macro Processing.The sulfur diffusion in the molten steel and reactions at the interface between the molten steel and the desulfurizer particle were considered.Calculated results agreed well with experimental results,indicating that the model can be used to predict the desulfurization rate and cost with various temperatures,chemical compositions,rotation speeds,and desulfurizer additions.The higher impeller rotation speed from 80 to 120 r/min,higher temperature from 1573 to 1673 K,smaller particle size from 2.5 to 1.5μm,and more desulfurizer addition from 0.35 to 0.64 kg/t were suggested to improve the desulfurization rate.Moreover,to synthetically increase the desulfurization efficiency and lower the cost,contours of S content and cost during the desulfurization process with various desulfurizer additions and time were calculated.Based on industrial cost data analysis of the added desulfurizer,the refractory erosion,and electric power consumption,the total cost of the hot metal desulfurization with time step(Δt)was fitted as Cost_(total)=0.066+1.58×10^(−7)·Δt.The less desulfurizer addition and longer desulfurization time contributed to lowering the cost,while more desulfurizer addition was conducive to improving the desulfurization efficiency.展开更多
To solve the technical problems of hot metal desulfurization by injecting magnesium particulate, a new method of hot metal desulfurization by bottom-blowing magnesium vapor combined with mechanical agitation was put f...To solve the technical problems of hot metal desulfurization by injecting magnesium particulate, a new method of hot metal desulfurization by bottom-blowing magnesium vapor combined with mechanical agitation was put forward. The effects of three different desulfurization processes on the desulfurization efficiency were studied in view of thermodynamics and kinetics. It was found that the utilization efficiency of magnesium can reach 82.6% and desulfurization efficiency can reach 86.2% during the first 4 min using the method of magnesium vapor injection combined with mechanical agitation. The gasification of magnesium powder leads to significant splashing and magnesium losses in the process of magnesium powder injection, resulting in a low utilization efficiency of magnesium of 51.8% and a low desulfurization efficiency of 55.76%. Activation energy for a first-order kinetic relationship between magnesium powder and sulfur was measured from the experiments, which was 142.82 kJ/mol in the temperature range of 1573-1723 K. The activation energy of the reaction between magnesium vapor and sulfur was around 54.8-65.0 kJ/mol in the temperature range of 1573-1723 K, which indicates that the desulfurization with magnesium vapor proceeds relatively easier than the desulfurization with magnesium powder.展开更多
To solve the technical problems of hot metal desulfurization by injecting magnesium particulate,a new idea of hot metal desulfurization by bottom-blowing magnesium vapor was put forward.The reaction mechanism of hot m...To solve the technical problems of hot metal desulfurization by injecting magnesium particulate,a new idea of hot metal desulfurization by bottom-blowing magnesium vapor was put forward.The reaction mechanism of hot metal desulfurization with magnesium vapor injection was analyzed,and the kinetic model of the desulfurization rate during the process of hot metal desulfurization with magnesium vapor injection was established.The dimensionless equation of the gas–liquid mass transfer coefficient under the injection conditions was obtained by the dimensional analysis method.And the theoretical calculation results were in good agreement with the experimental measurements.The results show that the diameter of the bubbles and the viscosity of the melt significantly affect the desulfurization rate of hot metal injected with magnesium vapor.When the temperature is 1573 K and the gas flow rate is 3 L/min,the desulfurization rate can reach 79%and the utilization rate of magnesium can reach 83%.展开更多
In blast furnace(BF)iron-making process,the hot metal silicon content was usually used to measure the quality of hot metal and to reflect the thermal state of BF.Principal component analysis(PCA)and partial least-squa...In blast furnace(BF)iron-making process,the hot metal silicon content was usually used to measure the quality of hot metal and to reflect the thermal state of BF.Principal component analysis(PCA)and partial least-square(PLS)regression methods were used to predict the hot metal silicon content.Under the conditions of BF relatively stable situation,PCA and PLS regression models of hot metal silicon content utilizing data from Baotou Steel No.6 BF were established,which provided the accuracy of 88.4% and 89.2%.PLS model used less variables and time than principal component analysis model,and it was simple to calculate.It is shown that the model gives good results and is helpful for practical production.展开更多
基金financially supported by the National Natural Science Foundation of China (No.51734004)the Key Program of the National Key R&D Program of China(No.2017YFB0304002)。
文摘The one-ladle technology requires an efficient ironmaking and steelmaking interface. The scheduling of the hot metal ladle in the steel plant determines the overall operational efficiency of the interface. Considering the strong uncertainties of real-world production environments, this work studies the dynamic scheduling problem of hot metal ladles and develops a data-driven three-layer approach to solve this problem. A dynamic scheduling optimization model of the hot metal ladle operation with a minimum average turnover time as the optimization objective is also constructed. Furthermore, the intelligent perception of industrial scenes and autonomous identification of disturbances, adaptive configuration of dynamic scheduling strategies, and real-time adjustment of schedules can be realized. The upper layer generates a demand-oriented prescheduling scheme for hot metal ladles. The middle layer adaptively adjusts this scheme to obtain an executable schedule according to the actual supply–demand relationship. In the lower layer, three types of dynamic scheduling strategies are designed according to the characteristics of the dynamic disturbance in the model:real-time flexible fine-tuning, local machine adjustment, and global rescheduling. Case test using 24 h production data on a certain day during the system operation of a steel plant shows that the method and system can effectively reduce the fluctuation and operation time of the hot metal ladle and improve the stability of the ironmaking and steelmaking interface production rhythm. The data-driven dynamic scheduling strategy is feasible and effective, and the proposed method can improve the operation efficiency of hot metal ladles.
文摘<span style="font-family:Verdana;">A straightforward kinetic model for the hot metal desulphurization process is presented. The model contains some of the most important parameters and variables that govern the process. The inputs, outputs and parameters of a desulphurization program employed at industry are discussed. The model is able to cope with different injection policies of desulphurizers such as mono-</span><span style="font-family:""> </span><span style="font-family:Verdana;">injection, co-injection or multi-injection. When compared to the rotary impeller method, results of this model shows that the weight of lime consumed in the lance injection method is lesser than that consumed in the rotary impeller method for the same conditions of the hot metal charge.</span>
文摘The time series data of silicon content in hot metal were identified to have the chaotic feature because of the positive maximum Lyapunov exponent, and then the time scales to predict future were estimated. Finally a chaotic local-region model was constructed to predict silicon content in hot metal with good performance due to high hitting rate.
文摘Some key operation variables influencing hot metal silicon content were selected, and time lag of each of them was obtained. A standardized fuzzy system model was developed to approach the random nonlinear dynamic system of the change of silicon content, forecast the change of silicon content and calculate silicon content. The prediction of hot metal silicon content is very successful with the data collected online from BF No.1 at Laiwu Iron and Steel Group Co.
文摘To resolve the difficulty in slag formation during steelmaking with low silicon hot metal and to increase productivity, a new 5-hole lance was developed by increasing oxygen flow from 50 000 m3/h to 60 000 m3/h. Synthetic slag was added to adjust the slag composition. The problems such as difficulty in dephosphorization and slag adhesion to oxygen lance and hood were settled. Steel production and metal yield were increased and the nozzle life was prolonged through these techniques.
基金Sponsored by Provincial Natural Science Foundation of Anhui of China
文摘The vacuum treatment for simultaneous desulphurization and dephosphorization of hot metal and molten steel with pre-melted CaO-based slag was carried out. For pre-treatment of hot metal, both desulphurization and dephosphorization are improved with the increase of CaO in slag, but deteriorated with the increase of CaF2 in slag. The average desulphurization and dephosphorization rate is 68.83 % and 78.46 %, respectively. For molten steel, the substitution of BaO for CaO in slag has minor effect on simultaneous desulphurization and dephosphorization. The desulphurization and dephosphorization rate is higher than 90 % and 50 % respectively with the lowest final sulfur and phosphorus mass percent being 0.001 2 % and 0.010 %, respectively. The overall effect of simultaneous desulphurization and dephosphorization of molten steel is better than that of hot metal.
文摘The spheroidiser is a necessary additive to manufacture ductile iron. Sometimes with the same hot metal, spheroidisers and treated technology, reactions differ greatly from each other. The reaction may be quite normal in one case, but very intensive for another one. The effects of kinetic factors such as size, surface area and morphology of spheroidiser on the reaction of spheoidization are studied.
文摘There are some problems in steelmaking with hot metal containing low silicon content such as difficulty in slag formation, less slag for dephosphorization and slag adhesion on oxygen lance and hood. To overcome these problems, experiments were conducted and some improvements were obtained, such as adding appropriate flux, increasing the lance position slightly during steelmaking and using effective multi-outlet nozzle. Moreover, to keep normal heating rate, the ore and scrap charge should be reduced due to less chemical heat input in steelmaking.
文摘The paper describes the recent developing situation and the latest research achievements of refractory for hot metal pretreatment. The relationship among desiliconization, dephosphorization and desulphurization techniques and the main corrosion reactions by various treating agents is analyzed. Some improving measures for several problems in practice are put forward while we anticipate the future developing direction of refractory for hot metal pretreatment.
文摘Hot metal transfer ladles were historically lined with high alumina refractories because of compatibility of high alumina refractories with the highly acidic slag,which is transferred from the iron making plant along with hot metal.With the introduction of higher capacity ladles,technological advancement in the process and increased productivity,calls for a higher campaign life of hot metal ladles,which could not be performed by ordinary high alumina refractories.Resin bonded Al2O3-SiC-C(hereinafter ASC)bricks gradually developed which at present taking place replacing the conventional refractories.Considerable work has been carried out in developing the ASC refractory to reach the present state.However,for higher capacity ladles still there is a lot of scope for improvement.The present paper deals with the newly developed ASC bricks,which was used in 165 ton capacity hot metal ladles in one European plant and has given a substantial increase in performance.But,the customer was not fully satisfied since the brick was reported to produce smokes during preheating of the ladle.In the subsequent supply the smoke generation problem was taken care by adjusting the binders and additives and eco-friendly bricks were re-engineered and supplied to the same plant,which also performed splendidly and created all time record in their plant history.
文摘In recent years,many Ni-containing materials manufactured from laterite have played a significant role in supporting the rapid development of the stainless steel industry in China. Currently,pyrometallurgy is the main process for laterite smelting,where blast furnaces are employed to make Ni-containing hot metal. With the aim of giving some references for making good use of laterite,technical and economic analysis was conducted in this paper,based on the discussion of the key technologies of Ni-containing hot metal production with laterite ( 50. 4% Fe) in blast furnaces.
文摘The desulfurization of hot metal by the mono-injection of lime powder and the co-injection of lime, calcium carbide and magnesium powders is mathematically modeled. The mono-injection model is derived from the continuity equation and is validated using experimental results and data previously reported in the literature. The co-injection model and the rate constant of the injected mixture are determined from the molar fractions and rate constants of the individual powders. The effect of the lime content of the mixture on the desulfurization dynamics is studied and discussed.
文摘To maintain the safety of an open-type hot-metal car and to reduce wheel-rail wear during transportation, simulation models of the main components of such car were built using Pro/E software and then tested. In particular, the Pro/E models were imported into ADAMS/Rail for assembly and then used to construct a complete hot-metal car dynamic model. Locomotive wheel-rail attack angle, wheel-rail lateral force, and wear index were used as evaluation parameters during the simulation to analyze the effects of bogie parameter, rail parameter, and speed of the hot-metal car on wheel-rail wear. An improvement scheme for reducing wheel-rail wear was proposed based on the result of the dynamic simulation, wherein wheel-rail wear and curving performance were analyzed and compared. The simulation provided an important reference for evaluating and improving the dynamic performance of the hot-metal car. The applied effect showed that the improvement scheme is effective.
基金the financial supports from the Basic Research Program of National Natural Science Foundation of China(52004096)the Natural Science Foundation of Hebei Province(E2020209208).
文摘The system of hot metal quality monitoring was established based on big data and machine learning using the real-time production data of a steel enterprise in China.A working method that combines big data technology with process theory was proposed for the characteristics of blast furnace production data.After the data have been comprehensively processed,the independent variables that affect the target parameters are selected by using the method of multivariate feature selection.The use of this method not only ensures the interpretability of the input variables,but also improves the accuracy of the machine learning process and is more easily accepted by enterprises.For timely guidance on production,specific evaluation rules are established for the key quality that affects the quality of hot metal on the basis of completed predictions work and uses computer technology to build a quality monitoring system for hot metal.The online results show that the hot metal quality monitoring system established by relying on big data and machine learning operates stably on site,and has good guiding significance for production.
基金Item Sponsored by National Natural Science Foundation of China and Baosteel Group Corporation of China(51074206)Fundamental Research Funds for Central Universities of China(N120402011)
文摘The reaction of CO_2 gas with hot metal was investigated based on the thermodynamic analysis and experimental results.It shows that both silicon and carbon in hot metal can be oxidized by CO_2 gas in the temperature range of 1 300-1 500 ℃.When using graphite crucible,temperature has little influence on final mass percent of carbon w[C]because of the carburization effect.Decarburization degree rises significantly with increasing gas injection rate and w[C]can be reduced to 3.2% at most when using MgO crucible.Lower temperature or higher gas injection rate is propitious to promote desilication reaction,but only 5%-10% of desilication ratio could be obtained in 20 min.The final mass percent of silicon w[Si]when using MgO crucible is lower than that when using graphite crucible.Experimental results also demonstrate that CO_2 injection has no effect on the concentration of manganese,sulfur and phosphorus in hot metal.In view of the weak oxidation ability and temperature drop of hot metal,CO_2 gas is suggested to be used as carrier gas in desilication process rather than oxidizing agent.
基金support from the National Science Foundation China(Grant Nos.U1860206,51725402)the S&T Program of Hebei(Grant No.20311005D,20591001D)the High Steel Center(HSC)at Yanshan University,and Beijing International Center of Advanced and Intelligent Manufacturing of High Quality Steel Materials(ICSM)and the High Quality Steel Consortium(HQSC)at University of Science and Technology Beijing(USTB),China.
文摘A kinetic model on hot metal desulfurization with mechanical stirring was established using FactSage Macro Processing.The sulfur diffusion in the molten steel and reactions at the interface between the molten steel and the desulfurizer particle were considered.Calculated results agreed well with experimental results,indicating that the model can be used to predict the desulfurization rate and cost with various temperatures,chemical compositions,rotation speeds,and desulfurizer additions.The higher impeller rotation speed from 80 to 120 r/min,higher temperature from 1573 to 1673 K,smaller particle size from 2.5 to 1.5μm,and more desulfurizer addition from 0.35 to 0.64 kg/t were suggested to improve the desulfurization rate.Moreover,to synthetically increase the desulfurization efficiency and lower the cost,contours of S content and cost during the desulfurization process with various desulfurizer additions and time were calculated.Based on industrial cost data analysis of the added desulfurizer,the refractory erosion,and electric power consumption,the total cost of the hot metal desulfurization with time step(Δt)was fitted as Cost_(total)=0.066+1.58×10^(−7)·Δt.The less desulfurizer addition and longer desulfurization time contributed to lowering the cost,while more desulfurizer addition was conducive to improving the desulfurization efficiency.
基金the National Natural Science Foundation of China(U1508217,U1702253 and 51774078)the Fundamental Research Funds for the Central Universities(N172506009 and N170908001).
文摘To solve the technical problems of hot metal desulfurization by injecting magnesium particulate, a new method of hot metal desulfurization by bottom-blowing magnesium vapor combined with mechanical agitation was put forward. The effects of three different desulfurization processes on the desulfurization efficiency were studied in view of thermodynamics and kinetics. It was found that the utilization efficiency of magnesium can reach 82.6% and desulfurization efficiency can reach 86.2% during the first 4 min using the method of magnesium vapor injection combined with mechanical agitation. The gasification of magnesium powder leads to significant splashing and magnesium losses in the process of magnesium powder injection, resulting in a low utilization efficiency of magnesium of 51.8% and a low desulfurization efficiency of 55.76%. Activation energy for a first-order kinetic relationship between magnesium powder and sulfur was measured from the experiments, which was 142.82 kJ/mol in the temperature range of 1573-1723 K. The activation energy of the reaction between magnesium vapor and sulfur was around 54.8-65.0 kJ/mol in the temperature range of 1573-1723 K, which indicates that the desulfurization with magnesium vapor proceeds relatively easier than the desulfurization with magnesium powder.
基金This research was supported by the National Natural Science Foundation of China(U1702253,51774078)the Fundamental Research Funds for the Central Universities(N172506009.N170908001).
文摘To solve the technical problems of hot metal desulfurization by injecting magnesium particulate,a new idea of hot metal desulfurization by bottom-blowing magnesium vapor was put forward.The reaction mechanism of hot metal desulfurization with magnesium vapor injection was analyzed,and the kinetic model of the desulfurization rate during the process of hot metal desulfurization with magnesium vapor injection was established.The dimensionless equation of the gas–liquid mass transfer coefficient under the injection conditions was obtained by the dimensional analysis method.And the theoretical calculation results were in good agreement with the experimental measurements.The results show that the diameter of the bubbles and the viscosity of the melt significantly affect the desulfurization rate of hot metal injected with magnesium vapor.When the temperature is 1573 K and the gas flow rate is 3 L/min,the desulfurization rate can reach 79%and the utilization rate of magnesium can reach 83%.
基金Item Sponsored by National Natural Science Foundation of China(51064019)Natural Science Foundation of Inner Mongolia of China(20010MS0911,NJzy08075)
文摘In blast furnace(BF)iron-making process,the hot metal silicon content was usually used to measure the quality of hot metal and to reflect the thermal state of BF.Principal component analysis(PCA)and partial least-square(PLS)regression methods were used to predict the hot metal silicon content.Under the conditions of BF relatively stable situation,PCA and PLS regression models of hot metal silicon content utilizing data from Baotou Steel No.6 BF were established,which provided the accuracy of 88.4% and 89.2%.PLS model used less variables and time than principal component analysis model,and it was simple to calculate.It is shown that the model gives good results and is helpful for practical production.